Page 6 of 6 (F3 Chem P3)

CHEMISTRY
233/3
FORM III
FEB 2022

END OF YEAR 2022 EVALUATION TEST

CHEMISTRY PAPER 3 (PRACTICAL)
CONFIDENTIAL
1. APPARATUS
• Burette (50ml)
• Pipette (25ml) and pipette filler
• Three conical flasks
• 250mls volumetric flask
• 100mls measuring cylinder
• 10ml measuring cylinder
• 250ml beaker
• 6 test tubes 2 boiling tubes
• Metallic spatula
• Glass rod
• Retort stand
• White tile
• Filter funnel
• Two labels
• Distilled water (500cm3)

2. Solids
i) Y–
Mixture of
sodium
chloride and
sodium
carbonate
(Nacl – 1g,
Na2CO3 –
1.5g) 2.5g.
Accurately
weighed.
ii) Z–
0.5g
Pb(NO3)2 iii)
W – 1g
Maleic acid

3. Solutions
A – (4g/dm3 NaoH) – 0.1m – 120cm3/student
B – (0.1M HCl) - 200cm3/student
P – 3cm3 of sodium chloride solution /Student
E – 3cm3 of Barium Nitrate solution / Student

4. Access to:
• Methyl orange indicator
• Phenolphthalein indicator
• Universal indicator
• Acidified KMnO4aq
• PH chart
• Source of heat
• NaOH(aq)
• NaCl(aq)
• Ba(No3)2(aq)
NB: All the bench solutions are provided with a dropper

CHEMISTRY
233/1
FORM III
FEB/MARCH 2022

END OF YEAR 2021 EVALUATION TEST

CHEMISTRY PAPER 1
MARKING SCHEME
1. a) B – Almost colourless region
C – Pale blue zone
b) Closing and opening of air
hole

2. a) Hydrogen bond
b) Both have covalent bonds between their atoms, methane molecules are joined by weak
vander walls forces that requires little energy to break
water molecules are joined by hydrogen bond that requires a lot of energy to break.

3. a) U
b) Giant ionic
c) W has a larger atomic radius than X because X has more protons hence a stronger nuclear
charge

4 a) NaOCl(aq) + dye(coloured) NaCL (aq) + (dye = O)-colourless

b) Oxidation
c) Chlorine water contains hydrochloric acid which may be corrosive/irritating the
body skin while sodium hypochlorite decomposes to harmless sodium
chloride

5. React lead oxide with nitric(V)acid to form lead(II)nitrate solution . Dissolve sodium sulphate

in water to form a solution . Mix sodium sulphate solution with lead (II) nitrate solution

to produce a ppt lead (II) sulphate. Filter and wash the residue and dry between filter
papers
6 a)

Page 1
b) V1 = V2 = 4.8 x 10-2 = 3.2 x 10-2
T1 T2 298 T2

T2 = 3.2 x 10-2 x 298

4.8 x 10-2

= 198.667K

7. a) H H H H

HC C =C C H

H H

b) CH3

C
CH3 CH3

CH3
c) i) 2 – methyl prop –I – ene
ii) Pent –I-yne

8 a) Q – Calcium hydroxide
(1mk) b) T – Calcium hydrogen carbonate
(1mk)
c) CaCO3(s) + H2O(l) + CO2(g) Ca(HCO3)2(aq) (1mk)

9. a) Volume occupied by one mole (6.0 x 103 molecules) of any gas at a specific temperature
and pressure.
b) 3 x 24dm3 produce 2 x 56g moles of iron=1x1000 =17.857142
‫ ؞‬1000g 56
3 x 24 x 1000 = 642.86dm3 moles of CO= 17.857142x3 = 26.7857142
2 x 56 2
Volume of CO =(26.7857142x24)/1= 642.86dm3
(2mk)

10. a) In covalent the shared pair is donat ed equally by both atoms but in coordinate the shared pair
is donated fully by one atom

