1 A non-conducting hollow cone has charge density .

A part ABP is cut and removed D

from the cone. The potential due to the remaining portion of the cone at point ‘P’ is

5R
6 0
5 R
24  0
5R
3 0
5 R
12  0
2   y C
A non-uniform magnetic field B  B0 1   k is present in the region of space
 
 d
between y = 0 and y = d. A particle of mass m and positive charge q has velocity
 3qB d
0 
v i at origin O. Find the angle made by velocity of the particle with the
m
positive x-axis when it leaves the field. (Ignore any interaction other than magnetic
field)
90o
30o
60o
45o
3 A non viscous, non compressible liquid of density  is filled in a large container. A A
cylinder of density 2, area of cross – section ‘A’ and length ‘L’ whose bottom just
touches the surface of the liquid is released gently as shown in the figure, the speed
of cylinder when whole length of cylinder is just immersed in the liquid is
 3 gL
2
2gL
5 gL
2
gL
2
4 When a system is taken through the process abc shown in figure, 80J of heat is B
absorbed by the system and 30J of work is done by it. If the system does 10J work
during process adc, the amount of heat that flows into the system during the process
adc is

P d c

a b
V
40 J
60 J
50 J
70 J
5 A conducting square ABCD of side a and resistance R is held in a region of magnetic C
field B (perpendicular to plane of square). The square is to maintain a constant
velocity V parallel to diagonal BD. If it starts motion at t = 0 from the position as
shown in the figure, then the power required to pull the square out of the magnetic
field as a function of time is
A
XXXXXXX
XXXXXXX
B D
V
XXXXXXX
B
XXXXXXX
C
2
4 B 2V 2  a 
  2Vt 
R  2 
2 2
BV  
2
a 2  Vt
R  
 2
4 B 2V 2  a 
  Vt 
R  2 
3B 2V 2
 a  Vt 2
R
6 A rod OA of mass ‘m’ and length L hinged at end O can rotate smoothly in vertical D
plane about an horizontal axis passing through O. It is released from a horizontal
position as shown in the figure and strikes a block of mass M kept vertically below O
at distance L on a smooth horizontal surface. The block after collision moves on the
smooth vertical circular track of diameter L such that the force exerted by the
circular track on the block at point C is one third of its weight. If the rod after
collision rotates through an angle 30o from the horizontal, the ratio of masses M/m
is

2 1
7
2 1
2 7
2 2
7
2 1
7
7 A particle of mass ‘m’ starts from origin and move in x-y plane velocity of particle is AD
 
given by v  k1i  k2 1   y j and its acceleration is a  g  ˆj where k1, k2 &  are
 
constant and ‘y’ is y-coordinate of position of particle. Choose the correct
statements:
m k22
Average force acting on particle
2
Force acting on particle decreases first then increases
Path of particle will be hyperbolic
Radius of curvature of the path followed by particle will decrease first then increase
8 A rod is free to rotate in horizontal plane about one of its end hinged at point ‘O’ as BCD
 shown in the figure. Point P & Q are fixed points located in horizontal plane in such
away that PO is perpendicular to rod & QO is along length of rod. A bullet hits the
rod perpendicularly at some distance from point ‘O’ and gets imbedded into it. Then:
Q

P O

Linear momentum of rod + bullet system will decrease after collision

Linear momentum of rod + bullet system may increase
Angular momentum of rod + bullet system about point ‘P’ will not change before &
after collision
Angular momentum of rod + bullet system about point ‘Q’ may increase after
collision
9 Two objects mass m and 4m are at rest at an infinite separation. They move towards BCD
each other under mutual attraction. If G is the universal gravitational constant. Then
at separation r.
The sum of energy of the two objects is negative
1/ 2
 10Gm 
Their relative velocity of approach is   in magnitude
 r 
4Gm2
The sum of kinetic energy of the objects is
r
The sum of angular momenta of both the objects is zero about any point
10 A block of mass 2kg is hanging over a smooth and light pulley through a light string. AD
The other end of string is pulled by a constant force F. The kinetic energy of block
increases by 16J in 2s, then
 Force F may be 24N
Force F must be 24N
Potential energy must be increased
Potential energy may increase
11 Charge q is uniformly distributed over the curved surface of a non-conducting hollow BD
right circular cone of mass ‘m’ and base radius R. Now a uniform vertical magnetic
field B parallel to the axis of cone is suddenly switched on in a vertical cylindrical
region of radius R whose axis coincides with the axis of the cone, then

