ALLEM

SECTION-I: (Maximum Marks: 80) ~-I : (~ 3T"ij) : 80)

• This section contains TWENTY questions.
• ~~~-B~~~~

• Each question has FOUR options (A), (B), (C)

and (D). ONLY ONE of these four options is
• ~~ ~~~ -B TlR Bm ~ (A), (B), (C)
(D) ~ I ~ ~Cf(Yf ~ tr @ ~I
3tT-x

•
correct.
For each question, darken the bubble corresponding
• ~~ ~~~ ~ fu"~ 3TI.31R.~ qx @
~ ~-q ~(Yf~~ cpT ·cpTc;rr ~ I
Bm ~

•
to the correct option in the ORS.
For each question, marks will be awarded in one
• ~~ ~~~ ~ fu"~
~~~~~"ffR~~l):
3lCP ~9C1 -qftft~ -B

of the following categories : rpf Jicp : +4 ~ ft1ct @ ~ ~ ~

Full Marks: +4 If only the bubble ~~~ cpT cpRYfT ~ ~ I
corresponding to the correct option is darkened. ~ Jicp : 0 ~ ~ ~II ~(Yf~~ cpT Cf)l(YfT ~
Zero Marks: 0 If none of the bubbles is darkened. ~~I
Negative Marks: -1 In all other cases ?f[UT Jicp: -1 ~ "ff~1I -qftft~-m -B I

~
1. Reaction CO(g) + 2"1 02(g) ~ CO 2(g)· The value 1.

K q)ll=fR ~ "6 -
_P of is-
Kc 1
(A) _1_ (B) vlRT (C) ..}RT (D) RT
(A) _1_ (B) vlRT
1 RT
(C) ..}RT (D) RT
RT
2. If 100 mole of H 202 decompose at 1 bar and 2. ~ H 202 ~ 100 mol, 1 bar Cf2lT 300 K qx ~~

300 K, the work done (kJ) by 02(g) as it expands m, en 1 bar ~ ~ ~ 3lf~ ~ ~Cf
against 1 bar pressure is :
m~ qx ~ Tf<lT q)l<l (kJ -if) m11T :
2H 202(l) ~ 2H 20(l) + °2(g)
2H 202(l) ~ 2H 20(l) + °2(g)
(R = 8.3 J K-I mol:")
(R = 8.3 J K-I mol:")
(A) 498.00 (B) 249.00 (A) 498.00 (B) 249.00
(C) 124.50 (D) 62.25 (C) 124.50 (D) 62.25

3. The incorrect order of decreasing oxidation 3. ~ <tIm) -B S etr 3lfCRirCf)XUT "ff~c<lT ~ ~ q)l

number of S in compounds is :- @ W11 ~ ~:-

(A) H 2S 20 7 > Na 2S406 > Na 2S20 3 > s, (A) H 2S 20 7 > Na 2S406 > Na 2S20 3 > s,
(B) H 2SOS > H 2S03 > SCl2 > H 2S (B) H 2SOs > H 2S03 > SCl2 > H 2S
(C) S03 > S02 > s, > H 2S (C) S03 > S02 > s, > H 2S
(D) H 2S0 4 > S02 > H 2S > H 2S20 g
(D) H 2S0 4 > S02 > H 2S > H 2S20 g
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4. H 20 2 acts as a reducing agent in: 4. ~ -B ~ ~ H 20 2 3iq-qI~Cf) ~ ~ -B "Cf>1<f
(A) FeCl 2 + HCI + H 20 2 -~ FeCl 3 + H 20 ~~:-
(B) Cl 2 + H 20 2 -~ HCI + 02 (A) FeCl 2 + HCI + H 20 2 -~ FeCl 3 + H 20

(C) HI + H 20 2 -~ 12 + H 20 (B) Cl 2 + H 20 2 -~ HCI + 02

(C) HI + H 20 2 -~ 12 + H 20
(D) H 2S0 3
+ H 20 2 -~ H 2S0 4
+ H 20
(D) H 2S0 3 + H 20 2 -~ H 2S0 4
+ H 20
5. The weight of 2.01 x 1023 molecules of CO is- 5 CO ~ 2.01 X 1023 ~3TI cpr ~TR ~ -
(A) 9.3 g (B) 7.2 g
(A) 9.3 g (B) 7.2 g
(C) 1.2 g (D) 3 g
(C) 1.2 g (D) 3 g

6. A metal carbonate decomposes according to 6. ~mg~~c~~~~31~~

following reaction mc=rr ~
M 2C03( S) ~ M 20(s) + CO 2(g) M 2C0 3( S) ~ M 20 (s) + CO 2(g)
Percentage loss In mass on complete M 2C0 3(S) cpr ~uf frcc:rc~ ~ qx ~C<ll1R -B -gT~
decomposition of M 2C0 3(S) ~ ~mm -g~ ~
(Atomic mass of M = 102) (M cpr ~ ~C<ll1R = 102)
(A) 100 % (B) 50 % (C) 25 % (D) 15% (A) 100 % (B) 50 % (C) 25 % (D) 15%
3 3 3 3 3 3
7. Which of the following contain largest number 7. ~ ~~ ~3TI etr "ff~c<lT ~~ ~ ?
of carbon atoms?
(A) 15 gm ~~~, C2H6
(A) 15 gm ethane, C2H6
(B) 40.2 gm sodium oxalate, Na 2C204 (B) 40.2 gm ~~ 31T~~c, Na 2C204
