Crude Oil: Safety Data Sheet

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Safety Data Sheet Date of issue: 03/17/2020

According to NOM-018-STPS-
2015 Version: 1.0

CRUDE OIL
SECTION 1: Identification of the hazardous chemical or mixture and of the supplier or
manufacturer
1) Name of the hazardous chemical or mixture: Crude oil
2) Other means of identification:
Chemical name: Petroleum
IUPAC name: Crude oil
CAS Number: 8002-05-9
3) Recommended use of the chemical or mixture and restrictions on use:
Raw material for chemical industries.
Recommended use are listed above; other uses are not recommended unless an assessment has
provided that risks are controlled.
4) Supplier or manufacturer details:
Mizamtec Operating Company, S. de R.L. de C.V.
Av. Paseo de las Palmas 425
Col. Lomas de Chapultepec
Alcaldía Miguel Hidalgo
C.P.: 11000 - Mexico City
Contact:
Francisco Vacas
Phone: +52 5531484577
MAIL Address: Francisco.Vacas@eni.com
5) Telephone number in case of emergency:
CENACOM: 01 800 00 41 300 (24 h)
COATEA: 01 800 710 49 43

SECTION 2: Hazard identification


1) Classification of the hazardous chemical or mixture:
Flammable liquids, Category 1
Aspiration hazard, Category 1
Eye irritation, Category 2A
Carcinogenicity, Category 1B
Specific target organ toxicity - Single exposure, Category 3
Specific target organ toxicity - Repeated exposure, Category 2
2) Label elements, including precautionary statements and hazard pictograms:

Identification of the hazardous chemical:

CRUDE OIL - CAS: 8002-05-9

Hazard pictograms:

Signal word:
DANGER
Hazard statements:

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Safety Data Sheet Date of issue: 03/17/2020
According to NOM-018-STPS-
2015 Version: 1.0

H224 - Extremely flammable liquid and vapour.


H304 - May be fatal if swallowed and enters airways.
H319 - Causes serious eye irritation.
H336 - May cause drowsiness or dizziness.
H350 - May cause cancer.
H373 - May cause damage to organs (blood, liver, spleen, thymus) through prolonged or
repeated exposure (dermal, oral).
Precautionary statements:
P201 - Obtain special instructions before use.
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 - Keep container tightly closed.
P260 - Do not breathe Fumes, mist, Vapours.
P273 - Avoid release to the environment.
P280 - Wear protective gloves, eye protection, face protection.
P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P308+P313 - IF exposed or concerned: Get medical advice/attention.
P312 - Call a POISON CENTER, a doctor if you feel unwell.
P331 - Do NOT induce vomiting.
P337+P313 - If eye irritation persists: Get medical advice/attention.
P370+P378 - In case of fire: Use dry extinguishing powder to extinguish.
P391 - Collect spillage.
P403+P235 - Store in a well-ventilated place. Keep cool.
P501 - Dispose of contents and container to according to national or local regulations.
3) Other hazards which do not result in classification:
The product may charge electrostatically: use earthing leads when transferring from one
container to another. The product is heavier than air and in the event of a leak, vapour may
accumulate in confined spaces and low lying areas where it may easily be accidentally ignited. If
the product is handled or used at high temperature, contact with hot product or vapours may
cause burns. Any substance, in case of accidents involving pressurized circuits and the like,
may be accidentally injected under the skin, even without external damage. In such a case, the
victim should be brought to an hospital as soon as possible, to get specialized medical
treatment. Do not wait for symptoms to develop.

SECTION 3: Composition/information on ingredients


1) Substances:
Petroleum; Crude oil; [A complex combination of hydrocarbons, It consists predominantly of aliphatic,
alicyclic and aromatic hydrocarbons. It may also contain small amounts of nitrogen, oxygen and sulfur
compounds. This category encompasses light, medium, and heavy petroleums, as well as the oils
extended from tar sands. Hydrocarbonaceous materials requiring major chemical changes for their
recovery or conversion to petroleum refinery feedstocks such as crude shale oils; upgraded shale oils
and liquid coal fuels are not included in this definition.]

