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Analytical Chemistry MCQ's

This document contains 28 questions about analytical chemistry concepts like precipitation, solubility of compounds, color of metal salts and metal hydroxides, reactions between reagents and compounds. Some key points covered are: - Zinc hydroxide is amphoteric and soluble in excess sodium hydroxide solution. - Ferric salts are brown in color while ferrous salts turn reddish-brown on oxidation. - Ammonium hydroxide forms a deep blue solution with copper sulfate. - Calcium hydroxide is the least soluble of the common alkali hydroxides.

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0% found this document useful (0 votes)
53 views14 pages

Analytical Chemistry MCQ's

This document contains 28 questions about analytical chemistry concepts like precipitation, solubility of compounds, color of metal salts and metal hydroxides, reactions between reagents and compounds. Some key points covered are: - Zinc hydroxide is amphoteric and soluble in excess sodium hydroxide solution. - Ferric salts are brown in color while ferrous salts turn reddish-brown on oxidation. - Ammonium hydroxide forms a deep blue solution with copper sulfate. - Calcium hydroxide is the least soluble of the common alkali hydroxides.

Uploaded by

Pdk
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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4 ANALYTICAL CHEMISTRY - UsE OF AMMONIUM

HYDROXIDE AND SODIUM HYDROXIDE

1. The process of formation of a solid substance by mixing the


solutions of substances.
(a) Condensation (b) Precipitation
() Sublimation (d) Distillation
Ans. (b) Precipitation
2. Which of the following alkali metal hydroxides is the least
soluble in water?
(a) CsOH (b) KOH
()NaOH d) LiOH
Ans. (d) iOH
3. Colour of ferric salts
(a) Red (b) Reddish-Brown
(c) Brown (d) Orange
Ans. (c) Brown
4. Dirty green precipitates are formed by
(a) Ferric Chloride (b) Ferrous Sulphate
(c) Ammonium Sulphate (d) Magnesium Sulphate
Ans. (b) Ferrous Sulphate
5. Soluble complex formed when zine reacts with sodium hydroxide
(a) Zinc Oxide (ZnO) (b) Zine Hydroxide (Zn|OH|,)
() Sodium Zincate Na,Zn0,I (d) No reaction
Ans. (c) Sodium Zincate
[Na ZnO]
6. A non-metal whieh evolves hydrogen when treated with hot
and conc. caustic soda
(a) Silicion |Si (b) Nitrogen |N]
(c) Carbon |C] (d) Fluorine |F|
Ans. (a) Silicon [Si]
7. A substance which reacts with another substance
(a) Produet (b) Reagent
(C) Catalyst (d) Inhibitor
Ans. (b) Reagent
8. Reagent which forms deep blue solution with copper sulphate
(a) Copper Sulphate (CuSo,)
(b) Calcite (CaCO,)
(c) Ammonia (NH,)
(d) Ammonium Hydroxide |NH,OH|
Ans. (d) Ammonium Hydroxide [NH,OH]]
9. A metal whose salts do not produce any precipitates with sodium
hydroxide
(a) Seandium (Sc) (b) Zine (Zn)
(c) Calcium (Ca) (d) Bariunm (Ba)
Ans. (b) Zinc (Zn)
10. Colour of potassium permanganate
(a) Pink (b) Green
(c) Purple (d) Brown
Ans. (c) Purple
11. Sodium and potassium salts are . in colour