Angular velocity acquired by the cone is qB/2m

Angular velocity acquired by the cone is qB/4m
Magnetic moment of cone is qR2/4
Magnetic moment of cone is qR2/2
12 Observe the circuit and consider the different operations. ABD
Operation I: Switch S1 is closed
Operation II: Switch S2 is closed
Operation III: Switch S3 is closed
Operation IV: Switch S4 is closed
(Assume all combined operations in each of the following options are simultaneous)
 E
Current derived by battery immediately after operation (I + II + III + IV) is
R1
Voltage across capacitor C1 immediately after operation (I + III) is zero
Voltage across capacitor C2 immediately after operation (I + IV) is E
Voltage across inductor long time after operations (I + III + IV) is zero
13 A charged particle of mass m and charge q is at rest due to the horizontal infinite ABD
non-conducting charged sheet as shown in the figure. If r is very small, then
m
q

2mq 0
Charge density of plate  
q
If charge particle is slowly displaced & released, it will still remain at rest in the new
position
If charge particle is displaced by a small distance & released then the motion of
charge particle is oscillatory
If charge particle is given a velocity v0 parallel to plate then it is continuously move
along the same direction with same velocity
14 A solenoid of inductance L and resistance r is connected in parallel to a resistance R. ABD
A battery of emf E and of negligible internal resistance is connected across this
parallel combination as shown in the figure. The circuit is in steady state. At time t =
0, switch S is opened. Choose the incorrect option(s).
 E r  R
Current in the inductor just after opening of the switch is 
rR
Total energy dissipated in the solenoid and the resistor long time after opening of
2 2
1 E R  r
the switch is L
2 r 2 R2
The amount of heat generated in the solenoid after the opening of switch is
E2L
2r  r  R 
The amount of heat generated in the solenoid after the opening of switch is
E2L
2R  r  R 
15 Paragraph for Questions 15 and 16 A
A cylinder of mass m and radius R is rolling without slipping on a horizontal surface
with angular velocity 0 . The velocity of centre of mass of cylinder is 0 R . The
cylinder comes across a step of height R/4. (Assume required friction is present at
edge of the step.) Answer the following questions based on above information.

Find the minimum angular velocity 0  of cylinder so that cylinder rides up the step
without slipping or jumping.
2 3g
5 R
3 3g
5 R
5 3g
2 R
g
3R
16 Find the maximum angular velocity   of cylinder so that cylinder rides up the A
0
step without slipping or jumping.
3 3g
5 R
2 3g
5 R
1 3g
2 R
5 3g
3 R
17 Paragraph for Questions 17 and 18 A
Nuclie of a radioactive element X are being produced at constant rate K and this
element decays to a stable nucleus Y with a decay constant  and half-life T1 . At
2
time t = 0, there are N0 nuclei of the element X.
The number Nx of nuclei of X at time t  T1 is
2
K   N0
2
1
 2 N0  K 

 K1
 N 0  2  
Data is insufficient
18 The number NY of nucleus Y at time is B
 K   N 0   t K   N 0
Kt   e 
   
 K   N 0   t K   N 0
Kt   e 
   
 K   N 0   t
Kt   e
  
 K   N 0   t
Kt   e
  
19 Compound [X] give following reactions- C
 Na - metal H 2  (gas)

2, 4 - DNP yellow - orange ppt

[X] , C6 H8O2

O3
B  C6 H 8O4 

[X] can be-

OH

CHO

H2C OH

O
OH

O
O

OH
H

O
20 A reaction gives the following results A
CH3OH
Ph - CH - Br  Ph - CH - OCH 3

CH 3 CH 3
70 % reacemisation
What should be the % age of back side attack assuming complete reactions?
65 %
30 %
35 %
85 %
21 A Ni anode and a Fe cathode are placed in a solution with  Ni 2   1M and then A
 
connected to a battery. The Fe cathode has the shape shown. Electrolysis be
continued with a current of 2A to build a 0.05 mm thick deposit of nickel (At.wt = 60)
on Fe. The time duration for which the electrolysis must be continued is
approximately:
[density of Ni  8.8g / cm3 & 1F  96500C ]
 3113.73 sec
1167.65 sec
4670.6 sec
2335.3 sec
22 Of the following statements concerning electrochemical cells, the correct one is: D
The cathode is the negative electrode in both voltaic and electrolytic cells
The function of a salt bridge is to permit the migration of electrons between the half
cell compartments of an electrochemical cell.
If electric current is drawn from a voltaic cell long enough, the cell becomes an
electrolytic cell
The negative terminal of a voltaic cell is connected to an electrode of an electrolytic
cell, it means that anode of voltaic cell is connected to cathode of electrolytic cell.
23 The disadvantage of carbon reduction method in metallurgy is: B
Low temperature needed which is expensive
Many metals combine with carbon forming carbides
Carbon combines with oxygen to form poisonous CO
Carbon cannot be used with highly electropositive metals
24 Which of the following has the highest value of bond angle? A
Cl2O
SF6
F2O
H2O
25 Identify the correct statement ABCD
H3C CH3

