NJEETS-2022 - FT - 3 -PCM -16

FIITJEE - NJEETS
(JEE MAIN TEST SERIES - 2022)
CLASS - XII
FULL TEST - 3
CONDUCTION DATE: 04/02/2022
TEST ID : T-76153
ANSWERS

Section – I (Physics)
PART – A
1. C 2. A 3. B 4. A
5. A 6. C 7. B 8. C
9. C 10. D 11. A 12. B
13. C 14. C 15. C 16. D
17. B 18. D 19. C 20. B
21. A 22. C 23. C 24. B

PART – C
1. 1 2. 4 3. 4 4. 3
5. 5

Section – II (Chemistry)
PART – A

1. D 2. A 3. D 4. D
5. A 6. D 7. A 8. B
9. D 10. B 11. D 12. B
13. C 14. B 15. D 16. A
17. C 18. C 19. B 20. C
PART – C
1. 2 2. 5 3. 5 4. 2
5. 1
Section – III (Mathematics)
PART – A
1. A 2. C 3. B 4. B
5. B 6. D 7. B 8. A
9. C 10. B 11. D 12. B
13. D 14. B 15. A 16. D
17. A 18. D 19. B 20. D
PART – C
1. 1 2. 1 3. 4 4. 2
5. 1

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NJEETS-2022 - FT - 3 -PCM -17

HINTS & SOLUTIONS

Section – I (Physics)
PART - A
1. C

" B2 "
Sol. is energy density of magnetic field.
2 0

2. A

D D 
Sol.  (  1)t or    1  1.5
d d t

3. B

l
Sol. The velocity in the direction A to B will be v 2  u2  t  same time is needed to come back from
v2  u2
2l
B to A  t net 
v  u2
2

u
v

A B
v2  u2

4. A
 
Sol. Magnetic field at point ‘P’ due to wire ‘OB’ is zero as Idl & r are anti parallel,
 
So Idl x r = 0
 I(sin90o + sin{-(90- )}]
So Bp = 0 .
4π dsin
0 I[1-cos ] I
= = 0 tan 
4π dsin 4π d 2
 
A B

I I

0
d 

P 90-

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NJEETS-2022 - FT - 3 -PCM -18

5. A
Sol. Net force will be in the direction of bigger force i.e. in the direction of acceleration.

6. C

Sol. As charge particle passes the region undeviated

 
So F = q [E i+ V + Bj] = 0
 E k
V = 2j + , satisfy the above result.
B

7. B
Sol. weight acts at COM.
L l W
 effective length = . Hence 
2 L/ 2 A Y
WL
or l 
2A Y

8. C
dx
Sol. v ; velocity will be maximum when slope will be maximum.
dt

9. C
Sol. Fact based.

10. D
Sol.
For T  0, that is, at low temperature, molar specific heat  T3 and at high temperature it becomes constant
= 3R.

11. A
Sol. It will oscillate.

12. B
Sol. Molar heat capacity
R R
C  Cv   Cv   Cv  2 R
1n 3
1
2
13. C
Sol. Conceptual.

14. C
Sol. Fact based.

15. C
(220)2
Sol. R  484 
100
(200)2
Pconsum ed 
484
4
10
=  82.6 W
121
Case (i) Light energy (100 – 40) (0.6) = 36W
Case (ii) (82.6 – 40) (0.6) = 25.6
(36  25.6)
%change =  29%
36
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NJEETS-2022 - FT - 3 -PCM -19

16. D
Sol. Total magnetic field will be sum of magnetic fields because each side.

17. B
Sol. Fact based.
18. D
Sol. Fact based.

19. C
 B B mgR cos 
Sol.    cos 
 A A mgR

20. B
Sol. Concept Based.

PART – C
1. 1
2
 R 
Sol. mg '  mg  
 Rh

2. 4
I
Sol. Radius of gyration K 
MR 2

3. 4
l
Sol. R 
2r r
(1.5  10 8 )(25)
R  0.03
2(3.14)0.02)(1  104 )
1.2
I  40m A
0.03

