Rivolta MTX 60 Forte

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SAFETY DATA SHEET

According to Regulation (EC) No. 1907/2006 (REACH) Article 31, Annex II as amended.

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier


Product name: Rivolta M.T.X. 60 forte

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified uses: Solvent-based cleaner


Uses advised against: No uses advised against identified.

1.3 Details of the supplier of the safety data sheet

Manufacturer / Supplier Bremer & Leguil GmbH US Distributor


Am Burgacker 30 - 42 Fuchs Lubricants Co.
47051 Duisburg 17050 Lathrop Avenue
info@bremer-leguil.de Harvey, IL 60426
www.bremer-leguil.de (708) 333-8900
(800) 255-3924 24 hrs Emergency
Telephone: +49 (0)203 / 9923-0
Fax: +49 (0)203 / 25901

Contact Person: Bremer & Leguil GmbH - Product Safety Management


E-mail: product-safety-management@bremer-leguil.de

1.4 Emergency telephone number: +49 (0) 6131 / 19240 (Giftinformationszentrum Mainz)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

The product has been classified and labelled as hazardous according to regulation (EU) 1272/2008 (CLP).

Classification according to Regulation (EC) No 1272/2008 as amended.


Health Hazards
Aspiration Hazard Category 1 H304: May be fatal if swallowed and enters
airways.

Hazard summary
Physical Hazards: Can form flammable vapour-air mixtures during the application.

Health Hazards

Skin Contact: At long or repeated contact with skin it may cause dermatitis due to the
degreasing effect of the solvent.

Ingestion: If ingested, material may be aspirated into the lungs and cause chemical
pneumonitis. Treat appropriately.

Issue Date: 16.02.2015


Revision Date: 16.02.2016 Version: 5.0
Print date:: 16.02.2016
SDS_DE - EN - 000000000600452155 1/13
Product name: Rivolta M.T.X. 60 forte

2.2 Label Elements


Contains: Hydrocarbons, low viscous

Signal Words: Danger

Hazard Statement(s): H304: May be fatal if swallowed and enters airways.

Precautionary Statement

Response: P301+P310: IF SWALLOWED: Immediately call a POISON


CENTER/doctor/…
P331: Do NOT induce vomiting.

Disposal: P501: Dispose of contents/container to an appropriate treatment and


disposal facility in accordance with applicable laws and regulations,
and product characteristics at time of disposal.

Supplemental label information


EUH066: Repeated exposure may cause skin dryness or cracking.

2.3 Other hazards: By handling of mineral oil products and chemical products no particular
hazard is known when normal precautions (item 7) and personal protective
equipment (item 8) are kept. The product may not be released into the
environment without control.

SECTION 3: Composition/information on ingredients

3.2 Mixtures

General information: Mixture based on volatile aromatic-free hydrocarbons and additives.

Chemical name Identifier Concentration * REACH Registration Notes


No.
Hydrocarbons, low viscous EC: 918-167-1 50,00 - <100,00% 01-2119472146-39
Glycol derivative EINECS: 203-961-6 1,00 - <5,00% 01-2119475104-44
Dipropylene glycol methyl ether, EINECS: 252-104-2 1,00 - <5,00% 01-2119450011-60
mixed isomers
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
PBT: persistent, bioaccumulative and toxic substance.
vPvB: very persistent and very bioaccumulative substance.

Issue Date: 16.02.2015


Revision Date: 16.02.2016 Version: 5.0
Print date:: 16.02.2016
SDS_DE - EN - 000000000600452155 2/13
Product name: Rivolta M.T.X. 60 forte

Classification

Chemical name Identifier Classification


Hydrocarbons, low viscous EC: 918-167-1 CLP: Asp. Tox. 1;H304
Glycol derivative EINECS: 203-961-6 CLP: Eye Irrit. 2;H319
Dipropylene glycol methyl ether, EINECS: 252-104-2 CLP:
mixed isomers
CLP: Regulation No. 1272/2008.

For the wording of the listed risk phrases refer to section 16.

SECTION 4: First aid measures

General: Instantly remove any clothing soiled by the product.

4.1 Description of first aid measures


Inhalation: Supply fresh air; consult doctor in case of symptoms.

Eye contact: Promptly wash eyes with plenty of water while lifting the eye lids.

Skin Contact: Wash with water and soap; pay attention: skin degreasing product.