CONCENTRATION
CHEMICAL NAME CAS NUMBER UN NUMBER
(% W/W)
Petroleum, Crude oil 8002-05-9 1267 100

2) Mixtures:
Not applicable.

SECTION 4: First-aid measures


1) Description of first-aid measures:
In case of inhalation: Remove to fresh air, keep the casualty warm and at rest. If casualty is

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Safety Data Sheet Date of issue: 03/17/2020
According to NOM-018-STPS-
2015 Version: 1.0

unconscious and not breathing: ensure that there is no obstruction to


breathing and give artificial respiration by trained personnel. If
necessary, give external cardiac massage and obtain medical advice.
If the casualty is breathing: Place in the recovery position. Administer
oxygen if necessary.
In case of skin contact: Remove contaminated clothing, contaminated footwear and dispose of
safely. Wash skin with soap and water. If inflammation or irritation
persists, seek medical advice. When using high-pressure equipment,
injection of product can occur. Send the casualty immediately to
hospital. Do not wait for symptoms to develop.
In case of eyes contact: Remove contact lenses, if present and easy to do so. Rinse eyes
thoroughly for at least 15 minutes. Keep eyelids well apart. If irritation,
blurred vision or swelling occurs and persists, obtain medical advice
from a specialist.
In case of ingestion: Do not induce vomiting to avoid aspiration into the lungs. If the person
is conscious, rinse mouth with water without swallowing. Keep at rest.
Call for medical assistance or bring to an hospital. If the casualty is
inconscious, place in the recovery position. In case of spontaneous
vomiting, keep head low, to avoid the risk of aspiration into the lungs.
2) Most important symptoms/effects, acute and delayed:
There are potential chronic health effects to consider. Overexposure to vapours (e.g. through
prolonged use in confined, insufficiently ventilated spaces) may cause irritation to airways, nausea and
dizziness. Exposure to high concentrations may cause asphyxiation as a consequence of oxygen
deficiency. Prolonged and repeated skin contact may cause reddening, irritation and dermatitis, due to
a defatting effect. Contact with hot product may cause thermal burns. Risk of serious damage to eyes.
Burning sensation, tearing, redness or swelling. Contact with hot product or vapours may cause burns.
Swallowing the liquid may cause aspiration into the lungs with the risk of chemical pneumonitis. May
be fatal if swallowed and enters airways. The effects may be delayed. May cause cancer. May cause
damage to organs (blood, liver, thymus, spleen) through prolonged or repeated exposure (oral,
dermal).
3) Indication of immediate medical attention and special treatment needed, if necessary:
Obtain medical attention if casualty has an altered state of consciousness or if symptoms do not
resolve. Seek medical attention in all cases of serious burns.

SECTION 5: Fire-fighting measures


1) Suitable extinguishing media:
Small-size fires: carbon dioxide, dry chemicals, foam, sand or earth. Large fires: foam or water fog
(mist). These means should be used by trained personnel only. Other extinguishing gases
(according to regulations).
Do not use water jets. They could cause splattering, and spread the fire. Simultaneous use of foam
and water on the same surface is to be avoided as water destroys the foam.
2) Specific hazards arising from the chemical:
Extremely flammable liquid and vapour. The vapours are flammable and may form explosive
mixtures with air. Incomplete combustion will generate poisonous carbon monoxide, carbon dioxide
and other toxic gases. Oxygenated compounds (aldehydes, etc.). Solid particulate.
3) Special protective actions for fire-fighters:
Shut off source of product. If possible, move containers and drums away from danger area. Spilled
product which is not burning should be covered with sand or foam. Use water sprays to cool
containers and surfaces exposed to the flames. If the fire cannot be controlled, evacuate area.
Wear self-contained breathing apparatus. Do not attempt to take action without suitable protective
equipment. In case of fire, do not discharge residual product, waste materials and runoff water:
collect separately and use a proper treatment.

