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Iodometric Titration

The document describes the process of iodometric titration. Iodometric titration involves titrating a standardized iodine solution with a reducing agent, and only one redox reaction occurs. Iodometry, on the other hand, is an indirect titration that involves reacting the sample with iodide to form iodine, then titrating the iodine with a reducing agent like thiosulfate. Starch indicator is added at the endpoint to detect when the colorless iodide forms. The document also provides objectives, materials, methodology, results, and treatment of results for standardizing a sodium thiosulfate solution using iodometric titration.

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761 views30 pages

Iodometric Titration

The document describes the process of iodometric titration. Iodometric titration involves titrating a standardized iodine solution with a reducing agent, and only one redox reaction occurs. Iodometry, on the other hand, is an indirect titration that involves reacting the sample with iodide to form iodine, then titrating the iodine with a reducing agent like thiosulfate. Starch indicator is added at the endpoint to detect when the colorless iodide forms. The document also provides objectives, materials, methodology, results, and treatment of results for standardizing a sodium thiosulfate solution using iodometric titration.

Uploaded by

Capsanne
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Iodometric Titration

ORAL REPORT
GROUP 9
GROUP 10
Introduction
Iodimetric Titration is a volumetric analysis that involves a
standardized solution of iodine. It is a direct method used to quantify
reducing agents and only one redox reaction is observed in this
titration.

Iodometric Titration is a quantitative analysis in which excess iodide


is reacted to an oxidizing agent and forms iodine. This kind of
reaction normally happens with a weak acidic or neutral medium and
is an indirect method that involves 2 reactions. The iodine then
reacts with a titrant such as a standard thiosulfate (Na2S2O3). It is
generally used to determine the concentration of an oxidizing agent
in a solution. A starch solution is then used as an indicator because
of its ability to absorb the iodine released from the reaction.
Objectives
Understand the
concept of iodometric
titration and the
difference between
iodometry and
iodimetry

Standardize a
Learn the concept of solution of sodium
redox reactions and thiosulfate and
how it was utilized in determine its
the titration concentration
Materials
● Funnel ● Graduated Pipette

● Sodium Thiosulfate ● Plastic Dropper

● Potassium Iodide ● Beaker

● Iodine

● Starch

● Glass Bottles

● Burret (50mL)

● Conical Flask (250mL)


CHEMICAL HAZARD RISK ASSESSMENT
CHEMICAL HAZARD RISK ASSESSMENT
Methodology
The burette was washed with distilled water twice
Methodology
The burette was washed with with Na2S2O3 once
Methodology
The burette was filled with Na2S2O3 solution
Methodology
25 mL of the I2/KI solution was transferred into a 250-mL conical flask
using a bulb or graduated pipette
Methodology
Na2S2O3 solution was added gradually into the conical flask while
continuous shaking.
Methodology
5 drops of starch indicator was added using plastic
dropper and the flask was swirled
Methodology
Na2S2O3 solution was added again in the burette
Methodology
Na2S2O3 was added drop by drop with continuous
shaking
Methodology
Schematic Diagram
Methodology
Set-up
Trial 1 Trial 2

Results Final volume of Na₂S₂O₃


(mL)
12.5 12.5

Initial volume of Na₂S₂O₃ 0.00 0.00


Calculation for the Volume of Na₂S₂O₃ Used: (mL)

Volume of Na₂S₂O₃ used 12.5 12.5


(mL)
Calculation for the Moles of I₃⁻ :
Volume of Standard I₂/KI 25.00 25.00
(mL)

Concentration of Standard 0.5000 0.5000


(M)

Mole of I₃⁻ (mol) 0.01250 0.01250


Calculation for the Moles of Na₂S₂O₃ :
Mole of Na₂S₂O₃ (mol) 0.02500 0.02500

Molarity of Na₂S₂O₃ (M) 2.00 2.00

Na₂S₂O₃ (mg/mL) 316 316


Results
Trial 3

Final volume of Na₂S₂O₃ (mL) 12.6

Calculation for the Volume of Na₂S₂O₃ Used:


Initial volume of Na₂S₂O₃ (mL) 0.00

Volume of Na₂S₂O₃ used (mL) 12.6


Calculation for the Moles of I₃⁻ :

Volume of Standard I₂/KI (mL) 25.00

Concentration of Standard (M) 0.5000

Mole of I₃⁻ (mol) 0.01250


Calculation for the Moles of Na₂S₂O₃ :
Mole of Na₂S₂O₃ (mol) 0.02500

Molarity of Na₂S₂O₃ (M) 1.98

Na₂S₂O₃ (mg/mL) 314


Treatment of Results
Calculations

Determination of the sodium thiosulfate concentration in M and mg/mL


Treatment of Results
Why is the starch solution added right before the endpoint
and not at the beginning of the titration?

- Color change of the starch indicator is not visible


when iodine solution is in high concentration

- High concentration of iodine will strongly bond with


the starch (starch-iodine complex)

- At the actual titration, in which the iodine solution


turns pale yellow because of the sodium thiosulfate
decreasing its concentration, the color change from
pale yellow to a colorless solution is not sharp
Direct vs. Indirect Titration
- Direct Titration is the basic method of titration.

- The titrant is directly added to the analyte.

- The endpoint of the reaction indicates the end of the


reaction.
Direct vs. Indirect Titration
- Indirect titration is also known as Back-titration.

- The analyte is reacted with an excess reagent with a


known concentration

- The resulting solution will be back-titrated.

- The concentration of the excess reagent is required in


the calculations.

- The endpoint of this method is easier to observe than


that of the direct titration.
Iodimetry
- Uses direct titration method that lets the standard
iodine solution directly titrated with a reducing
analyte.

- Iodine acts as the oxidizing agent as it gets reduced


during the reaction.

- There’s only one redox reaction involved in this


method.
Iodometry
- Uses indirect titration method or back-titration

- There are two redox reactions occurring in this


method

- The sample of a water that needs to be analyzed is


mixed with the iodide solution

- First Redox reaction: The water sample causes the


iodide solution to be oxidized to iodine and the
oxidizing agents are reduced.

- The iodine solution is then titrated with reducing


agents (Sodium Thiosulfate)

- Second Redox reaction: The iodine is reduced to


Iodide Ions while thiosulfate ions are oxidized further.
Iodometry

- Titration happens after the second redox reaction

- Starch is used an indicator

- Resulting to deep-blue solution

- The color disappears when the iodine is converted


back to iodide ions
HOw many electrons are involved
in the ff reactions?
HOw many electrons are involved in the ff reactions?

Electrons involved: 16
HOw many electrons are involved
in the ff reactions?
HOw many electrons are involved
in the ff reactions?

Electrons involved: 2
References

Madhusha (2017). Difference Between Back Titration and Direct Titration. Retrieved
from https://pediaa.com/difference-between-back-titration-and-direct-titration/

PEDIAA (2015). Difference Between Iodometry and Iodimetry. Retrieved from


https://pediaa.com/difference-between-iodometry-and-iodimetry/

ScienceStruck. (n.d.). Back Titration. Retrieved from


https://sciencestruck.com/back-titration

Titrations.info. (2014). Iodometric titration end point detection. Retrieved from


http://www.titrations.info/iodometric-titration-end-point-detection

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