4. 3
Sol. v 0  (R  h) g
emf = Blv0 = 8  10–5  2  8.2  103 = 1.3 V

5. 5
5
Sol.  25 mA
200

Section – II (Chemistry)
1. D
1
Sol. Rateof SN 2 reaction 
steric over crowding in transition state

2. A

Sol. Ni2+ = [18] 3d8

 Number of unpaired electrons is 2

   n  n  2   2  2  2   8  2.8BM

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NJEETS-2022 - FT - 3 -PCM -20

3. D

Sol.
CH2Cl CH2CN
NaCN

MF


I I
Side chain is attacked

4. D

Sol. Ksp [Cr(OH)3] 

 Cr 3  aq   3OH   aq 
Cr  OH 3  s  
 S  3S
4 -30
Ksp = 275 = 1.6 × 10
S = 4 1.6 1030 / 27
5. A

Sol. Only m-cresols give tribromo derivatives on treatment with Br2 water.
OH OH
Br Br
Br2 / H 2 O


CH3 CH3
Br
6. D

Sol. As per Kohlausch’s law,

oHOAc  oNaOAc  oHCl  oNaCl
 Value of  oNaCl is required.

7. A

Sol. From Kohlrausch’s law

CH3COOH  CH3 COONa  HCl
 
 NaCl
Hence, (A) is the correct answer.

8. B
Sol. Saytzeffs product.

9. D

Sol. PT  PAo X A  PBo XB

760 = 520XA  PBo 1  XA 
 X A  0.5
Thus, mole% of A = 50%

10. B

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NJEETS-2022 - FT - 3 -PCM -21

Sol. T f  Kt .m

11. D

Sol. We know, G  H  TS

So, lets find the equilibrium temperature, i.e. at which
G  0
H  TS
179.1 1000
T
160.2
= 1118 K
So, at temperature above this, the reaction will become spontaneous.
Hence, D is correct answer.
12. B

1
Sol. For the process Cl2  g  Claq


2
1
H  Hdiss of Cl2   egCl   hyd Cl
2
240
  349  381
2
=  610 kJ mol1

13. C

Sol. G o   RT ln K and G o  H o  TSo

14. B

Sol. Correct order of acidic strength is III > I > II > IV

15. D

Sol. 2Al  s   6HCl  aq   2Al3   aq   6Cl   aq   3H 2  g 

For each mole of HCl reacted, 0.5 mole of H2 gas is formed at STP.
1 mole of an ideal gas occupies 22.4 lit at STP.
Volume of H2 gas formed at STP per mole of HCl reacted is 22.4 × 0.5 litre

16. A

Sol. Metal oxide = M0.98O

If ‘x’ ions of M are in +3 state, then
3x + (0.98 – x) × 2 = 2
x = 0.04
0.04
So the percentage of metal in +3 state would be  100  4.08%
0.98
17. C

Sol. 4f  n  4
l3
m  l to  l
3 to  3

18. C
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NJEETS-2022 - FT - 3 -PCM -22

3
Sol. K.E. = RT
2
E T 293
 1  1 
E2 T2 313
313
 Change in average K.E. of neon atom by a factor =
293
19. B

Sol. Most probable velocity increase and fraction of molecule possessing most probable velocity decreases.

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NJEETS-2022 - FT - 3 -PCM -23

20. C

Sol. Let the mass of methane and oxygen is w

w
mole fraction of oxygen = 32
w w

32 16
1 1
32 32 1
  
1 1 3 3

32 16 32
Let the total pressure be P
The pressure exerted by oxygen (partial pressure) = XO2 × Ptotal
1
 P
3
Hence, C is correct.

PART – C
1. 2

Sol. Rate law equation = K  NOBr2  NO 

KC 
 NOBr2 
 NO Br2 
 NOBr2   kc  NO  Br2 
2
Rate law equation = K .KC  NO   Br2 
Hence order is 2 w.r.t. NO.

2. 5

HA   H 
Sol. 

