Electrodeppt
Electrodeppt
instrumentation
• The skin and other tissues of higher-order organisms, such as humans, are
electrolytic and so can be modeled as an Electrolytic Solution.
• Imagine a metallic electrode immersed in an electrolytic solution.
• Immediately after immersion, the electrode will begin to discharge some
metallic ions into the solution, while some of the ions in the solution start
combining with the metallic electrodes.
• A gradient charge build up, creating a potential difference, or electrode potential
and half cell potential.
Cont..
• This region is called the electrode double layer and its ionic
differences are the source of the electrode or half-cell potential.
Half Cell Potential
Polarizable and Non-Polarizable
Electrode
I. Perfectly Polarizable Electrodes
– Perfectly polarizable electrodes are those in which no actual charge crosses the electrode–
– Of course, there has to be current across the interface and the electrode behaves as though it were
a capacitor
II. Perfectly Polarizable Electrodes or Perfectly Reversible
– Perfectly non-polarizable electrodes are those in which current passes freely across the electrode–
• Microelectrodes are electrodes with tips having tips sufficiently small enough to penetrate a
• The tips must be small enough to permit penetration without damaging the minute cell.
injection.
• Microelectrodes are having high impedances in mega ohn range because of their
smaller size.
Types
Metal microelectrode Micropipette