C C C

H H has C2 axis of symmetry

H3C CH3 H CH3

C C C & C C C
H3C H
H H are enantiomers of each other.
 CH 2OH
H OH
H OH
H OH
H has plane of symmetry
H3C H3C

&

are geometrical isomers of ether other

26 Consider the nucleophilic attacks given below. Select the pair(s) in which (I) shows ABC
the greater S N 2 reaction rate than (II).
CH3
CH3
O O
H3C
Br
+ CN or H3C + CN
H3C

(I)
(II)
H 3C - Br + SH or H 3C - Br + CH 3SH
(I) (II)

Br + Cl or Br + I in DMSO

(I) (II)

Br + Cl or Br + I in methanol

(I) (II)
27 Cl O ABCD
NO 2 Me
NH 2 - NH 2 (2eq) Me
[R] [S] + [T]
-NH 2 .NH 3+ .Cl  pH = 4 - 5
NO 2

[Q]
Correct statements regarding above reaction sequence-
[R] is 2,4-DNP
[Q] to [R] formation is SN Ar reaction
[S] & [T] are non super imposable non mirror image
 R  S  involve nucleophilic addition
28 Which of the following graphs is/are correct regarding mixing of three equimolar AD
gases at constant temperature and pressure.

 G mixing 
 
 nRT 

0 1 2 1
3 3
Mole fraction(x)

 G mixing 
 
 nRT 

0 1 1
2

Mole fraction(x)

Smixing
nR

0 1 1
2

Mole fraction(x)
 Smixing
nR

0 1 2 1
3 3
Mole fraction(x)

29 In a FCC metallic solid of “A” the octahedral void present at body centre of each cube ABC
is exactly occupied by “B” atoms without disturbing the crystal of “A” atoms. Which
of the following are correct about the crystal:
The formula of the crystal will be A4 B
Edge length of cube =  2 2   metallic radius of A
rB
 2 1
rA
Packing fraction of unit cell = 0.74
30 In qualitative analysis, K 2CrO4 is used to identify ABC
Pb2
Ba 2 
Ag 
K
31 Go through the following complexes, ACD
 3
1) trans  Co NH3 4 Cl2  (2) cis  Co NH3 2 . en2 
3
3) trans  Co NH3 2  en2  (4) NiCl24

(5) TiF62  (6) CoF63 

Choose the incorrect option(s):
(1), (2) are optically active, (3) is optically inactive
(2) is optically active; (1), (3) are optically inactive
(4), (5) are coloured and (6) is diamagnetic
(4) is coloured and (5), (6) are para magnetic
32 Which of the following ammonia salts do not liberate ammonia gas on heating? BCD
NH4 2 CO3
NH4 2 Cr2O7
NH4 ClO4
NH4 NO3
33 Paragraph for Questions 33 and 34 A
 1. dil KMnO4 , 0°C 1.NaOH
 2.NaIO 4
 [Q] C11 H12O 2 
2.H + / Δ
 [R] C11 H12O 2

1.CH 3 MgBr
[P] (excess)
2. HBr

O
[T] NaH
  [S] C13 H 19 BrO

Identify the structure of [R], which provide final reaction product [T]-
O

O O

34 Identify the structure of [S], which provide final reaction product [T]- A
CH 2OH

Br

Br

OH

Br

OH

OH

Br
35 Paragraph for Questions 35 and 36 C
Titration of diprotic acid  H 2 A  by strong base has been summarized in following
graph.

What are the pH of solution when it show maximum buffer action.

2.34, 6
6, 9.66
2.34, 9.66
6, 12
36 What is composition of mixture when pH of solution is 10.137 A
25 % HA  , 75% A 2
75 % HA  , 25% A 2
25 % HA  , 75% H2A
75 % HA  , 25% H2A
37  x  0, C
Let us consider the D.E..  x  y ln y  ydx   y  x ln x xdy,  and if y 1  1 then
 y  0 
1
number of values x when y  equals
2
0
1
2
3
38 ABC is equilateral. Incircle of ABC touches sides AB, AC at P,Q respectively. A A
line through P and Q meets circumcircle of ABC at R and S. (R is nearer to P) then
PQ
the value of equals
PR
5 1
2
5 1
2
3 1
2
 3 1
2
39 n n 1 n  2 An 2  Bn C
If    ..............n terms  A, B, C, D N, G.C.D of  A, B, C   1
1.2.3 2.3.4 3.4.5 C  n  D
then A + B + C + D equals
4
6
8
10
40 If a,b,c,x,y,z are real numbers satisfying the equations 11x  by  cz  0 , ax  31 y  cz  0 D
, ax  by  41z  0 . Suppose a  11, b  31, c  41, x  0 then the value of
11 31 41
  equals
a  11 b  31 c  41
2
0
-1
-2
41 A line through P   2, 4, 7 that intersects and perpendicular to the line B
x  1  t , y  2  3t , z  4 meets the plane x  y  z  25 at Q  ,  ,   then the value of
 max of  ,  
 min of  ,   ( . is GIF is)
 
