Hexane

Revision : 04
Safety Data Sheet Effective Date : Januari 2017

I. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name : Hexane
Use : Hexane is used as a solvent in the extraction of vegetable oils from cotttonseed,
peanuts, copra, and other vegetable materials. It is also used in rubber cements as it
is virtually free of aromatics. It is also used as a selective and efficient diluent
during the polymerisation process in the manufacture of polyethylene and other
polymers and resins.They are also common constituents of gasoline and glues used
for shoes, leather products, and roofing. Additionally, it is used as a cleansing
agent for shoe, furniture and textile manufacturing.
Supplier : PT. Mulya Adhi Paramita
Supplier's Address : Kapuk Kamal No. 19
Jakarta 14470, Indonesia
Emergency Telephone Number : + 6221-5551314 (24 hours), emergency transportation

II. HAZARDS IDENTIFICATION

GHS Classification : Flammable liquids : category 2
Skin corrosion/irritation : category 2
Reproductive toxicity : category 2
Specific target organ toxicity, single exposure, narcotic effects : category 3
Specific target organ toxicity, repeated exposure : category 2
Aspiration hazard : category 1
Hazardous to the aquatic environment,acute toxicity
Hazardous to the aquatic environment,chronic toxicity : category 2
GHS label elements
Symbol(s) :

Signal words : Danger

GHS Hazard statements : Physical Hazards
H225 Highly flammable liquid and vapour
Health Hazards
H315 Causes skin irritation
H361 Suspected of damaging fertility or the unborn child
H336 May cause drowsiness and dizziness
H373 May cause damage to organs (peripheral nervous system) through prolonged or
repeated exposure.

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 Hexane
Revision : 04
Safety Data Sheet Effective Date : Januari 2017

H304 May be fatal if swallowed and enter airways

Environmental Hazards
H411 Toxic to aquatic life with long lasting effects
GHS Precautionary statements : Prevention
P201 Obtain special instruction before use
P202 Do not handle untill all safety precautions have been read and understood
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P261 Avoid breathing dust/fume/gas/mist/spray/vapour.
P264 Wash hands thoroughly after handling.
P271 Use only outdoors or in a well ventilated area.
P260 Do not breathe dust/fume/gas/mist/vapor/spray
P273 Avoid release to the environment
P281 Use personal protective equipment as required
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P308+P313 If exposed or concerned : get medical advice/attention
P301+P310 If swallowed : immediately call a poison center or doctor/physician.
P302+P352 If on skin : Wash with plenty of soap and water.
P303+P361+ If on skin : Remove/take off immediately all contaminated clothing. Rinse skin
P353 with water/shower.
P304+P340 If inhaled : Remove to fresh air and keep at rest in a position comfortable for
breathing.
P312 Call a poison center or doctor / physician if yu feel unweel.
P314 Get medical advice/ attention if you feel unweel.
P331 Do not induce vomiting.
P332+P313 If skin irritatio occurs : get medical advice/attention
P362 Take off contaminated clothing and wash before reuse.
P370+ P378 In case of fire: Use water spray, alcohol-resistant foam, dry chemical or carbon
dioxide to extinguish.
P391 Collect spillage.
Storage
P235 Keep cool
P405 Store locked up.
Disposal
P501 Dispose of contents and container to appropriate waste site or reclaimer in
accordance with local and national regulations.

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 Hexane
Revision : 04
Safety Data Sheet Effective Date : Januari 2017

III. COMPOSITION / INFORMATION ON INGREDIENTS

Identification of the substance : n-Hexane
Chemical Family : Alifatic hydrocarbon
Synonyms : Hexane
Molecular Formula : C6H14
CAS Number : 110-54-3
UN Number : 1208
EC Number : 203-777-6

IV. FIRST AID MEASURES

General Advice : When symptoms persist or in all cases of doubt seek medical advice.
Inhalation : Remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. If rapid recovery does not occur, transport to medical facility
for additional treatment.
Skin Contact : Remove contaminated clothing. Flush exposed area with water and follow by
washing with soap if available.
Eye Contact : Flush eyes with large amounts of water for at least 15 minutes, occasionally open
upper and lower eyelids. If irritation persist get medical attention.
Ingestion : Do not induce vomiting, transport to neasrest medical facility for additional
treatment. If vomiting occurs spontaneously, keep head below hips to prevent
aspiration.

V. FIRE - FIGHTING MEASURES

o
Flash Point : - 22 C
Auto-ignition Temperature : 225 oC
Explosive Limits : 1.2 - 7.5 %vol
Extinguishing Media : Carbon dioxide, dry extinguishing media, water spray, alcohol resistant foam.
Unsuitable extinguishing media : Water in a jet
Fire Fighting Procedures : Evacuate area. If a leak or spill spill has not ignited, use water spray to disperse the
vapours and to protect personnel attempting to stop a leak. Prevent run-off from
fire control or dilution from entering streams, sewers or drinking water supply. Use
water spray to cool fire-exposed surfaces and to protect personnel.
Special Protective Equipment for Fire- : Wear self-contained breathing apparatus with full face mask and protective
Fighter clothing.