(a) Red (b) Brown


(c) Blue (d) Colourless
Ans. (d) colourless
12. Ferrous salts on oxidation form. Salts.
(a) Ferrous (b) Ferrie
(c) Ferrate (d) Oxide
Ans. (b) Ferric
13. Potassium permanganate is in colour.
(a) Green (b) Brown
(c) Purple (d) Pink
Ans. (c) Purple
14. react with metal cations to produce coloured insoluble
hydroxides.
(a) Halogens (b) Alkalies
(c) Alkaline Metals (d) Transition Metals
Ans. (b) Alkalies
15. . is the least soluble of the common alkalies.
(a) Magnesium Hydroxide
(b) Lithium Hydroxide
() Potassium Hydroxide
(d) Calcium Hydroxide
Ans. (d) Calcium Hydroxide
16. Lead hydroxide is soluble in but insoluble in
..
(a) HCL, H,So, (b) H,sO NaOH
() NaOH, NH,OH (d) NH,OH, HCI
Ans. (c) NaOH, NH,OH
17. Pale blue precipitates are formed by
(a) FelOHI, (b) CulOHI,
(c)Zn[OH, (d) AlOH,
Ans. (b) Cu[OH],
18. Zine hydroxide forms gelatinous . ppts.
(a) white soluble (b) yellow insoluble
(c) red soluble (d) white insoluble
Ans. (a) white soluble
19. Dirty green precipitates are formed by . Salts.
(a) Copper (b) Zine

(C) Magnesium (d) Mercury


Ans. (b) Zine
20. Dilute sulphuric acid will produce a white precipitate when
added to a solution of
(a) Copper nitrate (b) Zine nitrate
()Lead nitrate (d) Sodium nitrate
Ans. (c) Lead nitrate
21. The salt which in solution gives a pale green precipitate with
sodium hydroxide solution and a white precipitate with barium
chloride solution is
(a) Iron (1) Sulphate (b) Iron (11) Sulphate
(c) Iron ( ) Chloride (d) Iron (11) Chloride
Ans. (b) Iron (11) Sulphate
22. Hydroxide of this metal is soluble in sodium hydroxide solution.

(a) Magnesium (b) Lead


(c) Silver (d) Copper
Ans. (B)Lead
23. Whieh of the following analysis deals with the identification of
unknown substance?
(a) Qualitative analysis (b) Quantitative analysis
() Both (a) and (b) (d) None of the above
Ans. (a) Qualitative analysis
24. A chloride which forms a precipitate that is soluble in excess
of ammonium hydroxide, is

(a) calcium chloride (b) ferrous chloride


() ferrie echloride (d) copper chloride
Ans. (d) copper chloride
25. Hydroxide of this metal is soluble in sodium hydroxide solution.
(a) Magnesium (b) Lead
(c) Silver (d) Copper
Ans. (b) Lead
26. The salt which gives a dirty green precipitate with sodium
hydroxide solution is |2008
(a) iron (II) sulphate (b) iron (11) sulphate
() iron ( ) chloride (d) iron (111) chloride

Ans. (b) iron (11) sulphate


27. Which of the following hydroxides possesses pale blue colour?
(a) Lead hydroxide (b) Copper bydroxide
(c) Zinc hydroxide (d) Ferrous hydroxide
Ans. (b) Copper hydroxide
28. The salt solution which does not react with ammonium hydroxide
is 2018
(a) calcium nitrate (b) zinc nitrate

() lead nitrate (d) copper nitrate

Ans. (a) calcium nitrate


15. A metal which is amphoteric in nature.

(a) Manganese (b) Copper


(c) Sodium (d) Zinc

Ans. (d) Zinc


16. A yellow monoxide that dissolves in hot and concentrated alkali.
(b) CuO
(a) ZnO
(c) PbO (d) AgO
Ans. (c) Pbo

17. An amphoterie hydroxide having gelatinous white ppt.


(a) Zinc hydroxide (b) Sodium hydroxide
(c) Copper (11) hydroxide (d) None of these
Ans. (a) Zinc hydroxide
18. The metal oxide which can react with acid as well as alkali is
(a) silver oxide (b) copper (11) oxide
(c) aluminium oxide (d) caleium oxide

Ans. (c) aluminium oxide

HorS
1. A metal hydroxide which is unsoluble in caustic but soluble in
excess of NH,OH is

(a) Cu(OH)2 (b) Zn(OH)


(e) co(O); (d) None of these
Ans. (a) Cu(OH)>
Cu(OH) is insoluble in excess of NaOH but soluble in excess of
ammonium hydroxide and gives deep blue or prussian blue solution.
The reaction is as folow
Cu(OH) +(NH),),SO, + 2NH,OH u(NH3),1S04+4H,0
Excess
2. A metal M shows different colour in differently combined state

as listed in the table below

Metal Compound Colour


K,MO4 Yellow

K,M,0, Orange
Identify the metal
(b) Mn
(a) Fe
(c) Cr (d) Ni

Ans. (c) Cr
As, per the colours given in the table, the metal "M' is Cr.

