SAFETY DATA SHEET

ARDROX 907PB Aerosol

Version: 1.2 Revision Date 13.01.2017 Print Date 13.01.2017

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

1.1 Product identifier

Trade name : ARDROX 907PB Aerosol

1.2 Relevant identified uses of the substance or mixture and uses advised against

1.3 Details of the supplier of the safety data sheet

Company : CHEMETALL AUSTRALASIA PTY LTD
17 TURBO DRIVE
3153 BAYSWATER VIC
Contact person : Customer Service
Telephone : +61 3 9729 6253 BUSINESS HOURS
Telefax : +61 3 9720 1711

Contact person product safety Technical Manager

Telephone : +61 3 9729 6253
E-mail address : customer.service.au@basf.com

1.4 Emergency telephone number

Emergency telephone number : +61 3 9720 0370 AFTER HOURS

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification
Flammable aerosols : Category 1

Serious eye damage/eye irri- : Category 1

tation

GHS label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : H222 Extremely flammable aerosol.

H229 Pressurised container: May burst if heated.
H318 Causes serious eye damage.
AUH066 Repeated exposure may cause skin dryness or crack-
ing

Precautionary statements : Prevention:

P210 Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.

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ARDROX 907PB Aerosol

Version: 1.2 Revision Date 13.01.2017 Print Date 13.01.2017

P262 Do not get in eyes, on skin, or on clothing.

P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ protective clothing/ eye protec-
tion/ face protection.
Response:
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/ physi-
cian.
Storage:
P410 + P412 Protect from sunlight. Do not expose to tempera-
tures exceeding 50 °C/ 122 °F.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.

Other hazards which do not result in classification

The information required is contained in this Safety Data Sheet.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Hazardous components
Chemical name CAS-No. Concentration (% w/w)
Distillates (Petroleum), hydrotreated light Kero- 64742-47-8 >= 30 - < 60
sine-unspecified
Alcohol ethoxylate 68439-45-2 < 10
2-(3-Methoxypropoxy)propan-1-ol 34590-94-8 < 10
Ethoxylated Secondary Alcohols (C11 - 15) 68131-40-8 < 10
Carbon dioxide 124-38-9 < 10
Distillates (petroleum), hydrotreated light naph- 64742-53-6 < 10
thenic
2-Naphthalenol, 1-[[4-(phenylazo)phenyl]azo]-, 92257-31-3 < 10
ar-heptyl ar',ar''-Me derivs.

SECTION 4. FIRST AID MEASURES

General advice : First Aid responders should pay attention to self-protection

and use the recommended protective clothing
Move out of dangerous area.
Take off contaminated clothing and shoes immediately.

Inhalation : Move to fresh air.

If symptoms persist, call a physician.

Skin contact : Wash off with soap and plenty of water.

If symptoms persist, call a physician.

Eye contact : Rinse immediately with plenty of water, also under the eyelids.
Consult a physician.

Ingestion : Rinse mouth with water.

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ARDROX 907PB Aerosol

Version: 1.2 Revision Date 13.01.2017 Print Date 13.01.2017

Do NOT induce vomiting.

Consult a physician.

Most important symptoms : No information available.

and effects, both acute and
delayed

Notes to physician : Treat symptomatically.

For specialist advice physicians should contact the Poisons
Information Service.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Carbon dioxide (CO2)

Dry powder
Alcohol-resistant foam
Water spray

Unsuitable extinguishing : High volume water jet

media

Specific hazards during fire- : Heating or fire can release toxic gas.
fighting Carbon monoxide
Carbon dioxide (CO2)

Specific extinguishing meth- : Use water spray to cool unopened containers.

ods Risk of bursting.

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Wear personal protective equipment.

tive equipment and emer- For further information see Section 8 of the safety data sheet.
gency procedures For disposal considerations see section 13.

Environmental precautions : Do not flush into surface water or sanitary sewer system.
Avoid subsoil penetration.

Methods and materials for : Ensure adequate ventilation.

containment and cleaning up Contain spillage, soak up with non-combustible absorbent
material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and transfer to a container for disposal according to local /
national regulations (see section 13).

