Crude Oil: Safety Data Sheet
Crude Oil: Safety Data Sheet
Crude Oil: Safety Data Sheet
According to NOM-018-STPS-
2015 Version: 1.0
CRUDE OIL
SECTION 1: Identification of the hazardous chemical or mixture and of the supplier or
manufacturer
1) Name of the hazardous chemical or mixture: Crude oil
2) Other means of identification:
Chemical name: Petroleum
IUPAC name: Crude oil
CAS Number: 8002-05-9
3) Recommended use of the chemical or mixture and restrictions on use:
Raw material for chemical industries.
Recommended use are listed above; other uses are not recommended unless an assessment has
provided that risks are controlled.
4) Supplier or manufacturer details:
Mizamtec Operating Company, S. de R.L. de C.V.
Av. Paseo de las Palmas 425
Col. Lomas de Chapultepec
Alcaldía Miguel Hidalgo
C.P.: 11000 - Mexico City
Contact:
Francisco Vacas
Phone: +52 5531484577
MAIL Address: Francisco.Vacas@eni.com
5) Telephone number in case of emergency:
CENACOM: 01 800 00 41 300 (24 h)
COATEA: 01 800 710 49 43
Hazard pictograms:
Signal word:
DANGER
Hazard statements:
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Safety Data Sheet Date of issue: 03/17/2020
According to NOM-018-STPS-
2015 Version: 1.0
CONCENTRATION
CHEMICAL NAME CAS NUMBER UN NUMBER
(% W/W)
Petroleum, Crude oil 8002-05-9 1267 100
2) Mixtures:
Not applicable.
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2015 Version: 1.0
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2015 Version: 1.0
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Safety Data Sheet Date of issue: 03/17/2020
According to NOM-018-STPS-
2015 Version: 1.0
Hygiene measures: Use adequate personal protective equipment as needed. Do not breathe fume/
mist/ vapours. Avoid contact with skin. Wash the hands thoroughly after handling. Do not ingest. Do
not smoke. Do not eat and do not drink during use. Keep away from food and beverages.
Contaminated materials should not be allowed to accumulate in the workplaces and should never
be kept inside the pockets. Separate working clothes from town clothes. Launder separately. Do not
re-use clothes, if they are still contaminated.
2) Conditions for safe storage, including any incompatibilities:
Storage conditions: Store in dry, well ventilated area. Do not smoke. Keep away from open flames,
hot surfaces and sources of ignition. Vapours are heavier than air and spread above ground.
Beware of accumulation in pits and confined spaces.
Incompatible products: Keep away from strong oxidants.
Storage area: Storage area layout, tank design, equipment and operating procedures must comply
with the relevant European, national or local legislation. Storage areas/installations should be
designed with adequate bunds so as to prevent ground and water pollution in case of leaks or
spills. Cleaning, inspection and maintenance of internal structure of storage tanks must be done
only by properly equipped and qualified personnel as defined by national, local or company
regulations.
Packages and containers: If the product is supplied in containers: Keep containers tightly closed
and properly labelled. Keep only in the original container or in a suitable container for this kind of
product. Store away from direct sunlight or other heat sources. Light hydrocarbon vapours can build
up in the headspace of containers. Open slowly in order to control possible pressure release.
Empty containers may contain flammable product residues. Do not weld, solder, drill, cut or
incinerate empty containers, unless they have been properly cleaned.
Packaging materials: Some synthetic materials may be unsuitable for containers or container
linings depending on the material specification and intended use. Recommended materials for
containers, or container linings use mild steel, stainless steel. Compatibility should be checked with
the manufacturer, according to the specific use conditions.
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Safety Data Sheet Date of issue: 03/17/2020
According to NOM-018-STPS-
2015 Version: 1.0
Respiratory protection:
Independently from other possible actions (technical modifications, operating procedures, and other
means to limit the exposure of workers), personal protection equipment can be used according to
necessity. Closed or confined areas (e.g. tank interiors): the use of protection measures for airways
(masks or self-contained breathing apparatus), must be assessed according to the specific activity,
as well as level and duration of predicted exposure. Combination filter device. If exposure levels
cannot be determined or estimated with adequate confidence, or an oxygen deficiency is possible,
only SCBA’s should be used. Open or well ventilated spaces: if the product is handled without
adequate containment, use full or half-face masks with adequate filter for dusts (and when
applicable for H 2 S).