Page 2
11. a) TCL3

b) Its hydrolysed/broken down by water to form hydrochloric acid which is a strong acid.
12. a) Chloroflurocarbons

b) They are non-biodegradable hence pollute the environment

13. a) C H O
64.9 13.5 21.6 12 1 16
5.41 13.5 1.35
4 10 1 EF: C4H10O
b) (12 x 4 + 1 x 10 + 16+ x 1) = 74
74n = 74
n=1
Mc =
C4H10O
H H H H

C - C HC - C - OH
H H
HH
14 a) I – Substitution
II –
Addition

b) C3H6 is more reactive than C3H8 hence sunlight is not required to split Br 2 molecule in (ii) but
required to split Br2 in (i)
c) Halogenation/Bromination

15. a) A; has irregular/unfixed M.P. and B.P

b. i) Particles in a solid are joined by stronger bonds, hence vibrate/move less while particles in
liquids and gases are joined by weaker bonds hence move far apart. ii) Particles in the gases
loose heat and move closer forming stronger bonds.
16. CaCL2(aq) Ca2(aq) + 2Cl(aq)
0.3 x 250 = 0.075 moles
1000

0.075 x 2 x 6.0 x 1023

 1
= 9.0
x 1022

17. a) A white solid and yellow solid are formed

- Burning magnesium continues to burn

b) 2Mg(s) + SO2(g) 2 MgO(s) + S(s) (penalize fully if not balanced)

18. a) Miscible liquids are liquids that mix to form a uniform solution.
Immiscible liquids and liquids that mix to form two layers.

Page 3
b) i) To dissolve iodine hence separating it from potassium chlorine
ii) Mixture of iodine and methylbenzene

19 a) L
b) L and P; AI2O3 is amphoteric
c) To neutralize acids

20a) Rate of diffusion of a gas is inversely proportional to the square root of its density at
constant temperature and pressure

b) RN2 = 280 = 4cm3/sec 4 =√44 R

70 R2 √28 √44
RCO2 = 400 R=V/T T= 400 =153.53sec
T 8√7/66

Or if 280 70sec =100sec T2=

400 ? √44 T 2 √28

21. a) I – Cu2+
II – Fe3+

b) 2Fe3+(aq) + H2S(g) 2Fe2+(aq) + 2H+(aq) + S(s)

22. a) Chlorine gas
b) Colourless gas produced
Solution becomes less yellow until it become colourless (any 1 mark)

c) Turns red then it is bleached. Hydrochloric acid is acidic which chloric(I) acid is a bleaching
agent

23. V3+ - Neutrons – 14, Electrons – 10 Q-2 atomic mass – 16, electrons – 10

24. a)Platinum wire continues to glow

A brown gas is produced
b) 4NH3(g) + 5O2(g) 4NO(g) + 6H2O(g)
2NO(g) + O2(g) 2NO2(g)

25. Nitrogen has a triple covalent bond which is very stable. Hence a lot of energy is required to
be broken

26. a)Thistle funnel does not touch the bottom of the flask
b) Hydrogen peroxide
c) Slightly soluble in water

27. Bulb lights and a brown gas is produced at the anode while grey beads are formed at the
cathode. This is due to decomposition of lead(II)bromide by electricity to lead and bromine
gas. -Experiment should be carried out in a fume chamber

Page 4
CHEMISTRY
233/2
FORM III
FEB 2022
 END OF YEAR 2021 EVALUATION TEST
CHEMISTRY PAPER 2
MARKING SCHEME
1. a) i) D
ii) E Has smallest atomic radius / strongest nuclear attraction/higher tendency to gain
electron.
b) Halogen
c) Group(VII) /above E and G, has a valency of one or can lose or gain one
electron d) D2F3 Rej. F3D2
e) i) B or J ii) C or K
f) 2J(s)+2H2O(l) 2JOH(aq)+H2(g)
g) i) K has a larger atomic radius than G G has more protons that pull its energy level closer to
the nucleus. /G has more protons hence stronger nuclear attraction reducing its size
ii) J is more reactive than B; J has more energy levels /weaker nuclear attraction/higher
tendency to lose electrons

