SAFETY DATA SHEET

17051

Section 1. Identification
Product name : ACE® GLO SPRAY Fluorescent
Sun Glow Orange
Product code : 17051
Other means of : Not available.
identification
Product type : Aerosol.
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.

Manufacturer : Mfd. for:

ACE HARDWARE COPORATION
Oak Brook, IL 60521

Emergency telephone : (216) 566-2917

number of the company
Product Information : Not available.
Telephone Number
Regulatory Information : (216) 566-2902
Telephone Number
Transportation Emergency : (800) 424-9300
Telephone Number

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE AEROSOLS - Category 1
substance or mixture GASES UNDER PRESSURE - Compressed gas
ACUTE TOXICITY (inhalation) - Category 4
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 1A
TOXIC TO REPRODUCTION (Fertility) - Category 2
TOXIC TO REPRODUCTION (Unborn child) - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation and Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 54.8%
GHS label elements
Hazard pictograms :

Signal word : Danger

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Section 2. Hazards identification
Hazard statements : Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
May cause cancer.
Suspected of damaging fertility or the unborn child.
May be fatal if swallowed and enters airways.
May cause respiratory irritation.
May cause drowsiness and dizziness.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
General : Read label before use. Keep out of reach of children. If medical advice is needed, have
product container or label at hand.
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Use personal protective equipment as required. Wear
protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces,
sparks, open flames and other ignition sources. No smoking. Pressurized container: Do
not pierce or burn, even after use. Do not spray on an open flame or other ignition
source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist.
Wash hands thoroughly after handling.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF
SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce
vomiting. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated
clothing. Wash contaminated clothing before reuse. If skin irritation occurs: Get
medical attention. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical attention.
Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label Adequate ventilation required when sanding or abrading the dried film. If Adequate
elements ventilation cannot be provided wear an approved particulate respirator (NIOSH
approved). Follow respirator manufacturer's directions for respirator use. DELAYED
EFFECTS FROM LONG TERM OVEREXPOSURE. Abrading or sanding of the dry film
may release crystalline silica which has been shown to cause lung damage and cancer
under long term exposure. DANGER: Rags, steel wool, other waste soaked with this
product, and sanding residue may spontaneously catch fire if improperly discarded.
Immediately place rags, steel wool, other waste soaked with this product, and sanding
residue in a sealed, water-filled, metal container. Dispose of in accordance with local fire
regulations. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains
solvents which can cause permanent brain and nervous system damage. Intentional
misuse by deliberately concentrating and inhaling the contents can be harmful or fatal.
WARNING: This product contains chemicals known to the State of California to cause
cancer and birth defects or other reproductive harm.
Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do
not discard empty can in trash compactor.
Hazards not otherwise : None known.
classified

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Section 3. Composition/information on ingredients
Substance/mixture : Mixture
Other means of : Not available.
identification

CAS number/other identifiers

Ingredient name % by weight CAS number
Acetone 15.0 67-64-1
Propane 12.7 74-98-6
Butane 12.2 106-97-8
Xylene 11.5 1330-20-7
Lt. Aliphatic Hydrocarbon Solvent 9.3 64742-89-8
Ethylbenzene 2.0 100-41-4
Toluene 1.2 108-88-3
Hexane 1.0 110-54-3
Quartz 0.2 14808-60-7
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause
drowsiness and dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation.
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Section 4. First aid measures
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways. Irritating to mouth, throat and stomach.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and
from the chemical the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled from
a fire at high speed. Runoff to sewer may create fire or explosion hazard.

