BCHCT-135 Chemistry Ignou

No.
of Printed Pages : 8 BCHCT-135
BACHELOR OF SCIENCE (GENERAL)

(BSCG)
Term-End Examination
December, 2021
BCHCT-135 : SOLUTIONS, PHASE EQUILIBRIUM,

CONDUCTANCE, ELECTROCHEMISTRY AND
FUNCTIONAL GROUP ORGANIC CHEMISTRY – II
Time : 2 hours Maximum Marks : 50

Note :
(i) Attempt any five questions from Part A and any
five questions from Part B on separate answer sheets.
(ii) All questions carry equal marks.
PART A (Maximum Marks : 25)
1. Explain the variation of mutual solubility of

phenol and water with temperature giving a
labelled diagram. 5
2. (a) State the criterion for the phase

equilibrium in a heterogeneous system. 1
(b) What is a metastable equilibrium ? Explain
with the help of an example. 3
(c) What is an ideal solution ? 1
BCHCT-135 1 P.T.O.
3. (a) Give one example of a solution exhibiting
negative deviation from Raoult’s law. 1
(b) Give the expression for phase rule for
condensed systems. 1
(c) Draw a schematic phase diagram for a
typical one-component system and mark
different two-phase equilibria on it. 3
4. (a) Define conductivity of a solution of an

electrolyte and give any four factors
affecting it. 3
(b) The molar conductivities at infinite dilution
for hydrochloric acid, sodium
monochloroacetate and sodium chloride are
425·9, 89·8 and 126·4 S cm2 mol–1,
respectively. Calculate the molar
conductivity of monochloroacetic acid at
infinite dilution. 2
5. (a) State Henry’s law. 1

(b) Define ionic mobility and state its SI unit. 2
(c) The molar conductivity of 0·001028 M acetic
acid solution at 298 K is 48·15 S cm2 mol–1.
If the molar conductivity at infinite dilution
is found to be 390·6 S cm2 mol–1, then
calculate the degree of ionisation of acetic
acid at this concentration. 2
BCHCT-135 2
6. (a) Differentiate between galvanic and
electrolytic cells. 2
(b) The standard cell potential for Daniell cell is

1·11 V. Calculate the equilibrium constant
for it under standard conditions. 3
7. (a) Define molarity. 1
(b) Give the polarity and nature of process on

cathode in a galvanic cell. 1
(c) Calculate the time for which a 0·8 A current

be passed through a sample of molten
sodium chloride to get 1·25 g of sodium
metal. 3
(Given : Mm(Na) = 23 g mol–1)
BCHCT-135 3 P.T.O.
PART B (Maximum Marks : 25)
8. Discuss the mechanism of Fischer esterification. 5
9. (a) Draw the resonance structures of an
amidate ion. 2
(b) What is the full form of DMF ? Write its
structure also. 2
(c) What are disaccharides ? 1
10. Describe Hinsberg method to distinguish
primary, secondary and tertiary amines. 5
11. (a) What is diazo coupling ? Write the reaction
and the products formed when benzene
diazonium chloride reacts with
(i) benzenol, and
(ii) N, N-dimethylbenzenamine. 4
(b) Name the product(s) obtained by hydrolysis
of maltose. 1
12. How can you prepare a 2-amino acid using
Gabriel phthalimide synthesis ? Explain using
the sequence of reactions involved. 5
13. (a) Explain the Sanger method used for end
group analysis giving suitable reactions. 4
(b) What is invert sugar ? 1
14. (a) Discuss Kiliani-Fischer synthesis by
starting with D-arabinose. Write the
sequence of reactions involved and the
products formed. 4
(b) Which one has branched structure —
amylose or amylopectin ? 1
BCHCT-135 4
~r.gr.EM.gr.Q>r.-135
{dkmZ ñZmVH$ (gm_mÝ`)
(~r.Eg.gr.Or.)
gÌm§V narjm
{Xgå~a, 2021
~r.gr.EM.gr.Q>r.-135 : {db`Z, àmdñWm gmå`, MmbH$Ëd,

d¡ÚwV-agm`Z Am¡a A{^bjH$s` g_yh H$m~©{ZH$ agm`Z – II
g_` : 2 KÊQ>o A{YH$V_ A§H$ : 50

