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JEE MAIN 2021

ONLINE
25th February
1st Shift

PHYSICS 6. Given below are two statements: one is labelled as

Assertion A and the other is labelled as Reason R.
SECTION-A (MULTIPLE CHOICE QUESTIONS) Assertion A : The escape velocities of planet A and B
1. Match List-I with List-II. are same. But A and B are of unequal mass.
List-I List-II Reason R : The product of their mass and radius must
(A) h (Planck’s constant) (i) [MLT–1] be same. M1R1 = M2R2.
(B) E (kinetic energy) (ii) [ML2T–1] In the light of the above statements, choose the most
(C) V (electric potential) (iii) [ML2T–2] appropriate answer from the options given below.
(D) P (linear momentum) (iv) [ML2I–1T–3] (a) A is correct but R is not correct.
Choose the correct answer from the options given (b) Both A and R are correct but R is not the correct
below. explanation of A.
(a) (A) → (ii), (B) → (iii), (C) → (iv), (D) → (i) (c) A is not correct but R is correct.
(b) (A) → (iii), (B) → (ii), (C) → (iv), (D) → (i) (d) Both A and R are correct and R is the correct
(c) (A) → (iii), (B) → (iv), (C) → (ii), (D) → (i)
explanation of A.
(d) (A) → (i), (B) → (ii), (C) → (iv), (D) → (iii)
7. Given below are two statements:
2. A proton, a deuteron and an a-particle are moving
Statement I: A speech signal of 2 kHz is used to
with same momentum in a uniform magnetic field. The
ratio of magnetic forces acting on them is _____ and modulate a carrier signal of 1 MHz. The bandwidth
their speed is ______, in the ratio. requirement for the signal is 4 kHz.
(a) 4 : 2 : 1 and 2 : 1 : 1 (b) 1 : 2 : 4 and 1 : 1 : 2 Statement II : The side band frequencies are 1002 kHz
(c) 2 : 1 : 1 and 4 : 2 : 1 (d) 1 : 2 : 4 and 2 : 1 : 1 and 998 kHz.
In the light of the above statements, choose the correct
3. Two radioactive substances X and Y originally have
N1 and N2 nuclei respectively. Half life of X is half of answer from the options given below.
the half life of Y. After three half lives of Y, number of (a) Both statement I and statement II are true.
N (b) Both statement I and statement II are false.
nuclei of both are equal. The ratio 1 will be equal to (c) Statement I is true but statement II is false.
N2
(d) Statement I is false but statement II is true.
(a) 1/8 (b) 3/1 (c) 1/3 (d) 8/1
4. Two coherent light sources having intensity in the 8. The angular frequency of alternating current in a LCR
ratio 2x produce an interference pattern. The ratio circuit is 100 rad/s. The components connected are
I max − I min shown in the figure. Find the value of inductance of the
will be coil and capacity of condenser.
I max + I min R = 60 W

2x 2 2x 15 V
2 2x 2x
(a) (b) (c) (d)
x +1 x +1 2x + 1 2x + 1 C 10 V R′ = 40 W L 20 V
5. A 5 V battery is connected D1 10 W
across the points X and Y.
Assume D1 and D2 to be (a) 0.8 H and 150 mF (b) 1.33 H and 250 mF
D2
normal silicon diodes. Find 5W
(c) 1.33 H and 150 mF (d) 0.8 H and 250 mF
the current supplied by the
battery if the +ve terminal 9. A solid sphere of radius R gravitationally attracts a
X Y
of the battery is connected particle placed at 3R from its centre with a force F1.
to point X. Now a spherical cavity of radius (R/2) is made in the
(a) ~ 0.86 A (b) ~ 0.5 A sphere (as shown in figure) and the force becomes F2.
(c) ~ 1.5 A (d) ~ 0.43 A The value of F1 : F2 is
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14. A student is performing the experiment of resonance

column. The diameter of the column tube is 6 cm. The
B A
frequency of the tuning fork is 504 Hz. Speed of the
O m sound at the given temperature is 336 m/s. The zero
2R of the metre scale coincides with the top end of the
resonance column tube. The reading of the water level
M
in the column when the first resonance occurs is
(a) 41 : 50 (b) 25 : 36 (a) 14.8 cm (b) 13 cm
(c) 36 : 25 (d) 50 : 41 (c) 16.6 cm (d) 18.4 cm
10. Given below are two statements: one is labelled as 7 5
15. A diatomic gas having CP = R and CV = R , is
Assertion A and the other is labelled as Reason R. 2 2
Assertion A : When a rod lying freely is heated, no heated at constant pressure. The ratio dU : dQ : dW
thermal stress is developed in it. (a) 3 : 7 : 2 (b) 5 : 7 : 2
Reason R : On heating, the length of the rod increases. (c) 3 : 5 : 2 (d) 5 : 7 : 3
In the light of the above statements, choose the correct 16. An a-particle and a proton are accelerated from rest
answer from the options given below. by a potential difference of 200 V. After this, their
(a) A is true but R is false. de-Broglie wavelengths are la and lP respectively. The
(b) Both A and R are true and R is the correct λ
ratio P is
explanation of A. λα
(c) Both A and R are true but R is not the correct
(a) 8 (b) 3.8 (c) 7.8 (d) 2.8
explanation of A.
(d) A is false but R is true. 17. If the time period of a two meter long simple pendulum
is 2 s, the acceleration due to gravity at the place where
11. Two satellites A and B of masses pendulum is executing simple harmonic motion is
200 kg and 400 kg are revolving B (a) 2p2 m s–2 (b) 9.8 m s–2
round the earth at height of 600 km A 2
(c) p m s –2
(d) 16 m s–2
and 1600 km respectively. If TA
E 18. The current (i ) at time t = 0 and t = ∞ respectively for
and TB are the time periods of A
the given circuit is
and B respectively then the value 5W 5W
of TB – TA
i
(Given : radius of earth = 6400 km,
E
mass of earth = 6 × 1024 kg)
(a) 4.24 × 103 s (b) 1.33 × 103 s 1W 4W

(c) 4.24 × 102 s (d) 3.33 × 102 s

12. In an octagon ABCDEFGH of equal side, what is the L
      
sum of AB + AC + AD + AE + AF + AG + AH , if 18 E 5E 10 E 5E
 (a) , (b) ,
^ ^ ^ A 55 18 33 18
AO = 2 i + 3 j − 4 k ? B
^ ^ ^ 5E 18 E 5E 10 E
(a) 16 i + 24 j + 32 k H C (c) , (d) ,
18 55 18 33
^ ^ ^ O
(b) 16 i + 24 j − 32 k 19. An engine of a train moving with uniform acceleration,
G D
(c) −16 i^− 24 ^j + 32 k^ passes the signal-post with velocity u and the last
^ ^ ^ F E compartment with velocity v. The velocity with which
(d) 16 i − 24 j + 32 k middle point of the train passes the signal post is
13. The pitch of the screw gauge is 1 mm and there are v 2 − u2
v −u
100 divisions on the circular scale. When nothing is (a) (b)
2 2
put in between the jaws, the zero of the circular scale
lies 8 divisions below the reference line. When a wire is u+v v 2 + u2
(c) (d)
placed between the jaws, the first linear scale division 2 2
is clearly visible while 72nd division on circular scale 20. Magnetic fields at two points on the axis of a circular
coincides with the reference line. The radius of the wire is coil at a distance of 0.05 m and 0.2 m from the centre
(a) 0.90 mm (b) 0.82 mm are in the ratio 8 : 1. The radius of the coil is _____.
(c) 1.64 mm (d) 1.80 mm (a) 1.0 m (b) 0.15 m (c) 0.2 m (d) 0.1 m
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SECTION-B (NUMERICAL VALUE TYPE) K1

