Page 1/9

Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 17.02.2015 Version number 1 Revision: 05.02.2015

SECTION 1: Identification of the substance/mixture and of the company/undertaking

· 1.1 Product identifier
· Trade name: ISOFLEX-PU 500
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the mixture Coating material
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
ISOMAT S.A.
Building Chemicals & Mortars
17th km Thessaloniki-Ag.Athanasios
GR-57003 Ag. Athanasios
Greece
· Further information obtainable from: purchase@isomat.gr
· 1.4 Emergency telephone number: +30 2310 576 000

SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture
· Classification according to Regulation EC No 1272/2008


 GHS02 flame

Flam. Liq. 3 H226 Flammable liquid and vapour.


 GHS08 health hazard

Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.


 GHS07

Skin Irrit. 2 H315 Causes skin irritation.

Eye Irrit. 2 H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
 Xn; Harmful


R20: Harmful by inhalation.

 Xn; Sensitising


R42/43: May cause sensitisation by inhalation and skin contact.

 Xi; Irritant


R36: Irritating to eyes.
R10: Flammable.
· Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
· Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
(Contd. on page 2)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.02.2015 Version number 1 Revision: 05.02.2015

Trade name: ISOFLEX-PU 500

(Contd. of page 1)

· 2.2 Label elements

· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms GHS02, GHS08
· Signal word Danger
· Hazard-determining components of labelling:
polyurethane prepolymer
m-tolylidene diisocyanate
xylene
· Hazard statements
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 May cause an allergic skin reaction.
· Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Additional information:
Contains isocyanates. May produce an allergic reaction.
· 2.3 Other hazards
The product does not contain any organic halogen compounds (AOX), nitrates, heavy metal compounds or
formaldehydes.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

SECTION 3: Composition/information on ingredients

· 3.2 Chemical characterisation: Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
polyurethane prepolymer 25-50%
 Xi R36; 

  Xi R43

 Eye Irrit. 2, H319; Skin Sens. 1, H317

CAS: 1330-20-7 xylene 10-<12.5%
EINECS: 215-535-7  Xn R20/21; 

  Xi R38

Index number: 601-022-00-9 R10
 Flam. Liq. 3, H226; 
  Acute Tox. 4, H312; Acute Tox. 4,
H332; Skin Irrit. 2, H315
(Contd. on page 3)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.02.2015 Version number 1 Revision: 05.02.2015

Trade name: ISOFLEX-PU 500

(Contd. of page 2)
CAS: 123-86-4 n-butyl acetate 1- 2.5%
EINECS: 204-658-1 R10-66-67
Index number: 607-025-00-1  Flam. Liq. 3, H226; 
  STOT SE 3, H336
CAS: 26471-62-5 m-tolylidene diisocyanate 0.1-<0.3%
EINECS: 247-722-4  T+ R26; 

  Xn R40; 
  Xn R42/43; 
  Xi R36/37/38

Index number: 615-006-00-4 R52/53
Carc. Cat. 3
 Acute Tox. 2, H330; 
  Resp. Sens. 1, H334; Carc. 2, H351;
 Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317;

STOT SE 3, H335; Aquatic Chronic 3, H412
CAS: 8052-41-3 Stoddard solvent (0.1% benzene, nota P) 0.1-<0.3%
 Xn R65; 

  N R51/53

 Asp. Tox. 1, H304; 
  Aquatic Chronic 2, H411
· Additional information: For the wording of the listed risk phrases refer to section 16.

SECTION 4: First aid measures

· 4.1 Description of first aid measures
· General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48
hours after the accident.
· After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: If symptoms persist consult doctor.
· 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures

· 5.1 Extinguishing media
· Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· 5.2 Special hazards arising from the substance or mixture No further relevant information available.
· 5.3 Advice for firefighters
· Protective equipment: Mouth respiratory protective device.

SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
· 6.2 Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
(Contd. on page 4)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.02.2015 Version number 1 Revision: 05.02.2015

Trade name: ISOFLEX-PU 500

(Contd. of page 3)
Do not flush with water or aqueous cleansing agents
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7: Handling and storage

· 7.1 Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Keep respiratory protective device available.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep container tightly sealed.
· 7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection

· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
1330-20-7 xylene
WEL Short-term value: 441 mg/m³, 100 ppm
Long-term value: 220 mg/m³, 50 ppm
Sk; BMGV
123-86-4 n-butyl acetate
WEL Short-term value: 966 mg/m³, 200 ppm
Long-term value: 724 mg/m³, 150 ppm
26471-62-5 m-tolylidene diisocyanate
WEL Short-term value: 0.07 mg/m³
Long-term value: 0.02 mg/m³
Sen; as -NCO
· Ingredients with biological limit values:
1330-20-7 xylene
BMGV 650 mmol/mol creatinine
Medium: urine
Sampling time: post shift
Parameter: methyl hippuric acid
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
(Contd. on page 5)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.02.2015 Version number 1 Revision: 05.02.2015