H2 A  
 HA  H

K1     ...(1)
H2 A 
H   A 2  


HA   
H  A
2
K2       ...(2)
HA 
 
For the reaction

H2 A   
 2H  A
2

2
H   A 2  
K     = K1 × K2
H2 A 
= 1 × 10-5 × 5 × 10-10
= 5 × 10-15

3. 5

Sol.  H    K a .C  103  K a .101

 K a  105

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NJEETS-2022 - FT - 3 -PCM -24

4. 2

Sol. In (NiX4)2– , Ni+2 = [18]3d8

4s 4p

3
sp hybridisation in [NiX4]

 Geometry is tetrahedral consisting of 2 unpaired electrons.

5. 1

Sol.  y y
Cx H y  x   O 2 
 xCO2  H 2 O
 4 2
Weight g 3.08 g 0.72 g
moles 0.07 0.04
x 0.07

y / 2 0.04
x 7
 
y 8

Section – III (Mathematics)

PART – A
1. A

x y 2 z 3 A (3, 1, 11)

Sol. Any point on the line   =  (say) is (2,
2 3 4
3 + 2, 4 + 3)
Dr’s of AB are (2 – 3, 3 + 3, 4 – 8) and that of the
given line are (2, 3, 4)
 29 – 29 = 0   = 1
 Point B is (2, 5, 7) and hence perpendicular
C (0, 2, 3) B (2, 3+2, 4+3)
distance is 53 .

2. C

4 2
Sol. v r
3
After 49 minutes volume  4500  49  72   972
4 3
r  927   r  9
3
dv 4 dr dr 72 2
 3r 2   
dt 3 dt dt 4.9.9 9
3. B

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NJEETS-2022 - FT - 3 -PCM -25

Sol. tr = 0.777 ….. r times

= 7 (10–1 + 10–2 + 10–3 + ….. + 10–r)
7
= 1  10 r 
9
20 20
7  7 1  7
S20   t r   20  10 r  =  20  1  1020   =
 179  10 20 
9   9  9  81
r 1  r 1 

4. B
10 10
10! 8! 8
Sol. S1 =  j  j  1 j  j  1 j  2 ! 10  j!  90  j  2! 8   j  2  !  90  2
j1 j2
.

10 10
10! 9! 9
S2 =  j j  j  1!  9   j  1 !  10  j  1!  9   j  1 !  10  2
j1 j1
.

10 10 10
10! 8 9
S3 =   j  j  1  j j! 10  j !   j  j  1
j 1 j 1
10
C j   j 10 C j = 90 . 2 + 10 . 2
j 1
8 8 8 9
= 90 . 2 + 20 . 2 = 110 . 2 = 55 . 2 .
5. B

Sol. Equation of circle (x  h)2 + (y  k)2 = k2

It is passing through ( 1, 1) then
( 1  h)2 + (1  k)2 = k2
h2 + 2h  2k + 2 = 0
D0
2k  1  0  k  1/2.

6. D
1 1
Sol.  4
 
2q = p + r
  2 ( + ) = 1 + 
 1 1 1
2    1
    
1
 =9

Equation having roots ,  is 9x2 + 4x  1 = 0
4  16  36
,  =
29
2 13
|  | = .
9

7. B

x
Sol. g  x    cos 4tdt
0

sin 4x sin 4x
 g '  x   cos 4x  g  x    k  g x   g  0   0 
4 4 
g  x    g  x   g    g     0 

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NJEETS-2022 - FT - 3 -PCM -26

8. A

Sol. For no solution

k 1 8 4k
  … (1)
k k  3 3k  1
 (k + 1) (k + 3)  8k = 0
2
or k  4k + 3 = 0  k = 1, 3
But for k = 1, equation (1) is not satisfied
Hence k = 3.