ZmoQ> :
(i) AbJ-AbJ CÎma nwpñVH$mAm| na ^mJ H$ go {H$Ýht nm±M àíZm|
Am¡a ^mJ I go {H$Ýht nm±M àíZm| Ho$ CÎma Xr{OE &
(ii) g^r àíZm| Ho$ A§H$ g_mZ h¢ &
^mJ H$ (A{YH$V_ A§H$ : 25)

1. Zm_m§{H$V {MÌ XoVo hþE µ\$sZm°b Am¡a Ob H$s Vmn Ho$ gmW
nmañn[aH$ {dbo`Vm _| n[adV©Z H$s ì`m»`m H$s{OE & 5
2. (H$) {H$gr {df_m§Jr V§Ì _| àmdñWm gmå` H$s H$gm¡Q>r

{b{IE & 1
(I) {_VñWm`r gmå` Š`m hmoVm h¡ ? EH$ CXmhaU H$s
ghm`Vm go ì`m»`m H$s{OE & 3
(J) AmXe© {db`Z Š`m hmoVm h¡ ? 1
BCHCT-135 5 P.T.O.
3. (H$) amCëQ> {Z`_ go G$UmË_H$ {dMbZ àX{e©V H$aZo
dmbo {H$gr {db`Z H$m EH$ CXmhaU Xr{OE & 1
(I) g§K{ZV V§Ìm| Ho$ {bE àmdñWm {Z`_ H$m ì`§OH$
Xr{OE & 1
(J) àê$nr EH$-KQ>H$ V§Ì Ho$ {bE ì`dñWmË_H$ àmdñWm
AmaoI ~ZmBE Am¡a Cg_| {d{^Þ {Û-àmdñWm gmå`m|
H$mo Xem©BE & 3
4. (H$) {H$gr {dÚwV²-AnKQ>ç Ho$ {db`Z Ho$ {bE MmbH$Vm

H$mo n[a^m{fV H$s{OE Am¡a Cgo à^m{dV H$aZo dmbo
H$moB© Mma H$maH$ {b{IE & 3
(I) hmBS´>moŠbmo[aH$ Aåb, gmo{S>`_ _moZmoŠbmoamoEogrQ>oQ> Am¡a
gmo{S>`_ ŠbmoamBS> Ho$ {bE AZ§V VZwVm na _moba
MmbH$Vm Ho$ _mZ H«$_e: 425·9, 89·8 Am¡a
126·4 S cm2 mol–1 h¢ & _moZmoŠbmoamoEogr{Q>H$ Aåb
Ho$ {bE AZ§V VZwVm na _moba MmbH$Vm n[aH${bV
H$s{OE & 2
5. (H$) hoZar {Z`_ {b{IE & 1

(I) Am`{ZH$ J{VerbVm H$mo n[a^m{fV H$s{OE VWm
BgH$m SI _mÌH$ {b{IE & 2
(J) 298 K na 0·001028 M Eogr{Q>H$ Aåb {db`Z H$s
_moba MmbH$Vm H$m _mZ 48·15 S cm2 mol–1 h¡ &
`{X AZ§V VZwVm na _moba MmbH$Vm H$m _mZ
390·6 S cm2 mol–1 nm`m J`m h¡, Vmo Bg gm§ÐVm na
Eogr{Q>H$ Aåb Ho$ {bE Am`ZZ H$s _mÌm n[aH${bV
H$s{OE & 2
BCHCT-135 6
6. (H$) J¡ëd¡Zr Am¡a {dÚwV²-AnKQ>Zr gobm| Ho$ ~rM A§Va
ñnï> H$s{OE & 2
(I) S>oÝ`b gob Ho$ {bE _mZH$ gob {d^d H$m _mZ
1·11 V h¡ & _mZH$ AdñWmAm| _| Bg gob Ho$ {bE
gmå` pñWam§H$ H$m _mZ n[aH${bV H$s{OE & 3
7. (H$) _mobaVm H$s n[a^mfm Xr{OE & 1
(I) J¡ëd¡Zr gob _| H¡$WmoS> H$s Y«wdVm VWm H¡$WmoS> na hmoZo

dmbr à{H«$`m H$s àH¥${V ~VmBE & 1
(J) J{bV gmo{S>`_ ŠbmoamBS> Ho$ {dÚwV²-AnKQ>Z Ûmam