SECTION 7. HANDLING AND STORAGE

Advice on protection against : Keep away from sources of ignition - No smoking. Take pre-
fire and explosion cautionary measures against static discharges. Vapours may
form explosive mixtures with air. Normal measures for preven-
tive fire protection.

Advice on safe handling : Provide sufficient air exchange and/or exhaust in work rooms.

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ARDROX 907PB Aerosol

Version: 1.2 Revision Date 13.01.2017 Print Date 13.01.2017

Provide exhaust ventilation close to floor level.

Have eye wash bottle or eye rinse ready at the work place.
To avoid risks to man and the environment, comply with the
instructions for use.

Hygiene measures : Take off contaminated clothing and shoes immediately.

Keep away from food, drink and animal feedingstuffs.
Wash hands before breaks and immediately after handling the
product.
Avoid contact with skin and eyes.
Do not breathe vapours, aerosols.

Conditions for safe storage : Keep containers tightly closed in a dry, cool and well-
ventilated place.
Store in a place accessible by authorized persons only.
To maintain product quality, do not store in heat or direct sun-
light.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value type Control parame- Basis
(Form of ters / Permissible
exposure) concentration
Distillates (Petroleum), hy- 64742-47-8 TWA (Mist) 5 mg/m3 AU OEL
drotreated light Kerosine-
unspecified
TWA 200 mg/m3 ACGIH
(total hydrocarbon
vapor)
2-(3-Methoxypropoxy)propan- 34590-94-8 TWA 50 ppm AU OEL
1-ol 308 mg/m3
Further information: Skin absorption
TWA 100 ppm ACGIH
STEL 150 ppm ACGIH
Carbon dioxide 124-38-9 STEL 30,000 ppm AU OEL
54,000 mg/m3
TWA 5,000 ppm AU OEL
9,000 mg/m3
TWA 12,500 ppm AU OEL
22,500 mg/m3
STEL 30,000 ppm AU OEL
54,000 mg/m3
TWA 5,000 ppm ACGIH
STEL 30,000 ppm ACGIH
Distillates (petroleum), hy- 64742-53-6 TWA (Mist) 5 mg/m3 AU OEL
drotreated light naphthenic
TWA (Inhal- 5 mg/m3 ACGIH
able fraction)
Engineering measures : Ensure adequate ventilation, especially in confined areas.
Electrical equipment should be protected to the appropriate
standard.
Use only explosion-proof equipment.

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ARDROX 907PB Aerosol

Version: 1.2 Revision Date 13.01.2017 Print Date 13.01.2017

Personal protective equipment

Respiratory protection : In case of insufficient ventilation, wear suitable respiratory
equipment according to AS/NZS 1715/1716
Recommended Filter type:
Type B
Hand protection
Material : Gloves: PVC, Nitrile, Neoprene or natural rubber according to
AS/NZS 2161.1

Remarks : Protective gloves complying with AS/NZS 2161.1. The exact

break through time can be obtained from the protective glove
producer and this has to be observed. Gloves should be dis-
carded and replaced if there is any indication of degradation
or chemical breakthrough.

Eye protection : Tightly fitting safety goggles or safety glasses with side
shields.
Eye protection (AS 1336/1337)

Skin and body protection : Chemical resistant protective clothing according to

AS3765/2210

Protective measures : Handle in accordance with good industrial hygiene and safety
practice.
Ensure that eye flushing systems and safety showers are
located close to the working place.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : mobile liquid

Colour : dark red

Odour : hydrocarbon-like

Initial boiling point and boiling : 225 °C

range

Flash point : min. 93 °C

Method: closed cup

Upper explosion limit : Upper flammability limit

estimated 12 %(V)

Lower explosion limit : lower flammability limit

estimated 1 %(V)

Density : ca. 0.87 g/cm³

Solubility(ies)
Water solubility : insoluble, Formation of an emulsion.

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No dangerous reaction known under conditions of normal use.