E1
Attempt any 5 questions out of 10.
G
21. A coil of inductance 2 H having negligble resistance is E2 K2
connected to a source of supply whose voltage is given E
K
by V = 3t volt (where t is in second). If the voltage is
applied when t = 0, then the energy stored in the coil 20 cm J1
after 4 s is ______ J.
22. A monoatomic gas of mass 4.0 u is kept in an
insulated container. Container is moving, with velocity Rh J2 60 cm
30 m/s. If container is suddenly stopped then change in
x
temperature of the gas (R = gas constant) is . Value
3R B 1m
of x is ______.
30. The electric field in a region is given by
23. A small bob tied at one end of a thin string of length
1 m is describing a vertical circle so that the maximum   3 ^ 4 ^
E =  E0 i + E0 j  N/C. The ratio of flux of reported
and minimum tension in the string are in the ratio 5 5 
5 : 1. The velocity of the bob at the highest position is field through the rectangular surface of area 0.2 m2
______ m/s. (Take g = 10 m/s2)
(parallel to y-z plane) to that of the surface of area
24. In a certain thermodynamical process, the pressure of a 0.3 m2 (parallel to x-z plane) is a : b, where a = ______.
gas depends on its volume as kV3. The work done when
^ ^ ^
the temperature changes from 100°C to 300°C will be [Here i , j and k are unit vectors along x, y and z-axes
_____ nR, where n denotes number of moles of a gas. respectively
25. 512 identical drops of mercury are charged to a potential
CHEMISTRY
of 2 V each. The drops are joined to form a single drop.
The potential of this drop is ______ V. SECTION-A (MULTIPLE CHOICE QUESTIONS)
26. A transmitting station releases waves of wavelength 31. Identify A in the given chemical reaction.
960 m. A capacitor of 2.56 mF is used in the resonant
circuit. The self inductance of coil necessary for CH3
resonance is _____ × 10–8 H. CH2
CH3 Mo2O3
27. The same size images formed by a convex lens when the CH2 CH (A)
object is placed at 20 cm or at 10 cm from the lens. The 773 K, 10-20 atm (Major product)
CH2 CH3
focal length of convex lens is ______ cm. CH3
28. The potential energy U of a diatomic molecule is a (a) (b)
function dependent on r (interatomic distance) as
α β CH3
U= − −3
10
r r5 (c) (d)

where, a and b are positive constants. The equilibrium
a /b 32. The solubility of AgCN in a buffer solution of pH = 3
 2α 
distance between two atoms will be   , where is x. The value of x is
 β 
a = ______. [Assume : No cyano complex is formed : Ksp(AgCN) =
2.2 × 10–16 and Ka(HCN) = 6.2 × 10–10]
29. In the given circuit of potentiometer, the potential
(a) 0.625 × 10–6 (b) 2.2 × 10–16
difference E across AB (10 m length) is larger than –6
E1 and E2 as well. For key K1 (closed), the jockey is (c) 1.6 × 10 (d) 1.9 × 10–5
adjusted to touch the wire at point J1 so that there is 33. Which of the following equations depicts the oxidizing
no deflection in the galvanometer. Now the first battery nature of H2O2?
(E1) is replaced by second battery (E2) for working by (a) I2 + H2O2 + 2OH– 2I– + 2H2O + O2
making K1 open and K2 closed. The galvanometer gives
(b) KIO4 + H2O2 KIO3 + H2O + O2
E a
then null deflection at J2. The value of 1 is , where (c) Cl2 + H2O2 2HCl + O2
E2 b
a = ______. (d) 2I– + H2O2 + 2H+ I2 + 2H2O
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34. The correct statement about B2H6 is OCH3 I

(a) terminal B H bonds have less p-character when Cl Cl
compared to bridging bonds (c) A = B=
(b) the two B H B bonds are not of same length
(c) its fragment BH3, behaves as a Lewis base
(d) all B H B angles are of 120°. NO2 NO2
35. According to molecular orbital theory, the species OCH3 I
among the following that does not exist is
(a) Be2 (b) He+2 (c) O22– (d) He–2 (d) A = B=
36. In which of the following pairs, the outermost electronic Cl Cl
configuration will be the same?
NO2 NO2
(a) Cr+ and Mn2+ (b) Ni2+ and Cu+
2+
(c) V and Cr +
(d) Fe2+ and Co+ 40. The hybridization and magnetic nature of [Mn(CN)6]4–
and [Fe(CN)6]3–, respectively are
37. In Freundlich adsorption isotherm at moderate
(a) d2sp3 and diamagnetic
x
pressure, the extent of adsorption   is directly (b) d2sp3 and paramagnetic
proportional to P . The value of x is  m 
x
(c) sp3d2 and diamagnetic
1 (d) sp3d2 and paramagnetic.
(a) zero (b) 1 (d) ∞
(c)
n 41. Which statement is correct?
38. Which of the following reaction/s will not give (a) Neoprene is an addition copolymer used in plastic
p-aminoazobenzene? bucket manufacturing.
NO2
(b) Buna-N is a natural polymer.
(i) Sn/HCl (c) Buna-S is a synthetic and linear thermosetting
A. polymer.
(ii) HNO2
(iii) Aniline (d) Synthesis of Buna-S needs nascent oxygen.
NO2
42. Ellingham diagram is a graphical representation of
(i) NaBH4 (a) DG vs P (b) DH vs T
B. (c) (DG – TDS) vs T (d) DG vs T.
(ii) NaOH
(iii) Aniline
43. Given below are two statements :
NH2
Statement I : An allotrope of oxygen is an important
(i) HNO2 intermediate in the formation of reducing smog.
C. Statement II : Gases such as oxides of nitrogen and
(ii) Aniline, HCl
sulphur present in troposphere contribute to the
(a) A only (b) A and B (c) B only (d) C only formation of photochemical smog.
39. Identify A and B in the chemical reaction. In the light of the above statements, choose the correct
OCH3 answer from the options given below.
(a) Statement I is true but statement II is false.
HCl NaI (b) Statement I is false but statement II is true.
[A] dry acetone
[B]
(major) (major) (c) Both statement I and statement II are true.
(d) Both statement I and statement II are false.
NO2
OCH3 OCH3 44. Which one of the following reactions will not form
acetaldehyde?
Cl I CrO3 — H2SO4
(a) A = B= (a) CH3CH2OH
Pd(II)/Cu(II)
(b) CH2 CH2 + O2 H2O
NO2 NO2
Cu
OCH3 OCH3 (c) CH3CH2OH 573 K
Cl (i) DIBAL-H
(b) A = B= (d) CH3CN (ii) H2O
Cl
45. Compound(s) which will liberate carbon dioxide with
NO2 NO2 sodium bicarbonate solution is/are
 5

NH2 COOH 49. Which of the glycosidic linkage between galactose and
glucose is present in lactose?
A= B= (a) C–1 of glucose and C–4 of galactose
(b) C–1 of galactose and C–6 of glucose
NH2 NH2 OH (c) C–1 of glucose and C–6 of galactose
OH NO2 NO2 (d) C–1 of galactose and C–4 of glucose
C= 50. Given below are two statements :
Statement I : CeO2 can be used for oxidation of
NO2 aldehydes and ketones.
(a) A and B only (b) C only Statement II : Aqueous solution of EuSO4 is a strong
(c) B and C only (d) B only. reducing agent.
46. The major product of the following chemical reaction is In the light of the above statements, choose the correct
(1) H3O+, D answer from the options given below.
(2) SOCl2 (a) Both statement I and statement II are true.
CH3CH2CN (3) Pd/BaSO4, H2
? (b) Statement I is true but statement II is false.
(a) (CH3CH2CO)2O (b) CH3CH2CH2OH (c) Both statement I and statement II are false.
(c) CH3CH2CH3 (d) CH3CH2CHO (d) Statement I is false but statement II is true.
47. The plots of radial distribution functions for various SECTION-B (NUMERICAL VALUE TYPE)
orbitals of hydrogen atom against ‘r’ are given below: Attempt any 5 questions out of 10.
8 51. Consider the following chemical reaction :
4pr2R2n, l(r)

(1) Red hot Fe tube, 873 K

CH CH (2) CO, HCl, AlCl3
Product
(A) 4
The number of sp2-hybridized carbon atom(s) present
0 in the product is .
5 10
r(Å) 52. Among the following, the number of halide(s) which
is/are inert to hydrolysis is .
3
4pr2R2n, l(r)

A. BF3 B. SiCl4 C. PCl5 D. SF6

2
(B) 53. In basic medium CrO42– oxidises S2O32– to form SO42–
1
and itself changes into Cr(OH)4–. The volume of
0
5 10 0.154 M CrO42– required to react with 40 mL of
r(Å) 0.25 M S2O32– is mL. (Rounded-off to the
3 nearest integer)
4pr2R2n, l(r)

2 54. Using the provided information in the following paper

(C) chromatogram :
1

0
5 10 Solvent front
r(Å) B
2.0 2 cm
5 cm
4pr2R2n, l(r)