Thermal hazards:
If contact with hot product is possible or anticipated, gloves should be heat-resistant and thermally
insulated. A combustible gas detector can be used to check for flammable gas or vapors.
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According to NOM-018-STPS-
2015 Version: 1.0
Skin corrosion/irritation:
Not classified (Conclusive but not sufficient for classification).
On basis of test data:
Skin irritation, mammalian, local, dermal, Rabbit, semi-occlusive: 0.7 – 1.5 (6 Hours, (Beryl crude
(Light crude oil), 1984), Not irritating)
Serious eye damage/irritation:
Causes serious eye irritation.
On basis of test data:
Eye irritation, mammalian, local, Eyes, Rabbit, Conjunctival redness: 1.0 – 1.7 (24 - 72 Hours,
(Beryl crude (Light crude oil), 1984), Causes eye irritation).
Respiratory or skin sensitisation:
Not classified (Conclusive but not sufficient for classification).
Germ cell mutagenicity:
Not classified (Conclusive but not sufficient for classification).
Carcinogenicity:
May cause cancer.
On basis of test data:
Carcinogenicity, mammalian, Skin irritation, Skin, male, female: 0.17 – 16.8 mg (24 months, (Lewis
et al, 1984) (Clark et al, 1988) (Renne et al, 1981), Carcinogen, cat 1A or 1B)
Reproductive toxicity:
Not classified (Conclusive but not sufficient for classification).
Specific target organ toxicity (single exposure):
May cause drowsiness or dizziness.
Estimated on the basis of the constituents.
Specific target organ toxicity (repeated exposure):
May cause damage to organs (blood, liver, spleen, thymus) through prolonged or repeated
exposure (dermal, oral).
On basis of test data:
Petroleum, Crude oil (8002-05-9)
LOAEL (oral, rat, 90 days) 2 (mL/Kg/d)
NOAEL (dermal, rat/rabbit, 90 days) 30 mg/kg bodyweight/day
NOAEC (inhalation, rat, vapour, 90 days) 1507 - 10153 mg/m³ (Read-across)
Aspiration hazard:
May be fatal if swallowed and enters airways.
For all low-viscosity petroleum products (less than 20.5 mm2/s at 40 °C), there is the risk of
aspiration into the lungs. This may occur directly after ingestion, or subsequently in case of
vomiting (spontaneous or induced).
In this case there is the possibility of an inflamation of the lung tissues (chemical pneumonia). This
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2015 Version: 1.0
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According to NOM-018-STPS-
2015 Version: 1.0
biodegradable", but not "readily biodegradable", and they may be moderately persistent, particularly
in anaerobic conditions.
Biodegradation: 18.9 - 29.4 % (28d, OECD 301F - OPPTS 835.3110, 1996)
3) Bioaccumulative potential:
According to the characteristics of the components, the product has a low biodegradability in
anaerobic conditions, and may be persistent. Some of the chemical compounds that are present in
the product have a potential for bioaccumulation, and may be harmful to aquatic organisms.
Log Pow: 3.43 - 3.96 (OECD 107)
Log Kow: 3 - 4 (OECD 107)
4) Mobility in soil:
According to the characteristics of the components, a fraction of the product will evaporate quickly,
diffusing in the atmosphere: this phenomenon promotes the creation of photochemical smog. The
remaining fraction has a low biodegradability in anaerobic conditions, and may be persistent. Some
of the hydrocarbons that are potentially present have a potential for bioaccumulation, and may be
harmful to aquatic organisms.
Log Koc: 80 - 10000
5) Other adverse effects:
None.
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Safety Data Sheet Date of issue: 03/17/2020
According to NOM-018-STPS-
2015 Version: 1.0
Notice to Reader: this information is based on our current knowledge and is intended to describe the
product for the purposes of health, safety and environmental requirements only. It should not therefore
be construed as guaranteeing any specific property of the product.
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