SAFETY DATA SHEET

Shell Diesoline B2

Version 2.0 Revision Date 19.11.2019 Print Date 19.02.2020

1. PRODUCT AND COMPANY IDENTIFICATION

Product name : Shell Diesoline B2

Product code : 002D5004

Manufacturer or supplier's details

Supplier : Pilipinas Shell Petroleum Corporation
41st Flr The Finance Center, 26th St Cor. 9th Ave, BGC,
1635 Taguig
Metro Manila
PHILIPPINES
Telephone : (+63) 2 8 802 7600
Telefax : (+63) 2 8 816 6565

Emergency telephone : (+63) 2 8 802 7600

number
Email Contact for Safety : If you have any enquiries about the content of this SDS
Data Sheet please email fuelSDS@shell.com

Recommended use of the chemical and restrictions on use

Recommended use : Fuel for on-road diesel-powered engines.

Restrictions on use :
This product must not be used in applications other than those
listed in Section 1 without first seeking the advice of the
supplier., This product is not to be used as a solvent or
cleaning agent; for lighting or brightening fires; as a skin
cleanser.

2. HAZARDS IDENTIFICATION

GHS Classification
Flammable liquids : Category 3
Aspiration hazard : Category 1
Acute toxicity (Inhalation) : Category 4
Skin irritation : Category 2
Carcinogenicity : Category 2
Specific target organ toxicity - : Category 2 (Blood, thymus, Liver)
repeated exposure
Short-term (acute) aquatic : Category 2
hazard
Long-term (chronic) aquatic : Category 2
hazard

GHS label elements

Hazard pictograms :

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Signal word : Danger

Hazard statements : PHYSICAL HAZARDS:

H226 Flammable liquid and vapour.
HEALTH HAZARDS:
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H332 Harmful if inhaled.
H373 May cause damage to organs (Blood, Liver, thymus)
through prolonged or repeated exposure.
H351 Suspected of causing cancer.
ENVIRONMENTAL HAZARDS:
H401 Toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.

Precautionary statements :
Prevention:
P210 Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye
protection/ face protection.

Response:
P301 + P310 IF SWALLOWED: Immediately call a POISON
CENTER/doctor.
P331 Do NOT induce vomiting.

Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
Keep container tightly closed.

Disposal:
P501 Dispose of contents and container to appropriate waste
site or reclaimer in accordance with local and national
regulations.

Other hazards which do not result in classification

May ignite on surfaces at temperatures above auto-ignition temperature.Vapour in the headspace
of tanks and containers may ignite and explode at temperatures exceeding auto-ignition
temperature, where vapour concentrations are within the flammability range.This material is a
static accumulator.Even with proper grounding and bonding, this material can still accumulate an
electrostatic charge.If sufficient charge is allowed to accumulate, electrostatic discharge and
ignition of flammable air-vapour mixtures can occur.This product is intended for use in closed
systems only.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature : A complex combination of hydrocarbons produced by the

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distillation of crude oil. It consists of hydrocarbons having
carbon numbers predominantly in the range of C9 through
C20 and boiling in the range of approximately 163°C to 357°C
(325°F to 675°F).
May also contain several additives at <0.1% v/v each.
May contain cetane improver (Ethyl Hexyl Nitrate) at <0.2%
v/v.

: May contain methyl and ethyl esters from lipid sources

: May contain catalytically cracked oils in which polycyclic

aromatic compounds, mainly 3-ring but some 4- to 6-ring
species are present.

Hazardous components

Chemical name CAS-No. Classification Concentration [%]

Fuels, diesel 68334-30-5 Flam. Liq.3; H226 97.8 - 98.3
Asp. Tox.1; H304
Acute Tox.4; H332
Skin Irrit.2; H315
Carc.2; H351
STOT RE2; H373
Aquatic Acute2; H401
Aquatic Chronic2; H411
Fatty acids, C16-18 and 67762-38-3 1.7 - 2.2
C18-unsatd., Me esters
(FAME, Biodiesel)
Dyes and markers can be used to indicate tax status and prevent fraud.
For explanation of abbreviations see section 16.

