Msdshfa 8030

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Safety data sheet


according to 1907/2006/EC, Article 31
Printing date 20.03.2014 Version number 8 Revision: 18.03.2014

1 Identification of the substance/mixture and of the company/


undertaking
· Product identifier
· Trade name: HFA 8030
· Relevant identified uses of the substance or mixture and uses advised against
Anti-oxidant
· Sector of Use SU3 Industrial uses: Uses of substances as such or in preparations at industrial sites
· Product category PC13 Fuels
· Application of the substance / the mixture Additive
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
WRT B.V.
Strawinskylaan 3067
1077ZX Amsterdam
The Netherlands
Tel.: 00-31-(0)20-644 2831
Fax.: 00-31-(0)20-642 3962
info@wrtbv.com
· Further information obtainable from:
Product Safety Department
Tel.: 00-31-(0)-644 2831
info@wrtbv.com
Support is only given in the following languages: Dutch, English and German
· Emergency telephone number:
Product Safety department
In case of a spill or accident, you can contact us at:
Tel.: 00-31-(0)20-644 2831
During office hours we can be contacted for general information at
Tel.: 00-31-(0)20-6442831
Support is only given in the following languages: Dutch, English, and German

2 Hazards identification
· Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008

GHS02 flame

Flam. Liq. 2 H225 Highly flammable liquid and vapour.

GHS08 health hazard

Repr. 2 H361d Suspected of damaging the unborn child.


STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.

GHS09 environment

Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects.

GHS07

Acute Tox. 4 H302 Harmful if swallowed.


Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2 H319 Causes serious eye irritation.
(Contd. on page 2)
GB

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Page 2/9
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 20.03.2014 Version number 8 Revision: 18.03.2014

Trade name: HFA 8030

(Contd. of page 1)
STOT SE 3 H336 May cause drowsiness or dizziness.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Xn; Harmful
R48/20-63-65: Harmful: danger of serious damage to health by prolonged exposure through inhalation.
Possible risk of harm to the unborn child. Harmful: may cause lung damage if swallowed.

Xi; Irritant
R36/38: Irritating to eyes and skin.

F; Highly flammable
R11: Highly flammable.
R67: Vapours may cause drowsiness and dizziness.
· Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
· Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
· Label elements
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms

GHS02 GHS07 GHS08 GHS09

· Signal word Danger


· Hazard-determining components of labelling:
2,6-di-tert-butyl-p-cresol
toluene
· Hazard statements
H225 Highly flammable liquid and vapour.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H361d Suspected of damaging the unborn child.
H336 May cause drowsiness or dizziness.
H373 May cause damage to organs through prolonged or repeated exposure.
H304 May be fatal if swallowed and enters airways.
H410 Very toxic to aquatic life with long lasting effects.
· Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
(Contd. on page 3)
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Page 3/9
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 20.03.2014 Version number 8 Revision: 18.03.2014

Trade name: HFA 8030

(Contd. of page 2)
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
CAS: 108-88-3 toluene 50%
EINECS: 203-625-9 Xn R48/20-63-65; Xi R38; F R11
Reg.nr.: 01-2119471310-51 R67
Repr. Cat. 3
Flam. Liq. 2, H225; Repr. 2, H361d; STOT RE 2, H373; Asp. Tox.
1, H304; Skin Irrit. 2, H315; STOT SE 3, H336
CAS: 128-37-0 2,6-di-tert-butyl-p-cresol 50%
EINECS: 204-881-4 Xi R36/38
Reg.nr.: 01-2119565113-46 Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Irrit. 2, H319
· Additional information: For the wording of the listed risk phrases refer to section 16.

4 First aid measures


· Description of first aid measures
· General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48
hours after the accident.
· After inhalation: In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: If symptoms persist consult doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture
Carbon monoxide (CO)
Carbon dioxide (CO2)
· Advice for firefighters
· Protective equipment:
(Contd. on page 4)
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Page 4/9
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 20.03.2014 Version number 8 Revision: 18.03.2014

Trade name: HFA 8030

(Contd. of page 3)
Wear impervious clothing and self contained breathing apparatus. Use water to keep fire-exposed containers
cool. If a leak or spill has not ignited use water spray to disperse the vapours and to provide protection for
personnel attempting to stop a leak. Take care not to spread the fire with water. Contain fire-fighting water to
prevent ingress to watercourses as it will cause oil pollution.

