BT Tech 28.5

Lab Report Outline
Gram isomer series method for determination of

Cu(ll)-salt complex composition
Abstract
I. Introduction
The Nitroso-R salt (symbol HR) is the common saddle of the bisodium salt 3-
hydroxy-4-nitroso-2,7 naphthalene disulfonic acid.
Reagents
1, CuSO4 solution 1.00.10-3M(l).
2, NItrozo R salt 1.00.10-3M(ll).
3, H2SO4 solution pH=4.00(lll).
4, 0.05M Na2SO4 solution has pH=4.0(llll).
II. Methodology
1, Construct a graph of the optical absorbance depending on the composition of
the solution
Use a volumetric flask with a capacity of 25.0 ml.
Measure the absorbance of the solutions on a photometer at λmax=490 nm with
a cuvette with a thickness of 1 (cm).
2, The experimental sequence and experimental results are presented in the
table below:
Take 9 volumetric flasks with a capacity of 25.0 ml, prepare a series of solutions
with the following composition:
III. Results
We obtain a graph of the optical absorbance A depending on the volume of CuSO 4
with the trend line being a quadratic curve of the form y=-0.036x 2+0.3672x-
0.1373 with R2=0.9167 . Amax=0.904 with VCu2+=5.06 ml
IV. Discussion
As the concentration of reagent R increases, the amount of complex formed will
increase. If you mix a series of solutions in which the relative amounts of Cu 2+ and
R are different, but the common quantity is constant, they will have a maximum
CuRn.
V. Conclusion
1, Cu-Nitrozo-R complexation depends on the medium and concentration:
2, Choose the incident ray wavelength corresponding to the absorption maximum
of the Cu/Nitrozo-R component = 1:1, VHCl=5.00 ml because then the absorbance
A of the solution reaches the maximum, the measurement will give results. the
most exactly.
3, If the concentration of the original solution is changed, on the graph of the
absorption composition of the solution, the positions of the peaks still coincide.
The maximum shift occurs only when we change the pH of the solution or
measure with different concentrations of Cu2+, Nitrozo-R.
References
[1] P. W. Atkins and J. de Paula, Atkins' Physical Chemistry. OUP Oxford, 2014.
[2] TAI LIEU HUONG DAN THI NGHIEM PHAN TICH BANG CONG CU HOC KY 2020.1 (in
Vietnamese)
[3] www.phongsachcongnghiep.com
DETERMINATION OF ADSORPTION WITH ACTIVATED CARBON OF

BUTYLIC ALCOHOL SOLUTION BY SURFACE TENSION
II. Methodology
1, Tool and chemicals
- Surface tension test kit (image 3)
- 4 triangular flasks with emery buttons numbered 1 4 used to conduct the
steaming process auxiliary and 4 regular triangular flasks numbered 1' 4' used to
store the solution after autoclaving extra; 4 filter funnels, filter paper.
- Burette took 25 ml of alcohol with different concentrations
- Activated carbon,
- Butylic alcohol solution has the concentration: 0.1; 0.2 ; 0.3 ; 0.4 M
- Before testing the conical flasks must be clean and dry and the coals have been
dried.
2, Instruments and methods for measuring surface tension:
The instrument shown in figure 3 allows measurement of the surface tension of a
solution through through the height h read on the manometer based on the
following simple relationship:
h = K’. σ
K’ is a constant that depends only on temperature. At constant temperature, h is
proportional to σ . In this lesson, we should have plotted the normal graph “σ - C”,
but thanks to the above relationship, we only need to draw graph “h – C” without
knowing the value of σ . On the other hand, to determine the value of , just know
the concentrations before and after adsorption of Ct and Cs (deduced from the
graph “h – C”).
The working principle of the measuring instrument is as follows: Put the liquid
to be measured into the tube (1). Insert the capillary (2) into the tube (note: The
capillary tip just touches the surface of the substance liquid). Place tube (1)
with capillary plug into beaker (4) to stabilize the temperature. Measure
temperature with heat next (5).
During the measurement, the temperature should be stable. Before measuring,
check the button and connecting pipes, lock to ensure sealing.
After stabilizing the temperature, unlock (7) slowly let the water in the tank
decrease pressure (6) flows down the cup (8). Then the pressure in the system
is less than the external pressure. Degree the pressure difference is reflected by
degrees height h of the manometer or also known as manometer (9). Control to
stay in it takes about 10 20 seconds to have 1 bubble exit. When air bubbles
come out from the capillaries manage (2), h has the largest value. Write price
that h value.
Image 3. Surface tension measuring instrument
3, Test order:
- Weigh into 4 conical flasks (1- 4), each with exactly 1 gram of activated
carbon and add to each in that flask 25 ml of solutions of the above
concentrations (using a burette). Shake with a shaker to increase the adsorption
rate. Leave to adsorb for about 60 minutes.
- Measure the cough value of distilled water and the 4 h values of the above 4
solutions. Volume distilled water and each solution should be the same so that
the measurement condition of the samples is close to be the same.
Note:
+ Measure the dilute solution first, then thicken it.
+ The values of ho and h must be read very carefully to reduce errors when
plotting standard “h – C”.
+ Keep the drip rate of the water in the pressure reducing vessel (6)
constant throughout experimental process.
+ After measuring, rinse the capillary and solution tube with distilled
water, shake off.
+ After about 60 minutes, it can be considered that the adsorption has
reached equilibrium. Bring the mixture in flasks (1- 4) filter through the filter
funnel into the corresponding flasks (1'- 4').
+ Measure the value of h corresponding to the solution in the 1' - 4' flasks.
Sequence of dilution first, thickening later. The h data obtained were used to
determine C s (equilibrium concentration) deduced from the standard plot '' h-
C''.
III. Result
As shown in Figure 2, the relationship diagram between the C'/ɼ value and the
C' concentration is a straight line and fits the first order trend line y = 0,0116x.
Figure 2. Relationship between C’/ɼ and concentration C’

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Lab Report Outline

Gram isomer series method for determination of

DETERMINATION OF ADSORPTION WITH ACTIVATED CARBON OF

Figure 2. Relationship between C’/ɼ and concentration C’

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