Taller 2 Separativas

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x mol Abs 9 10 Patron µg/mL Areas

0.2 0.032 Abs 0.116 5 0.0705


0.5 0.081 10 0.1743
1.3 0.206 20 0.3152
3.12 0.495 30 0.4953
7.81 0.703 40 0.7146
50 0.873
coef corr. 0.95326432 60 1.0642
pendiente 0.08724881
b 0.07777457
Conc. mM 0.44 R 0.99903
m 0.01804 1.200
0.8 Abs b -0.02434
1.000 f(x
0.7 f(x) = 0.087248812940628 x + 0.077774569735537 Abs 0.51360 R²
0.6 R² = 0.908712871903897 0.800
0.5 0.5379 0.600
0.4
[Cont] 29.0 0.400
0.3
0.2 0.200
0.1
0 0.000
0 1 2 3 4 5 6 7 8 9 0 1

Abs Linear (Abs)

12
A B C D E F
M. Probl. mL 25 25 25 25 25 25
dsln Patron mL 0 1 2 3 4 5
Dsln precip. mL 1 1 1 1 1 1
H 120 204 318 525 657 874
[Patron] ppm 0 2 4 6 8 10
r 0.98991069
b 68.5238095
m 76.2285714 H
900
[Analito] 1,79 ppm 800 f(x) = 76.2285714285714 x + 68.5238095238096
700 R² = 0.979923174311531
600
500
400
300
200
100
0
0 2 4 6 8 10 12
Areas promedio 11 Zn (ppm) Area
0.0703 0.0707 0.071 0 0
0.1742 0.1743 0.174 0.01 0.002
0.3155 0.3157 0.315 0.025 0.006
0.4959 0.4959 0.496 0.05 0.01
0.7144 0.715 0.1 0.019
0.8729 0.8728 0.873 0.15 0.027
1.064 1.0644 1.064 0.2 0.036
0.25 0.045

R 0.9994573
Areas m 0.17716387
0.05
1.200 f(x) = 0.1771638
b 0.00074080.04 R² = 0.99891490
1.000 f(x) = 0.018036704438149 x − 0.024336874409821 0.03
R² = 0.998054504316871
0.800 Area-b 0.02
0.600 0.0152592 0.01
0.400 0.0292592
0
0.0072592 0 0.05
0.200
0.0392592
0.000
0 10 20 30 40 50 60 70 0.0022592
Areas
Linear
(Areas)

13
sln dsl fenob mL pt fenob mL fluorometrica
1 5 0 3.26 fluorometrica
2 5 0.5 4.8
12
3 5 1 6.41
4 5 1.5 8.02 10
5 5 2 9.56 f(x) = 3.164 x + 3.246
8 R² = 0.999921691464369

Aforo/mL 50 [paton µg/mL] 2


6

r 0.99996084
4
m 3.164
b 3.246 2

[FB] 4.10E-01 0
0 0.5 1 1.5 2
Muestras Area [Zn]
de grifo 0.016 0
de rio 0.03
de pozo 0.008
residual 0.04
de mar 0.003

Area
0.05

0.04 f(x) = 0.177163866619006 x + 0.00074079558801


R² = 0.998914904192908
0.03

0.02
0.01

0
0 0.05 0.1 0.15 0.2 0.25 0.3

Area Linear (Area)

etrica

1.5 2 2.5
h v mL/min H-A
6.768 5 5.118 A 1.65
3.886 10 2.236 B 25.8
C
3.122 20 1.472 C 0.0236 8

2.358 30 0.708 B/V C*V 7


2.594 40 0.944 5 0.118 6
2.83 50 1.18 2 0.236 5
3.066 60 1.416 1 0.472 4
3.302 70 1.652 0 0.708 3
3.538 80 1.888 0 0.944 2
3.774 90 2.124 0 1.18 1
4.01 100 2.36 0 1.416 0
0 20 40
4.246 110 2.596 0 1.652
4.482 120 2.832 0 1.888 colu
0 2.124
6
0 2.36
0 2.596 5
0 2.832 4

0
0 20 40
CHCl2Br h
2 0.145 2.79
Chart Title 0.472 6.83
8 0.951 11.68
7 1.757 22.43
6 2.901 32.97
5
4
3
2
1
0
0 20 40 60 80 100 120 140

columna tobular
6

0
0 20 40 60 80 100 120 140
ChClBr2 h 1,2dibromopenteno
0.251 1.3 3.84 MeOH mL 5
0.504 2.38 2.75
1.008 4.56 2.36
2.004 9.96 2.06
3.009 13.8 1.62

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