VI. ACCIDENTAL RELEASE MEASURES

Personal Precautions : Avoid contact with spilled material. Warn or evacuate occupants in surrounding
and downwind areas if required, due to toxicity or flammability of the material.
Shut off leak, if possible to do so without risk. Remove all possible sources of
ignition in thePage
surrounding
3 of 7 area. Attempt to disperse the vapour or to direct its flow
to a safe location for example by using fog spary. Take precautionary measures
against static discharge. Ensure electrical continuity by bonding and grounding
(earthing) all equipments.
 Hexane
Revision : 04
Safety Data Sheet Effective Date : Januari 2017

Avoid contact with spilled material. Warn or evacuate occupants in surrounding

and downwind areas if required, due to toxicity or flammability of the material.
Shut off leak, if possible to do so without risk. Remove all possible sources of
ignition in the surrounding area. Attempt to disperse the vapour or to direct its flow
to a safe location for example by using fog spary. Take precautionary measures
against static discharge. Ensure electrical continuity by bonding and grounding
(earthing) all equipments.
Environment Precautions : Use appropriate containment (of product and fire fighting water) to avoid
environmental contamination. Prevent from spreading or entering drains, ditches, or
rivers by using sand, earth, or other appropriate barriers.
Methods for Cleaning Up : For Small Spill
Transfer by mechanical means to a labelled, sealable container for product
recovery or safe disposal. Allow residues to evaporate or soak up with an
appropriate absorbent material and dispose of safely. Remove contaminated soil
and dispose of safely.
For Large Spill
Transfer by mechanical means such as vacuum truck to a salvage tank for recovery
or safe disposal. Do not flush away residues with water. Retain as contaminated
waste. Allow residues to evaporate or soak up with an appropriate absorbent
material and dispose of safely. Remove contaminated soil and dispose of safely.

VII. HANDLING AND STORAGE

Handling : Avoid contact with skin, eyes and clothing. Do not breathe vapours or spray mist.
Handle with care. Use only in well-ventilated area. Extinguish any naked flames.
Do not smoke. Remove ignition sources. Avoid sparks. Electrostatic charges may
be generated during pumping. Electrostatic discharges may cause fire. Ensure
electrical continuity by bonding and grounding (earthing) all equipment. Avoid
splash filling. Do not use compressed air for filling, discharging or handling.
Storage : Must be stored in a diked (bunded) well-ventilated area, away from sunlight,
ignition sources and other sources of heat. Bulk storage tanks shoul be diked
(bunded). Keep away from aerosols, flammables, oxidizing agents, and corrosives
materials. Storage temperature : ambient.

VIII. EXPOSURE CONTROL / PERSONAL PROTECTION

Exposure standards : American Conference of Governmental Industrial Hygienists (ACGIH)
n-Hexane : TWA - 50 ppm
The time weighted average concentration for a normal 8-hour workday and a 40-
hour workweek, to which nearly all workers may be repeatedly exposed, day after
day, without adverse effect.

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 Hexane
Revision : 04
Safety Data Sheet Effective Date : Januari 2017

Respiratory Protection : If engineering control do not maintain airborne contaminant concentrations at a

level which is adequate to protect worker health, an approved respirator may be
appropriate. Types of respirators to be considered for this material include : half-
face respirator type A filter material. For high airborne concentrations, use an
approved supplied-air respirator, operated in positive pressure mode. Supplied air
respirators with an escape bottle may be appropriate when oxygen level are
inadequate.
Skin and Body Protection : Wear protective clothing which is chemical resistant to this material. Safety shoes
and boots should also be chemical resistant.
Eye Protection : If contact is likely, safety glasses with side shields are recommended.
Hand Protection : Wear appropriate chemical resistant gloves to prevent skin exposure.

IX. PHYSICAL AND CHEMICAL PROPERTIES

Form : Liquid
Colour : Colourless
Odour : Mild petroleum odor
Boiling Point Range : 64 - 70 oC
Melting Point : - 95 oC
Flash Point : - 22 oC
o
Auto-ignition Temperature : 225 C
Explosive Limits : 1.2 - 7.5 %vol
Vapour Pressure : 128 mmHg @ 21oC
Vapour Denstiy ( relative to air ) : 2.99
o
Specific Gravity : 0.660 - 0.686 (15.56 C)
Evaporation Rate : 8.4 ( BuAc = 1 )
o
Water Solubility (@ 25 C) : 9.5 x 10-4 %wt

X. STABILITY AND REACTIVITY

Stability : Stabil under ordinary conditions of use and storage.
Conditions to avoid : Heat, flame, ignition sources and incompatible materials.
Incompatible Materials : Strong oxidizing agents
Hazardous Polymerization : Will not occur
Hazardous Decomposition Products : Thermal decomposition is highly dependent on conditions. A complex mixture of
airborne solids, liquid and gases, including carbon monoxide, carbon dioxide and
other organic compounds will be evolved when this material undergoes combustion
or thermal or oxidative degradation.