Further information
Contains:
Chemical name Identification number Concentration [%]
cumene 98-82-8, 202-704-5 0 - 0.5
Naphthalene 91-20-3, 202-049-5 0 - 0.5

4. FIRST-AID MEASURES

If inhaled : Call emergency number for your location / facility.

Remove to fresh air. Do not attempt to rescue the victim
unless proper respiratory protection is worn. If the victim has
difficulty breathing or tightness of the chest, is dizzy, vomiting,
or unresponsive, give 100% oxygen with rescue breathing or
Cardio-Pulmonary Resuscitation as required and transport to
the nearest medical facility.

In case of skin contact : Remove contaminated clothing. Immediately flush skin with
large amounts of water for at least 15 minutes, and follow by
washing with soap and water if available. If redness, swelling,
pain and/or blisters occur, transport to the nearest medical
facility for additional treatment.
When using high pressure equipment, injection of product

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under the skin can occur. If high pressure injuries occur, the
casualty should be sent immediately to a hospital. Do not wait
for symptoms to develop.
Obtain medical attention even in the absence of apparent
wounds.

In case of eye contact : Immediately flush eye(s) with plenty of water.

Remove contact lenses, if present and easy to do. Continue
rinsing.
Transport to the nearest medical facility for additional
treatment.

If swallowed : Call emergency number for your location / facility.

If swallowed, do not induce vomiting: transport to nearest
medical facility for additional treatment. If vomiting occurs
spontaneously, keep head below hips to prevent aspiration.
If any of the following delayed signs and symptoms appear
within the next 6 hours, transport to the nearest medical
facility: fever greater than 101° F (38.3°C), shortness of
breath, chest congestion or continued coughing or wheezing.

Most important symptoms : If material enters lungs, signs and symptoms may include
and effects, both acute and coughing, choking, wheezing, difficulty in breathing, chest
delayed congestion, shortness of breath, and/or fever.
If any of the following delayed signs and symptoms appear
within the next 6 hours, transport to the nearest medical
facility: fever greater than 101° F (38.3°C), shortness of
breath, chest congestion or continued coughing or wheezing.
Respiratory irritation signs and symptoms may include a
temporary burning sensation of the nose and throat, coughing,
and/or difficulty breathing.
Skin irritation signs and symptoms may include a burning
sensation, redness, swelling, and/or blisters.
No specific hazards under normal use conditions.
Eye irritation signs and symptoms may include a burning
sensation, redness, swelling, and/or blurred vision.

Protection of first-aiders : When administering first aid, ensure that you are wearing the
appropriate personal protective equipment according to the
incident, injury and surroundings.

Notes to physician : Call a doctor or poison control center for guidance.

Potential for chemical pneumonitis.
Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Foam, water spray or fog. Dry chemical powder, carbon
dioxide, sand or earth may be used for small fires only.

Unsuitable extinguishing : Do not use direct water jets on the burning product as they
media could cause a steam explosion and spread of the fire.
Simultaneous use of foam and water on the same surface is
to be avoided as water destroys the foam.

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Specific hazards during : Hazardous combustion products may include:

firefighting A complex mixture of airborne solid and liquid particulates and
gases (smoke).
Oxides of sulphur.
Unidentified organic and inorganic compounds.
Carbon monoxide may be evolved if incomplete combustion
occurs.
Will float and can be reignited on surface water.
Flammable vapours may be present even at temperatures
below the flash point.
The vapour is heavier than air, spreads along the ground and
distant ignition is possible.

Specific extinguishing : Use extinguishing measures that are appropriate to local

methods circumstances and the surrounding environment.
Clear fire area of all non-emergency personnel.

Keep adjacent containers cool by spraying with water.

If possible remove containers from the danger zone.
If the fire cannot be extinguished the only course of action is
to evacuate immediately.
Contain residual material at affected sites to prevent material
from entering drains (sewers), ditches, and waterways.

