SULIT 4541/3

Answer all questions

Jawab semua soalan

1. An experiment to determine the effect of temperature to the rate of reaction is conducted

in laboratory as Diagram 1 below. 2 gram of zinc powder is added to 100 cm 3 of
hydrochloric acid of 0.2 mol dm -3 at room temperature in a conical flask. The hydrogen
gas released is collected in a burette and the time taken to collect 50 cm 3 is recorded.
Satu eksperimen untuk menentukan kesan suhu ke atas kadar tindak balas di jalankan
di dalam makmal seperti Rajah 1 di bawah. 2 gram serbuk zink di tambahkan kepada
100 cm3 asid hidroklorik 0.2 mol dm -3 pada suhu bilik di dalam kelalang kon. Gas
hidrogen yang di bebaskan di kumpulkan di dalam buret dan masa untuk mengumpul
50 cm3 gas di catatkan.

Retort stand
Kaki retort

Burette
100 cm3 of 0.2 moldm-3 Buret
of hydrochloric acid +
Zinc
100 cm3 asid hidroklorik
0.2 mol dm-3 + Zn Water
Air
Basin
Conical flask
Besin
Kelalang kon

Diagram 1 / Rajah 1

Termometer /
Thermometer

100 cm3 asid hidroklorik

0.2 mol dm-3 /
100 cm3 of 0.2 mol dm-3
of sulphuric acid Kelalang kon /
Conical flask
Kasa dawai /
Wire gauze

Tripod stand /
panas kaki segitiga
Heat

Diagram 2 / Rajah 2

4541©2020 Hak Cipta JPNJ

2
SULIT 4541/3

The experiment is repeat by using different temperature of hydrochloric acid. The acid is
heated at 35oC, 40oC, 45oC, 50oC as Diagram 2 above. And the time to collect 50 cm3 of
gas are recorded. Diagram 3 shows the stopwatch for each experiment.
Experiment itu di ulangi dengan suhu asid hidroklorik yang berbeza. Asid tersebut di
panaskan pada suhu 35oC, 40oC, 45oC, 50oC seperti Rajah 2 di atas. Dan masa untuk
mengumpulkan 50 cm3 gas di rekodkan. Rajah 3 menunjukkan jam randik untuk setiap
eksperiment.

Temperature
Exp. Stop watches Reading
Suhu
Eksp. Jam randik Bacaan
/ oC

Room
I temperature. ......................
Suhu bilik

II 35 ......................

4541©2020 Hak Cipta JPNJ

3
SULIT 4541/3

III 40 ......................

IV 45 ......................

V 50 ......................

Table 3
Jadual 3

4541©2020 Hak Cipta JPNJ

4
SULIT 4541/3

(a) Record the time taken to collect 50 cm 3 of hydrogen gas in this experiment in Table
3.
Rekodkan masa yang di ambil untuk mengumpul 50 cm 3 gas hidrogen di dalam
eksperimen ini dalam Jadual 3
[3 marks]

(b) Construct a table to record the time taken to collect 50 cm3 of hydrogen gas in this
experiment
Bina satu jadual dengan merekodkan masa yang di ambil untuk mengumpul 50
cm3 gas hidrogen di dalam eksperimen ini.
[3 marks]

(c) For this experiment, state

Untuk eksperimen ini, nyatakan;

(i) Manipulated variable

Pembolehubah dimanipulasi

………………………………………………………………………………………
(ii) Responding variable
Pembolehubah bergerak balas

………………………………………………………………………………………
(iii) Fixed variables
Pembolehubah dimalarkan

………………………………………………………………………………………
[3 marks]

4541©2020 Hak Cipta JPNJ

5
SULIT 4541/3

(d) State the hypothesis for this experiment

Nyatakan satu hipotesis bagi eksperimen ini.

.................................................................................................................................

.................................................................................................................................

.................................................................................................................................
[3 marks]

(e) State the observations for this experiment.

Nyatakan pemerhatian dalam eksperimen ini.

.................................................................................................................................

.................................................................................................................................
[3 marks]

(f) Based on the observation in question (e), state the inference.

Berdasarkan pemerhatian dalam soalan (e), nyatakan inferens.

.................................................................................................................................

.................................................................................................................................

