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Safety Data Sheet

d-Limonene
Version 1.4 Revision Date: 09/01/2019

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : d-Limonene

Recommended use of the chemical and restrictions on use
Recommended use : Solvent.
Cleaner.
Degreaser
Manufacturer or supplier's details
Company : Lab Alley LLC
Address 22111 Highway 71 West, Suite 601
Spicewood, Texas 78669
Tel.: 512-668-9918
Emergency telephone number:
InfoTrac: 800-535-5053

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification
Flammable liquids : Category 3

Skin irritation : Category 2

Eye irritation : Category 2B

Skin sensitisation : Category 1

Aspiration hazard : Category 1

GHS label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : H226 Flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.
H315 + H320 Causes skin and eye irritation.
H317 May cause an allergic skin reaction.

Precautionary statements : Prevention:

P210 Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.

SDS Number: 100000003281 1 / 12 d-Limonene

Safety Data Sheet
d-Limonene
Version 1.4 Revision Date: 09/01/2019

P241 Use explosion-proof electrical/ ventilating/ lighting equip-

ment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of
the workplace.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P301 + P310 IF SWALLOWED: Immediately call a POISON
CENTER/doctor.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water/shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P331 Do NOT induce vomiting.
P333 + P313 If skin irritation or rash occurs: Get medical advice/
attention.
P337 + P313 If eye irritation persists: Get medical advice/ atten-
tion.
P362 Take off contaminated clothing and wash before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or alco-
hol-resistant foam to extinguish.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.

Other hazards
None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Substance

Hazardous components
CAS-No. Chemical name Weight percent
5989-27-5 d-Limonene 90 - 100
Any Concentration shown as a range is due to batch variation.

SECTION 4. FIRST AID MEASURES

General advice : Move out of dangerous area.

Show this safety data sheet to the doctor in attendance.
Symptoms of poisoning may appear several hours later.
Do not leave the victim unattended.
If inhaled : If unconscious, place in recovery position and seek medical
advice.

SDS Number: 100000003281 2 / 12 d-Limonene

Safety Data Sheet
d-Limonene
Version 1.4 Revision Date: 09/01/2019

If symptoms persist, call a physician.

In case of skin contact : If on skin, rinse well with water.
If on clothes, remove clothes.
In case of eye contact : Flush eyes with water as a precaution.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed : Keep respiratory tract clear.
Do not induce vomiting without medical advice.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
Take victim immediately to hospital.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Alcohol-resistant foam

Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing : High volume water jet
media
Specific hazards during fire- : Do not allow run-off from fire fighting to enter drains or water
fighting courses.

Hazardous combustion prod- : Carbon oxides

ucts Acrid smoke and fumes

Further information : Collect contaminated fire extinguishing water separately. This

must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
For safety reasons in case of fire, cans should be stored sepa-
rately in closed containments.
Use a water spray to cool fully closed containers.
Special protective equipment : Wear self-contained breathing apparatus for firefighting if nec-
for firefighters essary.
Use personal protective equipment.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Use personal protective equipment.

tive equipment and emer- Ensure adequate ventilation.
gency procedures Remove all sources of ignition.
Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive concentra-
tions. Vapours can accumulate in low areas.

Environmental precautions : Prevent product from entering drains.

Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.

SDS Number: 100000003281 3 / 12 d-Limonene

 Safety Data Sheet
d-Limonene
Version 1.4 Revision Date: 09/01/2019

Methods and materials for : Contain spillage, and then collect with non-combustible ab-
containment and cleaning up sorbent material, (e.g. sand, earth, diatomaceous earth, ver-
miculite) and place in container for disposal according to local
/ national regulations (see section 13).

SECTION 7. HANDLING AND STORAGE

Advice on protection against : Do not spray on a naked flame or any incandescent material.
fire and explosion Take necessary action to avoid static electricity discharge
(which might cause ignition of organic vapours). Keep away
from open flames, hot surfaces and sources of ignition.

Advice on safe handling : Avoid formation of aerosol.