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Safety Data Sheet Date of issue: 03/17/2020
According to NOM-018-STPS-
2015 Version: 1.0

SECTION 6: Accidental release measures


1) Personal precautions, protective equipment and emergency procedures:
Stop or contain leak at the source, if safe to do so. Eliminate all ignition sources if safe to do so
(e.g. electricity, sparks, fires, flares). Use only non-sparking tools. Avoid direct contact with released
material. Keep upwind. Alert emergency personnel. Except in case of small spillages, the feasibility
of any actions should always be assessed and advised, if possible, by a trained, competent person
in charge of managing the emergency. Small spillages: normal antistatic working clothes are
usually adequate. Large spillages: full body suit of chemically resistant and antistatic material. Work
gloves providing adequate chemical resistance, specifically to aromatic hydrocarbons. Gloves
made of PVA are not water-resistant, and are not suitable for emergency use. Antistatic non-skid
safety shoes or boots, chemical resistant. Work helmet. Goggles and /or face shield, if splashes or
contact with eyes is possible or anticipated. Respiratory protection: a half or full-face respirator with
filter(s) for organic vapours (AX), or a Self-contained Breathing Apparatus (SCBA) can be used
according to the extent of spill and predictable amount of exposure. Notify local authorities
according to relevant regulations. In case of large spillages, alert occupants in downwind areas.
2) Environmental precautions:
Do not let the product accumulate in confined or underground spaces. Do not let the product flow
into sewers or water courses, or in any way contaminate the environment. In case of contamination
of environment compartments (soil, subsoil, surface or underground waters), remove contaminated
soil when possible, and in any case treat all involved compartments in accordance with local
regulations. The site should have a spill plan to ensure that adequate safeguards are in place to
minimize the impact of episodic releases. Danger of drinking-water pollution (ground water).
3) Methods and material for containment and cleaning up:
Contain spilled liquid with sand, earth or other suitable absorbents (non-flammable). Recover free
liquid and waste materials in suitable waterproof and oil-resistant containers. Clean contaminated
area. Dispose of according to local regulations. Large spillages may be cautiously covered with
foam, if available, to limit fire risk. Do not use direct jets. When inside buildings or confined spaces,
ensure adequate ventilation. If in water: In case of small spillages in closed waters (i.e. ports).
Confine the spillage. Remove from surface by suitable absorbents. Collect recovered product and
other waste materials in suitable waterproof, oil resistant containers. Recover or dispose of
according to local regulations. If possible, large spillages in open waters should be contained with
floating barriers or other suitable mechanical means. If this is not possible: Isolate the area and
prevent fire/explosion hazard for ships and other structures, taking into account wind direction and
speed, until the product is completely dispersed. Bund storage facilities to prevent soil and water
pollution in the event of spillage. Do not use solvents or dispersants, unless specifically advised by
an expert, and, if required, approved by local authorities.

SECTION 7: Handling and storage


1) Precautions for safe handling:
Special slow load procedures for switch loading must be followed to avoid the static ignition hazard
that can exist when this material is loaded into containers (tanks) previously containing gasoline or
other low flash point hydrocarbon products.
Precautions for safe handling: Obtain special instructions before use. Ensure that all relevant
regulations regarding handling and storage facilities of flammable products are followed. Do not use
electrical equipment (mobile phones etc.) not approved for use, according to the risk rating of the
area. Do not use compressed air for filling, discharging, or handling operations. Keep away from
heat/sparks/open flames/hot surfaces. Use and store only outdoors or in a well-ventilated area.
During transfer and mixing operations, ensure that all equipment is correctly grounded. Avoid the
build-up of electric charges. Use only bottom loading of tankers. Before entering storage tanks and
commencing any operation in a confined area (e.g. tunnels), carry out an adequate clean-up, and
check the atmosphere for oxygen content and flammability. Emptied containers can contain
combustible product residues. Do not cut, weld, drill, burn or incinerate empty containers or drums,
unless they have been drained and cleaned.