Ingestion: Call a physician or poison control center immediately. Rinse mouth. Never
give liquid to an unconscious person. If vomiting occurs, keep head low so
that stomach content doesn't get into the lungs. Do NOT induce vomiting.

4.2 Most important symptoms If ingested, material may be aspirated into the lungs and cause chemical
and effects, both acute and pneumonitis. Treat appropriately. Headache.
delayed:

4.3 Indication of any immediate Get medical attention if symptoms occur.


medical attention and
special treatment needed

SECTION 5: Firefighting measures

General Fire Hazards: Use water spray to keep fire-exposed containers cool.

5.1 Extinguishing media


Suitable extinguishing CO2, fire extinguishing powder or fog like water spraying. Extinguish larger
media: fires with alcohol resistant foam or spray water with suitable surfactant
added

Unsuitable extinguishing Water with a full water jet.


media:

5.2 Special hazards arising Can form explosive vapor-air mixtures at higher temperatures.
from the substance or
mixture:

5.3 Advice for firefighters

Issue Date: 16.02.2015


Revision Date: 16.02.2016 Version: 5.0
Print date:: 16.02.2016
SDS_DE - EN - 000000000600452155 3/13
Product name: Rivolta M.T.X. 60 forte

Special fire fighting Move container from fire area if it can be done without risk. Dispose of fire
procedures: debris and contaminated fire fighting water inaccordance with official
regulations. Collect contaminated fire fighting water separately. It must not
enter drains.

Special protective Self-contained breathing apparatus and full protective clothing must be
equipment for fire-fighters: worn in case of fire.

SECTION 6: Accidental release measures

6.1 Personal precautions, In case of spills, beware of slippery floors and surfaces. Keep away from
protective equipment and sources of ignition - No smoking.
emergency procedures:

6.2 Environmental Precautions: Prevent from spreading (e.g. by binding or oil barriers). Avoid release to the
environment. Environmental manager must be informed of all major
spillages. Prevent further leakage or spillage if safe to do so. Do not allow
to enter drainage system, surface or ground water.

6.3 Methods and material for Absorb with liquid-binding material (sand, diatomite, acidbinders, universal
containment and cleaning binders, sawdust). Dispose of the material collected according to
up: regulations. Stop the flow of material, if this is without risk.

6.4 Reference to other See Section 8 of the SDS for Personal Protective Equipment. See Section
sections: 7 for information on safe handling See Section 13 for information on
disposal.

SECTION 7: Handling and storage:

7.1 Precautions for safe Use only in well-ventilated areas. Risk of vapor concentration on the floor
handling: and in low-lying areas. Prevent formation of aerosols. Do not eat, drink or
smoke when working with the product. Take usual precautions when
handling mineral oil products or chemical products. Observe good industrial
hygiene practices. Provide adequate ventilation.

7.2 Conditions for safe storage, Store locked up. Local regulations concerning handling and storage of
including any waterpolluting products have to be followed. The precautions for storing
incompatibilities: and handling of flammable liquids have to be kept. Local regulations for
common storage of flammable liquids have to be followed.

7.3 Specific end use(s): not applicable

Storage Class: 10, Combustible liquids

SECTION 8: Exposure controls/personal protection

8.1 Control Parameters


Occupational Exposure Limits
Chemical name type Exposure Limit Values Source

Issue Date: 16.02.2015


Revision Date: 16.02.2016 Version: 5.0
Print date:: 16.02.2016
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Product name: Rivolta M.T.X. 60 forte

Hydrocarbons, low viscous AGW 600 mg/m3 Germany. DFG MAK List (advisory OELs).
Commission for the Investigation of Health
Hazards of Chemical Compounds in the Work
Area (DFG) (2011)
Glycol derivative - Vapor and AGW 10 ppm 67 mg/m3 Germany. TRGS 900, Limit Values in the
aerosol. Ambient Air at the Workplace (04 2014)
Dipropylene glycol methyl AGW 50 ppm 310 mg/m3 Germany. TRGS 900, Limit Values in the
ether, mixed isomers - Vapor Ambient Air at the Workplace (09 2013)
and aerosol.

8.2 Exposure controls


Appropriate engineering Provide adequate ventilation. Ventilation rates should be matched to
controls: conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below
recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level.

Individual protection measures, such as personal protective equipment

General information: Wash hands before breaks and after work. Use personal protective
equipment as required. Personal protection equipment should be chosen
according to the CEN standards and in discussion with the supplier of the
personal protective equipment. The usual precautionary measures should
be adhered to inhandling the chemicals or the mineral oil products.

