Exercise 4 ASC0304: (1.025 X 10 M, 2.92 X 10 S)
Exercise 4 ASC0304: (1.025 X 10 M, 2.92 X 10 S)
ASC0304
1 Calculate the wavelength and frequency of the second line in Lyman series.
[1.025 X 10-7 m, 2.92 X 1013 s-1]
2 Determine the transition of electron which emitted photon with wavelength 434 nm in
Balmer series.
[ni = 5 to nf=2]
3 Calculate the wavelength and energy of the first line in Balmer series
[6.562 X 10-7 m, 3.029 X 10-19 J]
4 Calculate the ionization energy of hydrogen atom in kJ mol-1 if ni = 1
[1312.36 kJ mol-1]
5 The difference energy between the second and fourth energy levels of a hydrogen
atom is 4.09 X 10-19 J. Calculate the wavelength and frequency of the photon emitted
when an electron makes transition from the fourth to the second energy level.
[486.3 nm, 6.17 X 1014 Hz]
6 Calculate the energy emitted and wavelength (nm) produced when an electron in
hydrogen atom is transferred from n=6 to n=2.
[4.844 X 10-19J, 410.3 nm]
7 Give all possible values of n, l, ml and ms for an electron in
(a 2p
)
(b 3d
)
8 The set of quantum numbers for two valence electrons of atom A are shown as below:
n=3, l= 0, ml=0, ms= +½
n=3, l= 0, ml=0, ms = -½
(a) Write the electronic configuration for atom A.
(b) Write the electronic configuration for ion A if two electrons were removed from
atom A..
11 Write the electronic configuration (orbital box diagram, spdf notation and noble gas
core notation) for the following atom/ions
(a Na (b) Na+ (c) Cl (d Cl-
) )
(e Al (f) Al3+ (g) Cr (h Cu
) )