Special protective equipment : Proper protective equipment including chemical resistant

for firefighters gloves are to be worn; chemical resistant suit is indicated if
large contact with spilled product is expected. Self-Contained
Breathing Apparatus must be worn when approaching a fire in
a confined space. Select fire fighter's clothing approved to
relevant Standards (e.g. Europe: EN469).

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Do not breathe fumes, vapour.

protective equipment and Do not operate electrical equipment.
emergency procedures
: Shut off leaks, if possible without personal risks. Remove all
possible sources of ignition in the surrounding area and
evacuate all personnel. Attempt to disperse the gas or to
direct its flow to a safe location for example by using fog
sprays. Take precautionary measures against static
discharge. Ensure electrical continuity by bonding and
grounding (earthing) all equipment. Monitor area with
combustible gas meter.

Environmental precautions : Take measures to minimise the effects on groundwater.

Contain residual material at affected sites to prevent material
from entering drains (sewers), ditches, and waterways.
Prevent from spreading or entering into drains, ditches or
rivers by using sand, earth, or other appropriate barriers.

Methods and materials for : For small liquid spills (< 1 drum), transfer by mechanical

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containment and cleaning up means to a labeled, sealable container for product recovery or
safe disposal. Allow residues to evaporate or soak up with an
appropriate absorbent material and dispose of safely. Remove
contaminated soil and dispose of safely.
For large liquid spills (> 1 drum), transfer by mechanical
means such as vacuum truck to a salvage tank for recovery or
safe disposal. Do not flush away residues with water. Retain
as contaminated waste. Allow residues to evaporate or soak
up with an appropriate absorbent material and dispose of
safely. Remove contaminated soil and dispose of safely
Prevent from spreading or entering into drains, ditches or
rivers by using sand, earth, or other appropriate barriers.

Observe all relevant local and international regulations.

Evacuate the area of all non-essential personnel.
Ventilate contaminated area thoroughly.

Additional advice : For guidance on selection of personal protective equipment

see Chapter 8 of this Safety Data Sheet.
Notify authorities if any exposure to the general public or the
environment occurs or is likely to occur.
For guidance on disposal of spilled material see Chapter 13 of
this Safety Data Sheet.
Local authorities should be advised if significant spillages
cannot be contained.
Maritime spillages should be dealt with using a Shipboard Oil
Pollution Emergency Plan (SOPEP), as required by MARPOL
Annex 1 Regulation 26.

7. HANDLING AND STORAGE

General Precautions : Avoid breathing of or direct contact with material. Only use in
well ventilated areas. Wash thoroughly after handling. For
guidance on selection of personal protective equipment see
Section 8 of this Safety Data Sheet.
Use the information in this data sheet as input to a risk
assessment of local circumstances to help determine
appropriate controls for safe handling, storage and disposal of
this material.
Air-dry contaminated clothing in a well-ventilated area before
laundering.
Prevent spillages.
Use local exhaust ventilation if there is risk of inhalation of
vapours, mists or aerosols.
Never siphon by mouth.
Contaminated leather articles including shoes cannot be
decontaminated and should be destroyed to prevent reuse.

Maintenance and Fuelling Activities - Avoid inhalation of

vapours and contact with skin.

Advice on safe handling : Ensure that all local regulations regarding handling and
storage facilities are followed.
Avoid inhaling vapour and/or mists.
Avoid prolonged or repeated contact with skin.

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When using do not eat or drink.
Extinguish any naked flames. Do not smoke. Remove ignition
sources. Avoid sparks.
Earth all equipment.
Properly dispose of any contaminated rags or cleaning
materials in order to prevent fires.
Use local exhaust ventilation if there is risk of inhalation of
vapours, mists or aerosols.

The vapour is heavier than air, spreads along the ground and
distant ignition is possible.

Avoidance of contact : Strong oxidising agents.