Eye/face protection: Safety glasses (EN 166) recommended during refilling.

Skin protection
Hand Protection: Material: Nitrile butyl rubber (NBR). Avoid long-term and repeated skin
contact. Suitable gloves can be recommended by the glove supplier. Use
skin protection cream for preventive skin protection. Protective gloves,
where permitted in acc. to safety directions. The exact break through time
has to be found out by the manufacturer of the protective gloves and has to
be observed.

Other: Do not carry cleaning cloths impregnated with the product in trouser
pockets. Wear suitable protective clothing.

Respiratory Protection: Ensure good ventilation/exhaustion at the workplace. Avoid breathing


vapour/ aerosol.

Thermal hazards: Not known.

Hygiene measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely
wash work clothing to remove contaminants. Discard contaminated
footwear that cannot be cleaned.

Environmental Controls: No data available.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties


Appearance

Issue Date: 16.02.2015


Revision Date: 16.02.2016 Version: 5.0
Print date:: 16.02.2016
SDS_DE - EN - 000000000600452155 5/13
Product name: Rivolta M.T.X. 60 forte

Physical state: liquid


Form: liquid
Color: Colorless
Odor: Slight
Odor Threshold: Not applicable for mixtures
pH: not applicable
Freezing point: Not applicable for mixtures
Boiling Point: > 175 °C
Flash Point: > 60 °C (DIN EN ISO 2719)
Evaporation Rate: Not applicable for mixtures
Flammability (solid, gas): Value not relevant for classification
Flammability Limit - Upper (%)–: Not applicable for mixtures
Flammability Limit - Lower (%)–: Not applicable for mixtures
Vapor pressure: Not applicable for mixtures
Vapor density (air=1): Not applicable for mixtures
Density: 0,76 g/cm3 (15 °C) (DIN 51757)
Solubility(ies)
Solubility in Water: The product is insoluble in water.
Solubility (other): No data available.
Partition coefficient (n-octanol/water): Not applicable for mixtures
Autoignition Temperature: Value not relevant for classification
Decomposition Temperature: Value not relevant for classification
Kinematic viscosity: 1,2 mm2/s (40 °C, DIN 51562)
Explosive properties: Value not relevant for classification
Oxidizing properties: Value not relevant for classification
9.2 Other information
Minimum ignition temperature: 265 °C (DIN 51794)

SECTION 10: Stability and reactivity

10.1 Reactivity: Stable under normal use conditions.

10.2 Chemical Stability: Stable under normal use conditions.

10.3 Possibility of hazardous Stable under normal use conditions.


reactions:

10.4 Conditions to avoid: Stable under normal use conditions.

10.5 Incompatible Materials: Strong oxidizing substances. Strong acids. Strong bases.

10.6 Hazardous Decomposition Thermal decomposition or combustion may liberate carbon oxides and
Products: other toxic gases or vapors.

Issue Date: 16.02.2015


Revision Date: 16.02.2016 Version: 5.0
Print date:: 16.02.2016
SDS_DE - EN - 000000000600452155 6/13
Product name: Rivolta M.T.X. 60 forte

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity

Oral
Product:
Not classified for acute toxicity based on available data.
Specified substance(s)
Hydrocarbons, low No data available.
viscous
Glycol derivative LD 50 (Rat): 3.384 mg/kg
Dipropylene glycol methyl LD 50 (Rat): 5.135 mg/kg
ether, mixed isomers

Dermal
Product:
Not classified for acute toxicity based on available data.

Specified substance(s)
Hydrocarbons, low No data available.
viscous
Glycol derivative LD 50 (Rabbit): 2.700 mg/kg
Dipropylene glycol methyl LD 50 (Rat): 9.500 mg/kg
ether, mixed isomers

Inhalation
Product:
Not classified for acute toxicity based on available data.

Specified substance(s)
Hydrocarbons, low No data available.
viscous
Glycol derivative No data available.
Dipropylene glycol methyl No data available.
ether, mixed isomers

Repeated dose toxicity


Product: No data available.

Specified substance(s)
Hydrocarbons, low No data available.
viscous
Glycol derivative No data available.
Dipropylene glycol methyl No data available.
ether, mixed isomers

Skin Corrosion/Irritation:
Product: No data available.