1.5
A
(D) 1.0
0.5 2 cm
0
5 10
r(Å)
Spot Base line
The correct plot for 3s-orbital is Fig : Paper chromatography for compounds A and B
(a) (C) (b) (A) (c) (B) (d) (D)
The calculated Rf value of A is × 10–1.
48. Complete combustion of 1.80 g of an oxygen containing
55. 0.4 g mixture of NaOH, Na2CO3 and some inert
compound (CxHyOz) gave 2.64 g of CO2 and 1.08 g
N
of H2O. The percentage of oxygen in the organic impurities was first titrated with HCl using
compound is 10
phenolphthalein as an indicator, 17.5 mL of HCl was
(a) 50.33 (b) 53.33 (c) 51.63 (d) 63.53
6

required at the end point. After this methyl orange was  π   π 3π   3π 11π 
added and titrated. 1.5 mL of same HCl was required for (b)  0,  ∪  , ∪ , 
the next end point. The weight percentage of Na2CO3  4 2 4   2 6 
in the mixture is . (Rounded-off to the nearest  π   3π 
(c)  0,  ∪  π,
integer)  2  2 
56. 1 molal aqueous solution of an electrolyte A2B3 is  π   π 3π   5π   3π 7 π 
(d)  0,  ∪  ,  ∪  π,  ∪  , 
60% ionised. The boiling point of the solution at 1 atm  4 2 4   4   2 4 
is K. (Rounded-off to the nearest integer)
63. The total number of positive integral solutions (x, y, z)
[Given : Kb for (H2O) = 0.52 K kg mol–1] such that xyz = 24 is
57. A car tyre is filled with nitrogen gas at 35 psi at 27°C. (a) 45 (b) 30 (c) 24 (d) 36
It will burst if pressure exceeds 40 psi. The temperature 64. A tangent is drawn to the parabola y2 = 6x which
in °C at which the car tyre will burst is . is perpendicular to the line 2x + y = 1. Which of the
(Rounded-off to the nearest integer) following points does NOT lie on it?
58. The reaction of cyanamide, NH2CN(s) with oxygen (a) (4, 5) (b) (5, 4) (c) (–6, 0) (d) (0, 3)
was run in a bomb calorimeter and DU was found to 65. A man is observing, from the top of a tower, a boat
be –742.24 kJ mol–1. The magnitude of DH298 for the speeding towards the tower from a certain point A,
reaction with uniform speed. At that point, angle of depression
3 of the boat with the man’s eye is 30° (Ignore man’s
NH2 CN(s ) + O2( g ) 
→ N2( g ) + O2( g ) + H2 O(l ) height). After sailing for 20 seconds, towards the base
2
of the tower (which is at the level of water), the boat has
is kJ. (Rounded-off to the nearest integer) reached a point B, where the angle of depression is 45°.
[Assume ideal gases and R = 8.314 J mol–1 K–1] Then the time taken (in seconds) by the boat from B to
59. For the reaction, aA + bB cC + dD, the plot of reach the base of the tower is
1 (a) 10( 3 + 1) (b) 10 3
log k vs is given below :
T (c) 10 (d) 10( 3 − 1)
The temperature at which the 2
slope = –10000 K x 2
y x2 y2
rate constant of the reaction log k 66. If the curves, + = 1 and + = 1 intersect
is 10–4 s–1 is K. a b c d
each other at an angle of 90°, then which of the following
(Rounded-off to the nearest
relations is TRUE?
integer) 1
T c+d
[Given : The rate constant of (a) ab = (b) a–b=c–d
a+b
the reaction is 10–5 s–1 at 500 K]
(c) a – c = b + d (d) a+b=c+d
60. The ionization enthalpy of Na+ formation from Na(g) is
67. When a missile is fired from a ship, the probability
495.8 kJ mol–1, while the electron gain enthalpy of Br is
that it is intercepted is 1/3 and the probability that the
–325.0 kJ mol–1. Given the lattice enthalpy of NaBr is
missile hits the target, given that it is not intercepted, is
–728.4 kJ mol–1. The energy for the formation of NaBr
ionic solid is (–) × 10–1 kJ mol–1. 3/4. If three missiles are fired independently from the
ship, then the probability that all three hit the target, is
MATHEMATICS (a) 1/8 (b) 3/8 (c) 3/4 (d) 1/27

SECTION-A (MULTIPLE CHOICE QUESTIONS) 68. Let f, g : N → N such that f(n + 1) = f(n) + f(1) ∀ n ∈ N
and g be any arbitrary function. Which of the following
∞ ∞
statements is NOT true?
61. If 0 < q, f < p/2, x = ∑ cos2n θ, y = ∑ sin2n φ and
n=0 n=0 (a) If f is onto, then f(n) = n ∀ n ∈ N
∞ (b) f is one-one
z= ∑ cos2n θ ⋅ sin2n φ, then (c) If fog is one-one, then g is one-one.
n=0
(a) xy – z = (x + y)z (b) xy + z = (x + y)z (d) If g is onto, then fog is one-one.
(c) xyz = 4 (d) xy + yz + zx = z 69. Let the lines (2 − i)z = (2 + i)z and (2 + i)z + (i − 2)z
62. All possible values of q ∈ [0, 2p] for which – 4i = 0, (here i2 = –1) be normal to a circle C. If the
sin2q + tan2q > 0 lie in line iz + z + 1 + i = 0 is tangent to this circle C, then its
radius is
 π   π 3π   7 π 
(a)  0,  ∪  , ∪ π, 3 3 1
 2   2 4   6  (a) (b) (c) (d) 3 2
2 2 2 2 2
 7

70. The equation of the line through the point (0, 1, 2) and 5 1 1 1
x −1 y +1 z −1 (a) (b) (c) (d)
perpendicular to the line = = is 216 72 36 54
2 3 −2
1
x y −1 z − 2 x y −1 z − 2 80. The value of
3
2 [x ]
(a) = = (b) = = ∫ x e dx , where [t] denotes the greatest
3 4 −3 3 4 3 −1
x y −1 z − 2 x y −1 z − 2 integer ≤ t, is
(c) = = (d) = =
−3 4 3 3 −4 3 1 e +1 e −1 e +1
(a) (b) (c) (d)
71. The integer k, for which the inequality x2 – 2(3k – 1)x + 3e 3e 3e 3
8k2 – 7 > 0 is valid for every x in R, is SECTION-B (NUMERICAL VALUE TYPE)
(a) 0 (b) 2 (c) 3 (d) 4 Attempt any 5 questions out of 10.
72. The value of the integral
  θ 
sin θ ⋅ sin 2θ(sin6 θ + sin 4 θ + sin2 θ) 2 sin 4 θ + 3 sin2 θ + 6  0 − tan   
dθ 2
∫ 1 − cos 2θ 81. If A =   and (I2 + A)(I2 – A)–1
 θ 
is (where c is a constant of integration)  tan  2  0 
1  
(a) [9 − 2 sin6 θ − 3 sin 4 θ − 6 sin2 θ]3/2 + c a −b 
18 2 2
= 
b a  , then 13(a + b ) is equal to .
1 2 4 6 3/ 2  
(b) [11 − 18 cos θ + 9 cos θ − 2 cos θ] + c
18 82. Let f(x) be a polynomial of degree 6 in x, in which
1 the coefficient of x6 is unity and it has extrema at
(c) [9 − 2 cos6 θ − 3 cos 4 θ − 6 cos2 θ]3/2 + c
18 f (x )
x = –1 and x = 1. If lim = 1, then 5 · f(2) is equal
1 x →0 x 3
(d) [11 − 18 sin2 θ + 9 sin 4 θ − 2 sin6 θ]3/2 + c to .
18
73. The image of the point (3, 5) in the line x – y + 1 = 0, lies x y z 
on  
83. Let A =  y z x  , where x, y and z are real numbers
(a) (x – 4)2 + (y + 2)2 = 16 (b) (x – 2)2 + (y – 2)2 = 12  z x y 
(c) (x – 4)2 + (y – 4)2 = 8 (d) (x – 2)2 + (y – 4)2 = 4
such that x + y + z > 0 and xyz = 2. If A2 = I3, then the
74. If Rolle’s theorem holds for the function f(x) = x3 – ax2
value of x3 + y3 + z3 is .
4
+ bx – 4, x ∈ [1, 2] with f ′   = 0, then ordered pair 84. The locus of the point of intersection of the lines
3
(a, b) is equal to ( 3 )kx + ky − 4 3 = 0 and 3x − y − 4( 3 )k = 0 is a
(a) (5, –8) (b) (5, 8) (c) (–5, 8) (d) (–5, –8) conic, whose eccentricity is .
75. Let a be the angle between the lines whose direction 85. The total number of numbers, lying between 100 and
cosines satisfy the equations l + m – n = 0 and 1000 that can be formed with the digits 1, 2, 3, 4, 5, if
l2 + m2 – n2 = 0. Then the value of sin4a + cos4a is the repetition of digits is not allowed and numbers are
(a) 3/4 (b) 5/8 (c) 3/8 (d) 1/2 divisible by either 3 or 5, is .
76. The statement A → (B → A) is equivalent to 86. If the system of equations
(a) A → (A ∧ B) (b) A → (A → B) kx + y + 2z = 1, 3x – y – 2z = 2, –2x – 2y – 4z = 3
(c) A → (A ∨ B) (d) A → (A ↔ B) has infinitely many solutions, then k is equal to .
77. If a curve passes through the origin and the slope of the 87. The graphs of sine and cosine functions, intersect
x2 − 4x + y + 8 each other at a number of points and between two
tangent to it at any point (x, y) is , then consecutive points of intersection, the two graphs
x −2
enclose the same area A. Then A4 is equal to .
this curve also passes through the point
(a) (5, 5) (b) (4, 4) (c) (4, 5) (d) (5, 4) 88. Let A1, A2, A3, .... be squares such that for each n ≥ 1, the
n length of the side of An equals the length of diagonal of
 1 1 An + 1. If the length of A1 is 12 cm, then the smallest value
1 + + ..... +
 2 n  of n for which area of An is less than one, is .
78. lim 1 +  is equal to
n→∞  n2  ^ ^ ^  ^ ^  ^ ^ ^
89. Let a = i + 2 j − k,b = i − j and c = i − j −k be three
 