Product Transfer : Avoid splash filling Wait 2 minutes after tank filling (for tanks
such as those on road tanker vehicles) before opening
hatches or manholes. Wait 30 minutes after tank filling ( for
large storage tanks) before opening hatches or manholes.
Keep containers closed when not in use. Contamination
resulting from product transfer may give rise to light
hydrocarbon vapour in the headspace of tanks that have
previously contained gasoline. This vapour may explode if
there is a source of ignition. Partly filled containers present a
greater hazard than those that are full, therefore handling,
transfer and sampling activities need special care. Even with
proper grounding and bonding, this material can still
accumulate an electrostatic charge. If sufficient charge is
allowed to accumulate, electrostatic discharge and ignition of
flammable air-vapour mixtures can occur. Be aware of
handling operations that may give rise to additional hazards
that result from the accumulation of static charges. These
include but are not limited to pumping (especially turbulent
flow), mixing, filtering, splash filling, cleaning and filling of
tanks and containers, sampling, switch loading, gauging,
vacuum truck operations, and mechanical movements. These
activities may lead to static discharge e.g. spark formation.
Restrict line velocity during pumping in order to avoid
generation of electrostatic discharge (≤ 1 m/s until fill pipe
submerged to twice its diameter, then ≤ 7 m/s). Avoid splash
filling. Do NOT use compressed air for filling, discharging, or
handling operations.

Storage
Other data : Drum and small container storage:
Drums should be stacked to a maximum of 3 high.
Use properly labeled and closable containers.
Tank storage:
Tanks must be specifically designed for use with this product.
Bulk storage tanks should be diked (bunded).
Locate tanks away from heat and other sources of ignition.
Must be stored in a diked (bunded) well- ventilated area, away
from sunlight, ignition sources and other sources of heat.
Vapours from tanks should not be released to atmosphere.
Breathing losses during storage should be controlled by a
suitable vapour treatment system.

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The vapour is heavier than air. Beware of accumulation in pits
and confined spaces.
Keep container tightly closed and in a cool, well-ventilated
place.
Keep in a cool place.
Electrostatic charges will be generated during pumping.
Electrostatic discharge may cause fire. Ensure electrical
continuity by bonding and grounding (earthing) all equipment
to reduce the risk.
The vapours in the head space of the storage vessel may lie
in the flammable/explosive range and hence may be
flammable.
Refer to section 15 for any additional specific legislation
covering the packaging and storage of this product.
Keep in a bunded area with a sealed (low permeability) floor,
to provide containment against spillage.
Prevent ingress of water.

Packaging material : Suitable material: For containers, or container linings use mild
steel, stainless steel., Aluminium may also be used for
applications where it does not present an unnecessary fire
hazard., Examples of suitable materials are: high density
polyethylene (HDPE) and Viton (FKM), which have been
specifically tested for compatibility with this product., For
container linings, use amine-adduct cured epoxy paint., For
seals and gaskets use: graphite, PTFE, Viton A, Viton B.
Unsuitable material: Some synthetic materials may be
unsuitable for containers or container linings depending on the
material specification and intended use. Examples of
materials to avoid are: natural rubber (NR), nitrile rubber
(NBR), ethylene propylene rubber (EPDM), polymethyl
methacrylate (PMMA), polystyrene, polyvinyl chloride (PVC),
polyisobutylene., However, some may be suitable for glove
materials.

Specific use(s) : See additional references that provide safe handling practices
for liquids that are determined to be static accumulators:
American Petroleum Institute 2003 (Protection Against
Ignitions Arising out of Static, Lightning and Stray Currents) or
National Fire Protection Agency 77 (Recommended Practices
on Static Electricity).
IEC/TS 60079-32-1: Electrostatic hazards, guidance
Ensure that all local regulations regarding handling and
storage facilities are followed.

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value type Control Basis
(Form of parameters /
exposure) Permissible
concentration
Fuels, diesel 68334-30-5 TWA 100 mg/m3 ACGIH

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(Inhalable
fraction and
vapor)
cumene 98-82-8 TWA 50 ppm PH OEL
245 mg/m3
Further information: Skin
cumene 98-82-8 TWA 50 ppm OSHA Z-1
245 mg/m3
cumene TWA 50 ppm ACGIH
Naphthalene 91-20-3 TWA 10 ppm PH OEL
50 mg/m3
Naphthalene 91-20-3 TWA 10 ppm NIOSH REL
50 mg/m3
Naphthalene ST 15 ppm NIOSH REL
75 mg/m3
Naphthalene TWA 10 ppm OSHA Z-1
50 mg/m3
Naphthalene TWA 10 ppm ACGIH

Biological occupational exposure limits

No biological limit allocated.