Do not breathe vapours/dust.
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Take precautionary measures against static discharges.
Provide sufficient air exchange and/or exhaust in work rooms.
Open drum carefully as content may be under pressure.
Dispose of rinse water in accordance with local and national
regulations.
Persons susceptible to skin sensitisation problems or asthma,
allergies, chronic or recurrent respiratory disease should not
be employed in any process in which this mixture is being
used.
Conditions for safe storage : No smoking.
Keep container tightly closed in a dry and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Contains no substances with occupational exposure limit values.
Personal protective equipment
Respiratory protection : No personal respiratory protective equipment normally re-
quired.
In the case of vapour formation use a respirator with an ap-
proved filter.
Hand protection

Remarks : The suitability for a specific workplace should be discussed

with the producers of the protective gloves.
Eye protection : Eye wash bottle with pure water
Tightly fitting safety goggles

SDS Number: 100000003281 4 / 12 d-Limonene

Safety Data Sheet
d-Limonene
Version 1.4 Revision Date: 09/01/2019

Skin and body protection : Impervious clothing

Choose body protection according to the amount and concen-
tration of the dangerous substance at the work place.
Hygiene measures : When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid
Colour : clear, light yellow
Odour : Citrus
Odour Threshold : No data available
pH : No data available

Freezing Point (Melting :

point/range)
Boiling Point (Boiling : 176 °C (349 °F)
point/boiling range)
Flash point : 46 °C (115 °F)

Evaporation rate : No data available

Flammability (solid, gas) : No data available
Upper explosion limit : 6.1 %(V)

Lower explosion limit : 0.7 %(V)

Vapour pressure : 2 mmHg @ 20 °C (68 °F)

Relative vapour density : No data available

Relative density : 0.84 @ 20 - 25 °C (68 - 77 °F)
Reference substance: (water = 1)

Density : 0.84 g/cm3 @ 20 - 25 °C (68 - 77 °F)

Water solubility : No data available

Solubility in other solvents : No data available
Partition coefficient: n- : No data available
octanol/water
Auto-ignition temperature : 237 °C
Thermal decomposition : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : Stable under normal conditions.
Possibility of hazardous reac- : Vapours may form explosive mixture with air.
tions
Conditions to avoid : Keep away from heat, flame, sparks and other ignition
sources.

SDS Number: 100000003281 5 / 12 d-Limonene

Safety Data Sheet
d-Limonene
Version 1.4 Revision Date: 09/01/2019

Incompatible materials : Strong acids

Strong oxidizing agents
Hazardous decomposition : Carbon oxides
products

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity

Product:
Acute oral toxicity : Acute toxicity estimate: 4,444 mg/kg

Components:
5989-27-5:
Acute oral toxicity : LD50 (Rat): 4,400 mg/kg
Assessment: The component/mixture is minimally toxic after
single ingestion.

Acute inhalation toxicity : Remarks: No data available

Acute dermal toxicity : LD50 (Rabbit): > 5,000 mg/kg

Assessment: The substance or mixture has no acute dermal
toxicity

Skin corrosion/irritation

Components:
5989-27-5:
Species: Rabbit
Result: Irritating to skin.

Serious eye damage/eye irritation

Components:
5989-27-5:
Species: Rabbit
Result: No eye irritation

Respiratory or skin sensitisation

Components:
5989-27-5:
Test Type: lymph node assay
Species: Mouse
Result: May cause sensitisation by skin contact.

SDS Number: 100000003281 6 / 12 d-Limonene

Safety Data Sheet
d-Limonene
Version 1.4 Revision Date: 09/01/2019

Germ cell mutagenicity

Components:
5989-27-5:
Genotoxicity in vitro : Test Type: Mammalian cell gene mutation assay
Species: mouse lymphoma cells
Metabolic activation: with and without metabolic activation
Result: negative

Genotoxicity in vivo : Test Type: DNA damage and/or repair

Species: Rat
Cell type: Kidney cells
Application Route: Oral
Result: negative

Germ cell mutagenicity - : Tests on bacterial or mammalian cell cultures did not show
Assessment mutagenic effects.

Carcinogenicity

Components:
5989-27-5:
Carcinogenicity - Assess- : Not classifiable as a human carcinogen.
ment
IARC No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.

OSHA No component of this product present at levels greater than or

equal to 0.1% is on OSHA’s list of regulated carcinogens.