Issue Date: 16.02.2015


Revision Date: 16.02.2016 Version: 5.0
Print date:: 16.02.2016
SDS_DE - EN - 000000000600452155 7/13
Product name: Rivolta M.T.X. 60 forte

Specified substance(s)
Hydrocarbons, low No data available.
viscous
Glycol derivative No data available.
Dipropylene glycol methyl No data available.
ether, mixed isomers

Serious Eye Damage/Eye Irritation:


Product: No data available.

Specified substance(s)
Hydrocarbons, low No data available.
viscous
Glycol derivative No data available.
Dipropylene glycol methyl No data available.
ether, mixed isomers

Respiratory or Skin Sensitization:


Product: No data available.

Specified substance(s)
Hydrocarbons, low No data available.
viscous
Glycol derivative No data available.
Dipropylene glycol methyl No data available.
ether, mixed isomers

Germ Cell Mutagenicity

In vitro
Product: No data available.

Specified substance(s)
Hydrocarbons, low No data available.
viscous
Glycol derivative No data available.
Dipropylene glycol methyl No data available.
ether, mixed isomers

In vivo
Product: No data available.

Specified substance(s)
Hydrocarbons, low No data available.
viscous
Glycol derivative No data available.
Dipropylene glycol methyl No data available.
ether, mixed isomers

Carcinogenicity
Product: No data available.

Specified substance(s)

Issue Date: 16.02.2015


Revision Date: 16.02.2016 Version: 5.0
Print date:: 16.02.2016
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Product name: Rivolta M.T.X. 60 forte

Hydrocarbons, low No data available.


viscous
Glycol derivative No data available.
Dipropylene glycol methyl No data available.
ether, mixed isomers

Reproductive toxicity
Product: No data available.

Specified substance(s)
Hydrocarbons, low No data available.
viscous
Glycol derivative No data available.
Dipropylene glycol methyl No data available.
ether, mixed isomers

Specific Target Organ Toxicity - Single Exposure


Product: No data available.

Specified substance(s)
Hydrocarbons, low No data available.
viscous
Glycol derivative No data available.
Dipropylene glycol methyl No data available.
ether, mixed isomers

Specific Target Organ Toxicity - Repeated Exposure


Product: No data available.

Specified substance(s)
Hydrocarbons, low No data available.
viscous
Glycol derivative No data available.
Dipropylene glycol methyl No data available.
ether, mixed isomers

Aspiration Hazard
Product: May be fatal if swallowed and enters airways.

Specified substance(s)
Hydrocarbons, low No data available.
viscous
Glycol derivative No data available.
Dipropylene glycol methyl No data available.
ether, mixed isomers

Other Adverse Effects: No data available.

SECTION 12: Ecological information

12.1 Toxicity

Acute toxicity

Issue Date: 16.02.2015


Revision Date: 16.02.2016 Version: 5.0
Print date:: 16.02.2016
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Product name: Rivolta M.T.X. 60 forte

Fish
Product: No data available.

Specified substance(s)
Hydrocarbons, low No data available.
viscous
Glycol derivative LC 50 (Fish, 96 h): 1.300 mg/l
Dipropylene glycol methyl LC 50 (Fish, 96 h): > 1.000 mg/l
ether, mixed isomers

Aquatic Invertebrates
Product: No data available.

Specified substance(s)
Hydrocarbons, low No data available.
viscous
Glycol derivative EC 50 (Water Flea, 48 h): > 101 mg/l
Dipropylene glycol methyl EC 50 (Water Flea, 48 h): 1.919 mg/l
ether, mixed isomers

Chronic Toxicity

Fish
Product: No data available.

Specified substance(s)
Hydrocarbons, low No data available.
viscous
Glycol derivative No data available.
Dipropylene glycol methyl No data available.
ether, mixed isomers

Aquatic Invertebrates
Product: No data available.

Specified substance(s)
Hydrocarbons, low No data available.
viscous
Glycol derivative No data available.
Dipropylene glycol methyl No data available.
ether, mixed isomers

Toxicity to Aquatic Plants


Product: No data available.

Specified substance(s)
Hydrocarbons, low No data available.
viscous
Glycol derivative EC 50 (Alga, 96 h): > 101 mg/l
Dipropylene glycol methyl No data available.
ether, mixed isomers

12.2 Persistence and Degradability

Issue Date: 16.02.2015


Revision Date: 16.02.2016 Version: 5.0
Print date:: 16.02.2016
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Product name: Rivolta M.T.X. 60 forte

Biodegradation
Product: No data available.

