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    Chemical Kinetics Num

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    VANESSA JOHNS CLASS XI
    1. For a first-order reaction, the time required for 99.9% completion is equal to the half-life. The half-life is the time required for the concentration to reduce to half of its initial value. 2. Reaction kinetics experiments provide data about changes in concentrations of reactants and products over time. This data can be used to determine the rate law, rate constant, order of reactions, and activation energy of reactions. 3. Common reaction orders include zero order, first order, and second order reactions. The rate of a reaction depends on the concentrations of reactants raised to their order in the rate law.

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    Chemical Kinetics Num

    Uploaded by

    VANESSA JOHNS CLASS XI
    55 views3 pages
    1. For a first-order reaction, the time required for 99.9% completion is equal to the half-life. The half-life is the time required for the concentration to reduce to half of its initial value. 2. Reaction kinetics experiments provide data about changes in concentrations of reactants and products over time. This data can be used to determine the rate law, rate constant, order of reactions, and activation energy of reactions. 3. Common reaction orders include zero order, first order, and second order reactions. The rate of a reaction depends on the concentrations of reactants raised to their order in the rate law.

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    1. For a first-order reaction, the time required for 99.9% completion is equal to the half-life. The half-life is the time required for the concentration to reduce to half of its initial value. 2. Reaction kinetics experiments provide data about changes in concentrations of reactants and products over time. This data can be used to determine the rate law, rate constant, order of reactions, and activation energy of reactions. 3. Common reaction orders include zero order, first order, and second order reactions. The rate of a reaction depends on the concentrations of reactants raised to their order in the rate law.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    55 views3 pages

    Chemical Kinetics Num

    Uploaded by

    VANESSA JOHNS CLASS XI
    1. For a first-order reaction, the time required for 99.9% completion is equal to the half-life. The half-life is the time required for the concentration to reduce to half of its initial value. 2. Reaction kinetics experiments provide data about changes in concentrations of reactants and products over time. This data can be used to determine the rate law, rate constant, order of reactions, and activation energy of reactions. 3. Common reaction orders include zero order, first order, and second order reactions. The rate of a reaction depends on the concentrations of reactants raised to their order in the rate law.

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    of 3

    CHEMICAL KINETICS

    1 For a reaction A → B , the concentration of the reactant changes from 0.03 M to


    0.02 M in 25 minutes. Calculate the average rate i) minutes ii) seconds
    2 In a reaction , 2A → Products, the concentration of A decreases from 0.5 mol/l/s
    to 0.4 mol/l in 10 min. Calculate the rate of the reaction
    0.005mol/L/min
    3 For a reaction , 2I─ + Cl2 → I2 + 2Cl─ , initial concentration of I─ was
    0.8mol/L. Calculate a) rate of disappearance of I─ b) rate of appearance of I2
    ( .006, .003)
    4 For a reaction A → B , rate constant is 2x10-3 mol/L/s. Calculate the rate of
    reaction if concentration of A is 0.1mol/L/s.
    (0.0025)
    5 Rate of formation of a dimmer in a second order dimerisation is 9.5x10-5 mol/L/s.
    At 0.01mol/L monomer concentration, calculate the rate constant.
    (0.95)
    6 For a reaction, 2A + B + C → A2B + C, the rate law is , r = k[A][B]2
    k= 2x10-5 mol-2L2s-1. Determine the rate of the reaction when [A] =0.1, [B] = 0.2,
    [C] = 0.6 mol/L. Also determine the rate when 0.06 mol of A has reacted.
    ( 8x10-8,
    -3
    2.3x10 )
    7 For a reaction, 2A + B → A2B the rate law is , r = k[A][B]2 k= 2x10-6 mol-
    2 2 -1
    L s . Determine the rate of the reaction when concentration of A is reduced to
    0.06 mol/L ( 3.89x10-9
    )