(a) 1/e (b) 1/2 (c) 1 (d) 0 given vectors. If r is a vector such that r × a = c × a
   
79. The coefficients a, b and c of the quadratic equation, and r ⋅ b = 0, then r ⋅ a is equal to .
ax2 + bx + c = 0 are obtained by throwing a dice three 90. The number of points, at which the function
times. The probability that this equation has equal f(x) = |2x + 1| – 3|x + 2| + |x2 + x – 2|, x ∈ R is not
roots is differentiable, is .
8

1. (a) : h → [ML2T–1], E → [ML2T–2], V → [M1L2T–2C–1] 6. (a) : Escape velocity of planet does not depend on mass
P → [MLT–1] of object.
\ (A) → (ii), (B) → (iii), (C) → (iv), (D) → (i) 7. (a) : fm = 2 kHz
2. (c) : Charge Mass fc = 1 MHz = 1000 kHz
Proton e m Bandwidth = 2fm = 4 kHz
a-particle 2e 4m
\ Side frequencies will be = fc + fm
Deuteron e 2m
speed, v = P/m = (1000 ± 2) kHz
P P P = 998 kHz and 1002 kHz
v1 = , v2 = , v3 =
m 2m 4m 8. (d) : When the key is opened, the current is
\ v1 : v2 : v3 = 4 : 2 : 1 15 = Irms × R
15 = Irms × 60 ⇒ Irms = 0.25 A
qPB 20
F = qvB = And, 20 = Irms × X L ⇒ X L = = 80 Ω
m 0.25
qPB q×P×B 2qPB XL = wL
F1 = , F2 = , F3 =
m 2m 4m 80 = 100 × L ⇒ L = 0.8 H
\ F1 : F2 : F3 = 4 : 2 : 2 = 2 : 1 : 1 10
or 10 = Irms × XC ⇒ XC = = 40 Ω
1 0.25
3. (d) : T(1/2) (x ) = T(1/2) ( y )
2 1 1
XC = ⇒ C= = 250 × 10−6 F
lx = 2ly ωC 100 × 40
Now, t = 3Ty 9. (d) : Let initial mass of sphere is ‘M’.
By the equation of radioactivity,
GMm
Nx = N1e–lx ·3Ty ... (i) F1 =  ... (i)
Ny = N2e –ly ·3Ty ... (ii) 9R2
Nx = Ny (from question)
N1e–lx ·3Ty = N2e –ly ·3Ty
B A
3×0.693 O m
−2 λy ⋅ − λy ⋅ 3×0.693
N1e λy= N2 e λy 2R

–6ln2 –3ln2
N1e = N2e M
N1 3
\ = e 3 ln 2 = e ln 2 = 8 = 8 : 1 M 4 R
3
M
N2 Mass of cavity, M ′ = ⋅ π or M ′ =
I 4 3 3  2  8
4. (d) : 1 = 2 x πR
3
I2
2 GMm G(M / 8)m
2 F2 = −
I max  I1 + I2  I max  2 x + 1  9R2 (5R / 2)2
=  = =
I min  I1 − I2  I min  2 x − 1 
GMm GMm 41GMm
2 2
F2 = − or F2 = ...(ii)
2 2
I max − I min ( 2 x + 1) − ( 2 x − 1) 9R 50R 50 × 9R2
=
I max + I min ( 2 x + 1)2 + ( 2 x − 1)2 Using (i) and (ii), we get
(2 2 x ) (2 ) 4 2x 2 2x \
F1 GMm × 50 × 9R2
= = 50 : 41
= = =
2 x + 1 + 2 x + 1 2(2 x + 1) 2 x + 1 F2 9R2 × 41 × GMm
5. (d) : If positive terminal is at x, it means D2 is in reverse 10. (c) : Thermal stress is there, if the rod is fixed between
bias, and no current flows through it. two supports. The rod will expand due to increase in
(Voltage drop in forward bias is 0.7 V) temperature.
5 − 0. 7 11. (b) : hA = 600 km, hB = 1600 km
\ I = = 0.43 A
10 R = 6400 km, M = 6 × 1024 kg
 9

From equation (i), (ii) and (iii), we have

T = 2π r3
5 7
GM dU : dQ : dW = n RDT : n RDT : nRDT
2 2
(6400 + 600)3 × 109 =5:7:2
TA = 2 π = 5813.9 s
6.67 × 10−11 × 6 × 1024 h h
16. (d) : de Broglie wavelength, λ = =
(6400 + 1600)3 × 109 p 2mK
TB = 2 π = 7103.2 s h
6.67 × 10−11 × 6 × 1024 λ=
\ TB – TA = 1.289 × 103s  1.33 × 103s 2mqV
  1
12. (b) : OA = a λ∝
 ^ ^ ^  mvq
AO = 2 i + 3 j − 4 k = a
       λP mα qα 4mP ⋅ 2e
AB + AC + AD + AE + AF + AG + AH = = = 2 2 = 2. 8
              λα mP qP mP × e
= (b − a ) + (c − a ) + (d − a ) + (e − a ) + ( f − a ) + ( g − a ) + (h − a )
        17. (a) : T = 2 s, L = 2 m
= b + c + d + e + f + g + h − 7a  ... (i) Time period for simple pendulum,
    A B
    L L
a +b +c +d +e + f + g +h T = 2π ⇒ T 2 = 4 π2
Here, =0 H C
8 g g
        O
a +b +c +d +e + f + g +h = 0 4 π2 L 4 π2 × 2
G D ⇒ g= = = 2 π2 m/s2
        T2 2×2
b + c + d + e + f + g + h = −a
F E
18. (d) : The circuit is shown in figure.
On putting value of a in eqn (i), we get At t = 0, current through inductor is zero (L = 0).
  
= − a − 7a = −8a
  Hence, Req = 6 × 9 = 18
^ ^ ^ 15 5
= −8 OA = 8 AO = 8 (2 i + 3 j − 4 k )
^ ^ ^ I= E = 5E
= 16 i + 24 j − 32 k 18 / 5 18
13. (b) : Least count = 0.01 mm
5W 4W
Positive zero error = 0.08 mm
Reading = 1 mm + 72 × 0.01 = 1.72 mm
True reading = 1.72 – zero error = 1.72 – 0.08
5W 1W
 = 1.64 mm
1.64
\ Radius = = 0.82 mm
2
14. (a) : Diameter = 0.06 m
At t = ∞, inductor becomes a simple wire
f = 504 Hz, v = 336 m/s
v 336 Hence, R eq = 5 + 4 × 1 = 5 + 4 = 33
Wavelength, λ = = = 66.66 cm 2 4 + 1 2 5 10
f 504 \ I = E = 10 E
For first resonance, 33 / 10 33
l/4 = l + e = l + 0.3d 19. (d) : Let the velocity at midpoint is v′.
a
66.66
\ = l + 0.3 × 6 ⇒ l = 14.86 cm v u
4 v′
7 5
15. (b) : CP = R, CV = R L
2 2
Equation of motion,
5 v2 = u2 + 2aL ... (i)
dU = nCV ∆T = n × R∆T ... (i)
2  v′2 = u2 + aL
7 ... (ii)
dQ = nCP ∆T = n × R∆T  v 2 − u2  v 2 + u2
2  2 2
From (i), v ′ = u +  =
dW = nRDT  ... (iii)  2  2
10

v2
v 2 + u2 Tmin
\ v ′ =
2
20. (d) : Magnetic field due to circular coil,
L
µ0 IR2 Tmax
B= B1 B2 v1
2 2 3/ 2
2(R + X ) Mg