XI. TOXICOLOGICAL INFORMATION

Acute Toxicity
Acute Oral Toxicity : Low toxicity : LD50 rat : >2000 mg/kg

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 Hexane
Revision : 04
Safety Data Sheet Effective Date : Januari 2017

Acute Inhalation Toxicity : low toxicity : LC50 rat : >20 mg/l / 4 hours
Acute Dermal Toxicity : low toxicity : LD50 rabbit >2000 mg/kg
Effects on Human
Inhalation : Vapor concentrations above recommended exposure levels may be irritating to the
eyes and the respiratory tract, may cause headaches and dizziness, could be
anesthetic and may have other central nervous system effects. May cause
peripheral nervous system disorder and/or damage.
Eye : Will cause eye discomfort, but will not injure eye tissue.
Skin : Frequent or prolonged contact may defat and dry the skin, leading to discomfort
and dermatitis.
Ingestion : Small amounts of liquid aspirated into the respiratory system during ingestion or
from vomiting may cause bronchopneumonia or pulmonary edema.
Chronic Exposure : Overexposure to n-hexane may cause progressive and potentially irreversible
damage to the peripheral nervous system, particularly in the arms and legs.

XII. ECOLOGICAL INFORMATION

Persistence and Degradability : Product is readily biodegradable
Ecotoxicity : Toxicity to fish: Toxic : 1 < LC/EC/IC50 <= 10 mg/l
Toxicity to algae : Toxic : 1 < LC/EC/IC50 <= 10 mg/l
Toxicity to aquatic invertebrates : Toxic : 1 < LC/EC/IC50 <= 10 mg/l
Toxicity to bacteria : EC50 (15 min): Toxic : 1 < LC/EC/IC50 <= 10 mg/l
Bioaccumulation : Expected to be toxic to aquatic organisms. Long term adverse effects to aquatic
organisms are possible if continuous exposure is maintained.
Mobility : This product is highly volatile and will rapidly evaporate to the air if released into
the water.

XIII. DISPOSAL CONSIDERATIONS

Substance : This material must be contained and not disposed to sewerage systems, drains or
waterways. Prohibited from disposing of the remaining ingredients into the
environmental media, without prior processing in accordance with Government
Regulation No. 101/ 2014, concerning the Management of Hazardous and Toxic
Waste.
Container : Dispose of all waste containers and used drums in accordance with local authority
guidelines. Empty containers must be decontaminated by rinsing with water. Non-
returnable containers should be de-gassed prior to disposal. Waste containers can
either be reused for the same material or disposed in accordance with Government
Regulation No. 101/ 2014, concerning the Management of Hazardous and Toxic
Waste.

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 Hexane
Revision : 04
Safety Data Sheet Effective Date : Januari 2017

Local Regulation Suitable for incineration by approved agent under controlled conditions if permitted
by local authorities, otherwise disposal must be in accordance with local waste and
environmental authority requirements.

XIV. TRANSPORTATION INFORMATION

Road and Rail Transport : UN number : 1208
Class :3
Packing Group : II
Marine Transport : UN number : 1208
Class :3
Packing Group : II
Air Transport : UN number : 1208
Class :3
Packing Group : II

XV. REGULATORY INFORMATION

The regulatory information is not intended to be comprehensive. Other regulations may apply to this material.
Related Regulations : Government Regulation of The Republic of Indonesia No 74 year 2001,
Concerning the Management of Hazardous and Toxic Materials.
Regulation of the Minister of Industry of the Republic of Indonesia No. 23 /M-IND
/ PER / 4/2013 which is an amendment to the Regulation of the Minister of
Industry of the Republic of Indonesia No. 87 / M-IND / PER / 9/2009, concerning
Global Harmonization System Classification and Labels on Chemicals.
Minister of Labour Decree of The Republic of Indonesia No 187 year 1999
Concerning Managing of Hazardous Chemical in the Workplaces.

XVI. OTHER INFORMATION

Abbreviation : ASTM American Society for Testing and Materials
ACGIH American Conference of Governmental Industrial Hygienists
EC50 Half Maximal Effective Concentration
LC50 Lethal Concentration and Time
LD50 Median Lethal Dose
TWA Time Weighted Averages
Disclaimer
The information contained in this Safety Data Sheet is intended to assist in the use of the above product without risk to safety
or health and is based on current knowledge and experience. This information relates only to the specific material designed
and may not be valid for such material used in combination with any other materials or in any process. It is the user's
responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use.

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