K,CrO4 Potassium chromate


KgCr,07 Potassium dichromate
3. Zn metal shows amphoteric behaviour. It can be shown by

(a) its reaction with dil. NaOH only


(b) its reaction with dil. HCI only
(c) its reaction with both dil. HCl and dil. NaOH

(d) it does not react with either dil. HCI or dil. NaOH
Ans. (c) its reaction with both dil. HCI and dil. NaOH
Zinc (Zn) shows amphoteric behaviour with dil., HCl and dil. NaOH,
as it reacts with both as follows.

) Zn +HCI(dil.) ZnClh+ H2
(i) Zn +2NaOH(dil.) NazZnO, + H2
4. Which of the following hydroxide is soluble in exeess of NaOH?
(a) Cr(OH) (b) Ca(OH)
() Zn(OH (d) FefOH)
Ans. (c) n(OH)2
When Zn(OH), is added in excess of NaOH solution, it dissolved in
that due to formation of soluble zincate ions.

Zn(OH) + 2NaOH(ag) >NayZnO + 2H,0


Sodium zincate

(soluble sal)
Zn{OH), is amphoteric, so it reacts as an acid with the base to give
a soluble complex.
5. A colourless gas having pungent irritating odour gives dense
while fumes with cone. HCl and turns Nessler's reagent brown.
The colourless gas is

(a) (b) NH
(c) NH,CI (d) Ch
Ans. (b) NH3
Nessler's reagent is prepared by combining potassium iodide and
mercuric chloride. It is used to test presence of NH3 or NH4" ions.

NH2
2KHgltNH,CI+4KOH>Hg
Hg 0+7K1 +KCI +
3H20

(iodide of millon base)


Also, NH3 when react with HCl (conc), it gives white fumes of

NH,CL
NH3(g) +HCI NH,CI
It has irritating odour also.
Hence, the given gas is NH3.
6. You are provided with two test-tubes, A and B. In A, when NaOH
was added white ppt. is formed. B whieh is yellow in colour,
when NaOH was added, a colourless solution is formed. A and
B are respectively

(a) FesO and Al,O (b) Ca(NO3)2 and


Pb(N0,)
(e) CuSO and ZnO (d) ZnSO, and Zno
Ans. (b) Ca(NO3)> and Pb(NO3)2
A NaOH white ppt

B+NaOH gives colourless solution


(Yellow)
Thus, (6) (A) is Ca(NO3),. because it gives white ppt. of Ca(OH)2
and NaNOD3

Ca(NO3) +2NaOH Ca(OH)2 +2NaNOg


White ppt.

i) (B) is Pb(NO,)2 + 2NaOH Pb(OH)+ 2NaNO


(B) (gives colourless solution on shaking)

Hence, option (b) is the correct answer


Q.1. Anhydrous iron ( ) chloride is prepared by: Explanation Amphoteric oxides and react
(A) Direct combination (8) Simple displacement hydroxides are those ompounw
with both acids and alkalis to torm salt and
(9 Decomposition (D) Neutralization
Ans. Option (A) is correct.
water

which anhydrous
1 n e cokur of sodium zincate
(Na, ZnO.) is:
Explanationm: The process by (A) Pale blue Ppt (B) Reddish brown ppt
m chloride is produced is a simple direct
combination. In this process, iron metal s (C) Colourless (D) Dirty green ppt
heated with dry chlorine gas.
Ans. Option ()is correct.
Q.2. Which one forms a white hydroide which dissolves
in an excess ot either aqueous sodiunm hydroxide or Explanation: Action of sodium hydroxide
and lead (action
nnonuunm hydroxide?
(NaOH) with
zinc,
of alkalis on metals):
aluminium
A AP ) Ca
() Cu Zn Zn+2NaOH NazZnO +Ha
fconc
Ans. Option (D) is correct