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Safety Data Sheet Date of issue: 03/17/2020
According to NOM-018-STPS-
2015 Version: 1.0

Hygiene measures: Use adequate personal protective equipment as needed. Do not breathe fume/
mist/ vapours. Avoid contact with skin. Wash the hands thoroughly after handling. Do not ingest. Do
not smoke. Do not eat and do not drink during use. Keep away from food and beverages.
Contaminated materials should not be allowed to accumulate in the workplaces and should never
be kept inside the pockets. Separate working clothes from town clothes. Launder separately. Do not
re-use clothes, if they are still contaminated.
2) Conditions for safe storage, including any incompatibilities:
Storage conditions: Store in dry, well ventilated area. Do not smoke. Keep away from open flames,
hot surfaces and sources of ignition. Vapours are heavier than air and spread above ground.
Beware of accumulation in pits and confined spaces.
Incompatible products: Keep away from strong oxidants.
Storage area: Storage area layout, tank design, equipment and operating procedures must comply
with the relevant European, national or local legislation. Storage areas/installations should be
designed with adequate bunds so as to prevent ground and water pollution in case of leaks or
spills. Cleaning, inspection and maintenance of internal structure of storage tanks must be done
only by properly equipped and qualified personnel as defined by national, local or company
regulations.
Packages and containers: If the product is supplied in containers: Keep containers tightly closed
and properly labelled. Keep only in the original container or in a suitable container for this kind of
product. Store away from direct sunlight or other heat sources. Light hydrocarbon vapours can build
up in the headspace of containers. Open slowly in order to control possible pressure release.
Empty containers may contain flammable product residues. Do not weld, solder, drill, cut or
incinerate empty containers, unless they have been properly cleaned.
Packaging materials: Some synthetic materials may be unsuitable for containers or container
linings depending on the material specification and intended use. Recommended materials for
containers, or container linings use mild steel, stainless steel. Compatibility should be checked with
the manufacturer, according to the specific use conditions.

SECTION 8: Exposure controls/personal protection


1) Control parameters:
Petroleum, Crude oil (8002-05-9)
NIOSH REL (TWA): 350 mg/m³
NIOSH REL (STEL): 1800 mg/m³
NIOSH REL (ceiling): 1800 mg/m³
2) Appropriate engineering controls:
Before entering storage tanks and commencing any operation in a confined area (e.g. tunnels),
carry out an adequate clean-up, and check the atmosphere for oxygen content and flammability.
Ensure that there is a suitable ventilation system. Minimize exposure to mists/vapours/aerosol.
Emergency eye wash fountains and safety showers should be available in the immediate vicinity of
any potential exposure. Prevent the build-up of electrostatic charge.
3) Individual protection measures, such as personal protective equipment (PPE):
Eye protection:
Chemical goggles or face shield. Emergency eye wash fountains and safety showers should be
available in the immediate vicinity of any potential exposure.
Hand protection:
When there is a risk of contact with the skin, use hydrocarbon-resistant, felt-lined gloves. Adequate
materials: nitrile (NBR) or PVC with a protection index > 5 (permeation time > 240 mins). Use
gloves respecting all the conditions and within the limits set by the manufacturer. Replace gloves
immediately in case of cuts, holes or other signs of damages or degradation.
Skin and body protection:
Long-sleeved overalls. Antistatic non-skid safety shoes or boots, chemical resistant, if necessary
heat resistant and insulated. Coveralls should be changed at the end of the work shift and cleaned
as necessary to avoid transfer of product to clothes or underwear.

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Safety Data Sheet Date of issue: 03/17/2020
According to NOM-018-STPS-
2015 Version: 1.0

Respiratory protection:
Independently from other possible actions (technical modifications, operating procedures, and other
means to limit the exposure of workers), personal protection equipment can be used according to
necessity. Closed or confined areas (e.g. tank interiors): the use of protection measures for airways
(masks or self-contained breathing apparatus), must be assessed according to the specific activity,
as well as level and duration of predicted exposure. Combination filter device. If exposure levels
cannot be determined or estimated with adequate confidence, or an oxygen deficiency is possible,
only SCBA’s should be used. Open or well ventilated spaces: if the product is handled without
adequate containment, use full or half-face masks with adequate filter for dusts (and when
applicable for H 2 S).
Thermal hazards:
If contact with hot product is possible or anticipated, gloves should be heat-resistant and thermally
insulated. A combustible gas detector can be used to check for flammable gas or vapors.