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Section 5. Fire-fighting measures
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
metal oxide/oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Pressurized
container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do
not pierce or burn, even after use. Avoid exposure - obtain special instructions before
use. Avoid exposure during pregnancy. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not swallow. Avoid breathing gas. Use only with adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Store and use away from
heat, sparks, open flame or any other ignition source. Use explosion-proof electrical
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Section 7. Handling and storage
(ventilating, lighting and material handling) equipment. Use only non-sparking tools.
Empty containers retain product residue and can be hazardous.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store away from direct sunlight in a dry, cool
including any and well-ventilated area, away from incompatible materials (see Section 10) and food
incompatibilities and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use
appropriate containment to avoid environmental contamination.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Acetone ACGIH TLV (United States, 4/2014).
TWA: 500 ppm 8 hours.
TWA: 1188 mg/m³ 8 hours.
STEL: 750 ppm 15 minutes.
STEL: 1782 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 250 ppm 10 hours.
TWA: 590 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 2400 mg/m³ 8 hours.
Propane NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours.
TWA: 1800 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
Butane NIOSH REL (United States, 10/2013).
TWA: 800 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
ACGIH TLV (United States, 4/2014).
STEL: 1000 ppm 15 minutes.
Xylene ACGIH TLV (United States, 4/2014).
TWA: 100 ppm 8 hours.
TWA: 434 mg/m³ 8 hours.
STEL: 150 ppm 15 minutes.
STEL: 651 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.
Ethylbenzene ACGIH TLV (United States, 4/2014).
TWA: 20 ppm 8 hours.
NIOSH REL (United States, 10/2013).
TWA: 100 ppm 10 hours.
TWA: 435 mg/m³ 10 hours.
STEL: 125 ppm 15 minutes.
STEL: 545 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.

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Section 8. Exposure controls/personal protection
Toluene OSHA PEL Z2 (United States, 2/2013).
TWA: 200 ppm 8 hours.
CEIL: 300 ppm
AMP: 500 ppm 10 minutes.
NIOSH REL (United States, 10/2013).
TWA: 100 ppm 10 hours.
TWA: 375 mg/m³ 10 hours.
STEL: 150 ppm 15 minutes.
STEL: 560 mg/m³ 15 minutes.
ACGIH TLV (United States, 4/2014).
TWA: 20 ppm 8 hours.
Hexane ACGIH TLV (United States, 4/2014).
Absorbed through skin.
TWA: 50 ppm 8 hours.
NIOSH REL (United States, 10/2013).
TWA: 50 ppm 10 hours.
TWA: 180 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 500 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
Quartz OSHA PEL Z3 (United States, 2/2013).
TWA: 250 MPPCF / (%SiO2+5) 8 hours.
Form: Respirable
TWA: 10 MG/M3 / (%SiO2+2) 8 hours. Form:
Respirable
ACGIH TLV (United States, 4/2014).
TWA: 0.025 mg/m³ 8 hours. Form:
Respirable fraction
NIOSH REL (United States, 10/2013).
TWA: 0.05 mg/m³ 10 hours. Form: respirable
dust

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection

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Section 8. Exposure controls/personal protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.

Section 9. Physical and chemical properties

Appearance
Physical state : Liquid.
Color : Not available.
Odor : Not available.
Odor threshold : Not available.
pH : 7
Melting point : Not available.
Boiling point : Not available.
Flash point : Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]
Evaporation rate : 9.1 (butyl acetate = 1)
Flammability (solid, gas) : Not available.
Lower and upper explosive : Lower: 0.9%
(flammable) limits Upper: 12.8%
Vapor pressure : 13.5 kPa (101.325 mm Hg) [at 20°C]
Vapor density : 1.55 [Air = 1]
Relative density : 0.83
Solubility : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (room temperature): <0.205 cm2/s (<20.5 cSt)
Kinematic (40°C (104°F)): <0.205 cm2/s (<20.5 cSt)
Aerosol product
Type of aerosol : Spray
Heat of combustion : 0.00002434 kJ/g

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Section 10. Stability and reactivity
Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame).

