Naptha: Petroleum Technology 17-03-2021

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Petroleum Technology 17-03-2021

Naptha
• Complex mixture of C5-C13, contains paraffins, oleffins, naphthenes and aromatics,
etc.

• Uses: Commercial solvent, varnish and paint manufacturing, fertilizer feed stock,
feed stock for steam cracker in petrochemical industry producing hydrogen,
methane, ethane, propene, butane, benzene, etc. which are raw material for further
processing

• Light distillate of crude oil, generic name given to light hydrocarbons boiling in
gasoline range of 36-235°C

• Boiling range of various napthas: e.g. C5-85°C, 60-85°C, C5-200°C

• Classification: Light neptha (B.P. < 100°C), Intermediate neptha (100 < B.P. <
150°C) and heavy naptha (B.P. > 150°C)

• Catalytic reforming of neptha yields a C6-C8 reformate rich in aromatic


hydrocarbons (Benzene, toluene, xylene, etc.) with high octane number 93-94,
suitable for gasoline blending

• Fluid catalytic cracking of neptha is used to produce high octane value product (92-
94) for gasoline blending

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Petroleum Technology 17-03-2021

Important characters and tests for Naptha


• Acidity

• Specific gravity

• Sulphur content

• C/H ratio

• Boiling point range

Acidity
• New and used petroleum products may contain acidic constituents present as
additives or as degradation products, such as oxidation products.

• Total acidity is an indication of the corrosive properties of the product.

• Total acidity is measure of combined organic and inorganic acidity.

• Inorganic acid is a measure of mineral acids present. Organic acidity is obtained by


deducting the inorganic acidity from total acidity.

• The acids in sample are extracted in neutral alcohol and then titrated against
standard alcoholic potassium hydroxide under hot conditions.

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Petroleum Technology 17-03-2021

Density and Specific Gravity


• Measured over range of temperatures, usually for convenience at the temperature at
which the fuel is to be stored.

• Specific gravity is the ratio of the density of a fluid to that of water at same
temperature. The temperature usually specified is 15.56°C.

• In USA, specific gravity of an oil is often expressed as ˚API.


.
°API = . ° / . °
− 131.5

• The specific gravity is an indication of the type of the hydrocarbon present, being
highest for aromatic and lowest for paraffins. The API gravity reverses the
relationship.

• The most accurate method of determining the specific gravity of the oil is to weigh a
known volume in a specific gravity bottle at 15.56°C.

• Another method for determining specific gravity of the oil is by means of a set of
hydrometers. A hydrometer is placed in oil sample at 15.56˚C and allowed to come
to rest. The specific gravity is shown on the scale at the point coincident with the
surface of the oil.

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Petroleum Technology 17-03-2021

Gasoline (Motor Spirit)


• One of most widely used petroleum product and light distillate (B.P. = 30-180˚C)

• Prepared by mixing various components (≈ C5-C10) produced from refining process


(e.g. atmospheric distillation, polymerization, alkylation, etc.)

• Constituents: Normal and branched paraffins, cyclo-paraffins, aromatics, olefins

• Isoparffins, cyclo-paraffins, aromatics present in gasoline have good octane


numbers. Minimum octane number reuired for motor gasoline = 87

• Olefins: unstable for storage and having gum forming tendency, Oxidation stability
= 360 minutes

• Total maximum sulphur content = 0.25 wt%, Max lead content: 0.8 g/L

• Primary quality factors required in any spark-ignition engines: Combustion,


volatility and cleanliness

• Use of additives to inhibit knocking, gum formation and icing of carburettor

Volatility Characteristics
• Sufficient volatile fuel, easy starting, rapid warm-up and adequate vaporization for
proper distribution between cylinders
• Not highly volatile to prevent excessive vapour loss from fuel tank and vapour lock
in fuel line

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