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DPP - 01

This document contains a guided revision plan for coordination chemistry with 11 multiple choice questions. Some key points covered include: 1) Carbon monoxide forms metal-carbon bonds with transition metals in metal carbonyl complexes. The most favorable bonding type has the metal in its lower oxidation state bonded to carbon with a metal-carbon π bond. 2) Metal carbonyl complexes I and II can be identified using the effective atomic number rule to determine the values of x and y. 3) The stretching frequency of the carbon-oxygen bond decreases in the order [V(CO)6]- > [Mn(CO)6]+. 4) Ligands such as carbon monoxide, is

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Mahir Mittal
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50 views3 pages

DPP - 01

This document contains a guided revision plan for coordination chemistry with 11 multiple choice questions. Some key points covered include: 1) Carbon monoxide forms metal-carbon bonds with transition metals in metal carbonyl complexes. The most favorable bonding type has the metal in its lower oxidation state bonded to carbon with a metal-carbon π bond. 2) Metal carbonyl complexes I and II can be identified using the effective atomic number rule to determine the values of x and y. 3) The stretching frequency of the carbon-oxygen bond decreases in the order [V(CO)6]- > [Mn(CO)6]+. 4) Ligands such as carbon monoxide, is

Uploaded by

Mahir Mittal
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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(INORGANIC CHEMISTRY) Rankers Group

GUIDED REVISION PLAN - SCORES ADVANCE – DPP-01


TOPIC : COORDINATION CHEMISTRY
Coordination Chemistry
Carbon monoxide (CO) is a colorless, odorless and tasteless gas that is lighter than air and highly
toxic to humans.
1. Draw Lewis structures of carbon monoxide (CO) and underline the one which follows the octet
rule, also write ratio of σ to π bond in CO.
2. Carbon monoxide forms many metal carbonyls with transition metals in which there is a Metal-
Carbon bond. Four possibilities of metal carbonyl bondings are given below, in which the metal
(M) is in its lower oxidation state. Select the most favourable bonding type.

(A) (B)

(C) (D)
3. Using the effective atomic number (EAN) rule identify the value of x and y in metal carbonyls I
and II, draw the structures of the metal carbonyls.

(I) Crx (CO)y x = y =

(II) [Mnx (CO)y ] x = y =

4. The V − C distance in V(CO)6 and [V(CO)6 ]− are respectively (in pm) -


(A) 200,200 (B) 193,200
(C) 200,193 (D) 193,193
5. Write oxidation number, coordination number and EAN of Ni in complex (P) formed in reaction
for the synthesis of pure nickel from impure nickel in monds process.
6. The maximum number of atoms lie in one plane in above complex (P) is -
(A) 5 (B) 8 (C) 9 (D) 4
7. Arrange the following given metal carbonyls according to the descending order of C − O
stretching frequency. (Write approprite alphabets in the boxes)
(i)
(a) MCO (b) M2 CO (c) M3 CO
where M stands for metal.

APNI KAKSHA 1
(INORGANIC CHEMISTRY) Rankers Group

8. With respect to the complex Co2 (CO)8 answer the following. In the IR spectrum, this complex in
the solid form shows separate bands, above and below 2000 cm−1 .
(i) Draw the structure of the complex in the solid form.
(ii) When it is dissolved in hexane the bands below 2000 cm−1 disappear. Draw the structure of
the complex in the solution.
9. Arrange the following complex in increasing order of strecthing vibrational frequency of C − O
bond -
(I) [(PPh3 )3 Mo(CO)3 ] (II) [(Ph2 PCl)3 Mo(CO)3 ]
(III) [(PhPCl2 )3 Mo(CO)3 ] (IV) [(PCl3 )3 Mo(CO)3 ]
(A) I > II > III > IV (B) I = IV > III > II
(D) I < II < III < IV
10. Select the correct statement
(A) [V(CO)6 ] can acts as an oxidizing agent
(B) The dc−o in bridging carbonyl group is longer than that of terminal carbonyl group
⊖ +
(C) Ligands such as CO, C N and NO are π-acceptor ligand.
(D) All are correct
11. Which of the following has lower stretching frequency for C-O bond -
(A) [Mn(CO)6 ]+
(B) [V(CO)6 ]−
(C) Both have equal stretching frequency
(D) None of these

APNI KAKSHA 2
(INORGANIC CHEMISTRY) Rankers Group
ANSWER KEY
SECTION -1
+ 𝜎 1 𝑥 = 1𝑦 = 6
1. C̅ ≡ O: (𝜋 = 2) 2. (B) 3. 4. (C)
𝑥 = 2𝑦 = 10

5. Oxidation number = Zero


Coordination number = 4

EAN = 36

6. (A)

7. (i) (a) > (b) > (c)

(ii) (b) > (c) > (a)

8. (i)

(ii)

9. (D) 10. (D) 11. (B)

APNI KAKSHA 3

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