Composite Materials CZ4B

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Composite Materials

Glass Fibers
Glass Fibers
• Glass fibers are the most common of all reinforcing fibers for
polymeric matrix composites (PMC).

E-Glass Low Cost

Highest Tensile
Strength
Glass Fibers S-Glass
Expensive

Corrosion
C-Glass
Resistant
Glass Fibers, Composition
• oxides, such as B2O3 and Al2O3, are added to modify the network
structure of SiO2 as well as to improve its workability.
• Lower Na2O and K2O gives a better corrosion resistance to water as
well as higher surface resistivity
Glass Fibers, Structure
• The internal structure of glass fibers is a three-dimensional, long
network of silicon, oxygen, and other atoms arranged in a random
fashion. Thus, glass fibers are amorphous (noncrystalline) and
isotropic (equal properties in all directions).
Glass Fibers, Structure

http://www.grandinetti.org/Research/Applications
Manufacturing
Dry Mixing &
Melting @ 1370C

Extrusion

Drawing into
10μm filaments

Coating

Collecting &
Winding

Coating (or size): lubricants, antistatic


agents, binder
Glass Melting
• Batch is delivered into the furnace section for melting, removal of
gaseous inclusions, and homogenization. Then, the molten glass flows
into the refiner section, where the temperature of the glass is
lowered from 1370 C (2500 F) to about 1260 C (2300F).
Fiberizing & Sizing
• The molten glass flows through a platinum-
rhodium alloy bushing with a large number
of holes or tips (400 to 8000, in typical
production).
• The bushing is heated electrically, and the
heat is controlled very precisely to
maintain a constant glass viscosity.
• The fibers are drawn down and cooled
rapidly as they exit the bushing.
• A sizing is then applied to the surface of
the fibers by passing them over an
applicator that continually rotates through
the sizing bath to maintain a thin film
through which the glass filaments pass.
Roving Production
• The entire process

ASM Handbook, Vol. 21: Composites (#06781G)


Glass Fiber Forms
• Strand: collection of parallel
filaments numbering 204 or
more
• Roving: a group of untwisted
parallel strands (ends)
wound on a cylindrical
forming package
• Chopped strands are produced by cutting continuous strand s into
short lengths.
• The ability of the individual filaments to hold together during or after
the chopping process depends largely on the type and amount of the
size applied during fiber manufacturing operation.

Strands

Hard (High Soft (Low


integrity) integrity)
Strands, Applications
• Chopped strands from 0.125 - 0.5 in: injection-molding operations.
• Longer strands, up to 2 in. are mixed with a binder and spread in a
two-dimensional random fashion to form chopped strand mats
(CSMs). These mats are used mostly for hand layup moldings and
provide nearly equal properties in all directions.
• Milled glass fibers: grinding continuous strands into 0.031–0. 125 in.
They are primarily used as a filler in the plastics industry and do not
possess any significant reinforcement value.
Fiber Degradation
• Fresh glass fibers >3.45 GPa (Tensile S.)
• Surface damage produced by abrasion (rubbing against each other or
by contact) tends to reduce it to values that are in the range of 1.72–
2.07 GPa
Effect of Water & Sustained Loads
• Water bleaches out the alkalis from the surface and deepens the surface flaws already present in
fibers.
• Under sustained loads, the growth of surface flaws is accelerated owing to stress corrosion by
atmospheric moisture. the tensile strength of glass fibers is decreased with increasing time of
load duration

Md Nuruzzaman Khan, Open Journal of Composite Materials


Vol.2 No.2(2012), Article ID:18805,8 pages

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