    8 For a reaction, 2A + B → C, the data are as follows


    Expt [A } [B] Initial rate
    1 0.2 0.3 5.07x10-5
    2 0.2 0.1 5.07x10-5
    3 0.4 0.05 7.16 x10-5
    What is the order with respect to A and B?. A = 0, B =
    0.5
    9 For a reaction, 2A + B → C, the data are as follows
    Expt [A } [B] Initial rate
    1 0.1 0.1 6x10-3
    2 0.3 0.2 7.2x10-2
    3 0.3 0.4 2.88 x10-1
    What is the rate law? Also calculate the rate of reaction when [A] = 0.2
    [B] = 0.2mol r = k[A][B]2 ,
    -2
    4.8x10

    10 The rate of reaction, 2NO + Cl2 → 2NOCl, is doubled when the concentration of
    Cl2 is doubled and it becomes 8 times when concentration of both NO and Cl2 are
    doubled. Deduce the order of the reaction. r=
    2
    k[NO] [Cl2]
    11 The pressure of a gas decomposing at surface of a solid catalyst has been
    measured at different times;
    Time 0 100 200 300

    Pressure(atm) 4x103 3.5x103 3x103 2.5x103


    Determine the order of reaction and also the half life. (zero, 8x102)

    12 Show that t99.9 = t1/2 for first order reaction


    13 Show that t3/4 = 2 t1/2 for first order reaction
    14 The rate constant of a first order reaction is 60 s-1. How much time will it take to
    reduce the initial concentration of the reactant to its 1/16 value. ( 4.6x10-2 )
    15 A first order reaction is 20% complete in 10 min. How much time does it take for
    75% completion, 62.2
    16 SO2Cl2 → SO2 + Cl2 is a first order reaction. k = 2.2x10 s . What % of the
    -5 -1

    initial concentration will get decomposed in 90 minutes. ( 11.2%)


    17 Consider a reaction A → B with k =2x10 s . Calculate the concentration of A
    -2 -1

    remaining after 100 s if the initial concentration A is 1.0 mol/L


    18 Show that t99.9 = 2 t90 for first order reaction
    19 During nuclear explosion, one of the products is 90Sr with half life of 28.1years. If
    1micro gram of 90Sr was absorbed in the bones of a newly born baby, how much it
    will remain after 60 years. 0.784
    20 The following data were obtained during the first order thermal decomposition of
    N2O5 2N2O5 → 2 N2O4 + O2
    Ext time/s Total pressure
    1 0 0.5
    2 100 0.512
    Calculate the rate constant 4.98x10-4 s-1
    21 The decomposition of azoisopropane to hexane and nitrogen the data is as follows
    (CH3)2 CHN=NCH (CH3)2 → N2 + C6H6
    Time/s Pressure (mmhg)
    0 35
    360 54
    720 63
    Calculate the rate constant 2.2x10 -3 s-1
    22 The rate constant of reaction quadruples when temperature changes from 293 K to
    313K. Calculate the activation energy. 52.8kJ/mol
    23 For a raction, Ea is zero. What is the value of rate constant at 300K if k = 1.6x106
    s-1 at 280K
    1.6x106 s-1
    24 The slope of a plot of logk vs 1/T is -5300K. Calculate the activation energy.
    101.478
    kJ/mol
    25 At 300K, a certain reaction is 50% complete in 20 min. At 350K , the same
    reaction is 50% complete in 5 min. Calculate the activation energy.
    24.2kJ/mol
    26 The rate constant of a reaction is 4.5x103 s-1 at 10oC and energy of activation is
    60kJ/mol.At what temperature would k be 1.5x104 s-1 297
    27 The rate constant of a first order reaction at600K is 1.6x10-5s-1. Its activation
    energy 209kJ. Calculate the rate constant at 700K. 6.36x10-
    3

    28 Ea of reaction 2HI → H2 + I2 is 209.5kJ/molat 581K. Calculate the fraction of the


    molecules of the reactant having energy greater than activation energy. 1.471x10-
    19

    29 Rate constant of a reaction 2.418x10-5 s-1 at 546K. If the activation energy is


    179.9 kJ/mol, calculate the pre exponential factor.
    3.9x1012 s-1
    30 The rate constants at 700K and 760K are 0.011s-1 0.105 s-1 respectively. Calculate
    the value of Arrhenius factor. Ea = 166.35kJ/mol, 2.8x1010
    s-1

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