SECTION 9: Physical and chemical properties


Physical state: Viscous liquid
Colour: Dark
Odour: Petroleum
Odour threshold: No data available
pH: No data available
Melting point/Freezing point: -6 (upper pour point) (ASTM D 5853)
Boiling point: ≤ 35 °C
Flash point: < 23 °C
Evaporation rate: No data available
Flammability (solid/gas): Not applicable
Upper/lower flammability limits: No data available
Vapour pressure: No data available
Vapour density: No data available
Density: 0.8841 - 0.8868 kg/l (15°C) (EN ISO 12185,
ASTM D1298)
Solubility: Material nearly insoluble in water
Partition coefficient (n-octanol/water): 3.43 - 3.96 (OECD 107)
Auto-ignition temperature: No data available
Decomposition temperature: No data available
Viscosity, kinematic: 5.421 – 12.386 mm²/s (40 °C) (ASTM D445, EN
ISO 3104)
Specific gravity @ 60/60 °F: 0.8743 - 0.8846 (ASTM D1298, EN ISO 12185)
Sulphur content: 0.948 – 1.18 %m/m (ASTM D 4294)

SECTION 10: Stability and reactivity


1) Reactivity:
This substance does not offer any further hazard for reactivity, except what is reported in the
following paragraphs.
2) Chemical stability:
Stable product, according to its intrinsic properties.
3) Possibility of hazardous reactions:
None (in normal conditions of storage and handling). Contact with strong oxidizers (peroxides,
chromates, etc.) may cause a fire hazard.
4) Conditions to avoid:
Keep away from open flames, hot surfaces and sources of ignition. Avoid the build-up of
electrostatic charge. Do not smoke.
5) Incompatible materials:
Strong oxidants.

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Safety Data Sheet Date of issue: 03/17/2020
According to NOM-018-STPS-
2015 Version: 1.0

6) Hazardous decomposition products:


Under normal conditions of storage and use, hazardous decomposition products should not be
produced. Thermal decomposition generates toxic fumes.

SECTION 11: Toxicological information


1) Information on toxicological effects:
Acute toxicity:
Acute toxicity (oral): Not classified (Conclusive but not sufficient for classification).
Acute toxicity (dermal): Not classified (Conclusive but not sufficient for classification).
Acute toxicity (inhalation): Not classified (Conclusive but not sufficient for classification).

Petroleum, Crude oil (8002-05-9)


LD 50 (oral, rat) > 5000 mg/kg bodyweight (Beryl crude (Light crude oil), 1984)
LD 50 (dermal, rabbit) > 2000 mg/kg bodyweight (Beryl crude (Light crude oil), 1984)

Skin corrosion/irritation:
Not classified (Conclusive but not sufficient for classification).
On basis of test data:
Skin irritation, mammalian, local, dermal, Rabbit, semi-occlusive: 0.7 – 1.5 (6 Hours, (Beryl crude
(Light crude oil), 1984), Not irritating)
Serious eye damage/irritation:
Causes serious eye irritation.
On basis of test data:
Eye irritation, mammalian, local, Eyes, Rabbit, Conjunctival redness: 1.0 – 1.7 (24 - 72 Hours,
(Beryl crude (Light crude oil), 1984), Causes eye irritation).
Respiratory or skin sensitisation:
Not classified (Conclusive but not sufficient for classification).
Germ cell mutagenicity:
Not classified (Conclusive but not sufficient for classification).
Carcinogenicity:
May cause cancer.
On basis of test data:
Carcinogenicity, mammalian, Skin irritation, Skin, male, female: 0.17 – 16.8 mg (24 months, (Lewis
et al, 1984) (Clark et al, 1988) (Renne et al, 1981), Carcinogen, cat 1A or 1B)
Reproductive toxicity:
Not classified (Conclusive but not sufficient for classification).
Specific target organ toxicity (single exposure):
May cause drowsiness or dizziness.
Estimated on the basis of the constituents.
Specific target organ toxicity (repeated exposure):
May cause damage to organs (blood, liver, spleen, thymus) through prolonged or repeated
exposure (dermal, oral).
On basis of test data:
Petroleum, Crude oil (8002-05-9)
LOAEL (oral, rat, 90 days) 2 (mL/Kg/d)
NOAEL (dermal, rat/rabbit, 90 days) 30 mg/kg bodyweight/day
NOAEC (inhalation, rat, vapour, 90 days) 1507 - 10153 mg/m³ (Read-across)
Aspiration hazard:
May be fatal if swallowed and enters airways.
For all low-viscosity petroleum products (less than 20.5 mm2/s at 40 °C), there is the risk of
aspiration into the lungs. This may occur directly after ingestion, or subsequently in case of
vomiting (spontaneous or induced).
In this case there is the possibility of an inflamation of the lung tissues (chemical pneumonia). This

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Safety Data Sheet Date of issue: 03/17/2020
According to NOM-018-STPS-
2015 Version: 1.0

is a serious condition requiring medical treatment.