Incompatible materials : No specific data.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Acetone LD50 Oral Rat 5800 mg/kg -
Butane LC50 Inhalation Vapor Rat 658000 mg/m³ 4 hours
Xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours
LD50 Oral Rat 4300 mg/kg -
Ethylbenzene LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 3500 mg/kg -
Toluene LC50 Inhalation Vapor Rat 49 g/m³ 4 hours
LD50 Oral Rat 636 mg/kg -
Hexane LC50 Inhalation Gas. Rat 48000 ppm 4 hours
LD50 Oral Rat 15840 mg/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Acetone Eyes - Mild irritant Human - 186300 parts -
per million
Eyes - Mild irritant Rabbit - 10 microliters -
Eyes - Moderate irritant Rabbit - 24 hours 20 -
milligrams
Eyes - Severe irritant Rabbit - 20 milligrams -
Skin - Mild irritant Rabbit - 24 hours 500 -
milligrams
Skin - Mild irritant Rabbit - 395 -
milligrams
Xylene Eyes - Mild irritant Rabbit - 87 milligrams -
Eyes - Severe irritant Rabbit - 24 hours 5 -
milligrams
Skin - Mild irritant Rat - 8 hours 60 -
microliters
Skin - Moderate irritant Rabbit - 24 hours 500 -
milligrams
Skin - Moderate irritant Rabbit - 100 Percent -
Ethylbenzene Eyes - Severe irritant Rabbit - 500 -
milligrams
Skin - Mild irritant Rabbit - 24 hours 15 -
milligrams
Toluene Eyes - Mild irritant Rabbit - 0.5 minutes -
100
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Section 11. Toxicological information
milligrams
Eyes - Mild irritant Rabbit - 870 -
Micrograms
Eyes - Severe irritant Rabbit - 24 hours 2 -
milligrams
Skin - Mild irritant Pig - 24 hours 250 -
microliters
Skin - Mild irritant Rabbit - 435 -
milligrams
Skin - Moderate irritant Rabbit - 24 hours 20 -
milligrams
Skin - Moderate irritant Rabbit - 500 -
milligrams
Hexane Eyes - Mild irritant Rabbit - 10 milligrams -
Sensitization
Not available.

Mutagenicity
Not available.

Carcinogenicity
Not available.
Classification
Product/ingredient name OSHA IARC NTP
Xylene - 3 -
Ethylbenzene - 2B -
Toluene - 3 -
Quartz - 1 Known to be a human carcinogen.
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Acetone Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Propane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Butane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Xylene Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Lt. Aliphatic Hydrocarbon Solvent Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Ethylbenzene Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Toluene Category 3 Not applicable. Respiratory tract
irritation and
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Section 11. Toxicological information
Narcotic effects
Hexane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
Acetone Category 2 Not determined Not determined
Propane Category 2 Not determined Not determined
Butane Category 2 Not determined Not determined
Xylene Category 2 Not determined Not determined
Lt. Aliphatic Hydrocarbon Solvent Category 2 Not determined Not determined
Ethylbenzene Category 2 Not determined Not determined
Toluene Category 2 Not determined Not determined
Hexane Category 2 Not determined Not determined
Aspiration hazard
Name Result
Propane ASPIRATION HAZARD - Category 1
Butane ASPIRATION HAZARD - Category 1
Xylene ASPIRATION HAZARD - Category 1
Lt. Aliphatic Hydrocarbon Solvent ASPIRATION HAZARD - Category 1
Ethylbenzene ASPIRATION HAZARD - Category 1
Toluene ASPIRATION HAZARD - Category 1
Hexane ASPIRATION HAZARD - Category 1

Information on the likely : Not available.

routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause
drowsiness and dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways. Irritating to mouth, throat and stomach.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations

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Skin contact : Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.

General : May cause damage to organs through prolonged or repeated exposure.

Carcinogenicity : May cause cancer. Risk of cancer depends on duration and level of exposure.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : Suspected of damaging the unborn child.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : Suspected of damaging fertility.