Specified substance(s)
Hydrocarbons, low No data available.
viscous
Glycol derivative No data available.
Dipropylene glycol methyl 75 % (28 d, OECD 301F) Readily biodegradable
ether, mixed isomers

12.3 Bioaccumulative Potential


Product: No data available.

Specified substance(s)
Hydrocarbons, low No data available.
viscous
Glycol derivative No data available.
Dipropylene glycol methyl No data available.
ether, mixed isomers

12.4 Mobility in Soil: No data available.

Known or predicted distribution to environmental compartments


Hydrocarbons, low viscous No data available.
Glycol derivative No data available.
Dipropylene glycol methyl No data available.
ether, mixed isomers

12.5 Results of PBT and vPvB The product does not contain any substances fulfilling the PBT/vPvB criteria.
assessment:

12.6 Other Adverse Effects: No data available.

Water Hazard Class WGK 1: slightly water-endangering.


(WGK):

SECTION 13: Disposal considerations

13.1 Waste treatment methods

General information: Dispose in accordance with all applicable regulations.

Disposal methods: Discharge, treatment, or disposal may be subject to national, state, or local
laws.

European Waste Codes


14 06 03*: other solvents and solvent mixtures

Issue Date: 16.02.2015


Revision Date: 16.02.2016 Version: 5.0
Print date:: 16.02.2016
SDS_DE - EN - 000000000600452155 11/13
Product name: Rivolta M.T.X. 60 forte

SECTION 14: Transport information

ADR/RID
14.1 UN Number: –
14.2 UN Proper Shipping Name: –
14.3 Transport Hazard Class(es)
Class: Non-dangerous goods
Label(s): –
Hazard No. (ADR): –
Tunnel restriction code: –
14.4 Packing Group: –
14.5 Environmental hazards: –
14.6 Special precautions for user: –

IMDG
14.1 UN Number: –
14.2 UN Proper Shipping Name: –
14.3 Transport Hazard Class(es)
Class: Non-dangerous goods
Label(s): –
EmS No.: –
14.3 Packing Group: –
14.5 Environmental hazards: –
14.6 Special precautions for user: –

IATA
14.1 UN Number: –
14.2 Proper Shipping Name: –
14.3 Transport Hazard Class(es):
Class: Non-dangerous goods
Label(s): –
14.4 Packing Group: –
14.5 Environmental hazards: –
14.6 Special precautions for user: –

14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: not applicable.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:

EU Regulations

Regulation (EC) No. 2037/2000 Substances that deplete the ozone layer: none

Regulation (EC) No. 850/2004 on persistent organic pollutants: none

National Regulations

Water Hazard Class WGK 1: slightly water-endangering.


(WGK):

Issue Date: 16.02.2015


Revision Date: 16.02.2016 Version: 5.0
Print date:: 16.02.2016
SDS_DE - EN - 000000000600452155 12/13
Product name: Rivolta M.T.X. 60 forte

15.2 Chemical safety No Chemical Safety Assessment has been carried out.
assessment:

SECTION 16: Other information

Revision Information: Vertical lines in the margin indicate an amendment.

Wording of the H-statements in section 2 and 3


H304 May be fatal if swallowed and enters airways.
H319 Causes serious eye irritation.

Other information: The classification is in line with current EC lists. It is expanded, however, by
information from technical literature and by information furnished by supplier
companies. The classification results from the Conventional Method
mentioned in regulation EU 1272/2008 (CLP).

Revision Date: 16.02.2016


Disclaimer: The data contained in this safety data sheet are based on our current
knowledge and experience and are given to the best of our knowledge and
belief. It characterizes the product only with regard to safety requirements for
handling, transport and disposal. The data do not describe the product's
properties (tech. product specification). Neither should any agreed property
nor the suitability of the product for any specific technical application be
deduced from the data contained in this safety data sheet. Modifications on
this document are not allowed. The data are not transferable to other
products. In the case of mixing the product with other products or in the case
of processing, the data in this safety data sheet are not necessarily valid for
the new-made material. It is the responsibility of the recipient of the product to
observe federal, state and local law. Please contact us to obtain up-to-date
safety data sheets. This document was issued electronically and has no
signature.

Issue Date: 16.02.2015


Revision Date: 16.02.2016 Version: 5.0
Print date:: 16.02.2016
SDS_DE - EN - 000000000600452155 13/13

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