.................................................................................................................................
[3 marks]

(g) State the relationship between the temperature of hydrochloric acid with the time
taken to collect 50 cm3 of hydrogen gas.
Nyatakan hubungan antara suhu asid hidroklorik dengan masa yang di ambil
untuk mengumpul gas hidrogen.

.................................................................................................................................

.................................................................................................................................

.................................................................................................................................
[3 marks]

(h) State the operational definition for the higher rate of reaction in this experiment.
Nyatakan definisi secara operasi kadar tindak balas yang lebih tinggi dalam
eksperimen ini.

.................................................................................................................................

.................................................................................................................................

.................................................................................................................................
[3 marks]

4541©2020 Hak Cipta JPNJ

6
SULIT 4541/3

(i) Predict the time taken to collect 50 cm 3 of hydrogen gas if the temperature of acid
is 55oC
Ramalkan masa yang di ambil untuk mengumpulkan 50 cm 3 gas hidrogen jika suhu
asid ialah 55oC
[3 marks]

.................................................................................................................................

(j) Given a list of five metals as Diagram 4 below.

Di beri senarai lima logam seperti Rajah 4 di bawah

Copper, Magnesium, zinc, lead, silver

Kuprum, Magnesium, Zink, Plumbum, Argentum

Diagram 4 / Rajah 4

Classify the metals that can reacts with hydrochloric acid to produced constant
hydrogen gas for this experiment and metals that are cannot.
Kelaskan logam yang boleh bertindak balas dengan asid hidroklorik untuk
menghasilkan gas hidrogen yang malar untuk eksperimen ini dan logam yang tidak
boleh
[3 marks]

4541©2020 Hak Cipta JPNJ

7
SULIT 4541/3

2. A conversation between two students is shown in diagram 3 below. They are discussing
about the chemical cell that are done in lab.
Perbualan di antara dua pelajar di tunjukkan seperti Rajah 3 di bawah. Mereka
membincangkan sel kimia yang telah mereka lakukan di makmal.

Diagram 3
Rajah 3

Referring to the diagram, plan a laboratory experiment to investigate the effect of position
of metals in the Electrochemical Series to the voltage produced.
Merujuk kepada rajah di atas, rancang satu eksperimen makmal untuk mengkaji kesan
kedudukan logam yang berlainan di dalam Siri Elektrokimia kepada voltan yang di
hasilkan.

Your planning should include the following aspects:

Perancangan anda hendaklah mengandungi aspek-aspek berikut:

(a) Problem statement

Pernyataan masalah

(b) All the variables

Semua pembolehubah

(c) Statement of the hypothesis

Pernyataan hipotesis

4541©2020 Hak Cipta JPNJ

8
SULIT 4541/3

(d) List of materials and apparatus

Senarai bahan dan radas

(e) Procedure of the experiment

Prosedur eksperimen

(f) Tabulation of data

Penjadualan data
[ 17 marks ]

END OF QUESTION PAPER

KERTAS SOALAN TAMAT

4541©2020 Hak Cipta JPNJ

9
SULIT 4541/3

Marking Scheme Paper 3 Set 2 Year 2020

Skema Pemarkahan Kertas 3 Set 2 Tahun 2020

Question Suggestion answer Marks

Soalan Cadangan jawapan Markah
Able to record the reading of stopwatch correctly in one decimal places
Dapat membaca jam randik dengan betul dalam satu tempat perpuluhan
berserta unit yang betul

Experiment Time / s
Eksperimen Masa / s

I 58.5
1 (a) II 43.0 3

III 32.5

IV 19.0

V 8.0

One mistake in recording of data such as unit, reading and decimal

places
2
Satu kesilapan dalam merekodkan data seperti unit, bacaan dan titik
perpuluhan

Two mistakes in recording of data such as unit, reading and decimal

places 1
Dua kesilapan dalam jadual seperti unit, bacaan dan titik perpuluhan

More than two mistakes

0
Lebih dari tiga kesilapan salah

Question Suggestion answer Marks

Soalan Cadangan jawapan Markah
Able to construct table correctly with correct unit
Dapat membina jadual dengan lengkap berserta unit yang betul