Trade name: ISOFLEX-PU 500

(Contd. of page 4)
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
· Protection of hands:


 Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:


 Tightly sealed goggles

SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Fluid
Colour: According to product specification
· Odour: Characteristic
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: Undetermined.
· Flash point: 24 °C
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature:
Decomposition temperature: Not determined.
(Contd. on page 6)
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Safety data sheet
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Printing date 17.02.2015 Version number 1 Revision: 05.02.2015

Trade name: ISOFLEX-PU 500

(Contd. of page 5)

· Self-igniting: Product is not selfigniting.

· Danger of explosion: Product is not explosive. However, formation of explosive air/vapour
mixtures are possible.
· Explosion limits:
Lower: Not determined.
Upper: Not determined.
· Vapour pressure: Not determined.
· Density at 20 °C: 1.4 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic at 20 °C: 1000 s (ISO 6 mm)
· 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity

· 10.1 Reactivity
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products: No dangerous decomposition products known.

SECTION 11: Toxicological information

· 11.1 Information on toxicological effects
· Acute toxicity:
· LD/LC50 values relevant for classification:
1330-20-7 xylene
Oral LD50 4300 mg/kg (rat)
Dermal LD50 2000 mg/kg (rabbit)
· Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: Irritating effect.
· Sensitisation:
Sensitisation possible through inhalation.
Sensitisation possible through skin contact.
· Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version:
Harmful
(Contd. on page 7)
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Safety data sheet
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Printing date 17.02.2015 Version number 1 Revision: 05.02.2015

Trade name: ISOFLEX-PU 500

(Contd. of page 6)
Irritant

SECTION 12: Ecological information

· 12.1 Toxicity
· Aquatic toxicity: No further relevant information available.
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

· 13.1 Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.

SECTION 14: Transport information

· 14.1 UN-Number
· ADR, ADN, IMDG Void
· IATA UN1993
· 14.2 UN proper shipping name
· ADR, ADN, IMDG Void
· IATA FLAMMABLE LIQUID, N.O.S. (XYLENES, BUTYL
ACETATES)
· 14.3 Transport hazard class(es)
· ADR, ADN, IMDG
· Class Void
· IATA





· Class 3 Flammable liquids.
· Label 3
· 14.4 Packing group
· ADR, IMDG Void
· IATA III
(Contd. on page 8)
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Safety data sheet
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Printing date 17.02.2015 Version number 1 Revision: 05.02.2015

Trade name: ISOFLEX-PU 500

(Contd. of page 7)

· 14.5 Environmental hazards:

· Marine pollutant: No
· 14.6 Special precautions for user Not applicable.
· 14.7 Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
· Transport/Additional information:
· ADR
· Remarks: > 450 l: 3 F1, III
· IMDG
· Remarks: > 30 l: 3, III
· UN "Model Regulation": -

SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms GHS02, GHS08
· Signal word Danger
· Hazard-determining components of labelling:
polyurethane prepolymer
m-tolylidene diisocyanate
xylene
· Hazard statements
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 May cause an allergic skin reaction.
· Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
(Contd. on page 9)
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(Contd. of page 8)
H330 Fatal if inhaled.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
R10 Flammable.
R20/21 Harmful by inhalation and in contact with skin.
R26 Very toxic by inhalation.
R36 Irritating to eyes.
R36/37/38 Irritating to eyes, respiratory system and skin.
R38 Irritating to skin.
R40 Limited evidence of a carcinogenic effect.
R42/43 May cause sensitisation by inhalation and skin contact.
R43 May cause sensitisation by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
· Department issuing MSDS: Product safety department.
· Contact:
Mrs. Demirtzoglou
Mrs. Papageorgiou
· Abbreviations and acronyms:
Flam. Liq. 3: Flammable liquids, Hazard Category 3
Acute Tox. 4: Acute toxicity, Hazard Category 4
Acute Tox. 2: Acute toxicity, Hazard Category 2
Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2
Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2
Resp. Sens. 1: Sensitisation - Respirat., Hazard Category 1
Skin Sens. 1: Sensitisation - Skin, Hazard Category 1
Carc. 2: Carcinogenicity, Hazard Category 2
STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3
Asp. Tox. 1: Aspiration hazard, Hazard Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2
Aquatic Chronic 3: Hazardous to the aquatic environment - Chronic Hazard, Category 3
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