Monitoring Methods
Monitoring of the concentration of substances in the breathing zone of workers or in the general
workplace may be required to confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also be appropriate.
Validated exposure measurement methods should be applied by a competent person and
samples analysed by an accredited laboratory.
Examples of sources of recommended exposure measurement methods are given below or
contact the supplier. Further national methods may be available.
National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods
http://www.cdc.gov/niosh/
Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods
http://www.osha.gov/
L'Institut National de Recherche et de Securité, (INRS), France http://www.inrs.fr/accueil
Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substances
http://www.hse.gov.uk/
Institut für Arbeitsschutz Deutschen Gesetzlichen Unfallversicherung (IFA) , Germany
http://www.dguv.de/inhalt/index.jsp

Engineering measures : The level of protection and types of controls necessary will
vary depending upon potential exposure conditions. Select
controls based on a risk assessment of local circumstances.
Appropriate measures include:
Use sealed systems as far as possible.
Firewater monitors and deluge systems are recommended.
Adequate explosion-proof ventilation to control airborne
concentrations below the exposure guidelines/limits.
Local exhaust ventilation is recommended.
Eye washes and showers for emergency use.

General Information:

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Always observe good personal hygiene measures, such as
washing hands after handling the material and before eating,
drinking, and/or smoking. Routinely wash work clothing and
protective equipment to remove contaminants. Discard
contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.
Define procedures for safe handling and maintenance of
controls.
Educate and train workers in the hazards and control
measures relevant to normal activities associated with this
product.
Ensure appropriate selection, testing and maintenance of
equipment used to control exposure, e.g. personal protective
equipment, local exhaust ventilation.
Drain down system prior to equipment break-in or
maintenance.
Retain drain downs in sealed storage pending disposal or
subsequent recycle.
Do not ingest. If swallowed, then seek immediate medical
assistance

Personal protective equipment

Protective measures
Personal protective equipment (PPE) should meet recommended national standards. Check with
PPE suppliers.

Respiratory protection : If engineering controls do not maintain airborne

concentrations to a level which is adequate to protect worker
health, select respiratory protection equipment suitable for the
specific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers.
Where air-filtering respirators are unsuitable (e.g. airborne
concentrations are high, risk of oxygen deficiency, confined
space) use appropriate positive pressure breathing apparatus.
Where air-filtering respirators are suitable, select an
appropriate combination of mask and filter.

Select a filter suitable for the combination of organic gases

and vapours and particles [Type A/Type P boiling point >65°C
(149°F)].

Hand protection
Remarks : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection. When prolonged or frequent
repeated contact occurs. Nitrile rubber. For incidental
contact/splash protection Neoprene, PVC gloves may be
suitable. For continuous contact we recommend gloves with
breakthrough time of more than 240 minutes with preference
for > 480 minutes where suitable gloves can be identified. For
short-term/splash protection we recommend the same but
recognize that suitable gloves offering this level of protection

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may not be available and in this case a lower breakthrough
time maybe acceptable so long as appropriate maintenance
and replacement regimes are followed. Glove thickness is not
a good predictor of glove resistance to a chemical as it is
dependent on the exact composition of the glove material.
Suitability and durability of a glove is dependent on usage,
e.g. frequency and duration of contact, chemical resistance of
glove material, dexterity. Always seek advice from glove
suppliers. Contaminated gloves should be replaced. Personal
hygiene is a key element of effective hand care. Gloves must
only be worn on clean hands. After using gloves, hands
should be washed and dried thoroughly. Application of a non-
perfumed moisturizer is recommended.

Eye protection : If material is handled such that it could be splashed into eyes,
protective eyewear is recommended.
If a local risk assessment deems it so then chemical splash
goggles may not be required and safety glasses may provide
adequate eye protection.

