Thermodynamics Report
Thermodynamics Report
REPORT
ON
The energy of the universe, like its mass, is constant. Yet most of the times we read articles
and listen speeches on how the energy can be conserved. The fact is we also know that the energy
is always conserved. And exergy is not conserved in our universe. Once the exergy is destroyed,
energy and exergy analysis is done. Both approach is useful in determining various characteristics
of thermal systems. But in practical application of generating power, exergy analysis is preferred
as it gives more exposure towards the potential of the thermal system and tells about how cost is
INTROUCTION
systems for the conversion of energy from one form to another. Conventional thermodynamic
analysis is based primarily on the first law of thermodynamics, which states the principle of
track of energies entering the system and energies leaving the system. The exiting energy is
categorized into two parts, namely products and wastes. Efficiencies are often evaluated as ratios
of energy quantities and are often used to assess and compare performance of various systems.
The thermodynamic losses takes place within a system are not accurately identified and assessed
with energy analysis. This drives the attention of engineers and scientists towards finding an
alternative way to describe those losses. Thus, exergy comes into the picture [3].
To understand exergy, let’s consider an isolated system consisting initially of a small container
of fuel surrounded by air. With time the fuel burns completely and produces warm air inside the
system. Say, we couple a machine with the fuel container such that we get some work while the
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fuel burns. Thus in the first case, the potential of the system to produce work is totally wasted and
Exergy is defined as the maximum amount of work that can be produced by a stream or system
as it is brought into equilibrium with a reference environment, and it can be thought of as a measure
of the usefulness or quality of energy. Exergy analysis involves the application of exergy concepts,
balances, and efficiencies to evaluate and improve energy and other systems. Application of exergy
analysis has given us more beneficial opportunities through a big part of a wide range of processes
and systems particularly for the evaluation of energy systems and technologies as well as an
environmental impact in all existing thermal and nuclear power plants [3].
Discussion
thermodynamics, so we start from the fact that it deals with the amounts of energy of various forms
transferred between the system and its surroundings and with the changes in the energy stored in
the system. It treats work and heat interactions as equivalent forms of energy in transit and specifies
nothing about the possibility of a spontaneous process proceeding in a certain direction. The first
law provides no restriction on the direction of a process, but satisfying the first law does not ensure
that the process can actually occur. This inadequacy of the first law to identify whether a process
can take place is remedied by introducing another general principle, the second law of
thermodynamics. The energy-related engineering systems are designed and their performance is
evaluated primarily by using the energy balance deduced from the First law of thermodynamics.
First law of thermodynamics is traditionally applied to calculate the enthalpy balances to quantify
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The exergy concept has gained considerable interest in the thermodynamic analysis of thermal
processes and plant systems since it has been seen that the First law analysis has been insufficient
from an energy performance stand point. The exergy method of analysis is based on the Second
law of thermodynamics and the concept of irreversible production of entropy. The simple energy
balance will not sometimes suffice to find out the system defect. In such circumstances the exergy
For high temperature air combustion and ultra-high temperature combined cycle it is necessary
to study the exergy analysis on combustion and thermodynamic processes, because ordinary
energy analysis does not have any evaluation supported at its temperature level. If we introduce
the exergy analysis against energy analysis, which is supported by this temperature level, it is clear
that the high temperature energy has a greater evaluation compared with low temperature one [3].
So, when considering the above mentioned processes, the exergy analysis must be introduced to
analyze power generation and heat pump cycles as against energy analysis. Recently a large
number of studies based on exergy analysis have been carried out by many researchers all over the
Conclusion
Exergy analysis is a powerful tool for developing, evaluating, and improving an energy
conversion system. Thermal system equipment efficiency and the optimization of existing thermal
power plants, energy losses in thermal systems can be easily assessed with the help of exergy
assessments. It can improve understanding of terms like energy conservation and energy crisis.
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References
[1] Moran, M. J., Shapiro, H. N., Boettner, D. D., & Bailey, M. B. (2010). Fundamentals
of engineering thermodynamics. John Wiley & Sons.
[4] Vundela Siva, R., Subash Chndra, K., Sudhir Kumar, T., & Narayanlal, P. (2010). An
approach to analyse energy and exergy analysis of thermal power plants: a review.
Smart Grid and Renewable Energy, 2010.