4
5
6
7
42 n
 n  k  n k k m  n m n m A
If S      p k .q m 1  p  1  q  and S 1     pq 1  pq then
k  m  k  m   m
S  S1
S  mn . S 1
S 1  mn . S
m
S1  . S
n
43 In a class of 20 students having 20 chairs in 5 rows of 4 each. If the class has 10 boys ABD
and 10 girls, and the number of ways in which all the students can sit in the chairs
such that no boy is sitting infront of, behind or next to another boy and no girl is
sitting infront of, behind or next to another girl is N then which is/are correct
Exponent of 2 in N is 17
Exponent of 3 in N is 8
Exponent of 5 in N is 6
Exponent of 7 in N is 2
44  at 2  3 ACD
 , t  5
If the function f  t  is continuous and given by f  t    t  5 then which
 bt  2, t  5
is/are correct
19
ab 
25
19
f 1  0  f 1  6 
5
The area bounded by y  f  x  , x  0, y  0 is 3/2
b
 a   5 . is GIF 
45 Let a, b, c be unit vectors. Let b and c are inclined to a , each at  . If the angle BCD


between b and c is then which is/are correct, given that x  a  b . a  c ,
3
 
y  abac .

 gives x  1/ 4
6

 gives y  2 / 3
6

 gives x  1/ 3
2

 gives y  1
2
46 If A is a 2 × 2 matrix over R (set of real numbers) with det  I  A  1  det A then ABCD
which of the following is/are correct (I is unit matrix)
trace of matrix A is 0
A2 is a diagonal matrix
A2 - I is a diagonal matrix
A  adj  A is a null matrix
47 If 3 apples (like) and 3 bananas (like) are distributed to three children at random then ABCD
which is/are correct
11
The chance that each child gets atleast one fruit is
20
The chance that each child gets one apple and one banana is p then sum of digits of
1
 p  is 6
 
3
The chance that all fruits go to one child is
100
3
The chance that all apples go to one child is
10
48 If the differential equation representing the family of confocal ellipses given by ABC
  
x2 y2  dy   y 
  2 where  is a parameter is given by  x  y.   x  dy   K then which
7 4 dx
 
dx 
is/are correct
K>2
K>3
K<7
K>6
49 Two circles C1 and C2 of radii 8 each are placed inside a semicircle C of radius 25. ABD
The two circles C1 and C2 are each tangent to the diameter of semicircle C and also
tangent to the semicircle C. Then which of the following is/are correct
The length of direct common tangent of C1 and C2 is 30
The length of transverse common tangent of C1 and C2 is 2 161
Area of  formed by centers of C , C1 , C2 is 60
15
The in radius of  formed by centers of C , C1 , C2 is
4
50 Let 3 x  y  8  0 is the equation of tangent to a parabola at the point  7,13 . If the ABD
focus of the parabola is at  1, 1 then which is/are correct
If x  py  q  0 is directrix then p < q
If lx  y  m  0 is its axis then l > m
5
Length of latus rectum of parabola is 2
13
x intercept of latus rectum line is - 9
51 Paragraph for Questions 51 and 52 B
Let f  x   sin 4  x and g  x   ln x . Let x0 , x1 , x2 ..........xn 1 be the roots of f  x  g  x  in
increasing order.
Answer the following.
The maximum value of n is equal to
2
3
4
5
52 The whole area bounded by y  f  x  , y  g  x  , x  0 is equal to A
11
8
15
8
13
8
17
8
53 Paragraph for Questions 53 and 54 A
Let a, b, c be 3 vectors whose magnitudes are a,b,c respectively and c  a  b . If a > b
and c divides angle between the two vectors a and b in the ratio 1:  then answer
the following
For the value of   2 which is correct
a 2  b2
c
b
a  b2
2
c
2b
a  b2
2
c
a
a  b2
2
c
2a
54 For the value of   3 which is correct A
c
 a  b a b
b

c
 a  b ab
b

c
 a  b a b
a

c
 a  b a b
2 b