Skin and body protection : Wear chemical resistant gloves/gauntlets and boots. Where
risk of splashing, also wear an apron.

Hygiene measures : Always observe good personal hygiene measures, such as

washing hands after handling the material and before eating,
drinking, and/or smoking. Routinely wash work clothing and
protective equipment to remove contaminants. Discard
contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.
Define procedures for safe handling and maintenance of
controls.
Educate and train workers in the hazards and control
measures relevant to normal activities associated with this
product.
Ensure appropriate selection, testing and maintenance of
equipment used to control exposure, e.g. personal protective
equipment, local exhaust ventilation.
Drain down system prior to equipment break-in or
maintenance.
Retain drain downs in sealed storage pending disposal or
subsequent recycle.
Do not ingest. If swallowed, then seek immediate medical
assistance.
If repeated and/or prolonged skin exposure to the substance
is likely, then wear suitable gloves tested to EN374 and
provide employee skin care programmes.

Environmental exposure controls

General advice : Local guidelines on emission limits for volatile substances
must be observed for the discharge of exhaust air containing
vapour.
Minimise release to the environment. An environmental
assessment must be made to ensure compliance with local
environmental legislation.
Information on accidental release measures are to be found in

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section 6.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Colour : Undyed
Odour : Unstenched
Odour Threshold : Data not available
pH : Not applicable
Melting / freezing point : Data not available
Boiling point/boiling range : 170 - 390 °C / 338 - 734 °FMethod: Unspecified

Flash point : 55 - 75 °C / 131 - 167 °F

Method: Unspecified

Evaporation rate : Data not available

Flammability (solid, gas) : Not applicable

Upper explosion limit : 6 %(V)

Lower explosion limit : 1 %(V)

Vapour pressure : <= 0.4 kPa (38.0 °C / 100.4 °F)

Method: Unspecified

<= 0.6 kPa (50.0 °C / 122.0 °F)

Method: Unspecified

Relative vapour density : Data not available

Relative density : Data not available
Density : 820 - 860 kg/m3 (15 °C / 59 °F)
Method: Unspecified

Solubility(ies)
Water solubility : negligible
Solubility in other solvents : Data not available

Partition coefficient: n- : log Pow: ca. 2 - 15

octanol/water
Auto-ignition temperature : > 220 °C / 428 °F

Viscosity
Viscosity, kinematic : 2 - 4.5 mm2/s (40.0 °C / 104.0 °F)

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Method: Unspecified

Explosive properties : Classification Code: Not classified.

Oxidizing properties : Not applicable

Conductivity : Low conductivity: < 100 pS/m, The conductivity of this material
makes it a static accumulator., A liquid is typically considered
nonconductive if its conductivity is below 100 pS/m and is
considered semi-conductive if its conductivity is below 10,000
pS/m., Whether a liquid is nonconductive or semiconductive,
the precautions are the same., A number of factors, for
example liquid temperature, presence of contaminants, and
anti-static additives can greatly influence the conductivity of a
liquid

10. STABILITY AND REACTIVITY

Reactivity : The product does not pose any further reactivity hazards in
addition to those listed in the following sub-paragraph.

Chemical stability : Stable under normal use conditions.

Possibility of hazardous : No hazardous reaction is expected when handled and stored

reactions according to provisions

Conditions to avoid : Avoid heat, sparks, open flames and other ignition sources.

In certain circumstances product can ignite due to static

electricity.

Incompatible materials : Strong oxidising agents.

Hazardous decomposition : Hazardous decomposition products are not expected to form

products during normal storage.
Thermal decomposition is highly dependent on conditions. A
complex mixture of airborne solids, liquids and gases
including carbon monoxide, carbon dioxide, sulphur oxides
and unidentified organic compounds will be evolved when this
material undergoes combustion or thermal or oxidative
degradation.

11. TOXICOLOGICAL INFORMATION

Basis for assessment : Information given is based on product data, a knowledge of

the components and the toxicology of similar products.
Unless indicated otherwise, the data presented is
representative of the product as a whole, rather than for
individual component(s).