As B1 : B2 = 8 : 1 0.05 m mv 22
Tmin + mg =
3/ 2 L
8  (R + X 2 ) 
2 2
B
So, 1 = =   0.2 m mv 22
B2 1  (R2 + X12 )  ⇒ Tmin = − mg ...(ii)
L
R2 + X22 mv12
⇒ (23 )2/3 = T mg +
From equation (i) and (ii), max = L ...(iii)
R2 + X12
Tmin mv 22
⇒ 4[R2 + (0.05)2] = [R2 + (0.2)2] − mg
L
⇒ 4R2 – R2 = 0.0375 T
Also, max = 5 ...(iv)
⇒ R2 = 0.01 or R = 0.1 m Tmin 1
21. (144) : L = 2 H, V = 3t, t = 4 s mv12
di di mg +
V =L or 3t = L From equation (iii) and (iv), L =5
dt dt 2
mv 2 1
− mg
L
L ∫ di = ∫ 3t dt
mv12  mv 22 
3t 2 3t 2 ⇒ mg + = − mg  × 5
Li = ⇒ i= L  L 
2 2L
5 mv 22
1 1
Eneregy, E = Li 2 = × L ×
(3t 2 )2 9 ⇒ mg + m v 22 + 4 gL  = − 5 mg
= × t4 L L
2 2 2 8L
4L
9 4mv 22
\ E = × (4)4 = 144 J ⇒ 10 mg =
8×2 L
22. (3600) : Degree of freedom for monoatomic gas, f = 3 ⇒ v 22 = 10 × 10 × 1 (Q L = 1 m)
4
Using conservation of energy,
⇒ v 2 = 5 m/s
1 2 f f
mu + nRTi = nRT f
2 2 2 24. (50) : T1 = 100°C ; T2 = 300°C
3 1 DT = T2 – T1 = 200°C
nR(T f − Ti ) = mu2 Now, PV = nRT
2 2
Also, P = kV 3
3 1
× 1 × R∆T = × 4 × (30)2 \ kV4 = nRT
2 2 4kV3dV = nRdT
4 × 900 1200 ⇒ PdV = nRdT
∆T = =
3R R 4
x 1200 Work done = ∫ PdV = ∫ nRdT = nR ∆T
According to given statement, = ⇒ x = 3600 4 4
3R R
23. (5) : Let the speed of bob at lowest position be v1 and at W = 200 × nR = 50 nR
4
the highest position be v2.
Maximum tension is at lowest position and minimum 25. (128) : Let the radius of big drop is R
tension is at highest position. 4 4
512 × πr 3 = πR3
mv12 3 3
Now, Tmax − mg =
L R = 8r
mv12 Kq Kq × 512
V= ... (i); V′ = ... (ii)
⇒ Tmax = mg + ...(i) r R
L
 11

From equation (i) and (ii) 31. (b) :

V 512Kq ⋅ r 2 × 512 × r CH3
= ⇒ V= = 128 V CH3
2 R × Kq 8r CH2 Mo2O3
26. (10) : l = 960 m; C = 256 mF CH3 773 K, 10-20 atm
CH2 CH
At resonance, ω 0 = 1 CH2 CH3 (A)
LC (Major product)
32. (d) : HCN 
 + −
2 2 
 H + CN
Squaring both sides, 4 π 2c = 1
λ LC
[H + ][CN − ] [HCN] [H + ]
8 2
4 × 10 × (3 × 10 ) 1 Ka = ⇒ =
⇒ = [HCN] [CN − ] [K a ]
(960) 2
L × 2.56 × 10 −6
Given, Ka = 6.2 × 10–10, pH = 3.0
⇒ L = 10 × 10–8 H ⇒ [H+] = 10–3
L = 10–7 H = 10 × 10–8 H [HCN] 1 × 10−3
27. (15) : u = 20 cm or 10 cm, m = 1 ∴ = = 1.6 × 106
[CN − ] 6.2 × 10−10
f
Magnification, m = (Q m1 = –m2) Solubility equilibrium, AgCN( s ) 



+
 Ag + CN
−
f +u x x
f −f But CN– will react with H+ ions
So, = ⇒ f − 20 = − f + 10 CN– + H+ HCN
f − 10 f − 20
Initial conc. x 1 × 10–3 0
2f = 30 ⇒ f = 15 cm At Equilibrium x – y 1 × 10–3 y

α β (Concentration of H+ remains same due to buffer action)

28. (1) : U = −
−3 Thus, [CN–]Total = x = [CN–]eqm. + [HCN]eqm.
r10
r5
dU Since, [HCN]eqm. = 1.6 × 106 [CN–]eqm. hence [CN–]eqm. can
For equilibrium, =0 be neglected.
dr
\ [HCN]eqm. = x
a(10)r–11 – b(5)r–6 = 0
[HCN] x
10α 2α Also, [CN − ] = =
r5 = = 1.6 × 106 1.6 × 106
5β β
Solubility product Ksp = [Ag+] [CN–]
1/5 a /b
 2α   2α  x
r=  =  2.2 × 10 −16 = x ×
 β   β  1.6 × 106
a 1 x2 = 1.6 × 106 × 2.2 × 10–16 = 3.52 × 10–10
∴ = ⇒ a = 1, b = 5
b 5
x = 3.52 × 10 −10 = 1.88 × 10 −5 ≈ 1.9 × 10 −5
29. (1) : E1 ∝ 380 cm
33. (d) : 2I– + H2O2 + 2H+ I2 + 2H2O
E2 ∝ 760 cm
In this equation oxidation number of oxygen changes from
E1 380 1 a
= = = –1 to –2 i.e., reduction of H2O2 takes place. Therefore, it
E2 760 2 b behaves as an oxidising agent and oxidises I– (–1) to I2 (0).
a=1 In other options, oxidation state of oxygen changes from –1
 3 ^ 4 ^ to 0, that means H2O2 is getting oxidised, so behaving as
30. (1) : E = E0 i + E0 j, A ′ = 0.2 m2 ( y − z plane)
5 5 reducing agent.
A ′′ = 0.3 m2 (x − y plane) 34. (a) : In B2H6, terminal bond angle is greater than that
of bridged bond angle.
   3 ^ 4 ^ ^ 0. 6
φ1 = E ⋅ A ′ =  E0 i + E0 j  ⋅ (0.2 i ) = E ... (i) H H H
5 5  5 0 B a B b
H H H
   3 ^ 4 ^ ^ 1.2 Bond angle b > a
φ2 = E ⋅ A ′′ =  E0 i + E0 j  ⋅ (0.3 j) = E ... (ii)
5 5  5 0 Bond angle ∝ s-character ∝ 1
p − character
a φ1 0.6 1 Therefore, terminal B H bonds have less p-character or
= = = ⇒ a =1
b φ 2 1.2 2 more s-character as compared to bridging bonds.
12

35. (a) : Be2 : s1s2, s*1s2, s2s2 s*2s2 41. (d) : (a) Neoprene is an addition homopolymer.
N − Na 4 − 4 (b) Buna–N is a synthetic polymer.
Bond order = b = =0 (c) Buna-S is an elastomer.
2 2
Bond order of Be2 is 0. So, it does not exist. (d) Synthesis of Buna-S needs nascent oxygen or free
36. (a) : Outer electronic configuration of given species : radical.
V2+ = [Ar]3d3 Cr+ = [Ar]3d5 42. (d) : The graphical representation showing the
2+
Ni = [Ar]3d 8
Cu+ = [Ar]3d10 variation of Gibbs energy (DG) with temperature (T) for the
2+
Mn = [Ar]3d 5
Co+ = [Ar]3d74s1 formation of oxide is known as Ellingham diagram.
2+ 6
Fe = [Ar]3d 43. (d) : Classical smog is reducing in nature and is known
So, Cr+ and Mn2+ have the same outer electronic as reducing smog.
configuration. Ozone, which is an allotrope of oxygen, is an important
x intermediate in the formation of photochemical smog.
37. (c) : = KP x  Hydrocarbons and oxides of nitrogen contribute to the
m x
At moderate pressure m formation of photochemical smog.
1 CrO3—H2SO4
x 44. (a) : CH3CH2OH CH3COOH
∝ Pn
m P Pd(II)/Cu(II)
NO2 NH2 CH2 CH2 + O2 H2O
CH3CHO
Cu
38. (c) : (A) (i) Sn/HCl (ii) HNO2 CH3CH2OH 573 K
CH3CHO
(i) DIBAL-H
N+2 CH3CN CH3CHO
(ii) H2O
(iii) Ph — NH2 CrO3 H2SO4 is a strong oxidizing agent which further
Ph N N NH2
(pH 4 – 5) oxidises aldehyde to carboxylic acid.
Diazonium ion 45. (c) : Compounds which are more acidic than H2CO3,
NH2 N+2 gives CO2 gas on reaction with NaHCO3.
Compound B i.e., benzoic acid and compound C i.e., picric
(i) HNO2 (ii) Ph—NH2 acid both are more acidic than H2CO3. +I effect of —NH2
(C)
HCl group decreases acidic nature of phenol, hence A is less
acidic than H2CO3.
Ph N N NH2 COOH COONa