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ARDROX 907PB Aerosol

Version: 1.2 Revision Date 13.01.2017 Print Date 13.01.2017

Chemical stability : Stable under normal conditions.

Possibility of hazardous reac- : Vapours may form explosive mixture with air.
tions Pressurised container: May burst if heated.

Conditions to avoid : Keep away from open flames, hot surfaces and sources of
ignition.
Strong sunlight for prolonged periods.

Hazardous decomposition : No decomposition if stored and applied as directed.

products

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Product:
Acute oral toxicity : Acute toxicity estimate: > 2,000 mg/kg
Method: Calculation method

Components:
Distillates (Petroleum), hydrotreated light Kerosine-unspecified:
Acute oral toxicity : LD50: > 2,000 mg/kg

Acute inhalation toxicity : LC50: > 5 mg/l

Acute dermal toxicity : LD50: > 2,000 mg/kg

Alcohol ethoxylate:
Acute oral toxicity : LD50 (Rat): > 300 - 2,000 mg/kg

Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg

2-(3-Methoxypropoxy)propan-1-ol:
Acute oral toxicity : LD50 (Rat): 5,135 mg/kg

Acute dermal toxicity : LD50 (Rabbit): 9,510 mg/kg

Ethoxylated Secondary Alcohols (C11 - 15):

Acute oral toxicity : LD50: 1,800 mg/kg

Carbon dioxide:
Acute oral toxicity : Remarks: No data available

Skin corrosion/irritation
Product : No data available

Serious eye damage/eye irritation

Product : No data available

Respiratory or skin sensitisation

Product:

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ARDROX 907PB Aerosol

Version: 1.2 Revision Date 13.01.2017 Print Date 13.01.2017

Remarks: No data available

Chronic toxicity
Germ cell mutagenicity
Product : No data available

Carcinogenicity
Product : No data available

Reproductive toxicity
Product : No data available

STOT - single exposure

Product : No data available

STOT - repeated exposure

Product : No data available

Aspiration toxicity

Product : No data available

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Components:
Alcohol ethoxylate:
Toxicity to fish : LC50 (Fish): 10 - 100 mg/l

Toxicity to daphnia and other : LC50 (Daphnia (water flea)): > 1 - 10 mg/l
aquatic invertebrates

Toxicity to algae : EC50 (Algae): 10 - 100 mg/l

Toxicity to bacteria : IC50 (Bacteria): > 100 mg/l

2-(3-Methoxypropoxy)propan-1-ol:
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 10,000 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : LC50 (Daphnia magna (Water flea)): 1,919 mg/l
aquatic invertebrates Exposure time: 48 h

NOEC (Daphnia magna (Water flea)): 0.5 mg/l

Exposure time: 22 d

Toxicity to algae : EC50 (Selenastrum capricornutum (green algae)): 1,000 mg/l

Exposure time: 72 h

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ARDROX 907PB Aerosol

Version: 1.2 Revision Date 13.01.2017 Print Date 13.01.2017

Toxicity to bacteria : EC10 (Pseudomonas putida): 4,168 mg/l

Test Type: Growth inhibition

Ethoxylated Secondary Alcohols (C11 - 15):

Toxicity to fish : LC50 (Pimephales promelas (Fathead minnow)): 1 - 10 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 4.1 mg/l
aquatic invertebrates Exposure time: 48 h

Toxicity to bacteria : EC50 (Bacteria): > 1,000 mg/l

Carbon dioxide:
Toxicity to fish : Remarks: No data available

Persistence and degradability

Product:
Biodegradability : Remarks: No data available

Components:
Alcohol ethoxylate:
Biodegradability : Remarks: Readily biodegradable
This surfactant complies with the biodegradability criteria as
laid down in Regulation (EC) No.907/2006 on detergents.
Data to support this assertion are held at the disposal of the
competent authorities of the Member States and will be made
available to them, at their direct request or at the request of a
detergent manufacturer.