Experiment Temperature / oC Time / s

Eksperimen Suhu / oC Masa / s

I 30 58.5

1 (b) II 35 43.0 3

III 40 32.5

IV 45 19.0

V 50 8.0

4541©2020 Hak Cipta JPNJ

10
SULIT 4541/3

One mistake in table such as, unit, reading, construction of table and
decimal places
2
Satu kesilapan dalam jadual seperti unit, bacaan, pembinaan jadual dan
titik perpuluhan
Two mistake in table such as, unit, reading, construction of table and
decimal places 1
Dua kesilapan dalam jadual seperti unit, bacaan dan titik perpuluhan
More than two mistakes
0
Lebih dari tiga kesilapan salah

Question Suggestion answer Marks

Soalan Cadangan jawapan Markah

All correct variables given are correct

Semua pemboleh ubah di berikan adalah betul

(a) Manipulation : Temperature of acid

1 (c) Manipulasi : Suhu asid 3
(b) Responding : Rate of reaction // Time taken to collect gas
Bergerak balas : Kadar tindak balas // Masa mengumpulkan gas
(c) Constant : Concentration and volume of acid // size of zinc
Di malarkan : Kepekatan dan isipadu asid // saiz zink

One mistake in variable

2
Satu kesilapan dalam pembolehubah
Two mistakes in variables
1
Dua kesilapan dalam pembolehubah
More than two mistakes
0
Lebih dari dua kesilapan

Question Suggestion answer Marks

Soalan Cadangan jawapan Markah
Able to state the hypothesis correctly
Dapat menyatakan hipotesis dengan betul
1 (d) 3
The higher the temperature of acid the higher the rate of reaction
Semakin tinggi suhu asid semakin tinggi kadar tindak balas

Slight mistakes in hypothesis

Sedikit kesilapan dalam hipotesis
2
The higher the temperature the higher the rate of reaction
Semakin tinggi suhu semakin tinggi kadar tindak balas

Idea of hypothesis is given

Idea hipotesis di berikan 1

4541©2020 Hak Cipta JPNJ

11
SULIT 4541/3

Rate of reaction depends on the temperature of acid // The higher the

rate of reaction the higher the temperature
Kadar tindak balas bergantung kepada suhu asid // semakin tinggi kadar
tindak balas semakin tinggi suhu asid

Wrong response
0
Respons yang salah

Question Suggestion answer Marks

Soalan Cadangan jawapan Markah

Able to give correct observation

Dapat menyatakan pemerhatian dengan betul
(e) 3
Bubbles of gas is released
Gelembung gas di bebaskan
Slight mistake in observation
Sedikit kesilapan pada pemerhatian
2
Bubbles of gas
Gelembung gas

Idea of observation given

Idea pemerhatian di berikan
1
Hydrogen gas is released
Gas hidrogen di bebaskan

Wrong response
0
Respons yang salah

Question Suggestion answer Marks

Soalan Cadangan jawapan Markah

Able to state the inference correctly

Dapat menyatakan inferens dengan betul
(f) 3
Acid reacts with zinc to produced hydrogen gas
Asid bertindak balas dengan zink menghasilkan gas hidrogen

Slight mistake in inference

Sedikit kesilapan pada inferens
2
Hydrogen gas is produced
Hidrogen gas di bebaskan

4541©2020 Hak Cipta JPNJ

12
SULIT 4541/3

Idea of inference is given

Idea inferens di berikan
1
Gas is released
Gas di bebaskan

Wrong response
0
Respons yang salah

Question Suggestion answer Marks

Soalan Cadangan jawapan Markah
Able to give relationship correctly
Dapat memberikan hubungan yang betul

The higher the temperature of hydrochloric acid the shorter the time
(g) 3
taken to collect 50 cm3 of hydrogen gas
Semakin tinggi suhu asid hidroklorik semakin singkat masa yang di
ambil untuk mengumpul gas hidrogen.

Slight mistake in relationship

Sedikit kesilapan dalam hubungan

The higher the temperature of hydrochloric acid the lower the time
2
taken to collect 50 cm3 of hydrogen gas
Semakin tinggi suhu asid hidroklorik semakin rendah masa yang di
ambil untuk mengumpul gas hidrogen.