Numerical measures of toxicity

Acute toxicity estimates
Route ATE value
Oral 8824.8 mg/kg
Inhalation (gases) 19638.7 ppm

Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
Acetone Acute EC50 20.565 mg/l Marine water Algae - Ulva pertusa 96 hours
Acute LC50 6000000 µg/l Fresh water Crustaceans - Gammarus pulex 48 hours
Acute LC50 10000 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 5600 ppm Fresh water Fish - Poecilia reticulata 96 hours
Chronic NOEC 4.95 mg/l Marine water Algae - Ulva pertusa 96 hours
Chronic NOEC 0.016 ml/L Fresh water Crustaceans - Daphniidae 21 days
Chronic NOEC 0.1 ml/L Fresh water Daphnia - Daphnia magna - 21 days
Neonate
Chronic NOEC 5 µg/l Marine water Fish - Gasterosteus aculeatus - 42 days
Larvae
Xylene Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes 48 hours
pugio

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Section 12. Ecological information
Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours
Lt. Aliphatic Hydrocarbon Acute LC50 >100000 ppm Fresh water Fish - Oncorhynchus mykiss 96 hours
Solvent
Ethylbenzene Acute EC50 4600 µg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata
Acute EC50 3600 µg/l Fresh water Algae - Pseudokirchneriella 96 hours
subcapitata
Acute EC50 6530 µg/l Fresh water Crustaceans - Artemia sp. - 48 hours
Nauplii
Acute EC50 2930 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Neonate
Acute LC50 4200 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours
Toluene Acute EC50 12500 µg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata
Acute EC50 11600 µg/l Fresh water Crustaceans - Gammarus 48 hours
pseudolimnaeus - Adult
Acute EC50 6000 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Juvenile (Fledgling, Hatchling,
Weanling)
Acute LC50 5500 µg/l Fresh water Fish - Oncorhynchus kisutch - Fry 96 hours
Chronic NOEC 1000 µg/l Fresh water Daphnia - Daphnia magna 21 days
Hexane Acute LC50 2500 µg/l Fresh water Fish - Pimephales promelas 96 hours

Persistence and degradability

Product/ingredient name Aquatic half-life Photolysis Biodegradability
Acetone - - Readily
Xylene - - Readily
Ethylbenzene - - Readily
Toluene - - Readily

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Xylene - 8.1 to 25.9 low
Lt. Aliphatic Hydrocarbon - 10 to 2500 high
Solvent
Toluene - 90 low
Hexane - 501.187 high

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Do not
puncture or incinerate container.
Date of issue/Date of revision : 5/1/2015. Date of previous issue : No previous validation. Version :1 13/15
Section 14. Transport information
DOT TDG Mexico IATA IMDG
Classification Classification Classification
UN number UN1950 UN1950 UN1950 UN1950 UN1950

UN proper AEROSOLS AEROSOLS AEROSOLS AEROSOLS, AEROSOLS

shipping name flammable
Transport 2.1 2.1 2.1 2.1 2.1
hazard class(es)

Packing group - - - - -
Environmental No. No. No. No. No.
hazards
Additional Special Special Special Special Emergency
information provisions provisions provisions provisions schedules (EmS)
LIMITED LIMITED (ERG#126) LIMITED LIMITED
QUANTITY QUANTITY QUANTITY QUANTITY, F-D,
S-U

Special precautions for user : Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.

Transport in bulk according : Not available.

to Annex II of MARPOL
73/78 and the IBC Code

Section 15. Regulatory information

U.S. Federal regulations :
State regulations
California Prop. 65
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.

Section 16. Other information

Hazardous Material Information System (U.S.A.)
Health * 2

Flammability 3
Physical hazards 0

Date of issue/Date of revision : 5/1/2015. Date of previous issue : No previous validation. Version :1 14/15
Section 16. Other information
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.

Notice to reader
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Regulatory requirements are subject to change and may differ between various
locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all
country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of
the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use
of this product. The customer/buyer/user should not use the product for any purpose other than the purpose
shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling
instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the
manufacturer cannot be responsible for SDSs obtained from any other source.

Date of issue/Date of revision : 5/1/2015. Date of previous issue : No previous validation. Version :1 15/15