Reversible Reactions:) Is Exceptionally High, Then This

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Reversible Reactions

Many chemical reactions can proceed in one direction only. i.e. they cannot be reversed and
they go towards completion.

e.g. Neutralisation reaction between potassium hydroxide & hydrochloric Acid

KOH(aq) + HCl(aq) → KCl(aq) + H2O(l)

Some chemical reactions can be reversible .i.e. reactions can go either directions and they
reached an equilibrium, instead of going towards completion.

At equilibrium, the forward and backward reactions do not stop; they continue, but at the same
speed. Hence, there is no overall change in the amounts of reactants and products.

At the end of reaction, a mixture of reactants and products is present and they are known to be
in equilibrium.

e.g. Haber Process:           N2(g) + 3H2(g) ⇌ 2NH3(g)

By altering conditions of temperature, pressure and  use of catalysts, these reactions can be
adjusted to favour more reactants or more products.

Whether a reaction is reversible or irreversible depends on activation energy.

If the activation energy of the reverse reaction (i.e. Eb) is exceptionally high, then this
reaction will be unfavourable and the reaction is described as irreversible.

A reversible reaction (⇌) is a reaction that can take place in both directions – i.e. forward reaction
and backward reaction.

When the rate of forward reaction is equal to the rate of backward reaction, the reaction is said to
have reached a state of dynamic equilibrium.
When a chemical reaction reaches a state of dynamic equilibrium:

 the rate of forward reaction is equal to the rate of backward reaction


 the concentration of reactants and products remain unchanged (constant)
The composition of an equilibrium mixture in a reversible reaction can be altered by changes in:

 concentration
 temperature
 pressure
 We have already seen that a reversible reaction is one that occurs in both directions

 When during the course of reaction, the rate of the forward reaction equals the rate of the

reverse reaction, then the overall reaction is said to be in a state of equilibrium

 Equilibrium is dynamic i.e. the molecules on the left and right of the equation

are changing into each other by chemical reactions constantly and at the same rate

 The concentration of reactants and products remains constant (given there is no other change

to the system such as temperature and pressure)

 It only occurs in a closed system so that none of the participating chemical species are able to

leave the reaction vessel

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