Relationship written in the opposite or wrong manner / Idea of

relationship
Hubungan tersalah atau terbalik di tuliskan / Idea hubungan

The higher the temperature of hydrochloric acid the longer / higher 1

the time taken to collect 50 cm3 of hydrogen gas
Semakin tinggi suhu asid hidroklorik semakin panjang / higher
masa yang di ambil untuk mengumpul gas hidrogen

Wrong response
0
Respons yang salah

Question Suggestion answer Marks

Soalan Cadangan jawapan Markah

Able to give correct operational definition

Dapat memberikan operasi secara definisi dengan betul

When zinc is added to hydrochloric acid in different temperature, the

(h) 3
shortest time to collect 50 cm3 of gas have the highest rate of reaction
Apabila zink di masukkan ke dalam asid hidroklorik pada suhu yang
berlainan, masa yang paling singkat untuk mengutip 50 cm3 gas hidrogen
adalah yang paling tinggi kadar tindak balasnya.

4541©2020 Hak Cipta JPNJ

13
SULIT 4541/3

Slight mistake in operational definition

Sedikit kesilapan pada operasi secara definisi

When zinc is added to hydrochloric acid in different temperature, the

2
shortest time to collect 50 cm3 of gas is the highest rate of reaction
Apabila zink di masukkan ke dalam asid hidroklorik pada suhu yang
berlainan, masa yang paling singkat untuk mengutip 50 cm3 gas
hidrogen adalah yang paling tinggi kadar tindak balasnya.
Idea of operational definition / Part of operational definition given
Idea operasi secara definisi di berikan / Sebahagian dari operasi secara
define di berikan.

Zinc is added to hydrochloric acid // highest rate of reaction is 1

experiment with 50oC // shorter time to collect gas
Zink di tambahkan kepada asid // kadar tindak balas paling tinggi
menggunakan suhu paling tinggi // masa yang di ambil paling cepat

Wrong response
0
Respons yang salah

Question Suggestion answer Marks

Soalan Cadangan jawapan Markah

Correct answer with correct unit and decimal places

Jawapan di berikan betul serta unit dan titik perpuluhan juga betul
(i) 3
[3 – 6] saat

One mistake in predicting of data such as unit, reading and decimal

places
2
Satu kesilapan dalam meramal seperti unit, bacaan dan titik perpuluhan

Two mistakes in predicting such as unit, reading and decimal places

Dua kesilapan dalam meramal seperti unit, bacaan dan titik perpuluhan 1

More than two mistakes

Lebih dari tiga kesilapan salah 0

Question Suggestion answer Marks

Soalan Cadangan jawapan Markah
Able to classify correctly
Dapat mengelaskan dengan betul

metals that can react with metals that cannot react with
HCL HCL
(j) 3
logam yang boleh bertindak logam yang tidak boleh
balas dengan HCl bertindak balas dengan HCl

lead
Magnesium
Plumbum

4541©2020 Hak Cipta JPNJ

14
SULIT 4541/3

zinc silver
zink Argentum

Copper
Kuprum

One mistake
2
Satu kesilapan
Two mistake
1
Dua kesilapan

More than two mistakes

0
Lebih dari dua kesilapan

4541©2020 Hak Cipta JPNJ

15
SULIT 4541/3

Question Suggestion answer Marks

Soalan Cadangan jawapan Markah

Able to state correct problem statement

Dapat memberikan pernyataan masalah dengan betul

2(a) What is the effect of position of metals in Electrochemical Series 3

to the voltage produced?
Apakah kesan kedudukan logam di dalam Siri Elektrokimia kepada
voltan yang dihasilkan?

Slight mistake in problem statement

Sedikit kesilapan pada pernyataan masalah

What is the effect of position of metals to the voltage produced? //

Does the position of metal influence the voltage produced? 2
Apakah kesan kedudukan logam kepada voltan yang dihasilkan?
// Adakah kedudukan logam mempengaruhi voltan yang di
hasilkan?

Able to give idea of problem statement // Statement not in a

question form.
Idea pernyataan masalah di berikan // Pernyataan bukan dalam
bentuk soalan
1
The position of metal influences the voltage produced.
Kesan kepekatan larutan natrium klorida ke atas hasilan
elektrolisis di anod

Wrong response
0
Respons yang salah

Question Suggestion answer Marks

Soalan Cadangan jawapan Markah
Able to list the correct variables
Dapat memberikan pembolehubah dengan betul

Manipulative : Metal
Manipulasi : Logam
2(b) 3
Responding : Product at negative terminal
Bergerak balas : Hasilan di terminal negatif

