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    Mole Concept/Redox Reactions: 3cu + 8H + 2NO 3 Cu + 4 H O + 2no

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    Ashley Lewis
    1. The document discusses several redox reactions involving caproic acid, hydrocarbons, copper, and manganese. It provides the empirical and molecular formulas for caproic acid and a hydrocarbon based on combustion data. 2. It also examines the oxidation states of nitrogen in different compounds involved in the reaction of copper with nitric acid. The document identifies steps in this reaction as oxidation or reduction and deduces related half equations. 3. Finally, it analyzes the redox reaction of manganese(VII) ion with iodide, defining oxidation and reduction, identifying the role of manganate ion, and deducing the overall equation.

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    Mole Concept/Redox Reactions: 3cu + 8H + 2NO 3 Cu + 4 H O + 2no

    Uploaded by

    Ashley Lewis
    38 views1 page
    1. The document discusses several redox reactions involving caproic acid, hydrocarbons, copper, and manganese. It provides the empirical and molecular formulas for caproic acid and a hydrocarbon based on combustion data. 2. It also examines the oxidation states of nitrogen in different compounds involved in the reaction of copper with nitric acid. The document identifies steps in this reaction as oxidation or reduction and deduces related half equations. 3. Finally, it analyzes the redox reaction of manganese(VII) ion with iodide, defining oxidation and reduction, identifying the role of manganate ion, and deducing the overall equation.

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    MOLE CONCEPT cw1

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    1. The document discusses several redox reactions involving caproic acid, hydrocarbons, copper, and manganese. It provides the empirical and molecular formulas for caproic acid and a hydrocarbon based on combustion data. 2. It also examines the oxidation states of nitrogen in different compounds involved in the reaction of copper with nitric acid. The document identifies steps in this reaction as oxidation or reduction and deduces related half equations. 3. Finally, it analyzes the redox reaction of manganese(VII) ion with iodide, defining oxidation and reduction, identifying the role of manganate ion, and deducing the overall equation.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    38 views1 page

    Mole Concept/Redox Reactions: 3cu + 8H + 2NO 3 Cu + 4 H O + 2no

    Uploaded by

    Ashley Lewis
    1. The document discusses several redox reactions involving caproic acid, hydrocarbons, copper, and manganese. It provides the empirical and molecular formulas for caproic acid and a hydrocarbon based on combustion data. 2. It also examines the oxidation states of nitrogen in different compounds involved in the reaction of copper with nitric acid. The document identifies steps in this reaction as oxidation or reduction and deduces related half equations. 3. Finally, it analyzes the redox reaction of manganese(VII) ion with iodide, defining oxidation and reduction, identifying the role of manganate ion, and deducing the overall equation.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 1

    MOLE CONCEPT/REDOX REACTIONS

    1. The foul odour of dirty socks may be attributed to caproic acid, an organic acid made of
    carbon, hydrogen and oxygen. The results of combustion of a 0.450 g sample of caproic
    acid indicate that it contains 0.279 g of C, 0.0467 g of H and 0.124 g of O. Calculate the
    empirical and molecular formula of caproic acid, given that its molar mass is 116 gmol-1.
    [6]
    2. A hydrocarbon, X gave 3.52 g of carbon dioxide and 1.62 g of water on complete
    combustion. Calculate the empirical formula and molecular formula of X if its molar
    mass is 114 gmol-1.
    [6]
    3. The oxide of nitrogen formed when copper reacts with nitric acid is indicated by the
    following equation:-
    3Cu + 8H+ + 2NO3- → 3 Cu2+ + 4 H2O + 2NO
    In warm, concentrated acid, NO2 is formed.
    (a) Give the oxidation states of nitrogen in NO3-, NO2 and NO. [3]
    (b) Identify, as oxidation or reduction, the formation of NO from NO3 in the presence of
    -

    H+ and deduce the half equation for the reaction. [2]


    (c) Deduce the half-equation for the formation of NO2 from NO3 . -
    [1]
    (d) Deduce the overall equation for the reaction of copper with NO 3 and H to produce
    - +

    Cu2+ ions, NO2 and water. [2]


    4. The manganite (VII) ion reacts in an acidic medium according to the half equation:-
    MnO4 - (aq) + 8H+ (aq) + 5e → Mn2+ (aq) + H2O (l)
    (a) (i) Define reduction and oxidation in terms of oxidation number. [2]
    (ii) Identify the role played by the MnO4 - ion in the redox reaction above and
    explain your answer in terms of oxidation number. [2]
    (b) An aqueous solution of potassium iodide, KI, reacts with acidified MnO 4– to form a
    red-brown solution on completion of the reaction.
    (i) Identify the species responsible for the red-brown colour. [1]
    (ii) Given that iodide ions react according to the following half equation:-
    2I- (aq) → I2 (aq) + 2e
    Deduce the equation for the redox reaction between MnO4- and I-. [3]

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