Msdshfa 8030
Msdshfa 8030
Msdshfa 8030
2 Hazards identification
· Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
GHS02 flame
GHS09 environment
Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects.
GHS07
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STOT SE 3 H336 May cause drowsiness or dizziness.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Xn; Harmful
R48/20-63-65: Harmful: danger of serious damage to health by prolonged exposure through inhalation.
Possible risk of harm to the unborn child. Harmful: may cause lung damage if swallowed.
Xi; Irritant
R36/38: Irritating to eyes and skin.
F; Highly flammable
R11: Highly flammable.
R67: Vapours may cause drowsiness and dizziness.
· Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
· Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
· Label elements
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms
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· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
CAS: 108-88-3 toluene 50%
EINECS: 203-625-9 Xn R48/20-63-65; Xi R38; F R11
Reg.nr.: 01-2119471310-51 R67
Repr. Cat. 3
Flam. Liq. 2, H225; Repr. 2, H361d; STOT RE 2, H373; Asp. Tox.
1, H304; Skin Irrit. 2, H315; STOT SE 3, H336
CAS: 128-37-0 2,6-di-tert-butyl-p-cresol 50%
EINECS: 204-881-4 Xi R36/38
Reg.nr.: 01-2119565113-46 Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Irrit. 2, H319
· Additional information: For the wording of the listed risk phrases refer to section 16.
5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture
Carbon monoxide (CO)
Carbon dioxide (CO2)
· Advice for firefighters
· Protective equipment:
(Contd. on page 4)
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Wear impervious clothing and self contained breathing apparatus. Use water to keep fire-exposed containers
cool. If a leak or spill has not ignited use water spray to disperse the vapours and to provide protection for
personnel attempting to stop a leak. Take care not to spread the fire with water. Contain fire-fighting water to
prevent ingress to watercourses as it will cause oil pollution.
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Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:
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Upper: 7.0 Vol %
· Vapour pressure at 20 °C: 29 hPa
· Density at 20 °C: 0.91 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water: Insoluble.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic at 20 °C: 2 mPas
Kinematic: Not determined.
· Other information No further relevant information available.
11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values relevant for classification:
108-88-3 toluene
Oral LD50 5000 mg/kg (rat)
Dermal LD50 12124 mg/kg (rabbit)
Inhalative LC50/4 h 5320 mg/l (mouse)
128-37-0 2,6-di-tert-butyl-p-cresol
Oral LD50 890 mg/kg (rat)
· Primary irritant effect:
· on the skin: Irritant to skin and mucous membranes.
· on the eye: Irritating effect.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU Classification
Guidelines for Preparations as issued in the latest version:
Irritant
(Contd. on page 7)
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· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
Repr. 2
12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
13 Disposal considerations
· Waste treatment methods
· Recommendation
The generation of waste should be avoided or minimised wherever possible. Significant quantities of waste
product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment
plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of
this product, solutions and any by-products should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local authority requirements. Waste packaging
should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This
material and its container must be disposed of in safe way. Care should be taken when handling emptied
containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product
residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the
container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally.
Avoid dispersal of split material and runoff and contact with soil, waterways, drains and sewers.
· Uncleaned packaging:
· Recommendation:
Disposal must be made according to official regulations.
This material and its container must be disposed of in a safe way. Care should be taken when handling
emptied containers that have been cleaned or rinsed out. Emptied containers or liners may retain some
product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside
the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally.
Avoid dispersal of split material and runoff and contact with soil, waterways, drains and sewers.
· Recommended cleansing agents: Water, if necessary together with cleansing agents.
14 Transport information
· UN-Number
· ADR, IMDG, IATA UN1993
· UN proper shipping name
· ADR 1993 FLAMMABLE LIQUID, N.O.S., ( toluene, 2,6di-tert-
butyl-p-cresol )
(Contd. on page 8)
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· IMDG FLAMMABLE LIQUID, N.O.S., ( toluene, 2,6 di-tert-butyl-
p-cresol ) MARINE POLLUTANT
· IATA FLAMMABLE LIQUID, N.O.S., ( toluene, 2,6 di-tert-butyl-
p-cresol )
· Transport hazard class(es)
· ADR, IMDG
15 Regulatory information
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H225 Highly flammable liquid and vapour.
(Contd. on page 9)
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H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H361d Suspected of damaging the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
R11 Highly flammable.
R36/38 Irritating to eyes and skin.
R38 Irritating to skin.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R63 Possible risk of harm to the unborn child.
R65 Harmful: may cause lung damage if swallowed.
R67 Vapours may cause drowsiness and dizziness.
· Department issuing MSDS: Product safety department
· Contact: Mr. G.C. Spruijt
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
·* Data compared to the previous version altered. added reach registration numbers
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