9. C

dy y y y
Sol.   log
dx x x x
dy dv
Let y  vx v x
dx dx
dv
 v  x  v  v log v
dx
dv dx
 v log v   x
1
Let log v  t dv  dt
v
dt dx
 t  x
t  cx
log v  cx
 y
log    cx
x

10. B

Sol.
x2 y 2
x 2  4y 2  4    1  a  2, b  1  P   2, 1
4 1
x2 y 2 x2 y2 P (2, 1)
Required Ellipse is 2  2  1  2  2  1
a b 4 b
1
(2, 1) lies on it V’ V
A 2 (4, 0)
4 1 1 1 3 4 A’ 2
   1  2  1    b2 
16 b2 b 4 4 3
x2 y2 x 2 3y2
   1   1  x 2  12y 2  16
16  4  16 4
 
3
11. D
1 1
Sol.
4
 sin 4 x  cos 4 x    sin 6 x  cos 6 x 
6
3  sin x  cos x   2  sin 6 x  cos 6 x 
4 4

=
12
3 1  2 sin 2 x cos 2 x   2 1  3 sin 2 x cos 2 x  1
= =
12 12

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NJEETS-2022 - FT - 3 -PCM -27

12. B
Sol.  f  x  dx    x 
3
Let x = t
2
3x dx = dt
1
 x f  x  dx tf  t  dt
5 3
then =
3
1 1
=
3 
 
t f  t dt   1   f  t  dt dt  = x 3   x 3    x 2   x 3  dx  C .
 3

13. D
Sol. f (g (x)) = x
f (g (x)) g (x) = 1
5
g (x) = 1   g  x  

14. B
 13 
Sol. S  , 1  , P(2, 2)
 2 
2
Slope = 
9
y 1 2
Equation will be 
x 1 9
9y + 9 + 2x – 2 = 0
2x + 9y + 7 = 0

15. A
 2x  1   1
Sol. f  x    x  cos      x  cos  x   
 2   2
  x  sin x is continuous for every real x

16. D
1  1
   
1
Sol. A  u1  u 2    1   u1  u 2  A  1 
0 0
   
A 1
 1 2 1  1 0 1
Co-factor (A) = 0
 1 2  A   2 1 0 
1

 1 0 1   1 2 1 
 1 0 1  1   1 
 u1  u2  2 1 0   1    1
 1 2 1   0   1
17. A

Sol. Q  2t 2 , 4t  , P  1, 0  , mid point M  h, k 

2t 2  1 4t  0
h ,k
2 2
2
k 
 2h  2    1  y2  4x  2
2
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NJEETS-2022 - FT - 3 -PCM -28

18. D
7!
Sol. Other than S, seven letters M, I, I, I, P, P, I can be arranged in = 7 . 5 . 3.
2! 4!
Now four S can be placed in 8 spaces in 8C4 ways.
8 6 8
Desired number of ways = 7 . 5 . 3 . C4 = 7 . C4 . C4.

19. B
Sol. Let A be the event that maximum is 6.
B be event that minimum is 3
5
C2
P A  8  the numbers  6 are 5
C3
5
C2
P  B  8  the numbers  3are 5 
C3
2
C1
P  A  B  8
C3
 B  P  A  B
2
C 2 1
Required probability is P     5 1  
A PA C 2 10 5

20. D
p
 2a 1   p  1 d  p 2 2a   p  1 d p
Sol. 2  2 1 
q
 2a 1   q  1 d  q 2a1   q  1 d q
2
 p 1 
a1   d
 2  p
 q 1  q
a1   d
 2 
a a 11
For 6 , p  11, q  41  6 
a 21 a 21 41

PART – C
1. 1

Sol. curve passes through (0, 1) and  1  e, 0 

curve: x  e y  e y axis: x  0
1 1
1
A    x y  axis  xcurve  dy   0   e y  e  dy  ey  e y  0   e  e    0  1   1
0 0

2. 1

Sol. Let z = x + iy
|z – 1| = |z + 1|  Re z = 0 x=0
|z – 1| = |z – i| x=y
|z + 1| = |z – i|  y = –x
Only (0, 0) will satisfy all conditions.
 Number of complex number z = 1

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NJEETS-2022 - FT - 3 -PCM -29

3. 4

Sol.  2 sin x  1  sin x  3   0

1
sin x 
2
 5 13 17 
 4 solutions in  0, 3 , , and
6 6 6 6
4. 2

p 1 1
Sol. 1 q 1
1 1 r
p(qr  1)  1(r  1) + (1  q) = 0
pqr  p  r + 1 + 1  q = 0
pqr  (p + r + q) = 2.

5. 1

       2
Sol. a  b b  c c  a   a b c 
   
 = 1.

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