Ethoxylated Secondary Alcohols (C11 - 15):

Biodegradability : Biodegradation: 65 %
Exposure time: 28 d
Method: OECD Test Guideline 301F
Remarks: Readily biodegradable
This surfactant complies with the biodegradability criteria as
laid down in Regulation (EC) No.648/2004 on detergents.
Data to support this assertion are held at the disposal of the
competent authorities of the Member States and will be made
available to them, at their direct request or at the request of a
detergent manufacturer.

Bioaccumulative potential

Product:
Bioaccumulation : Remarks: Bioaccumulation is unlikely.

Components:
Ethoxylated Secondary Alcohols (C11 - 15):
Bioaccumulation : Remarks: Does not bioaccumulate.

Mobility in soil
Product:

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ARDROX 907PB Aerosol

Version: 1.2 Revision Date 13.01.2017 Print Date 13.01.2017

Distribution among environ- : Remarks: No data available

mental compartments

Other adverse effects

No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : In accordance with local and national regulations.

Packaging : Dispose of as unused product.

SECTION 14. TRANSPORT INFORMATION

International Regulation
IATA-DGR
UN/ID No. : UN 1950
Proper shipping name : Aerosols, flammable
Class : 2.1
Packing group : Not assigned by regulation
Labels : Flammable gas
Packing instruction (cargo : 203
aircraft)
Packing instruction (passen- : 203
ger aircraft)
IMDG-Code
UN number : UN 1950
Proper shipping name : AEROSOLS

Class : 2.1
Packing group : Not assigned by regulation
Labels : 2.1
EmS Code : F-D, S-U
Marine pollutant : no
Remarks : "IMDG-Code segregation group not applicable"., Protected
from sources of heat., For AEROSOLS with a maximum ca-
pacity of 1 litre: Category A. For AEROSOLS with a capacity
above 1 litre: Category B. For WASTE AEROSOLS: Category
C, Clear of living quarters., For AEROSOLS with a maximum
capacity of 1 litre: Segregation as for class 9. Stow "separated
from" class 1 except for division 1.4. For AEROSOLS with a
capacity above 1 litre: Segregation as for the appropriate sub-
division of class 2. For WASTE AEROSOLS: Segregation as
for the appropriate subdivision of class 2.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
National Regulations

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ARDROX 907PB Aerosol

Version: 1.2 Revision Date 13.01.2017 Print Date 13.01.2017

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mi x-

ture
The product is classified and labelled in accordance with EC directives or respective national
laws.
Regional or national implementations of GHS may not implement all hazard classes and catego-
ries.
Classification and labelling according to Directive 75/324/EEC.

Standard for the Uniform : No poison schedule number allocated

Scheduling of Medicines and
Poisons

SECTION 16. OTHER INFORMATION

Full text of other abbreviations

AICS - Australian Inventory of Chemical Substances; ANTT - National Agency for Transport by
Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; CPR - Controlled Products Regulations; DIN -
Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada);
ECx - Concentration associated with x% response; ELx - Loading rate associated with x% re-
sponse; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan);
ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response
Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC - Internation-
al Agency for Research on Cancer; IATA - International Air Transport Association; IBC - Interna-
tional Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk;
IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization;
IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dan-
gerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health
Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemi-
cals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to
50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Pre-
vention of Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC -
No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level;
NOELR - No Observable Effect Loading Rate; NOM - Official Mexican Norm; NTP - National Tox-
icology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Eco-
nomic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Preven-
tion; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of
Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship;
REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concern-
ing the Registration, Evaluation, Authorisation and Restriction of Chemicals; SADT - Self-
Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical
Substance Inventory; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Con-
trol Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on
the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative; WHMIS -
Workplace Hazardous Materials Information System

Further information
Other information : The information provided is based on our current knowledge
and experience and apply to the product as delivered. Re-

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SAFETY DATA SHEET
ARDROX 907PB Aerosol

Version: 1.2 Revision Date 13.01.2017 Print Date 13.01.2017

garding the product properties, these are not guaranteed. The

delivery of this safety datasheet does not free the recipient of
the product from his own responsibility to follow the relevant
rules and regulations concerning this product.
Date format : dd.mm.yyyy

AU / EN

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