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Information on likely routes of : Skin and eye contact are the primary routes of exposure
exposure although exposure may occur through inhalation or following
accidental ingestion.

Acute toxicity
Product:
Acute oral toxicity : LD50 rat: > 5,000 mg/kg
Remarks: Low toxicity:

Acute inhalation toxicity : LC 50 rat: > 1 - <=5 mg/l

Exposure time: 4 h
Remarks: Harmful if inhaled.

Acute dermal toxicity : LD 50 Rabbit: > 2,000 mg/kg

Remarks: Low toxicity:

Skin corrosion/irritation
Product:
Remarks: Irritating to skin.

Serious eye damage/eye irritation

Product:
Remarks: Slightly irritating to the eye., Based on available data, the classification criteria are not
met.

Respiratory or skin sensitisation

Product:
Remarks: Not a sensitiser.
Based on available data, the classification criteria are not met.

Germ cell mutagenicity

Product:
: Remarks: Positive in in-vitro, but negative in in-vivo
mutagenicity assays.
Carcinogenicity
Product:

Remarks: Limited evidence of carcinogenic effect, Repeated skin contact has resulted in irritation
and skin cancer in animals.

Material GHS/CLP Carcinogenicity Classification

Fuels, diesel Carcinogenicity Category 2
Fatty acids, C16-18 and C18- No carcinogenicity classification.

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unsatd., Me esters (FAME,
Biodiesel)
cumene No carcinogenicity classification.
Naphthalene Carcinogenicity Category 2

Material Other Carcinogenicity Classification

cumene IARC: Group 2B: Possibly carcinogenic to humans
Naphthalene IARC: Group 2B: Possibly carcinogenic to humans

Reproductive toxicity

Product:
:
Remarks: Not a developmental toxicant., Based on available
data, the classification criteria are not met., Does not impair
fertility.

STOT - single exposure

Product:
Remarks: Not classified.

STOT - repeated exposure

Product:
Target Organs: Blood, thymus, Liver
Remarks: May cause damage to organs or organ systems through prolonged or repeated
exposure.

Aspiration toxicity
Product:
Aspiration into the lungs when swallowed or vomited may cause chemical pneumonitis which
can be fatal.

Further information
Product:
Remarks: Classifications by other authorities under varying regulatory frameworks may exist.

12. ECOLOGICAL INFORMATION

Basis for assessment : Information given is based on a knowledge of the components

and the ecotoxicology of similar products.
Fuels are typically made from blending several refinery
streams. Ecotoxicological studies have been carried out on a

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variety of hydrocarbon blends and streams but not those
containing additives.
Unless indicated otherwise, the data presented is
representative of the product as a whole, rather than for
individual component(s).

Ecotoxicity
Product:
Toxicity to fish (Acute :
toxicity) Remarks: LL/EL/IL50 > 1 <= 10 mg/l
Toxic

Toxicity to crustacean (Acute :

toxicity) Remarks: LL/EL/IL50 > 1 <= 10 mg/l
Toxic

Toxicity to algae/aquatic :
plants (Acute toxicity) Remarks: LL/EL/IL50 > 1 <= 10 mg/l
Toxic

Toxicity to fish (Chronic : Remarks: Data not available

toxicity)
Toxicity to crustacean : Remarks: Data not available
(Chronic toxicity)
Toxicity to microorganisms : Remarks: LL/EL/IL50 > 100 mg/l
(Acute toxicity) Practically non toxic:
Based on available data, the classification criteria are not met.

Persistence and degradability

Product:
Biodegradability : Remarks: Readily biodegradable.

Bioaccumulative potential
Product:
Bioaccumulation : Remarks: Contains constituents with the potential to
bioaccumulate.

Partition coefficient: n- : log Pow: ca. 2 - 15

octanol/water
Mobility in soil
Product:
Mobility : Remarks: Partly evaporates from water or soil surfaces, but a
significant proportion will remain after one day., If product
enters soil, one or more constituents will be mobile and may
contaminate groundwater., Large volumes may penetrate soil
and could contaminate groundwater., Floats on water.
Other adverse effects
no data available
Product:

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Additional ecological : Films formed on water may affect oxygen transfer and
information damage organisms.