Explanation When ammonium hydroxide


is added to zinc nitrate solution, a white 2AI+2NaOH+2H,0 2NaAlO; +3H
precipitate is formed. neta-alun ate

.3. 1dentity the missing part in the tollowing chemical (ookura


reacton:
Pb+2NaOH NaaPbO+ 2
2Al +2KOH+2H,0>
A) 2KAIO
KH
B) KAIL(OH)
KAIO,
C)
Ans. Option (A) is correct. Which of the following is correctly matched 7

fio (A)Hydrogen Turns moist lead acetate


num Ca h
sulplhide Paper to silvery black:
(6) Nifrotus micde Turns reddish brown

when it reacts with


Q.4. Which reagent can be used to distinguish a solution
containing a lead salt froun a solution containing a znc
(C)Sulphur 1urns nnhe water hmuky.

(A) Aluminium hydronide dioxide


D) Carbon Turns aciditied potassium
dionide dichromatesolution
rue
(D) Sodium hydroade green.
Ans. Option (A) is correct
Ans. Option (8) s coret

paitho ZAne nitrate

solitiorn to
reacts with
ExplanatiomHydrogen slphide-furts moist
anmoniuni
hydroxicde torm white
Hydrogen urns most lead acetate
suphicde paper to silEy Diack
ead nitrate reacts with ammonium
hydroxide solution to form white (i) Nitrous oxide Turns reddish brown
This white not
precipitate precipitate
dissolve in exCess ammonum hydroside
does
Carbon acidified
.5. 2Zm(OF and AlOH, (11) m dichromate
hydroxides
PbO are.
solution greet.
A))Acidic Bsic
Gv) Sulphur Ttarns ltme water millky
9Amphoteric Alkaline
dioxide
Ans. Option () is correct.
soluble is sodium
Q.8. Hydroxide
hy
of this
solution
metal is
(C) Formation of blue PpPpt.
ormationn ot white
D
A) Magnesium Ans. Option (D) is corect.
Lead
Silver (D) Copper
Ans. Option (B) is correct
Explanation:On addin8 silver nitrate solution
Exylanationm: Pbo + NaOH-Na Pbo,+ H,O
in Calcium chloride, white prepitate ap
whiich is 5oluble in excess of ammont

odit te
hydroxide
that is soluble
. 10, A chlonde wlich forims a
precipitate
ble) um nyraiae 1s
sotution to calciuin chloride ACauhloride
a a n g sver nitrte (B) Ferrous chloride
(A) No change (C) Copper chloride
B) No reaction (D) Ferric chloride
Ans. O p t i o n (C) is correct.

Copper chloride forms a


precipitate that is
soluble in excess of amnonium hydroxide.
Explantion:
Cu" CusO, Cuso,+2NH,OH>Cu(OH), +{NHJSO, Cu(OH), Pale blue Soluble
(Copper Cu(OH),+(NHJSO, + 2NH,OH
sulphate) (Cu(NHJJ sO+otN
(Bue) Tetraammine Deep
copper (0
phate solution

acidifed potassium
1 n gas wen us Exylanution: Limewater is alkaline in nature
(A) CO B) O, contains citric acid which gives it a sour taste.
(9NO (D) H, the correctly matched ions with their
Q.14. Determine
Ans. Option (B) is correct colour
Explanation: When the sulphur dioxide gas is (A) Cr=Green
(8Mg nk
hen it vields chromium sulphate and water. In (C) Zn= White
D) Fe Brown
the
given reaction, the potassium dichromate
15
reduced to the chromium sulphate Le., Irom Ans. Option (D) is corect
+1 to +5 which is responsible tor gving the

