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    Chem

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    Daniel Concessao
    The seminar will cover photophysical processes such as absorption, emission, and relaxation of energy in molecules. A31-A37 will present on these topics, interpreting the Jablonski diagram which illustrates the various radiative and non-radiative transitions between energy levels that occur during these processes. Key processes discussed will include absorption, vibrational relaxation, internal conversion, fluorescence, intersystem crossing, and phosphorescence.

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    Chem

    Uploaded by

    Daniel Concessao
    8 views24 pages
    The seminar will cover photophysical processes such as absorption, emission, and relaxation of energy in molecules. A31-A37 will present on these topics, interpreting the Jablonski diagram which illustrates the various radiative and non-radiative transitions between energy levels that occur during these processes. Key processes discussed will include absorption, vibrational relaxation, internal conversion, fluorescence, intersystem crossing, and phosphorescence.

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    The seminar will cover photophysical processes such as absorption, emission, and relaxation of energy in molecules. A31-A37 will present on these topics, interpreting the Jablonski diagram which illustrates the various radiative and non-radiative transitions between energy levels that occur during these processes. Key processes discussed will include absorption, vibrational relaxation, internal conversion, fluorescence, intersystem crossing, and phosphorescence.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    8 views24 pages

    Chem

    Uploaded by

    Daniel Concessao
    The seminar will cover photophysical processes such as absorption, emission, and relaxation of energy in molecules. A31-A37 will present on these topics, interpreting the Jablonski diagram which illustrates the various radiative and non-radiative transitions between energy levels that occur during these processes. Key processes discussed will include absorption, vibrational relaxation, internal conversion, fluorescence, intersystem crossing, and phosphorescence.

    Copyright:

    © All Rights Reserved
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    of 24

    SEMINAR

    A31-A37 will be presenting today’s topic.


    Introduction

    Principle

    Interpreting the diagram

    Absorption

    Vibrational Relaxation

    Internal Conversion

    Fluorescence

    Intersystem crossing

    Phosphorence
    Jabłoński
    Aleksander
    Jabłoński
    - Jabłoński, a Polish physicist, pioneered fluorescence spectroscopy.
    - Explored fluorescence spectra and excitation light impact.
    - Verified that fluorescence spectrum isn't affected by excitation light
    wavelength.
    - Named for Jean Baptiste Perrin and Aleksander Jabłoński.
    - Illustrates fluorescence processes and kinetics.
    - Jean Perrin introduced energy transfer concepts; Francis Perrin
    refined with quenching models and relationships.

    26 Feb, 1898 9 Sep, 1980


    1. Introduction and
    Principle:
    • Photophysical processes involve
    interactions between light and
    molecules, leading to energy
    changes and transitions.
    • These processes play a crucial role
    in spectroscopy, photovoltaics, and
    materials science fields.
    • At their core, photophysical
    processes encompass the
    absorption, emission, and relaxation
    of energy in molecules.
    2. Interpreting the Diagram
    - Diagrams visualize energy levels and
    transitions, aiding comprehension of molecu
    processes.
    - They illustrate the absorption of energy,
    emission of light, and relaxation pathways.
    - The diagram's vertical axis represents ener

    ATO M B O M B
    and transitions occur when energy differenc
    match photon energies.`
    A nuclear weapon[a] is an explosive device that derives its destructive force from
    nuclear reactions, either fission or a combination of fission and fusion reactions,
    producing a nuclear explosion. Both bomb types release large quantities of
    energy from relatively small amounts of matter.
    3. Absorption:
    - Absorption is a radiative transition.
    - A molecule absorbs a photon, moving from a lower
    state to a higher electronic state.
    - Shown as blue arrows on the diagram.
    - This transition is rapid (around 10^-15 seconds).
    - Most molecules at room temperature start in the
    lowest vibrational level of the ground state (Boltzmann
    distribution).
    - Absorption promotes the molecule to vibrational
    levels of singlet excited states (S1, S2, ...).
    v
    Vibrational Relaxation:
    - Non-radiative transition within the same
    electronic state to lower vibrational level.
    - Dissipates excess energy gained from
    absorption.
    - Happens rapidly (10^-12 to 10^-10
    seconds).
    - Competes with other transitions.
    Internal Conversion:
    - Non-radiative transition between two
    electronic states of same spin
    multiplicity.
    - Follows internal conversion and
    vibrational relaxation.
    - Faster for closely spaced states
    (10^-11 to 10^-9 seconds).
    - Slower for states with wider energy
    gap, competing with other transitions.
    Fluorescence:
    - Radiative transition between electronic
    states of same spin multiplicity.
    - Emission of photons from S1 → S0
    transition.
    - Occurs rapidly (10^-10 to 10^-7
    seconds).
    - Usually from lowest vibrational level of
    excited singlet state to singlet ground
    state.
    - Explains Kasha's Rule and Stokes-Shift.
    Intersystem Crossing:
    - Non-radiative transition between
    vibrational levels of different spin
    multiplicity.
    - From S1 to T1 state through spin-orbit
    coupling.
    - Competes with internal conversion
    and fluorescence.
    - Slow for most organic molecules,
    except with heavy atom incorporation
    Phosphorescence:
    - Radiative transition between
    electronic states of different spin
    multiplicity.
    - Emission of photons from T1 → S0
    transition.
    - Weaker allowed transition due to
    spin-orbit coupling.
    - Slower compared to fluorescence
    (10^-6 to 10 seconds).
    Chrisyl Danica M
    A31 Clarissa Clera A34
    A32 A33

    Danica D Deeksha
    A35 Daniel A37
    A36

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