NTP No component of this product present at levels greater than or

equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

ACGIH No component of this product present at levels greater than or

equal to 0.1% is identified as a carcinogen or potential carcino-
gen by ACGIH.

Reproductive toxicity

Components:
5989-27-5:
Reproductive toxicity - As- Fertility classification not possible from current data.
sessment

Teratogenicity - Assessment : Embryotoxicity classification not possible from current data.

Aspiration toxicity

Components:
5989-27-5:

SDS Number: 100000003281 7 / 12 d-Limonene

Safety Data Sheet
d-Limonene
Version 1.4 Revision Date: 09/01/2019

May be fatal if swallowed and enters airways.

Further information

Product:
Remarks: Solvents may degrease the skin.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Components:
5989-27-5:
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 0.702 mg/l
Exposure time: 96 h
Test Type: flow-through test

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 0.36 mg/l
aquatic invertebrates Exposure time: 48 h
Test Type: static test

Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): 150 mg/l

Exposure time: 72 h
Test Type: static test

M-Factor (Acute aquatic tox- : 1

icity)
Toxicity to fish (Chronic tox- : NOEC: 0.19 mg/l
icity) Exposure time: 8 d

Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 0.08 mg/l
aquatic invertebrates (Chron- Exposure time: 21 d
ic toxicity)
Acute aquatic toxicity- As- : Very toxic to aquatic life.
sessment
Chronic aquatic toxicity- As- : Very toxic to aquatic life with long lasting effects.
sessment
Persistence and degradability
No data available
Bioaccumulative potential

Components:
5989-27-5:
Bioaccumulation : Bioconcentration factor (BCF): 908.5

Partition coefficient: n- : log Pow: 4.57

octanol/water
log Pow: 4.38 (37 °C)
pH: 7.2

SDS Number: 100000003281 8 / 12 d-Limonene

Safety Data Sheet
d-Limonene
Version 1.4 Revision Date: 09/01/2019

Mobility in soil
No data available

Other adverse effects

Product:
Ozone-Depletion Potential : Regulation: 40 CFR Protection of Environment; Part 82 Pro-
tection of Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks: This product neither contains, nor was manufac-
tured with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).

Additional ecological infor- : An environmental hazard cannot be excluded in the event of

mation unprofessional handling or disposal.
Very toxic to aquatic life with long lasting effects.

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Contaminated packaging : Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.

SECTION 14. TRANSPORT INFORMATION

DOT (Department of Transportation):

UN1197, Extracts, flavoring, liquid, 3, III

IATA (International Air Transport Association):

UN1197, EXTRACTS, FLAVOURING, LIQUID, 3, III

IMDG (International Maritime Dangerous Goods):

UN1197, EXTRACTS, FLAVOURING, LIQUID, 3, III, Marine Pollutant (D-LIMONENE) , Flash Point:46 °C(115 °F)

Special Notes: : The flash point for this material is greater than 100 F (38 C).
Therefore, in accordance with 49 CFR 173.150(f) non-bulk
containers (<450L or <119 gallon capacity) of this material
may be shipped as non-regulated when transported solely by
land, as long as the material is not a hazardous waste, a ma-
rine pollutant, or specifically listed as a hazardous substance.

SECTION 15. REGULATORY INFORMATION

WHMIS Classification : B3: Combustible Liquid

D2B: Toxic Material Causing Other Toxic Effects

EPCRA - Emergency Planning and Community Right-to-Know Act

SDS Number: 100000003281 9 / 12 d-Limonene

Safety Data Sheet
d-Limonene
Version 1.4 Revision Date: 09/01/2019

CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards : Fire Hazard

Acute Health Hazard

SARA 302 : No chemicals in this material are subject to the reporting re-
quirements of SARA Title III, Section 302.