8reen colour Explanation


Q.12.On performing the flame test salt P produces a
lilac-coloured arna
tiame ts u 8
e in ammonium hydroxide solution. Pis: Ferrois gnt greenh
(A) ZnCO, or zinc carbonate Yellowbrown
Fermic ion Fe
TOF Potissium chloride Nickel ion N Green
( 9 MgC1, or magnesium chloride
(D) PbNoJ, or kead nitrate Chronin ton
Pink
Ans. Option (B) is correct. ngalnese jonMn"

ation n oh s9.15.Ahydroxide when added with


lead saltshows excess ammonium

t h e white precipitate is must be of silver


(A) Soluble wite caty P
chloride and is dissolved in ammonium
hydroxide
So, the salt is KCL D) Soluble gelatinous ppt.
KCI+ AgNO,KNO, +AgC Ans. Option (B) is correct.
whereas lime juice is n
0.13. Limewater is
ta e Explanation
PbNOJ, +2NH,OH_Pb(OH), + 2NHJNO,
(A) Bitet, Bitter Sour, Sour
(D) Sou, Bitter Lead () Ammonium
(C) Bttter, Sour
hydroxide nitrate
Ans. Option (C) is correct.
Directions : In the
Assertion (A) s
following questions, astatement of Q.5.Assertion
tollowed by a statement ot Keason (
(A) Zinc silphate and Zinc chloricde
solution can be distinguished by adding banum
a t k the cortect cfhoice as:
chloride.
(A) Both (A) and (R) are true, and (R) is the correct Both the salts give white insofuble
Keason (K):
Both (A) and (R) are true,
(B) but (8) s not t e
precipitate.
co Ans. Option (C) is correct.
explanation of tA
gA) is true, but
but
(k) Iss false. Erplanation: By adding burum chloride
(DA)is talse, (R)
true. solution : On adding barium chloride solution
Q.1. Assertion (A): The salts of normal elements ie,
zinc sulphate, white
the elements ot group E and 1s to i7 are getetally preipitate appears
which is insoluble in al the mineral acids
the case of zinc chloride there is no
Reason (R): Salts of transition elements ie, the whereas in
Visible reacton.
eens 0 group
s to 12are
geerally coloured.
Ans. Option (5) is correct.
Q.6. metal
Assertion (A): Hydrogen gas is evolved when
reacts witn
The salts of normal elements
Elanation () reaction is also Knawn as
ie, the elements of group 2 and 13 to 17 Reason This
displacement reaction.
are 8eneraly colourless. Salts ot transition
the of group 3 to 12 are Ans. Option (A) is correct.
elements ie. elements
Beneraly coloured. Explanation: Hydrogen gas is evolved when
Q.2 Assertion (A): Alkalis such
NH.OH are important laboratory reagents
as NaOH, KOH,
a metal reacts with an acid. Thus, assertion is
Reason substance
right
(R):A reagent is a out
that reacts
qualntatve
This känd of reactions also called displacement
w E
sutanoe to
cary reactions. hus, reason is also correct and gives
Correct explanation
Ans. Option (A) is correct.
Q7.Assertion (A): Lead nitrate
Hydrochloric acid
solution when drop into
white
Explanationn Qualitative analysis s carried gives precipitate.
is a Reason (R) : Lead nitrate is a blue colour reagent,
out with the help of reagents.A reagent Ans. Option (C) 1s correct.

Explanation: PtNOJ, +2HC-PbCl, +2HNO,


important laboratory reagents. Thes Ikalis In the above reaction, lead chloride formed is
gve characteristic tests with various metal ions
r o m which these metal ions can be 1dentihed a white precipitate which is insoluble in water
Lead nitrateis not a blue colour reagent instead
.3. Assertion (A): Colour of the precipitate identifies
e specic metal 1on. copper sulphate is a blue colour reagent.
Hence, assertion is correct whereas reaon i a
Reason (R) : Precipitate are soluble substances that
dissolve completely. Wrong statement
Ans. Option ()is correct Q.8. Assertion (A): Dichronmate lon is orange in colour.
Chromate ion is yellow in colour,
ExplanationPrecipitate is anwater
insoluble Reason (R):
Ans. Option (A) 1s cotect.
that not thus
SuDstance do
reason is incorrect
dissolve in
Explanatio
Q.4. Assertion (A) :Ca does not form a precipitate
with ammonitum hydronide.
forms precipitate with sodium
Reason (R) :Ca
hydroxide
Ans. Option (6) is correct.
Chromate ionCroYellow
Q.9. Assertion (A): FeOH), (Ferrous hydroxide or Iron
Exyplanatiom Sodium hydroxide solution (u hydroxide) gives colourless ppt on reaction with
reacts with
when Ca
jon, it forms a white
precipitate of calcium hydroide. Ammonium
small amount of NaOH.