13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Recover or recycle if possible.
Send to drum recoverer or metal reclaimer.It is the
responsibility of the waste generator to determine the toxicity
and physical properties of the material generated to determine
the proper waste classification and disposal methods in
compliance with applicable regulations.
Drain container thoroughly.Do not dispose into the
environment, in drains or in water courses
After draining, vent in a safe place away from sparks and
fire.Do not dispose of tank water bottoms by allowing them to
drain into the ground.
Residues may cause an explosion hazard. Do not puncture,
cut or weld uncleaned drums.This will result in soil and
groundwater contamination.
Waste arising from a spillage or tank cleaning should be
disposed of in accordance with prevailing regulations,
preferably to a recognised collector or contractor. The
competence of the collector or contractor should be
established beforehand.

Contaminated packaging : Residues may cause an explosion hazard if heated above the
flash point. Do not puncture, cut or weld uncleaned drums.
Do not pollute the soil, water or environment with the waste
container.
Comply with any local recovery or waste disposal regulations.
Dispose in accordance with prevailing regulations, preferably
to a recognized collector or contractor. The competence of
the collector or contractor should be established beforehand.

Local legislation
Remarks : Disposal should be in accordance with applicable regional,
national, and local laws and regulations.
Local regulations may be more stringent than regional or
national requirements and must be complied with.

14. TRANSPORT INFORMATION

International Regulations
ADR
UN number : 1202
Proper shipping name : DIESEL FUEL
Class : 3
Packing group : III

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Labels : 3
Hazard Identification Number : 30
Environmentally hazardous : yes
IATA-DGR
UN/ID No. : UN 1202
Proper shipping name : DIESEL FUEL
Class : 3
Packing group : III
Labels : 3
IMDG-Code
UN number : UN 1202
Proper shipping name : DIESEL FUEL
Class : 3
Packing group : III
Labels : 3
Marine pollutant : yes
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied. MARPOL Annex 1 rules apply for bulk shipments by sea.

Special precautions for user

Remarks : Special Precautions: Refer to Section 7, Handling & Storage,
for special precautions which a user needs to be aware of or
needs to comply with in connection with transport.

15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or

mixture
The regulatory information is not intended to be comprehensive. Other regulations may apply to
this material.
Product Classification, Labelling and SDS: DOLE Administrative Order 136-14 Guidelines for the
Implementation of GHS in Chemical Safety Program in the Workplace.
Other international regulations
The components of this product are reported in the following inventories:
PICCS : All components listed or polymer exempt.

16. OTHER INFORMATION

Full text of H-Statements

H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H332 Harmful if inhaled.
H351 Suspected of causing cancer.
H373 May cause damage to organs through prolonged or repeated exposure.

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H401 Toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.
Full text of other abbreviations
Acute Tox. Acute toxicity
Aquatic Acute Short-term (acute) aquatic hazard
Aquatic Chronic Long-term (chronic) aquatic hazard
Asp. Tox. Aspiration hazard
Carc. Carcinogenicity
Flam. Liq. Flammable liquids
Skin Irrit. Skin irritation
STOT RE Specific target organ toxicity - repeated exposure

AICS - Australian Inventory of Chemical Substances; ANTT - National Agency for Transport by
Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for
Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with
x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized
System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer;
IATA - International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory
concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing
Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 -
Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population
(Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from
Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed (Adverse)
Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable
Effect Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program; NZIoC -
New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and
Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent,
Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical
Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC)
No 1907/2006 of the European Parliament and of the Council concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals; SADT - Self-Accelerating Decomposition
Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG -
Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act (United States); UN -
United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous
Goods; vPvB - Very Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous
Materials Information System

Further information
Training advice : Provide adequate information, instruction and training for
operators.

Other information : This product is intended for use in closed systems only.

A vertical bar (|) in the left margin indicates an amendment

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from the previous version.

Due to a change of detail in Section 1, this document has

been released as a significant change.

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text.

PH / EN

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