(C) 72 gm glucose, C 6H l 20 6 (C) 72 gm ~"Cf>1\Jf, C6Hl 206
(D) 35 gm pentene, CSH10 (D) 35 gm -q~~, CSH10
8. The IUPAC name of 8. IUPAC~ ~

Br Br

(A) 2-bromo-3-methylbut-3-ene (A) 2-~Tl11-3- ~c-3-~~

(B) 4-bromo-3-methylpent-2-ene
(B) 4- ~Tl11-3- ~c;r-q-;:c -2- ~~
(C) 2-bromo-3-methylpent-3-ene
(C) 2- ~Tl11-3- ~c;r-q-;:c -3- ~~
(D) 4-bromo-2,3-dimethylbut-2-ene
(D) 4- ~Tl11-2,3- ~~~-2- ~~

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9. The IUPAC name of the following compound 9. ~ <tTfTrcp cpr IUPAC ~TB ~?

aCOOC2H5 aCOOC2H5

COCf COCf
(A) Ethyl-2-(chlorocarbonyl)benzoate (A) -q~-2-(q:c;frxT~T~)~\Jl1~c
(B) Ethyl-2-(chlorocarbonyl) hexanoate (B) -q~ -2-(q:c;frxT~T~)-gcffi-;:fr~
(C) 2-(ethoxycarbonyl)benzoyl chloride (C) 2-(~~Cf~ircpr6l1~)~\Jl1-;ff<l(Yf q:c;fr~
(D) None of these (D) cp)~ ~
10. Which of the following carbanions is resonance 10. ~ -B ~ ctT~ ~?f[Ul~ 31TfTG &RT ~~~
stabilized? ~ ?
(A) CH 3-O
8
(A) CH 3- O
8
8 8
(B) CH 3-C=O (B) CH 3-C=O

8 8
(C) CH 2-CH=O (C) CH 2-CH=O

(D) All of these (D) All of these

11. Which of the following carbanion is most stable: 11. ~ -B ~ cp'T~ cpffl?f[UTI~ 3K~ ~~~ ~:
SCH2 0 0 CH2
SCH CH

(A)~ F
(B)~ CI
(A)~ F
(B)~ CI
SCH2 SCH2
SCH2

(C)@ (D)~ CH 3
(D)~ CH 3
12.

cx::
How many geometrical isomers are possible for

given compound?

(A) 0 (B) 1
12. ~

(A) 0
-rm- ~ cfi ~ ~ \Y~lf?I~~ '{iJilq~~

cx:: (B) 1
%?

(C) 2 (D) 3 (C) 2 (D) 3

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13. Which of the following compound show cis and 13. ~ -B ~ ctT~ <TrfTrcp ft1fr (f~T ~~
trans isomerism? '!iJiIClllCldT ~T(fT ~?
CI Br
<, -: CI Br
(A) CI - CH = CH - CI (B) /C=C" <, -:
(A) CI - CH = CH - CI (B) /C=C"
CI Br
CI Br

6 CJ= CJ=
(C) (D)
/CH
C"
CH 3
3

(C) 6 (D)
/CH
C"
CH 3
3

14. Which of the following is not an electrophile? 14. ~ -B ~ cp'T-;::r ~~Tffitr -;::rtr ~?
(A) H+ (B) NO; (A) H+ (B) NO;
(C) BF 3 (D) CH 2=CH2 (C) BF 3 (D) CH 2=CH2
15. Uranium is a member of 15. W~~~-
(A) Transition elements (B) III period (A) ~l1UT c=rc=q (B) 3rd 31TCKf
(C) Actinide series (D) None of these (C) ~~ ~ufr (D) ~ ~ cp)~ ~fr ~
16. Which type of element are yet unknown in the VII 16. VII 31TCKf -B ~ ~"Cf)"R ~ c=rc=q 31~fr ~fr ~cTI~ -;::rtr
period -rp) ~-
(A)s (B)p (C)d (D)f (A)s (B)p (C)d (D)f
17. Which rule is not followed by configuration 17. cfr ~ ~ -B ctT~ ~ q)l ~ ~
[j] ffi] [[I[] mCIT ~:-
[j] ffi] [[I[]
(A) Hund's rule
(A)S~ q)l ~
(B) Aufbase rule
(B) (n + f) q)l ~
(C) (n + f) rule (C) 3i1Cf)61I\3? ~
(D) Pauli's rule (D)~q)l~
18. In the protonation of NH 3 molecule, following 18. NH 3 ~ ~ ~TcT~ -B, ~ -rp) crr~ -B ~ ~
statement is true :
CfT"CRl m11T I
(A) a covalent bond is formed
(A) ~ ~-m\Jfi 6ft[ ~T ~
(B) Hydrogen bond is formed
(B) ~\JPl 6ft[ q)l ~UT m11T
(C) Hybridization of N is change
(C) N q)l "ffCf)XUT ~11T
(D) Shape of NH 3 is changed (D) NH 3 q)l ~ "6I"G(Yfd1 ~
19. In which of the following KI is highly soluble: 19. ~ -B ~ ~ KI 31~(fl1 ~(Yf~(Yf ~ :

(A) (CH3)2CO (E = 21) (A) (CH3)2CO (E = 21)

(B) CH 30H (E = 32) (B) CH 30H (E = 32)
(C) CCl 4 (E = 0) (C) CCl 4 (E = 0)
(D) C6H6 ( E = 0) (D) C6H6 ( E = 0)
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