hydroxide don't effectively react with Ca Reason (R): Fe(OH), (Ferric hydroxide on
or Iron (1)
reaction
hydroxide) gives reddish brown ppt
ions due to low concentration of hydronyl witi snall amount ot NaO.
ions. Ans. Option (D) is correct
green Ppt on reaction with

Explanation ofFe(OH)Ferrous
:
NaoH.
hydroxide or Iron (1) hydronide) gives dirty
Snall amount reddish brown ppt on reaction with small anmount

FeOH), (FRerric hydroxide or Iron ( ) hydroxide) gives


of NaOH.
Fel Feso FeSO+2NaOH Fe(OH), Dirty gree Insoluble
Iron (
lron ( ) hydroxide
(OH),J+Na,SO,

sulphate)
(Green Reddish Insoluble
e FeCI,+3NaOH Fe(OH) brown
(Tron (L1) FeOH),+3NaC1 ron () hydroxide)
chloride)
Brown
Q.10. Assertion (A): Oxides of Al, Zn ete are amphoteric Ans.Option (A) is correct.
in nature are those
Amphotenc
owhich shows oxides
oxides the properties of botts
Reason (R): Amphoteric oxides and hydroxides are
those compounds which react witn o a metals and non-metals.
alkalts to form salt ana wat

CASE-BASED MCQs the of pulp and paper, textiles, drinking


water, and
passage and answer
L
Read the following
detergents is added first in a small
known as lye or oxdium hydroude soution
r e (NaoH, also
austic metallic base. An alkal,
fo the
quantity, then in excess aqueous salt solution
of copper (1) sulphate, zinc nitrate, lead nitrate,
Caustic soda is widely used in many inuustnes
calcium chloride and
mostly as a strong chemical base in the manufacture iron ( sulpate
to (V) questions on the basts ot the table given Delow

Nature of precipitate (soluble or


Aqueous salt solution
Colour ot precipiate w msoluble) when NaOH is added in
excess

CoPper () sulphate

Zi
Lead nitrate
Calcum chloride
Iron (11) sulphate
is correct
Q.1. What is the
the
precipitate
colour of on adding Ans.Option (6)
NaOH in copper (1) sulphate ? when
Explanatiom : Calcium chloride (CaCl)
(A) White (B) rale yellow reacts with aqueous NaOH produce calciumm

(C) Pale blue (D) Reddish brown white insoluble


nydroside (Ca(OH)) as

Ans. Option (C) is correct precipitate and Nac


to When sodium hydroxide (NaOH) is added to
Explanation: On adding sodium hydroxide
opper sulphate solution, apale bluepreupitate white soluble
zinc nitrate (Zn[NOJ) gves a

of copper hydroxde 15 tormed which


excess ot sodium hydroxide, Preaplt
msolubie n
Q.2 The nature of Calcium chloride and Zinc nitrate on Q.3. Name the compound X which givesreddustrow
eachon w t n excess ot NaOH? r Wnen NaOt isadded in small quantity

(A) Soluble, nsoluble (8) Insoluble, Soluble (8) Lead nitrate


(A) Iron (11) sulphate
Both soluble (D) Bothi are insoluble
(C) are
(D) Zinc nitrate
(C) Copper chloride
Ans. Option (A) is correct. () Transition elements
D ner transition elements
Explanatio: Fe with
NaOH gves reddsn
Ans. Option (C) is correct.
orw p r p t a t e ot e o n
Ealanation The sats of normal elements
Q.4.Identity the correct formula of Lead Nitrate. Le, the elements of group 1, 2 and 13 to 17

A) PbO are generaly colouress. Salts ot transition


PBNO
the ot group 3 to 12 are
PbNO, PbNO elements Le, eiements
Ans. Option (D) is correct. Q.4. Which salt is white in colour in its natural form ?
Q.5. Caustic soda is used in (A) MgsSo (B) uSC
(A) Manufacture of pulp and paper (C)FesO (D) FeC1,
Ans. Option (A) is correct.
Textiles
(C) Detergents Exyplamation
Mgso,-White
: MgsO
[D) All of these

Ans. Option (D) is correct.


