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    05 Worksheet 3 (Gen Chem) Relevo

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    cessarine relevo
    1. The document provides examples and explanations of equilibrium constant expressions (Kc and KP) for various chemical reactions. It includes the expressions for 5 chemical reactions, calculations of equilibrium concentrations and constants for the reactions 2NOCl(g) ⇌ 2NO(g) + Cl2(g) and PCl5(g) ⇌ PCl3(g) + Cl2(g), and expressions for the homogeneous/heterogeneous nature and equilibrium constants of 5 additional reactions.

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    © All Rights Reserved
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    05 Worksheet 3 (Gen Chem) Relevo

    Uploaded by

    cessarine relevo
    37 views2 pages
    1. The document provides examples and explanations of equilibrium constant expressions (Kc and KP) for various chemical reactions. It includes the expressions for 5 chemical reactions, calculations of equilibrium concentrations and constants for the reactions 2NOCl(g) ⇌ 2NO(g) + Cl2(g) and PCl5(g) ⇌ PCl3(g) + Cl2(g), and expressions for the homogeneous/heterogeneous nature and equilibrium constants of 5 additional reactions.

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    05 Worksheet 3 (gen chem) relevo

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    1. The document provides examples and explanations of equilibrium constant expressions (Kc and KP) for various chemical reactions. It includes the expressions for 5 chemical reactions, calculations of equilibrium concentrations and constants for the reactions 2NOCl(g) ⇌ 2NO(g) + Cl2(g) and PCl5(g) ⇌ PCl3(g) + Cl2(g), and expressions for the homogeneous/heterogeneous nature and equilibrium constants of 5 additional reactions.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    37 views2 pages

    05 Worksheet 3 (Gen Chem) Relevo

    Uploaded by

    cessarine relevo
    1. The document provides examples and explanations of equilibrium constant expressions (Kc and KP) for various chemical reactions. It includes the expressions for 5 chemical reactions, calculations of equilibrium concentrations and constants for the reactions 2NOCl(g) ⇌ 2NO(g) + Cl2(g) and PCl5(g) ⇌ PCl3(g) + Cl2(g), and expressions for the homogeneous/heterogeneous nature and equilibrium constants of 5 additional reactions.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 2

    SH1726

    Name: Relevo, Princess Margareth B. Section: ST1201


    Date: May 20, 2022 Score:

    Equilibrium Constant Expression


    Chemical Equilibrium

    Directions: Answer the following items. (5 items x 5 points)

    1. Write the expressions for the equilibrium constants KP of these thermal decompositions:
    a. 2NaHCO3(s) ⇌ Na2CO3(s) + CO2(g) + H2O(g)
    𝐴𝑛𝑠𝑤𝑒𝑟: 𝑲𝒑 = [𝑪𝑶𝟐 ][𝑯𝟐 𝑶]
    b. 2CaSO4(s) ⇌ 2CaO(s) + 2SO2(g) + O2(g)
    𝐴𝑛𝑠𝑤𝑒𝑟: 𝑲𝒑 = [𝑺𝑶𝟐 ]𝟐 [𝑶𝟐 ]
    2. A 2.50-mol quantity of NOCl was initially placed in a 1.50-L reaction chamber at 400°C.
    After equilibrium was established, it was found that 28.0 percent of the NOCl had
    dissociated:
    2NOCl(g) ⇌ 2NO(g) + Cl2(g)
    𝐴𝑛𝑠𝑤𝑒𝑟𝑠:
    2.50 𝑚𝑜𝑙
    [𝑁𝑂𝐶𝑙] = = 1.667 𝑚𝑜𝑙
    1.50 𝐿

    [𝑁𝑂𝐶𝑙] [𝑁𝑂] [𝐶𝑙2 ]


    Initial 1.667 0 0
    Change −2𝑥 +2𝑥 +𝑥
    Equilibrium 1.667 − 2𝑥 2𝑥 𝑥
    Calculate the equilibrium constant Kc for the reaction.

    [𝑁𝑂]2 [𝐶𝑙2 ] (2𝑥)2 (𝑥)


    [𝑁𝑂𝐶𝑙] − [NOCl equil] 𝐾𝑐 = =
    [𝑁𝑂𝐶𝑙]2 (1.667−2𝑥)2
    [2(0.2338]2 [0.2338]
    2𝑥 − 0.28 𝐾𝑐 = [1.667−2(0.2338)]2
    2𝑥 = 0.28(1.667) 𝑲𝒄 = 𝟎. 𝟎𝟑𝟓
    2𝑥 0.46676
    =
    2 2
    𝑥 = 0.2338

    3. The equilibrium constant KP for the decomposition of phosphorus pentachloride to


    phosphorus trichloride and molecular chlorine

    PCl5(g) ⇌ PCl3(g) + Cl2 (g)


    is found to be 1.05 at 250°C. If the equilibrium partial pressures of PCl5 and PCl3 are
    0.973 atm and 0.548 atm, respectively, what is the equilibrium partial pressure of Cl2 at
    250°C.
    𝐴𝑛𝑠𝑤𝑒𝑟𝑠:
    𝑎𝐴 ∙ 𝑏𝐵 ⇌ cC
    [0.548] 𝐶𝑙2 = 1.05 𝑥 0.973
    [0.548] 𝐶𝑙2 1.02165
    =
    0.548 0.548
    𝑪𝒍𝟐 = 𝟏. 𝟖𝟔 𝒂𝒕𝒎

    4. Methanol (CH3OH) is manufactured industrially by the reaction

    CO(g) + 2H2(g) ⇌ CH3OH(g)


    The equilibrium constant (Kc) for the reaction is 10.5 at 220°C. What is the value of KP at
    this temperature?
    𝐴𝑛𝑠𝑤𝑒𝑟𝑠:
    𝐹𝑜𝑟𝑚𝑢𝑙𝑎: 𝐾𝑝 = 𝑘𝑐 (𝑅𝑇)∆𝜂
    𝑆𝑜𝑙𝑢𝑡𝑖𝑜𝑛: ∆𝜂 = 1 − (2 + 1) = −2
    𝑅 = 0.08206
    𝑇 = 220 + 273.15
    = 493.15
    𝐾𝑝 = 10.5 (0.08206 𝑥 493.15)−2
    𝑲𝒑 = 𝟔. 𝟒 𝒙 𝟏𝟎−𝟑

    5. Write the equilibrium constant expression, Kc, for the following reactions. Indicate also if
    the equilibrium is homogeneous or heterogeneous.
    Type of
    Kc Expression
    Equilibrium
    [𝑁2𝑂][𝑁𝑂2]
    a. 3NO(g) ⇌ N2O(g) + NO2(g) 𝑘𝑐 = Homogenous
    [𝑁𝑂]3
    [𝐶𝑆2 ][𝐻2 ]4
    b. CH4(g) + 2H2S(g) ⇌ CS2(g) + 4H2(g) 𝑘𝑐 = Homogenous
    [𝑁𝑂]3
    [𝐻][𝑅]
    c. HF(aq) ⇌ H+(aq) + F–(aq) 𝑘𝑐 = Homogenous
    [𝐻]
    [𝐴𝑔]2
    d. 2Ag(s) + Zn2+(aq)⇌ 2Ag+(aq) + Zn(s) 𝑘𝑐 = Homogenous
    [𝑍𝑛 ]
    [𝐶𝑙 ]2
    e. 4HCl(aq) + O2(g) ⇌ 2H2O(l) + 2Cl2(g) 𝑘𝑐 = [𝐻𝐶𝑙]23[𝑂 Homogenous
    2]

    05 Worksheet 3 *Property of STI Page 1 of 1

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