OCH3 OCH3 OCH3 + NaHCO3 + CO2↑ + H2O

Cl I
HCl NaI (B)
39. (a) : dry acetone OH ONa
O2N NO2 O2N NO2
NO2 NO2 NO2
+ NaHCO3
(Finkelstein reaction)
40. (b) : [Mn(CN)6]4– :
NO2 NO2
3d 4s 4p (C)
+ CO2↑ + H2O
Mn2+ ⇒
O
d2sp3 (1) H3O+, D
46. (d) : CH3CH2CN CH3 CH2 C OH
Due to presence of one unpaired electron, [Mn(CN)6]4– is
paramagnetic in nature. (2) SOCl2
[Fe(CN)6]3– : O
3d 4s 4p
(3) Pd /BaSO4
CH3CH2CHO CH3 CH2 C Cl
Fe3+ ⇒ (Rosenmund reduction)
H2

d2sp3 47. (d) : Number of radial nodes = n – l – 1

Due to presence of one unpaired electron, [Fe(CN)6]3– is For 3s-orbital n = 3, l = 0
also paramagnetic in nature. \ Number of radial nodes = 3 – 0 – 1 = 2
 13

 y  y NaOH + HCl NaCl + H2O

48. (b) : C x H y Oz +  x + − z  O2 
→ xCO2 + H2 O Na2CO3 + HCl NaHCO3 + NaCl
 4  2
1
12 x + y = × 17.5 ...(i)
Mass of ‘C’ in 2.64 g of CO2 = × 2.64 = 0.72 g 10
44 For second end point (methyl orange)
2 NaHCO3 + HCl NaCl + H2O + CO2
Mass of ‘H’ in 1.08 g of H2O = × 1.08 = 0.12 g
18 mmol of NaHCO3 = mmol of HCl
Mass of ‘O’ in compound = 1.80 – (0.72 + 0.12) = 0.96 g 1
y = × 1.5 ...(ii)
0.96 10
% of oxygen = × 100 = 53.33% From equation (i) and (ii), x = 1.60, y = 0.15
1.80
Weight of Na2CO3 = 0.15 × 10–3 × 106 = 1.59 × 10–2 g
6 6
CH2OH CH2OH 1.59 × 10−2
5 Weight % of Na2CO3 = × 100 = 3.975 ≈ 4
O 5
O 0. 4
HO H OH
49. (d) : H H 56. (375) : A2B3 2A3+ + 3B2–
4 1 O 4 1
OH H OH H Number of ions = 2 + 3 = 5
H 2 H H i = 1 + (n – 1)a
3 3 2
H OH = 1 + (5 – 1) × 0.6 = 3.4
H OH
b-D-Galactose b-D-Glucose
DTb = Kb × m × i
The linkage is present between C–1 of galactose and C–4 = 0.52 × 1 × 3.4 = 1.768°C
of glucose. DTb = Tb(solution) – Tb(H2O)
50. (a) : +3 oxidation state of lanthanides is most stable 1.768 = Tb(solution) – 100
and hence Ce4+ compounds are good oxidising agents. Eu2+ Tb(solution) = 100 + 1.768 = 101.768°C
will act as a reducing agent so that it itself gets oxidised to a = 273 + 101.768 = 374.768 K ≈ 375 K
more stable +3 oxidation state. P1 P2
57. (70) : =
Red hot Fe tube T1 T2
51. (7) : CH CH
873 K
35 40
CHO = ⇒ T2 = 342.86 K
(273 + 27) T2
CO, HCl, AlCl3 T2 = 342.86 − 273 = 69.86 °C ≈ 70 °C
Gattermann-Koch reaction
58. (741) : Note : The correct equation should be :
Benzaldehyde
3
2
All carbon atoms in benzaldehyde are sp -hybridised. NH2CN(s) + O2(g) → N2(g) + CO2(g) + H2O(l)
2
52. (1) : SF6 does not undergo hydrolysis due to steric DH = DU + DngRT
hindrance. 3
53. (173) : Balanced chemical equation is given as : From the given reaction, ∆n g = 2 −= 0. 5
2
–
8CrO2– 2–
4 + 3S2O3 + 17H2O 6SO2–
4 + 8Cr(OH)4 + 2OH
–
\ DH = –742.24 + 0.5 × 8.314 × 10–3 × 298 = –741 kJ
Applying molarity equation, Ea
59. (526) : log k = log A − (Arrhenius equation)
0.154 × V 40 × 0.25 2.303RT
= ⇒ V ≈ 173 mL Ea
8 3 Slope = − = −10000
2.303R
Distance travelled by compound
54. (4) : R f = k2 Ea  1 1 
Distance travelled by solvent log = −
k1 2.303R  T1 T2 
From chromatogram, distance travelled by compound
A = 2 cm and distance travelled by solvent = 5 cm 10−4  1 1
2 log = 10000  − 
−5  500 T2 
∴ R f = = 4 × 10−1 10
5
1 1 1
55. (4) : Let mmol of NaOH = x = −
and mmol of Na2CO3 = y 10000 500 T2
For first end point (phenolphthalein) T2 = 526.32 ≈ 526 K
14

60. (5576) : Na(g) Na+(g) ; DH1 = 495.8 kJ mol–1 64. (b) : Slope of tangent, m = 1/2
1 –
Equation of tangent in slope form to the parabola y2 = 6x
Br2(l) Br(g) ; DH2 = –325 kJ mol–1 is given by
2
Na+(g) + Br–(g) NaBr(s) ; DH3 = –728.4 kJ mol–1 3
y = mx + (Q 4a = 6 ⇒ a = 3/2)
1 2m
Na(s) + Br2(l) NaBr(s) ; DH = ?
2 1 3 x
⇒ y= x+ ⇒ y = +3
DH = 495.8 – 325 – 728.4 = –557.6 kJ/mol 2 1 2
2×
= –5576 × 10–1 kJ/mol 2
Note : Data is incomplete in this question. The question has ⇒ 2y = x + 6
been solved only with the help of given information.
Only point (5, 4) does not lie on it.
The value of DHsublimation of Na(s), DHvaporisation of Br2(l) and D
DHdissociation of Br2(g) must be given. 65. (a) :
45° 30°

