Adobe Scan 11-Feb-2023
Adobe Scan 11-Feb-2023
Adobe Scan 11-Feb-2023
PTmary Vdence: The valence related to the oxidation number is called primary vaence(a
) Merldo-
Exampies
22 ICo(NH,),cnc
1. ICo(NHJJC SAQ26. Usin
H
NH NH
NH
AH NH
Ce --C Co -a (AI)
Ans:
NH,
NH, NH NH, C Tetrahy
NH
The coordination number of cobalt is 6. It
q) Hexaam
Coordination number of cobalt is 6. It as
an octahedral shape. In this compound, the NH
has an octahedral shape. But these are only 5 NH
molecules. Thus, the chloride ion occupies the
(i) Potassiu
Ihus, the chloride ion occupiessh
and C1, satisfy molecules. w) Potassiu
igand satisfies secondary valency remained position. In this compound, one C ion
primary valency. satisfies both secondary and primary valencies. A027. WhM
isomerism in coordination compounds
glving suitable examples.
SAQ25. Explain geometrical
nis
compound, the NH
ligand satisfies secondary valency and C, molecules. Thus, the chloride ion OCcupies the
primary valency. satisfy
remained position. In this compound, one C ion
satisfies both secondary and primary valencies
SAQ25. Explain geomerical isomerism in coordination
Ans
compounds giving suitable examples
Geomefrical Isomerism: The
geometrical Isomerism occurs due to the different possible geoinetr
arrangements of the ligand in coordination complex. There are two types of geometrical isomers
They are cis and trans isomers.
(a) Cis isomers: If the ligands of same type are positioned adjacent in the sphere ot central metal
atom, is known as cis isomers.
rdina NH
Cis i o t e Trare i he
OR
Write the characteristics
properties of transition elements? tTS) Aug-22, a18 (TS) May-22. Q231
Ans: The characteristic properties exhibited by transition elements are,
) They are good conductors of heat and electricity.
(ii) They are hard and heavy with high melting and boiling points.
(ii) They form coloured hydrated ions or salts.
37
CH HC H
C C
C C
HC=C-CH=CH, HC CH
CH C C CHCH CH
Isoprene HC H
39
CHEMISTRY
(TS) March-18, Q16
What are hormones? Give one example for each of the following:
derlvatives
(a) Steroid hormones.(b) Polypeptide hormones (c)Amirno acid
Ans
Hormones: The organic compounds that transfer biological information from one part into anoner
part in plant or animal body are called as hormones. It helps in maintaining balanced biological
activities in the body.
Examples: Thyroxine, parathyroxine, estrogen etc.
Types of Hormones
() Steriod Hormone: These hormones are produced by the adrenal cortex and gonads.
Example: Testosterone.
() Polypeptide Derivatives: It is produced by pancreas, parathyroid, pituitary and
mucosa. gastrointestinal
Example: Insulin, Vasopressin.
(li) Amino Acid Hormone: It is
produced by thyroid and adrenal medulla.
Example: Thyroxine.
SAQ34. Give the sources of the following vitamins and name the diseages caused by
deflciency A, D, E, K. thetr
(TS) June-19, Q15
OR
Give the sources of the
following vitamins and name th
deficiency. caused by their
(a) A (b) D (c) E (d) K
ns:
E(TS) Ma
17 51(
INTERMEDIATE (2 YEAR)
SAQ35. Explain the denaturation of proteins. (TS) Aug-22, a21
Ans: Denaturation is reversible or an irreversible change in the structure of the protein molecule
resulting in the reduction or loss of its biological properties.
Acids, alkalies, organic solvents, urea, salts of heavy metals are chemical agents of denaturation.
SAQ36. Write notes on aminoaclds.
Amino acids, which consists of amino (- NH,) and carboxyl (- COOH) as its functional
Ans
groups. The general structure is given as,
R
HN-C-COOH
H
A: Ethenie is comverted into alcohol by direct addition of water in the presenceof phosphoric Acid (H,PO4).
CH =CH +H20- H CH,CH,OH
Mechanism: The mechanism of the reaction involves the following three steps:
Step 1: Protonation of alkene to form carbocation by electrophilic attack ofH0Ot
H2O+H® H,0
H H
H H H H
H-C cH+Hö=H H
H H H H
Step 3: Deprotonation to form an alcohol
H H H H :OH
H-C C H +H H-C-C-HH +H0e s t
H H e todoo H H
Ethanol
53. Explain the role of electron withdrawing and electron releasing groups on theacidityo
carboxylic acids.
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