2. a) i) A substance that is formed when the hydrogen ion in an acid are wholly or partially
replaced by a positive ion. /metal/metallic radical
ii) Heat copper in air to form copper(II)oxide Addthe formed oxide into dilute HCl and stir
till excess
filter to recover the unreacted CuO and solution of copper(II)chloride Saturate the

fil;trate and set it for crystallization /heat filtrate to evaporate excess water, cool for
crystal to form. Filter and dry the crystals between filter papers

b) i) Reaction between lead(II)carbonate and dilute sulphuric(VI)acid form insoluble

lead(II)sulphate that coated the remaining carbonate preventing its contact with the acid
hence reaction stopped.
ii) Calcium carbonate
c) i) Formation of brown fumes Mercury nitrate decomposed to form nitrogen(IV)oxide which is
brown mercury and oxygen gas. (Tied)
ii) Hg(NO3)2 Hg(s) + 2NO2(g) + O2(g)
iii) Making fire works and Gun powder
D. Sulphur(IV)oxide , Sulphur(VI)oxide
3. i) But – 2 – ene
ii) But – i- yne

b) i)
CnH2n
ii) 72

Page 1
iii) C5H12

H H HH

C = C -C - C -C = H

H H H H H

c) i) Step 1
Hydrogen gas Rej. H2
Step II
Hydrogen chloride Rej HCL

ii) 2C2H2 + 5O2 4CO2 + 2H2O

iii) H H H H

H -C -C -C -C - H

H H H 2,2-dimethylpropane

H - C - H
H C - C - C - C -
H H C = H n-pentane
 H HH H H
H H H H H
H

H - C - H

H - H - C - C - H 2,2-dimethylpropane

H H

H - C - H

H
4. a) Fractional distillation of liquid air
b) i) H – Dust particles ii) Gas P – Carbon(IV)oxide
c) It would react with carbon(IV)oxide to form solid calcium carbonate that would block the
system /system would be blocked by calcium carbonate. Rej. System would be blocked.
d) Air is cooled to -250c and separates as ice (Tied)
e) Temperature of -2000c pressure of 200 atm. Penalize fully if units omitted.
f) Fractional distillation is carried out, Nitrogen has the lowest boiling point, distills out first
followed by oxygen and then argon
g) Nitrogen prepared in the laboratory contains nobble gases while one prepared in this
method does not
(tied)/nitrogen prepared in laboratory is impure and the one in this method is
pure/Nitrogen prepared in the laboratory is heavier than the one in this method.
h) As a refrigerant in storage of semen for artificial insemination.
5. (i)
ii) CO. MM = 12+16= 28
800cm3 ± 10
1g 800cm3
28g
28 x 800 = 22400cm3
1
b) i) 2NaOH(aq) + H2SO4(aq) Na2SO4(aq) + 2H2O(l)
ii) moles = 0.5 x 40 = 0.02 moles

1000
iii) NaOH:
H2SO4
2 : 1
Moles of NaOH used = 2 x moles of H2SO4 moles of NaOH in 100cm3 =2x0.02=0.04
= 2 x 0.02 = 0.04 moles moles of NaOH in 1000cm3=0.04x1000/100
=0.4moles
Mass of NaOH in 100cm3 = 0.04 x 40 Mass of NaOH =0.4x40
=1.6g = 16g

Mass of NaOH in 1000cm3

1000 x 1.6 =16g
100

iv) Mas of NaCl = 17.6 =1.0g

– 16.0

v) 1 x 100 = 5.68%
17.6

6. a) i) Dehydration
ii) To absorb carbon(IV)oxide
iii) PbO(s) + CO(g) Pb(s) + CO2(g)

b) i) Black CuO turns to brown solid ii) It is poisonous when inhaled

iii) 2CO(g) + O2(g) 2CO2(g) iv) Prevents blowing off copper(II)oxide solid
by CO2 gas coming under pressure

7. a) Frasch process

b) i) Super heated water at 1700c; to melt the sulphuror ore

ii) Hot compressed air , To force air out
through pipe iii)Transport sulphur froth to the
surface c) Ore occurs close to the surface
Insoluble in water
Has low melting point (any two)

d) Yellow sulphur dissolves to form a colourless solution; sulphur is oxidized to