61. (b) : x = 1 + cos2q + cos4q + ...... = 1 1

2
=
1 − cos θ sin2 θ h

1
⇒ sin2 θ = .... (i) 30° 45°
x A B C
1 1 t=0 t = 20 s
y = 1 + sin2f + sin4f + .... = =
1 − sin2 φ cos2 φ x y
Let speed of boat is u and height of tower is h,
1
⇒ cos2 φ = ... (ii) AB = x and BC = y.
y
h
z = 1 + cos2q sin2f + cos4q sin4f + ..... In DBCD, = tan 45° ⇒ h = y
y
1 1
= = h y 1
1 − cos θ sin φ 1 − (1 − sin θ)(1 − cos2 φ)
2 2 2 Also, in DACD, = tan30° ⇒ =
x+y x+y 3
1 1
⇒ z= ⇒ z= ⇒ x + y = 3 y ⇒ x = ( 3 − 1) y
 1  1  xy − (x − 1)( y − 1)
1 − 1 −  1 −  Distance x ( 3 − 1) y
 x  y  xy
Since, Speed = ⇒ u= =
xy Time 20 20
⇒ z= ⇒ xy + z = z (x + y ) Distance
x + y −1 \ Time taken to travel from B to C =
Speed
62. (d) : Given, sin2q + tan2q > 0 y y 20
sin 2θ (cos 2θ + 1) = = = = 10( 3 + 1) secs
⇒ sin 2θ + > 0 ⇒ sin 2θ >0 u ( 3 − 1) 3 −1
cos 2θ cos 2θ y
20
⇒ tan2q (1 + cos2q) > 0
x2 y2
⇒ tan2q > 0 (Q cos2q + 1 > 0) 66. (b) : We have, + = 1 ... (i)
a b
 π   3π   5π   7π  Differentiating (i) with respect to x, we get
⇒ 2θ ∈  0,  ∪  π,  ∪  2 π,  ∪  3π, 
 2  2   2   2  2 x 2 y dy dy bx
+ =0 ⇒ = − = m1
 π   π 3π   5π   3π 7 π  a b dx dx ay
⇒ θ ∈  0,  ∪  ,  ∪  π,  ∪  , 
 4 2 4   4   2 4  x2 y2
Also, + = 1 ... (ii)
63. (b) : We have, xyz = 23 × 3 c d
Let x = 2a1 × 3b1, y = 2a2 × 3b2 and z = 2a3 × 3b3 Differentiating (ii) with respect to x, we get
Since, a1 + a2 + a3 = 3 2 x 2 y dy
+ =0
\ Number of non-negative integral solutions c d dx
dy dx
= 3 + 3 – 1C3 – 1 = 5C2 = 10 ⇒ m2 = =−
dx cy
Also, b1 + b2 + b3 = 1
Now, m1m2 = –1 [Given]
\ Number of non-negative integral solutions
 bx   −dx 
= 1 + 3 – 1C3 – 1 = 3C2 = 3 ⇒ 2 2
 − ay   cy  = −1 ⇒ bdx = –acy  ... (iii)
Total number of positive integral solutions = 10 × 3 = 30
 15

Now, subtracting (ii) from (i), we get  21 −11 13 

So, P ≡  , ,
1 1 2 1 1  2  17 17 17 
 a − c  x +  b − d  y = 0

 −21 i^+ 28 ^j + 21k^ 7 ^ ^ ^
c −a 2 d −b 2 ∴ PQ = = (−3 i + 4 j + 3 k)
⇒  x + y =0
 ac   bd  17 17

(c − a) 2  d − b   −bdx 2  So, required line is x = y − 1 = z − 2

⇒ x + =0 [Using (iii)] −3 4 3
ac  bd   ac 
71. (c) : We have, x2 – 2(3k – 1)x + 8k2 – 7 > 0
⇒ (c – a) – (d – b) = 0 ⇒ c – d = a – b
Now, D < 0
3
2 3 1 ⇒ 4(3k – 1)2 – 4 × 1 × (8k2 – 7) < 0
67. (a) : Required probability =  ×  =
3 4 8 ⇒ 9k2 – 6k + 1 – 8k2 + 7 < 0
68. (d) : We have, f(n + 1) = f(n) + f(1) ⇒ k2 – 6k + 8 < 0
f(2) = f(1) + f(1) = 2f(1) ⇒ (k – 4)(k – 2) < 0 ⇒ k ∈ (2, 4)
f(3) = f(2) + f(1) = 3f(1) i.e., k = 3
...........................................
........................................... sin θ ⋅ sin 2θ(sin6 θ + sin 4 θ + sin2 θ)
f(n) = n f(1)
\ f is one-one. 2 sin 4 θ + 3 sin2 θ + 6
72. (b) : Let I = ∫ dθ
Now, let f (g(x2)) = f(g(x1)) 1 − cos 2θ
⇒ g(x2) = g(x1) (Q f is one-one)
sin θ ⋅ 2 sin θ cos θ ⋅ sin2 θ(sin 4 θ + sin2 θ + 1)
⇒ x1 = x2 (Q fog is one-one)
⇒ g is one-one (2 sin 4 θ + 3 sin2 θ + 6)1/2
=∫ dθ
Now, f(g(n)) = g(n) f(1) 2 sin2 θ
\ fog may be many-one if g(n) is many-one.
= ∫ sin2 θ ⋅ cos θ(sin4 θ + sin2 θ + 1)(2 sin 4 θ + 3 sin2 θ + 6)1/2 dθ
69. (a) : Let z = x + iy and z = x − iy
∴ (2 − i)z = (2 + i)z ⇒ (2 − i)( x + iy ) = (2 + i)( x − iy ) Putting sinq = t ⇒ cosq dq = dt, we get
⇒ 2x + 2iy – ix + y = 2x – 2iy + ix + y ⇒ 2y = x ... (i) I = ∫ t 2 (t 4 + t 2 + 1)(2t 4 + 3t 2 + 6)1/2 dt

Also, (2 + i)z + (i − 2)z − 4i = 0
⇒ (2 + i)(x + iy) + (i – 2)(x – iy) – 4i = 0 = ∫ (t 5 + t 3 + t ) t (2t 4 + 3t 2 + 6)1/2 dt

⇒ 2x + 2iy + ix – y + ix – 2x + y + 2iy – 4i = 0 = ∫ (t 5 + t 3 + t ) (2t 6 + 3t 4 + 6t 2 )1/2 dt
⇒ x + 2y – 2 = 0 .... (ii)
Solving (i) and (ii), we get x = 1, y = 1/2 Again put 2t6 + 3t4 + 6t2 = u2
Equation of tangent is iz + z + 1 + i = 0 ⇒ 12(t5 + t3 + t)dt = 2udu
⇒ i(x + iy) + (x – iy) + 1 + i = 0 2udu u2 u3
⇒ ix – y + x – iy + 1 + i = 0 ∴ I = ∫ (u2 )1/2 = ∫ du = +c
12 6 18
⇒ i(x – y + 1) + (x – y + 1) = 0
⇒ x – y + 1 = 0 (2t 6 + 3t 4 + 6t 2 )3/2
= +c
1 18
1− +1 3
2 1
∴ Radius, r = = = (2 sin6 θ + 3 sin 4 θ + 6 sin2 θ)3/2 + c
2 2 2 18
1
x −1 y +1 z −1 = [2(1 − cos2 θ)3 + 3(1 − cos2 θ)2 + 6(1 − cos2 θ)]3/2 + c
70. (c) : Let = = = r (say ) 18
2 3 −2
\ P(x, y, z) = (2r + 1, 3r – 1, –2r + 1) 1
= {(1 − cos2 θ)[2(1 − cos2 θ)2 + 3(1 − cos2 θ) + 6]}3/2 + c
 18
Since, QP ⊥ (2 i^ + 3 ^j − 2 k^).
1
\ (2r + 1) ⋅ 2 + (3r – 2) ⋅ 3 + (–2r – 1) ⋅ (–2) = 0 = [(1 − cos2 θ)(2 cos 4 θ − 7 cos2 θ + 11)]3/2 + c
Q(0, 1, 2) 18
⇒ 4r + 2 + 9r – 6 + 4r + 2 = 0
2 1
⇒ r= = [11 − 18 cos2 θ + 9 cos 4 θ − 2 cos6 θ]3/2 + c
17 18
P
16

73. (d) : P(3, 5) ≡ (~A ∨ A) ∨ B

≡ ~A ∨ (A ∨ B)
x–y+1=0 ≡ A → (A ∨ B)
77. (a) : Given, y(0) = 0
2 2
and dy = x − 4 x + y + 8 = (x − 2) + y + 4
P′(x, y) dx x −2 x −2
Image of point P(3, 5) in the line x – y + 1 = 0, is given by dy y 4
⇒ − = (x − 2) + , which is L.D.E.
x −3 y −5  3 − 5 +1 dx x − 2 x −2
= = −2  =1
 1 + 1 
1
1 − 1 −∫ 1 dx
Here, I.F. = e x −2 =
⇒ x = 4 and y = 4, which lies on (x – 2)2 + (y – 4)2 = 4. x −2
74. (b) : Since, f(1) = f(2) \ Required solution is given by
⇒ 1 – a + b – 4 = 8 – 4a + 2b – 4 1 1  4 
y⋅ =∫  (x − 2) + dx
⇒ 3a – b = 7 ... (i) x −2 x −2 x − 2 
f(x) = x3 – ax2 + bx – 4 y 4
⇒ =x− +C
⇒ f ′(x) = 3x2 – 2ax + b x −2 x −2
2 At x = 0, y = 0 ⇒ C = –2
4 4 4
∴ f ′   = 3   − 2a   + b = 0 (given) \ y = x(x – 2) – 4 – 2(x – 2)
3 3 3
⇒ y = x2 – 4x, which passes through (5, 5).
16 8a
⇒ − +b = 0 78. (c) : Given limit is of 1∞ form.
3 3
 1 1 1
⇒ 8a – 3b – 16 = 0 ... (ii) 1 + + + ..... +
 2 3 n 
Solving (i) and (ii), we get a = 5 and b = 8 So, given limit (l ) = exp  lim 
n→∞ n
75. (b) : We know that l2 + m2 + n2 = 1  
 
