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    Answer: Step 1

    Uploaded by

    cj
    The document shows steps to derive expressions for fugacity coefficients of pure gases and gas mixtures using generalized correlations and equations of state. It also shows calculating the fugacity coefficient and mole fraction of a species in a vapor mixture at equilibrium.

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    Answer: Step 1

    Uploaded by

    cj
    27 views3 pages
    The document shows steps to derive expressions for fugacity coefficients of pure gases and gas mixtures using generalized correlations and equations of state. It also shows calculating the fugacity coefficient and mole fraction of a species in a vapor mixture at equilibrium.

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    5,6,7

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    The document shows steps to derive expressions for fugacity coefficients of pure gases and gas mixtures using generalized correlations and equations of state. It also shows calculating the fugacity coefficient and mole fraction of a species in a vapor mixture at equilibrium.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    27 views3 pages

    Answer: Step 1

    Uploaded by

    cj
    The document shows steps to derive expressions for fugacity coefficients of pure gases and gas mixtures using generalized correlations and equations of state. It also shows calculating the fugacity coefficient and mole fraction of a species in a vapor mixture at equilibrium.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
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    4/8/2021 https://fkchegg.com/cg27/?auth=eyJhbGciOiJIUzI1NiIsInR5cCI6IkpXVCJ9.

    eyJ1dWlkIjoiOTc4MDQ3MDI1OTYxMC0xNzg4MDU1NyIsImlhd…

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    Question

    Answer
    Step 1
    (a)

    Write the expression for the fugacity coefficient of a pure gas using generalized correlations.

    …… (1)

    Here, , temperature is T, and gas constant is R, system pressure is P, low pressure for an ideal gas is ,
    fugacity of pure species in the vapor phase is , and molar volume of pure species is .

    Step 2
    Write the expression of molar volume by setting the mole fraction of species 1 equal to unity.

    …… (2)

    Substitute the value of from Equation (2) in Equation (1) and integrate it.

    …… (3)

    Simplify Equation (3) and let .

    …… (4)

    Step 3
    Express the expression for fugacity coefficient for species in the vapor .

    …… (5)

    Substitute the value of from Equation (4) in Equation (5).

    …… (6)

    https://fkchegg.com/cg27/?auth=eyJhbGciOiJIUzI1NiIsInR5cCI6IkpXVCJ9.eyJ1dWlkIjoiOTc4MDQ3MDI1OTYxMC0xNzg4MDU1NyIsImlhdCI6MTYxNz… 1/3
    4/8/2021 https://fkchegg.com/cg27/?auth=eyJhbGciOiJIUzI1NiIsInR5cCI6IkpXVCJ9.eyJ1dWlkIjoiOTc4MDQ3MDI1OTYxMC0xNzg4MDU1NyIsImlhd…

    Step 4
    Substitute for , for , 50 atm for P in Equation (6).

    Hence, the fugacity coefficient for species in the vapor is .

    Step 5
    Write the expression for the fugacity coefficient of a vapor mixture using equation of state.

    …… (7)

    Here, mole fraction of species 1 is and volume of species 1 is .

    Write an expression for extensive volume.

    …… (8)

    Here, constants for species 1, 2, and 3 are respectively.

    Differentiate Equation (8).

    Step 6
    Substitute the value of in Equation (7).

    …… (9)

    Integrate Equation (9) to find

    …… (10)

    Step 7
    Substitute for , for , 50 atm for P in Equation (10).

    Hence, the fugacity coefficient of species in the mixture is .

    Step 8
    https://fkchegg.com/cg27/?auth=eyJhbGciOiJIUzI1NiIsInR5cCI6IkpXVCJ9.eyJ1dWlkIjoiOTc4MDQ3MDI1OTYxMC0xNzg4MDU1NyIsImlhdCI6MTYxNz… 2/3
    4/8/2021 https://fkchegg.com/cg27/?auth=eyJhbGciOiJIUzI1NiIsInR5cCI6IkpXVCJ9.eyJ1dWlkIjoiOTc4MDQ3MDI1OTYxMC0xNzg4MDU1NyIsImlhd…

    (b)

    Write the equilibrium state for vapor and liquid.

    Calculate the fugacity coefficient for species in the vapor.

    …… (11)

    Here, mole fraction of vapor species 1 is .

    Rearrange Equation (12) to find .

    …… (12)

    Substitute 15 atm for , 0.93 for , and 50 atm for P in Equation (12).

    Hence, the mole fraction of vapor species 1 is .

    https://fkchegg.com/cg27/?auth=eyJhbGciOiJIUzI1NiIsInR5cCI6IkpXVCJ9.eyJ1dWlkIjoiOTc4MDQ3MDI1OTYxMC0xNzg4MDU1NyIsImlhdCI6MTYxNz… 3/3

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