Aspiration into lungs can cause a chemical pneumonia.
Viscosity, kinematic: 5.421 – 12.386 mm²/s (40 °C) (ASTM D445, EN ISO 3104)
2) Information on the likely routes of exposure:
Inhalation: Overexposure to vapours (e.g. through prolonged use in confined, insufficiently
ventilated spaces) may cause irritation to airways, nausea and dizziness. Exposure to high
concentrations may cause asphyxiation as a consequence of oxygen deficiency.
Eye contact: Risk of serious damage to eyes. Burning sensation, tearing, redness or swelling.
Contact with hot product or vapours may cause burns.
Skin contact: Prolonged and repeated skin contact may cause reddening, irritation and dermatitis,
due to a defatting effect. Contact with hot product may cause thermal burns.
Ingestion: Swallowing the liquid may cause aspiration into the lungs with the risk of chemical
pneumonitis. May be fatal if swallowed and enters airways. The effects may be delayed.
Chronic symptoms: May cause cancer. May cause damage to organs (blood, liver, thymus, spleen)
through prolonged or repeated exposure (oral, dermal).
3) Symptoms related to the physical, chemical and toxicological characteristics:
May cause cancer. May cause damage to organs (blood, liver, thymus, spleen) through prolonged
or repeated exposure (if swallowed, in contact with skin). Prolonged and repeated skin contact may
cause reddening, irritation and dermatitis, due to a defatting effect. High concentration of vapours
may induce: headache, nausea, dizziness. High concentrations may cause injuries to
gastrointestinal tract, liver, kidneys and central nervous system. Aspiration into lungs can cause a
chemical pneumonia. Contact with eyes may cause reddening and irritation.
4) Other information:
None.

SECTION 12: Ecological information


1) Ecotoxicity:
According to the components, and by comparison with other products of the same type and
composition, it is expected that this product has a toxicity for aquatic organisms between 1 and 10
mg/l, and must be regarded as Dangerous to the environment. This product is not soluble in water.
It floats on water and forms a film on the surface. The damage to aquatic organisms is of
mechanical kind (immobilization and entrapment). An uncontrolled release to the environment may
produce a contamination of different environmental compartments (air, soil, underground, surface
water bodies, aquifers). Handle according to general working hygiene practices to avoid pollution
and release into the environment. Notify authorities if product enters sewers or public waters.
According to the characteristics of the components, a fraction of the product will evaporate quickly,
diffusing in the atmosphere: this phenomenon may promote the creation of photochemical smog.
Use vapour recovery units when necessary. Toxic to aquatic life with long lasting effects. Will not
undergo hydrolysis.

Petroleum, Crude oil (8002-05-9)


LC 50 (fish) 1 1641 - 4965 mg/l Rhoton (1999), Rhoton et al. (2001)
> 100 mg/l (Danio rerio, OECD 203, 1992 - OPPTS 850,1075, 1992)
LC 50 (fish) 2
(2011)
LC 50 (other aquatic
27 - 119 mg/l (96h) (Brown shrimp) (1984)
organisms)
EC 50 (Daphnia) 12.48 - 160 mg/l Rhoton (1999), Rhoton et al. (2001)
EC 50 (algae, 72h) > 100 mg/l (Pseudokirchneriella subcapitata, OECD 201)
LOEC (acute) > 100 mg/l (Daphnia Magna, OECD 202)
NOEC (acute) 100 mg/l (Daphnia Magna, OECD 202)

2) Persistence and degradability:


The most significant constituents of the product should be considered as "inherently