And given that l2 + m2 – n2 = 0 1 1 1 1 1 1
1 Now, 0 ≤ 1 + + + ... + ≤ 1 + + + .... +
⇒ 2n2 = 1 ⇒ n = ± 2 3 n 2 3 n
2 ≤ 2 n − 1
Also, l + m = n ⇒ l + m2 + 2lm = n2
2
⇒ n2 + 2lm = n2 ⇒ lm = 0 So, l = exp(0) (from sandwich theorem)
=1
1
If l = 0, then m = n = ± 79. (a) : Given quadratic equation is
2
ax2 + bx + c = 0
1
And if m = 0, then l = n = ± For equal roots, D = 0 ⇒ b2 = 4ac
2 Case-I : If b = 2, then ac = 1
So, direction cosines of two lines are \ (a, b, c) = (1, 2, 1)
 1 1   1 1  Case-II : If b = 4, then ac = 4
 0, ,  and  , 0,  So, (a, b, c) = (1, 4, 4) or (4, 4, 1) or (2, 4, 2)
2 2 2 2
Case III : If b = 6, then ac = 9
1
0+0+ So, (a, b, c) = (3, 6, 3)
2=1 π
So, cosα = ⇒ α= 5
1 1 2 3 \ Required probability =
216
4 4
 π  π 1 3
\ sin4a + cos4a =  sin  +  cos  80. (b) : Let I = 2 [x ]
 3  3 ∫ x e dx
−1
4
 3   1 4 9 1 5 0 3 1 0 1
2 [x3 ]
=  +   = 16 + 16 = 8 = ∫ x 2 e[ x ]dx + ∫ x e dx = ∫ x 2 e −1dx + ∫ x 2 e 0 dx
 2  2 −1 0 −1 0
76. (c) : A → (B → A) 0 1
1  x3   x3  1   −1   1
≡ A → (~B ∨ A) =   +   = × 0 −    +
e  3  3  e   3  3
≡ ~A ∨ (~B ∨ A) ≡ ~A ∨ (A ∨ ~ B) −1  0
≡ (~A ∨ A) ∨ ~B ≡ T ∨ ~B ≡ T 1 1 1+ e
Also, T ≡ T ∨ B = + =
3e 3 3e
 17

 and f(x) = x3(x3 + ax2 + bx + c)

 θ 
 0 − tan    f (x )
2 ⇒ lim = c =1
81. (13) : We have, A =   x →0 x 3
 θ 
 tan  2  0  Now, as f(x) = x6 + ax5 + bx4 + x3
  ⇒ f ′(x) = 6x5 + 5ax4 + 4bx3 + 3x2
1 0  Also, f ′(x) = 0 at x = 1 and x = –1
and I2 =  
0 1  Now, f ′(1) = 0 ⇒ 6 + 5a + 4b + 3 = 0
⇒ 5a + 4b = –9 ... (i)
  θ 
 1 − tan    and f ′(–1) = 0
2
Now, I2 + A =   ⇒ –6 + 5a – 4b + 3 = 0
 θ  ⇒ 5a – 4b = 3 ... (ii)
 tan  2  1 
  Solving (i) and (ii), we get
  θ  −3 −3
1 tan    a= and b =
 2 5 2
and I2 − A =   3 3
 θ  ∴ f (x ) = x 6 − x 5 − x 4 + x 3
 − tan  2  1  5 2
 
 3 3 
T Hence, 5 f (2) = 5 64 − ⋅ 32 − ⋅ 16 + 8
  θ   5 2 
 1 tan   
1 2 = 320 – 96 – 120 + 40 = 144
(I2 − A)−1 =  
2 θ  θ  83. (7) : Given, A2 = I
sec    − tan   1 
2  2  ⇒ AA′ = I (Q A′ = A)
  θ  ⇒ A is orthogonal.
 1 − tan    So, x2 + y2 + z2 = 1 and xy + yz + zx = 0
1 2
=   Now, (x + y + z)2 = (x2 + y2 + z2) + 2(xy + yz + zx)
2  θ   θ
  
sec    tan   1  = 1 + 2 (0)
2  2 
⇒ x + y + z = 1 [Q x + y + z > 0]
Now, (I2 + A)(I2 – A)–1 Hence, x3 + y3 + z3
  θ    θ  = 3xyz + (x + y + z)(x2 + y2 + z2 – xy – yz – zx)
 1 − tan     1 − tan    = 3 × 2 + 1 (1 – 0) = 7
1 2 2
=   
2  θ   θ
    θ
   4 3 3x − y
sec    tan   1 tan   1 84. (2) : k = =
2  2    3x + y 4 3
 2 
 θ θ  x y2 2
1 − tan2   −2 tan    ⇒ 3x2 – y2 = 48 ⇒ − = 1, which is a hyperbola.
1   2  2 16 48
=   Now, 48 = 16(e2 – 1) ⇒ 4 = e2
2 θ  θ 2  θ 
sec    2 tan   1 − tan    ⇒ Eccentricity, e = 2
2  2  2 
85. (32) : Three digit numbers formed with digits 1, 2, 3, 4,
θ 5 which are divisible by 3 = 4 × 3! = 24
1 + tan2  
 2  cos θ − sin θ Three digit numbers formed with digits 1, 2, 3, 4, 5 which
=  
  sin θ cos θ 
θ are divisible by 5 = 4 × 3 = 12
sec2   
2 Three digit numbers formed with digits 1, 2, 3, 4, 5 which

are divisible by 15 = 1 × 2 × 2! = 4
a −b  \ Required numbers = 24 + 12 – 4 = 32
= 
b a  k 1 2
So, a = cosq, b = sinq 86. (21) : Here, D = 3 −1 −2 = 0 for k ∈ R
\ 13(a2 + b2) = 13(cos2q + sin2q) = 13
−2 −2 −4
82. (144) : Let f(x) = x6 + ax5 + bx4 + cx3 + dx2 + ex + f
f (x ) 1 1 2
Since, lim = 1, which is non-zero and finite.
x →0 x 3 Also, D1 = 2 −1 −2 = 0
\ d = e = f = 0 3 −2 −4
18

So, for the given system to have infinite many solutions, 12

D2 = 0. Length of side of A3 =
( 2 )2
k 1 2
------------------------------------
⇒ 3 2 −2 = 0
12
−2 3 −4 Length of side of An =
( 2 )n−1
⇒ k(–8 + 6) – 1(–12 – 4) + 2(9 + 4) = 0
2
⇒ –2k + 16 + 26 = 0 ⇒ 2k = 42 ⇒ k = 21  12  144
y
\ Area of An =   < 1 ⇒ (n−1) < 1
n
 ( 2) −1
2
⇒ 2(n – 1) > 144 ⇒ n – 1 > 7
y = sinx
⇒ n > 8
5p/4 Since, n is a natural number.
87. (64) : x
p/4 \ Least value of n is 9.
       
89. (12) : Given, r × a = c × a ⇒ (r − c ) × a = 0
y = cosx      
⇒ r − c = λa ⇒ r = c + λa
5 π/ 4          
Area, A = ∫ (sin x − cos x ) dx = [ − cos x − sin x ]π/ 4
5 π/ 4
⇒ r ⋅ b = c ⋅ b + λa ⋅ b ⇒ 0 = c ⋅ b + λa ⋅ b
π/ 4  
−c ⋅ b −2
⇒ λ=   = =2
 5π 5π   π π  a ⋅b −1 ’
= −   cos + sin  −  cos + sin  
  4 4   4 4       
∴ r ⋅ a = c ⋅ a + λa ⋅ a = 0 + 2(6) = 12
 1 1   1 1  2 2 90. (2) : f(x) = |2x + 1| – 3|x + 2| + |x2 + x – 2|
= −  − −  − +   = + =2 2
 2 2  2 2  2 2 = |2x + 1| – 3|x + 2| + |x + 2||x – 1|
⇒ A4 = (2 2 )4 = 16 × 4 = 64 = |2x + 1| + |x + 2|(|x – 1| – 3)
88. (9) : Given, length of side of A1 = 12 Critical points are x = –1/2, –2 and 1.
Length of diagonal of A2 = 12 But x = –2 is making a zero twice in product so, points of
12 non differentiability are x = –1/2 and x = 1.
\ Length of side of A2 =
2 \ Number of points of non-differentiability is 2.