H2SO4 acid A brown gas is produced ; HNO3 is reduced to
Nitrogen(IV)oxide

e) Sulphur is heated in air to form sulphur(IV)oxide

Sulphur(IV)oxide is reacted with oxygen in the presence of V 2O5 catalyst to form SO3 gas

SO3 is dissolved in conc. H2SO4 to form Oleum

Oleum is dissolved in water to form H2SO4

f) i) 2NH3(g) + H2SO4 (NH4)2 SO4(aq) RFM(NH4)2SO4

132 ii) 0.098kg H2SO4 0.132kg moles of (NH4)2SO4 =
25x1000/132 =189.394 moles
‫؞‬ 25kg

= 25 x 0.098 = 18.561 kg moles of H2SO4=moles of (NH4)2SO4

0.132 =189.394 moles
Mass of H2SO4= (189.394x98)kg
1000

=18.560kg
 Page 4
CHEMISTRY
233/3
FORM III
FEB 2022
END OF YEAR 2021 EVALUATION TEST
CHEMISTRY PAPER 3
MARKING SCHEME
PROCEDURE 1
1. Table 1
Complete table (1mk)
Decimal (1mk) (1dp or 2dp)
Accuracy ± 0.1 ± 0.2 of S.V
Averaging – consistent values ± 0.1 or ± 0.2
- working
Final answer – Compare average volume with
S.V ± 0.1 ± 0.2
b) i) Moles of NaOH
= 4 = 0.1M
40
Moles in 25cm3
= 0.1 x 25
1000
= 0.0025 moles
ii) Mole ratio NaOH : Moles of HCl 1:1
Moles of HCl in average volume = Moles of NaOH = 0.0025 x 1
1
= 0.0025 moles
iii) Molarity of acid = 0.0025 x 1000 = Answer b(iii)
 Average volume (answ. a)
PROCEDU
RE II
Table II
(5mks)
i) Complete table
ii) Decimal (1 or 2dp)
iii) Accuracy ± or ± 0.2 of S.V
iv) Averaging – Consistent values ± 0.1 or ± 0.2
- Working
v) Final answer – compare average volume with S.V ± 0.1 or ±0.2
d) = answer b(iii) x answer c
1000 = answer (d)
e) i) Moles of X2CO3
= Answer d = Answer e (i)
2
ii) Molarity of X2CO3
= Answer e(i) x 1000 = Answer e (ii)
25

Page 1
f) Mass of X2CO3
2.5 x 1000 =
100g/dm3 25
g) Mass of X2CO3
= e (ii) x 106 = Answer g
Mass of chloride XCl = 100 – answer g
Percentage of XCl = 100 – answer g x 100%
100
= Final answer
2 a)
Procedure one Expected observations
 - To solid K in a boiling tube, Add 8cm 3 of - Solid
distilled water and shake. Divide the dissolvesto form
resulting solution into three portions. colourless solution
- To the first portion add three drops of
ammonia, then add the alkali in excess - White precipitate . Insoluble in
excess
Procedure two Expected observations
- To the second portion, add three drops of White precipitate
sodium sulphate
Procedure three Expected observations
- To the third portion in a slanted test tube
carefully add three drops of conc. Sulphuric Brown ring
(VI) acid followed by Iron(II)sulphate
b)
Observation Inference
i) White precipitate soluble in excess Zn2+, Al3+, Pb2+ present
ii) White precipitate Pb2+ present
iii) No white precipitate SO32-, SO42-, CO32- absent
c)
Solution Observation Inference
P Yellow flame Na+ present
E Green flame Ba2+ present
3.
Observations Inferences
a) Solid melts and burns with a yellow flame

b) i) Solid dissolves to form a colourless - solid is soluble

solution - compound is polar
ii) Purple colour of acidified potassium
manganate VII changes to colourless

iii)
Procedure Observation Nature of solution
- to about 2cm3 of the solution add two PH4 Weak acid
drops of universal indicator.
- Match the colour obtained against the
PH chart/scale