236 Midterm 2021

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Quantum Mechanics 236

by of an operator O
The adjoint O b is de…ned by
Z 1 Z 1
b
1 (x)O 2 (x) dx =
by
(O 1 (x)) 2 (x) dx;
1 1

for any wave functions 1 ; 2 . Using integration by parts and stating clearly what properties
of the wave functions you use, …nd the adjoint of @=@x. Hence show that the momentum
operator is Hermitian, pbyx = pbx . Express in mathematical form the statement that the eigen-
functions, n (x), of a Hermitian operator are orthonormal. Prove that the eigenvalues, n , of a
Hermitian operator are real and that the eigenfunctions corresponding to di¤erent eigenvalues
are orthogonal.
For a certain system, the operator corresponding to the physical quantity A does not commute
with the Hamiltonian. It has eigenvalues a1 and a2 , corresponding to eigenfunctions
(u1 + u2 ) (u1 u2 )
1 = p ; 2 = p :
2 2
where u1 and u2 are eigenfunctions of the Hamiltonian with eigenvalues E1 and E2 . If the
system is in state = 1 at time t = 0, what are the probabilities of obtaining a1 and a2
when measuring A at time t? show that the expectation value of A at time t is

a1 + a2 a1 a2 (E1 E2 )t
< A >= + cos
2 2 h
For a one-dimensional harmonic oscillator of mass m and frequency w, the Hamiltonian can
^ = hw(^
be expressed as H ^ + 12 ). The operators a
ay a ^y are de…ned by
^ and a
1 1
a
^ = (2mhw) 2 (mw^
x + i^ ^y = (2mhw)
p); a 2 (mw^
x i^
p)
where x^ is the displacement and p^ is the momentum. If un are normalized eigenfunctions of
the Hamiltonian corresponding to the eigenvalue En , then
p p
a
^un = nun 1 ; ^y un = n + 1un+1 :
a
Show that the ground state eigenfunction u0 is a Gaussian, the expectation values of position
and momentum are zero and the expectation values of the potential and kinetic energies are
equal. The harmonic oscillator has charge q and is placed in a uniform electric …eld E0 . Show
that the new Hamiltonian may be written in the form
1

^ = h! a 1 y h 2
H ^a^+ qE0 (^ ^y ):
a+a
2 2m!

An operator ^b is de…ned as ^b = a ^ c; where c is a real number. Calculate the commutator


[^b; ^by ]. Show that with a suitable choice of c one can write

^ = h! ^by^b + 1 q 2 E02
H :
2 2m! 2

1
A wavefunction 0 (x) is de…ned to be a solution of the equation ^b 0 (x) = 0: Show that 0 (x)
^ and …nd its corresponding eigenvalue. (Note that an explicit expression
is an eigenfunction of H
for 0 is not needed.) Hence show that ^by 0 is an eigenfunction of H
^ and obtain its corresponding
eigenvalue.

Consider an electron bound in a hydrogen atom under the in‡uence of a homogeneous magnetic
jejB
…eld B = B z^. Ignore the electron spin. The Hamiltonian of the system is H = H0 2m ec
Lz .
The eigenstates jn; m; li and eigenvalues of the hydrogen atom Hamiltonian H0 are assumed
to be known. Initially (at t = 0) the system is in the state
1
j (0)i = p (j2; 1; 1i j2; 1; 1i)
2

For each of the following states, calculate the probability of …nding the system, at some later
time t > 0, in that state:

1 1
j2px i = p (j2; 1; 1i j2; 1; 1i) ; j2py i = p (j2; 1; 1i + j2; 1; 1i) ; j2pz i = j2; 1; 0i
2 2

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