Reactors: Mode of Operation 1. Single Phase 2. Multi Phase Phases Based Classification Catalyst Base End Use Application

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Reactors are vessels designed to contain

chemical reactions.

Reactors

Phases
Mode of End use based Catalyst
Operation application Classification Base
1. Polymerization 1. Single
1. Batch reactors
phase 1. Homogenous
2. Continuous 2. Biological reactors
2. Multi 2. Heterogeneous
3. Electrochemical
3. Semi-batch
reactors phase 1
Classification by Mode of Operation

1. Batch Reactors
• A “batch” of reactants is introduced into the reactor
operated at the desired conditions until the target
conversion is reached.
• Batch processes are suited to small production
rates, too long reaction times, to achieve desired
selectivity, and for flexibility in campaigning different
products.
Applications of Batch reactor
• Soap manufacture
• Waste water treatment
• Fermentation process
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Classification by Mode of Operation
1. Batch Reactors

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Classification by Mode of Operation

2. Continuous Reactors
• Reactants are added and products removed
continuously at a constant mass flow rate. Large
daily production rates are mostly conducted in
continuous equipment.
• Continuous Reactors:
A. CSTR
B. Plug Flow Reactor
C. Tubular flow reactor

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2. Continuous Reactors

A. Continuous Stirred Tank Reactor (CSTR)


• It is a vessel to which reactants are added and
products removed while the contents within the
vessel are vigorously stirred using internal agitation
or by internally (or externally) recycling the contents.
• Continuous stirred-tank reactors are most commonly
used in industrial processing, primarily in
homogeneous liquid-phase flow reactions, where
constant agitation is required.
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2. Continuous Reactors
A. Continuous Stirred Tank Reactor (CSTR)

Advantages/Disadvantages of
CSTR
• Good temperature control is
easily maintained
• Cheap to construct
• Reactor has large heat capacity
• Interior of reactor is easily
accessed
Disadvantage:
• Conversion of reactant to product
per volume of reactor is small
compared to other flow reactors
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2. Continuous Reactors

B. Plug Flow Reactor (continuous tubular reactor)


Plug flow, or tubular, reactors consist of a hollow
pipe or tube through which reactants flow.
Water at a controlled temperature is circulated
through the tank to maintain constant reactant
temperature.

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2. Continuous Reactors

B. Plug Flow Reactor (continuous tubular reactor)

Plug flow reactors have a wide


variety of applications in either gas or
liquid phase systems.
Common industrial uses of tubular
reactors are in gasoline production,
oil cracking, synthesis of ammonia
from its elements, and the oxidation
of sulphur dioxide to sulphur trioxide.

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2. Continuous Reactors

C. Tubular Flow Reactor


• A tubular flow reactor (TFR) is a tube (or pipe)
through which reactants flow and are converted
to product.
• Generally used for gaseous reactions but are
also suitable for some liquid-phase reactions.

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2. Continuous Reactors

C. Tubular Flow Reactor

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Classification by Mode of Operation

3. Semi Batch Reactor


Some of the reactants are loaded into the reactor, and
the rest of the reactants are fed gradually. Alternatively,
one reactant is loaded into the reactor, and the other
reactant is fed continuously.
• Neither batch or continuous, may be combination of
both.

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Semi-batch reactor 11
Continuous Process Batch Process

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