CusO-B
FesO-Green
Explanation: Caustic soda (sodium hydroxide) eC Brown
sa versiatile alkalt. Its uses are Q.5. The process of tormation of an insoluble solid
substance in water by mixing which is called ?
manufacture of pulp and paper
(A) Analysis
alumina, soap nd deterge
8) recipitation
petroleum products and chemical (D) Decomposition
I1. Read the passage and answer the following Ans.Opon (6) 1s correct

questions:
Analytical chemistry is the branch of chemistry Eplation Preipitation reaction those
produced during a chemical reaction
wchdeals with eperimental study by
qualitative and quantitative mieans, It includes the
Insoluble substance is called precipitate which
identificathon of unknown salt solition by chemmca
do not dissolve in wate
tests. Use of sodium and ammonitum
hydrndes o
salt solution is involved in the chemical tests and
I1 Read the passage and answer the
tollowing
study of observation of the colour and solubility of questions:
1ne Latn hame tor iron 1 terrum. 1heretore, the
ferne ana terrouss nocate tne preEnee o
Q. 1.Oxides and hydroides of which metal is anmphoterc
in nature. n o u s endings
(A) ine (B) ron compound. Ferric means the iron ato h
hree electrons to form F e , and ferrous means
(C) opper (D) Lead
the iron atom nas ost w o electrons to rorm r
Ans. option (A) is corect

Fvml Oern nomencture uses Roman numerals after it


p odes and has aalte wnat charge
with both acids and alkalis to form salt and Forexample, ferric would be FeII) indicating Fe
water. n d terrus wotuld De
etu acating te
deals with the
identification of unknown Ferrousion
sDstances in a gven sample Dy chemcal tests FesO,+2NH,OH Fe(OH), 4+ (NHJSO,
Ferric ion
wneres deals with the determination of
composition ot a nikture
Q.1. Colour of fo
6NH,OH 2Fe(OH), 4 3(NHJSO, +

(A) Quantitative, qualitative


(B) Qualitative, quantitative
A) Blue B) Green
(C Both qualitative analysis Pink (D) Light green
Both quantitative analysis AnsOption ( is correct
0.2.A
Ans. Option (5) is corect. silt which in solutio gves a
blushawute
white
precipitate with Nao otion a
PpitdteE wil ba,>0ution s :
Eanatio: Qualitative, quantitative
0.3. Name the elenments of group 3 to 12 which are csE Specimen Paper, 20171
generally coloured: CUFe.S
(A) Normal elements
Ans. Option (A) is correct.
(B) Representative elements
Explanation: Copper sulphate gives bluish A) Soluble (B) Insoluble
white precipitate of cupric hydroxide with
NaOH and white precipitate with barium
(C)Colourles Substance (D) None of these
Ans. Option (8) is correct.
chloride
Q.3. FeCl,+3NaOH +3NaCI Explanation: Fe(OH), Iron () hydroxide will
Identify the missing compound : reddish brown
(A) Fe(OH), (B) FeO
produce
insoluble
which is
precipitate
(C)FeOH (D) Fe(OH) Q.5. Which of the following is the property of a
Ans. Option (A) is correct. precipitate formed during a chemical reaction ?
Explanation: (A) Soluble in water
FeCL,+2NaOHFe(OH),+2NaCI (B) Always colourful
Fe(OH), precipitates are dirty green gelatinous (C)Evolved out of test-tube
in nature.
(D) Insoluble in water
FeC1,+3NaOH FefOH), + 3NaCI
Ans, Option (D)is correct.
FeOH),
colour
precipitates are reddish brown in
Explanation: Precipitation is the process of
Q.4.FeC1,+3NH OHFe(OH),J+3NH CI formation of an insoluble solid substance in
In the above reaction, what is the nature of
water by
mixing which is called precipitate
precipitate Fe(OHI), ? Hence precipitate is always insoluble in water.

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