SARA 313 : This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

Clean Air Act

This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Sec-
tion 112 (40 CFR 61).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental
Release Prevention (40 CFR 68.130, Subpart F).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Inter-
mediate or Final VOC's (40 CFR 60.489).
Clean Water Act
This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section
311, Table 116.4A.
This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311,
Table 117.3.
This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307
US State Regulations

Massachusetts Right To Know

No components are subject to the Massachusetts Right to
Know Act.
Pennsylvania Right To Know
5989-27-5 d-Limonene 90 - 100 %
New Jersey Right To Know
5989-27-5 d-Limonene 90 - 100 %

California Prop 65 : This product does not contain any chemicals known to State
of California to cause cancer, birth defects, or any other re-
productive harm.
The components of this product are reported in the following inventories:
TSCA : On TSCA Inventory

DSL : All components of this product are on the Canadian DSL

AICS : On the inventory, or in compliance with the inventory

SDS Number: 100000003281 10 / 12 d-Limonene

Safety Data Sheet
d-Limonene
Version 1.4 Revision Date: 09/01/2019

NZIoC : On the inventory, or in compliance with the inventory

ENCS : On the inventory, or in compliance with the inventory

KECI : On the inventory, or in compliance with the inventory

PHIL : On the inventory, or in compliance with the inventory

IECSC : On the inventory, or in compliance with the inventory

SECTION16. OTHER INFORMATION

NFPA: HMIS III:

Flammability

HEALTH 2
3
Instability
Health

2 0 FLAMMABILITY 3
PHYSICAL HAZARD 0

0 = not significant, 1 =Slight,

Special hazard. 2 = Moderate, 3 = High
4 =Extreme, * = Chronic

The information accumulated is based on the data of which we are aware and is believed
to be correct as of the date hereof. Since this information may be applied under conditions
beyond our control and with which we may be unfamiliar and since data made become
available subsequently to the date hereof, we do not assume any responsibility for the
results of its use. Recipients are advised to confirm in advance of need that the information
is current, applicable, and suitable to their circumstances. This SDS has been prepared by
Lab Alley Product Compliance Department.

Revision Date : 09/01/2019

Legacy SDS: : R0111643

Material number:
16133660, 16122015, 16120696, 16062075, 16056042, 16056014, 16056013, 16056012,
16056011, 16037740, 16013558, 763681, 728284, 554323, 554287, 554254, 554210, 554139,
508584, 504369, 139240, 104220, 103451, 103445, 103335, 102799, 87227, 87063, 86953,
86747, 70685, 70604, 70040, 69374, 55064, 54193, 20823, 20822

Key or legend to abbreviations and acronyms used in the safety data sheet
ACGIH American Conference of Govern- LD50 Lethal Dose 50%
ment Industrial Hygienists
AICS Australia, Inventory of Chemical LOAEL Lowest Observed Adverse Effect

SDS Number: 100000003281 11 / 12 d-Limonene

Safety Data Sheet
d-Limonene
Version 1.4 Revision Date: 09/01/2019

Substances Level
DSL Canada, Domestic Substances List NFPA National Fire Protection Agency
NDSL Canada, Non-Domestic Subs- NIOSH National Institute for Occupational
tances List Safety & Health
CNS Central Nervous System NTP National Toxicology Program
CAS Chemical Abstract Service NZloC New Zealand Inventory of Chemi-
cals
EC50 Effective Concentration NOAEL No Observable Adverse Effect
Level
EC50 Effective Concentration 50% NOEC No Observed Effect Concentration
EGEST EOSCA Generic Exposure Scenar- OSHA Occupational Safety & Health
io Tool Administration
EOSCA European Oilfield Specialty Chem- PEL Permissible Exposure Limit
icals Association
EINECS European Inventory of Existing PICCS Philippines Inventory of Commer-
Chemical Substances cial Chemical Substances
MAK Germany Maximum Concentration PRNT Presumed Not Toxic
Values
GHS Globally Harmonized System RCRA Resource Conservation Recovery
Act
>= Greater Than or Equal To STEL Short-term Exposure Limit
IC50 Inhibition Concentration 50% SARA Superfund Amendments and
Reauthorization Act.
IARC International Agency for Research TLV Threshold Limit Value
on Cancer
IECSC Inventory of Existing Chemical TWA Time Weighted Average
Substances in China
ENCS Japan, Inventory of Existing and TSCA Toxic Substance Control Act
New Chemical Substances
KECI Korea, Existing Chemical Inventory UVCB Unknown or Variable Composi-
tion, Complex Reaction Products,
and Biological Materials
<= Less Than or Equal To WHMIS Workplace Hazardous Materials
Information System
LC50 Lethal Concentration 50%

SDS Number: 100000003281 12 / 12 d-Limonene