Granite Greisen & VMS Mineralization - 14112014

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S-type Granite

S-typeGranite

I-type Granite
Source: Brazil, England (Cornwall), Germany
(Saxony), Namibia, Pakistan, USA

The semi-precious gemstone known as "schorl" (aks


schšrle, schurel, schŸrl, schurl German, afrisite
Spanish) is a translucent to opaque mineral variety that
belongs to the tourmaline group of minerals. Schorl is
typically black or charcoal-gray in color.

The mineral was first identified in the early 1500s, by a German physician
named Ulrich RŸlein von Calw (1465-1523) of Freiberg, who wrote about
schŸrl in his book on mining entitled BergbŸchlein [2]. It was also mentioned
in the book Sarepta oder Bergpostill, written in 1562 by a German minister
named Johannes Mathesius, who lived in the mining town of J‡chymov, in
the St. Joachim's valley.
Crystal System trigonal
Crystal Habit parallel elongated, striated - asymmetrically terminated
Specific gravity (SG) 3.03 - 3.25
Mohs Hardness Scale 7.0 to 7.5
Toughness fair, brittle
Fracture irregular, uneven, small conchoidal
Cleavage indistinct, poor
Streak gray
Chemical Composition NaFe2+3Al6(BO3)3Si6O18(OH)4

Optical Properties double refractive, uniaxial negative


Refractive Index 1.61- 1.65
Birefringence -0.018 to -0.040
Pleochroism moderate to strong
Surface Luster vitreous to resinous
Diaphaneity translucent to opaque
Gem Color black, bluish-black, brownish-black, charcoal gray
Chemical and boron isotopic variations of tourmaline in the Hnilec granite-related hydrothermal syst
Constraints on magmatic and metamorphic fluid evolution
•Shao-Yong Jianga, Martin Radvanecb, Eizo Nakamurac, Martin Palmerd, Katsura Kobayashic, Hai-Xiang Zh
•Kui-Dong Zhaoa
•a State Key Laboratory for Mineral Deposits Research, Department of Earth Sciences, Nanjing University, N
PR China
•b Dionýz Štúr Institute of Geology, Geological Survey of Slovak Republic, Spišská Nová Ves, Slovakia
•c The Pheasant Memorial Laboratory for Geochemistry and Cosmochemistry, Institute for Study of the Earth
Okayama University at Misasa, Tottori-ken 682-0193, Japan
•d School of Ocean and Earth Sciences, University of Southampton, European Way, Southampton SO14 3ZH
•Received 30 August 2007. Accepted 22 April 2008. Available online 3 May 2008.

Abstract
Multi-stage formation of tourmaline occurs in the Hnilec granite-related
hydrothermal tin mineralisation system from the Western Carpathians,
Slovakia. The tourmalines belong to the schorl–dravite series and have two
major stages of formation: the majority crystallized during the first stage
(defined as M-stage), forming zoned tourmaline crystals with the cores being
generally more Fe, Al, and Mn rich than the rims. During the second stage
(defined as L-stage), tourmaline formed as small veins or irregular patches
along fractures and cracks in the M-stage tourmaline grains. In the contact
metapelites near the granite body, the L-stage tourmalines are more Mg-rich
and Fe, Al, Mn depleted than the M-stage tourmalines. In the granites, the L-
stage tourmalines have generally similar compositions to those of the M-
stage tourmaline rims. The boron isotopic compositions of the M-stage
tourmalines vary from − 10.3‰ to − 15.4‰; with no clear variation between
the cores and the rims, however, some of the tourmaline grains from the
contact metapelites show a slightly higher δ11B in the cores than in the rims.
The L-stage tourmalines have lower δ11B value of − 16.0‰ to − 17.1‰. We
suggest that these trends reflect a changing fluid source from a dominant
magmatic–hydrothermal fluid derived from the granites to a late-stage
metamorphic fluid derived from the regional metamorphism (chlorite and
biotite zone) in the metapelites. The significantly higher Fe3+ in the L-stage
than the M-stage tourmalines reflect changing redox conditions towards a
more oxidising environment. This redox condition change may have
important implications for the hydrothermal tin mineralisation in the area.
TOURMALINE

CHRYSOBERYL
AQUAMARINE
BERYL & MICROCLINE
Volcanic
Massive
Sulfide (VMS)
217.8 carats One of the World's
Biggest Emeralds - Mogul
Emerald, late 1690's. Photo
courtesy : Christie's.
Quartz and feldspars, Elongated microcline, Fluorite
octahedron,
size about 10cm. size 15,5 cm. from Zimnik quarry,
size 5.1 cm.

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