Constant : Type of electrolyte

4541©2020 Hak Cipta JPNJ
16
SULIT 4541/3

Di malarkan : jenis elektrolit

One mistake
2
Satu kesilapan

Two mistakes
1
Dua kesilapan

Wrong response
0
Respons yang salah

Question Suggestion answer Marks

Soalan Cadangan jawapan Markah

Able to give hypothesis correctly

Dapat memberikan hipotesis dengan betul

The further the distance between metals in Electrochemical series

2(c) the higher the voltage // The higher the position of metal in 3
Electrochemical Series the higher the voltage
Semakin jauh kedudukan logam dalam Siri Elektrokimia semakin
tinggi voltan di hasilkan // Semakin tinggi kedudukan logam dalam
Siri Elektrokimia semakin tinggi nilai voltan

Slight mistake in hypothesis

Sedikit kesilapan pada hipotesis

The further the distance between metals the higher the voltage //
The higher the position of metal in the higher the voltage 2
Semakin jauh kedudukan logam dalam semakin tinggi voltan di
hasilkan // Semakin tinggi kedudukan logam dalam semakin tinggi
nilai voltan

Idea of hypothesis is given

Idea hipotesis di berikan

The higher the voltage the further the distance between metals in
Electrochemical series // The higher the voltage the higher the 1
position of metal in Electrochemical Series
Semakin tinggi voltan di hasilkan semakin jauh kedudukan logam
dalam Siri Elektrokimia // Semakin tinggi nilai voltan semakin
tinggi kedudukan logam dalam Siri Elektrokimia
Wrong respons
0
Respons yang salah

4541©2020 Hak Cipta JPNJ

17
SULIT 4541/3

Question Suggestion answer Marks

Soalan Cadangan jawapan Markah

Able to give all the list of apparatus and material

Dapat memberikan alat radas dan bahan dengan betul

Apparatus:
Beaker, connecting wire, battery, sandpaper, voltmeter
Materials:
[0.1 – 2.0] mol dm-3 of copper (II) sulphate solution, copper,
(d) magnesium, zinc, tin, lead 3

Alat radas:
Bikar, rod karbon, dawai penyambung, bateri, kertas pasir,
voltmeter
Bahan :
Larutan kuprum (II) sulfat [0.1 – 2.0] mol dm-3, kuprum,
magnesium, zink, stanum, plumbum

One mistake
2
Satu kesilapan
Two mistakes
1
Dua kesilapan
Wrong response
0
Respons yang salah

Question Suggestion answer Marks

Soalan Cadangan jawapan Markah
Able to write a correct procedure
Dapat memberikan prosedur dengan betul

1. Pour 0.5 mol dm-3 of copper (II) sulphate solution into a beaker
Tuangkan 0.5 mol dm-3- larutan kuprum (II) sulfat ke dalam
sebuah bikar

2. Clean magnesium ribbon with sandpaper

Bersihkan pita magnesium dengan kertas pasir
(e) 3
3. Connect the magnesium ribbon and copper strip to the battery
Sambungkan pita magnesium dan kepingan kuprum kepada
bateri

4. Dip magnesium and copper into copper (II) sulphate solution

Celup magnesium dan kuprum ke dalam larutan kuprum (II)
sulfat

4541©2020 Hak Cipta JPNJ

18
SULIT 4541/3

5. Determine the negative terminal

Tentukan terminal negatif

6. Record the voltmeter reading

Rekodkan bacaan voltmeter

7. Repeat experiment by using zinc, tin and lead to replace

magnesium
Ulangi eksperimen dengan zink, stanum dan plumbum untuk
menggantikan magnesium.

One mistake
2
Satu kesilapan
Two mistakes
1
Dua kesilapan
Wrong response
0
Respons yang salah

Question Suggestion answer Marks

Soalan Cadangan jawapan Markah
Able to draw suitable table
Dapat memberikan penjadual data dengan sesuai

Voltmeter
Negative
Type of metal readings / v
terminal
Jenis logam Bacaan
Terminal negatif
voltmeter / v

(f) Mg 3

Zn

Sn

Pb

One mistake in tabulation of data example unit and line

2
Satu kesilapan pada jadual seperti unit dan garisan jadual
Two mistakes in tabulation of data example unit and line
1
Dua kesilapan pada jadual seperti unit dan garisan jadual
More than two mistakes
0
Lebih dari dua kesilapan

4541©2020 Hak Cipta JPNJ

19