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Safety Data Sheet Date of issue: 03/17/2020
According to NOM-018-STPS-
2015 Version: 1.0

biodegradable", but not "readily biodegradable", and they may be moderately persistent, particularly
in anaerobic conditions.
Biodegradation: 18.9 - 29.4 % (28d, OECD 301F - OPPTS 835.3110, 1996)
3) Bioaccumulative potential:
According to the characteristics of the components, the product has a low biodegradability in
anaerobic conditions, and may be persistent. Some of the chemical compounds that are present in
the product have a potential for bioaccumulation, and may be harmful to aquatic organisms.
Log Pow: 3.43 - 3.96 (OECD 107)
Log Kow: 3 - 4 (OECD 107)
4) Mobility in soil:
According to the characteristics of the components, a fraction of the product will evaporate quickly,
diffusing in the atmosphere: this phenomenon promotes the creation of photochemical smog. The
remaining fraction has a low biodegradability in anaerobic conditions, and may be persistent. Some
of the hydrocarbons that are potentially present have a potential for bioaccumulation, and may be
harmful to aquatic organisms.
Log Koc: 80 - 10000
5) Other adverse effects:
None.

SECTION 13: Disposal considerations


1) Disposal methods:
Waste treatment methods:
Do not dispose of the product, either new or used, by discharging into sewers, tunnels, lakes or
water courses. Deliver to a qualified official collector.
Sewage disposal recommendations:
Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or
reclaimed.
Additional information:
Do not cut, weld, drill, burn or incinerate empty containers or drums, unless they have been
cleaned, and declared safe. Empty containers may contain flammable product residues. Dispose of
empty, not cleaned containers safely, according to local regulations.
Ecology - waste materials:
The product as it is does not contain halogenated substances.

SECTION 14: Transport information

Land transport Maritime transport Air transport


(ADR/RID/ADN) (IMDG Code) (ICAO T.I./IATA)
UN Number 1267 1267 1267
UN proper shipping PETROLEUM CRUDE PETROLEUM CRUDE PETROLEUM CRUDE
name OIL OIL OIL
Transport hazard class 3 3 3
Packing group I I I
Enviromental hazards Classified Classified Classified
Special precautions
D/E EmS: F-E, S-E Not applicable
for user
Transport in bulk
according to Annex II
Not applicable Not applicable Not applicable
of MARPOL 73/78 and
the IBC Code

Page 9 of 10
Safety Data Sheet Date of issue: 03/17/2020
According to NOM-018-STPS-
2015 Version: 1.0

SECTION 15: Regulatory information


Montreal Protocol: not listed.
Stockholm Convention: not listed.
Rotterdam Convention: not listed.
1) Safety, health and environmental regulations specific for the substance or mixture:
No data available.

SECTION 16: Other information


1) Date of issue: 03/17/2020
Version: 1.0
Comply with NOM-018-STPS-2015.
This document was prepared by a competent person who has received appropriate training.

2) Acronyms and abbreviations


ACGIH: American Conference of Governmental Industrial Hygienists.
CAS: Chemical Abstracts Service (division of the American Chemical Society).
EC 50 : Effective concentration, for 50 percent of test population.
GHS: Globally Harmonized System of Classification and Labelling of Chemicals.
IATA: International Air Transport Association.
IBC: International Code for the Construction and Equipment of Ships carrying
Dangerous Chemicals in Bulk.
ICAO T.I.: International Civil Aviation Organization Technical Instructions.
IMDG Code: International Maritime Dangerous Goods Code.
LC 50 : Lethal concentration, for 50 percent of test population.
LD 50 : Lethal dose, for 50 percent of test population.
MARPOL 73/78: International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978.
STEL: Short Term Exposure limit.
TLV: Threshold Limit Value.
TWA/TLV: Threshold Limit Value for the Time Weighted Average 8 hour day.
UN: United Nations.

3) Legislation and reference sources:


- GHS - Globally Harmonized System of Classification and Labelling of Chemicals;
- ADR (European Agreement concerning the International Carriage of Dangerous Goods by Road);
- International Maritime Dangerous Goods Code (IMDG Code);
- International Air Transport Association (IATA).

Notice to Reader: this information is based on our current knowledge and is intended to describe the
product for the purposes of health, safety and environmental requirements only. It should not therefore
be construed as guaranteeing any specific property of the product.

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