1·25 g gmo{S>`_ YmVw H$mo àmßV H$aZo Ho$ {bE 0·8 A
H$s {dÚwV²-Ymam H$mo {H$VZo g_` VH$ àdm{hV H$aZm
hmoJm ? 3
({X`m J`m h¡ : Mm(Na) = 23 g mol–1)
BCHCT-135 7 P.T.O.
^mJ I (A{YH$V_ A§H$ : 25)
8. {\$ea EñQ>arH$aU H$s {H«$`m{d{Y H$s MMm© H$s{OE & 5
9. (H$) Eo{_S>oQ> Am`Z H$s AZwZmXr g§aMZmE± Amao{IV
H$s{OE & 2
(I) S>r.E_.E\$. (DMF) H$m nyam ê$n Š`m h¡ ? BgH$s
g§aMZm ^r {b{IE & 2
(J) S>mBg¡Ho$amBS> Š`m hmoVo h¢ ? 1
10. àmW{_H$, {ÛVr`H$ Am¡a V¥Vr`H$ Eo_rZm| _| A§Va H$aZo H$s
qhg~J© {d{Y H$m dU©Z H$s{OE & 5
11. (H$) S>mBEoµOmo `w½_Z Š`m hmoVm h¡ ? ~oÝµOrZ S>mBEoµOmo{Z`_
ŠbmoamBS> H$s {ZåZ{b{IV Ho$ gmW hmoZo dmbr
A{^{H«$`m Am¡a àmßV CËnmX {b{IE : 4
(i) ~oÝµOrZm°b VWm
(ii) N, N - S>mB_o{Wb~oÝµOrZ¡_rZ
(I) _mëQ>mog Ho$ Ob-AnKQ>Z go àmßV CËnmX/CËnmXm| Ho$
Zm_ {b{IE & 1
12. J¡{~«b W¡{b_mBS> g§íbofU Ûmam Amn {H$gr 2-Eo_rZmo Aåb
H$mo {H$g àH$ma ~ZmE±Jo ? Bg_| hmoZo dmbr A{^{H«$`mAm| H$m
H«$_ XoVo hþE ì`m»`m H$s{OE & 5
13. (H$) A§Ë` g_yh {díbofU Ho$ {bE à`moJ H$s OmZo dmbr
g¡ÝJa {d{Y H$s C{MV A{^{H«$`mE± XoVo hþE ì`m»`m
H$s{OE & 4
(I) àVrn eH©$am Š`m hmoVr h¡ ? 1
14. (H$) D-Eoa¡{~Zmog go Ama§^ H$aHo$ {H$ë`mZr-{\$ea
g§íbofU H$s MMm© H$s{OE & Bg_| hmoZo dmbr
A{^{H«$`mAm| H$m H«$_ Am¡a àmßV CËnmX {b{IE & 4
(I) Eo{_bmog `m Eo{_bmonopŠQ>Z _| go {H$gH$s em{IV
g§aMZm hmoVr h¡ ? 1
BCHCT-135 8

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No.

of Printed Pages : 8 BCHCT-135

BACHELOR OF SCIENCE (GENERAL)

BCHCT-135 : SOLUTIONS, PHASE EQUILIBRIUM,

Time : 2 hours Maximum Marks : 50

PART A (Maximum Marks : 25)

1. Explain the variation of mutual solubility of

2. (a) State the criterion for the phase

4. (a) Define conductivity of a solution of an

5. (a) State Henry’s law. 1

(b) The standard cell potential for Daniell cell is

7. (a) Define molarity. 1

(b) Give the polarity and nature of process on

(c) Calculate the time for which a 0·8 A current

~r.gr.EM.gr.Q>r.-135 : {db`Z, àmdñWm gmå`, MmbH$Ëd,

g_` : 2 KÊQ>o A{YH$V_ A§H$ : 50

^mJ H$ (A{YH$V_ A§H$ : 25)

2. (H$) {H$gr {df_m§Jr V§Ì _| àmdñWm gmå` H$s H$gm¡Q>r

4. (H$) {H$gr {dÚwV²-AnKQ>ç Ho$ {db`Z Ho$ {bE MmbH$Vm

5. (H$) hoZar {Z`_ {b{IE & 1

7. (H$) _mobaVm H$s n[a^mfm Xr{OE & 1

(I) J¡ëd¡Zr gob _| H¡$WmoS> H$s Y«wdVm VWm H¡$WmoS> na hmoZo

(J) J{bV gmo{S>`_ ŠbmoamBS> Ho$ {dÚwV²-AnKQ>Z Ûmam

({X`m J`m h¡ : Mm(Na) = 23 g mol–1)

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