6 Accidental release measures


· Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
· Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

7 Handling and storage


· Handling:
· Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Store only in unopened original receptacles.
Store inside, protect from cold as crystalisation can start to form from < 15 degrees Celsius.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep container tightly sealed.
· Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection


· Additional information about design of technical facilities: No further data; see item 7.
· Control parameters
· Ingredients with limit values that require monitoring at the workplace:
108-88-3 toluene
WEL Short-term value: 384 mg/m³, 100 ppm
Long-term value: 191 mg/m³, 50 ppm
Sk
128-37-0 2,6-di-tert-butyl-p-cresol
WEL Long-term value: 10 mg/m³
· Additional information: The lists valid during the making were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
(Contd. on page 5)
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Page 5/9
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 20.03.2014 Version number 8 Revision: 18.03.2014

Trade name: HFA 8030

(Contd. of page 4)
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
· Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:

Tightly sealed goggles

9 Physical and chemical properties


· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Liquid
Colour: Light yellow
· Odour: Aromatic
· Odour threshold: Not determined.
· pH-value: Not applicable.
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 110 °C
· Pour point < minus 30 °C
· Flash point: 14 °C
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature: 345 °C
· Decomposition temperature: Not determined.
· Self-igniting: Product is not selfigniting.
· Danger of explosion: Product is not explosive. However, formation of explosive
air/vapour mixtures are possible.
· Explosion limits:
Lower: 1.2 Vol %
(Contd. on page 6)
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Page 6/9
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 20.03.2014 Version number 8 Revision: 18.03.2014

Trade name: HFA 8030

(Contd. of page 5)
Upper: 7.0 Vol %
· Vapour pressure at 20 °C: 29 hPa
· Density at 20 °C: 0.91 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water: Insoluble.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic at 20 °C: 2 mPas
Kinematic: Not determined.
· Other information No further relevant information available.

10 Stability and reactivity


· Reactivity
· Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid
High temperature
Sources of ignition
Avoid the build-up of electrostatic charge
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.

11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values relevant for classification:
108-88-3 toluene
Oral LD50 5000 mg/kg (rat)
Dermal LD50 12124 mg/kg (rabbit)
Inhalative LC50/4 h 5320 mg/l (mouse)
128-37-0 2,6-di-tert-butyl-p-cresol
Oral LD50 890 mg/kg (rat)
· Primary irritant effect:
· on the skin: Irritant to skin and mucous membranes.
· on the eye: Irritating effect.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU Classification
Guidelines for Preparations as issued in the latest version:
Irritant
(Contd. on page 7)
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Page 7/9
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 20.03.2014 Version number 8 Revision: 18.03.2014

Trade name: HFA 8030

(Contd. of page 6)
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
Repr. 2

12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.

13 Disposal considerations
· Waste treatment methods
· Recommendation
The generation of waste should be avoided or minimised wherever possible. Significant quantities of waste
product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment
plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of
this product, solutions and any by-products should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local authority requirements. Waste packaging
should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This
material and its container must be disposed of in safe way. Care should be taken when handling emptied
containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product
residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the
container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally.
Avoid dispersal of split material and runoff and contact with soil, waterways, drains and sewers.
· Uncleaned packaging:
· Recommendation:
Disposal must be made according to official regulations.
This material and its container must be disposed of in a safe way. Care should be taken when handling
emptied containers that have been cleaned or rinsed out. Emptied containers or liners may retain some
product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside
the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally.
Avoid dispersal of split material and runoff and contact with soil, waterways, drains and sewers.
· Recommended cleansing agents: Water, if necessary together with cleansing agents.

14 Transport information
· UN-Number
· ADR, IMDG, IATA UN1993
· UN proper shipping name
· ADR 1993 FLAMMABLE LIQUID, N.O.S., ( toluene, 2,6di-tert-
butyl-p-cresol )
(Contd. on page 8)
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Page 8/9
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 20.03.2014 Version number 8 Revision: 18.03.2014

Trade name: HFA 8030

(Contd. of page 7)
· IMDG FLAMMABLE LIQUID, N.O.S., ( toluene, 2,6 di-tert-butyl-
p-cresol ) MARINE POLLUTANT
· IATA FLAMMABLE LIQUID, N.O.S., ( toluene, 2,6 di-tert-butyl-
p-cresol )
· Transport hazard class(es)
· ADR, IMDG

· Class 3 Flammable liquids.


· Label 3
· IATA

· Class 3 Flammable liquids.


· Label 3
· Packing group
· ADR, IMDG, IATA II
· Environmental hazards: Product contains environmentally hazardous substances:
2,6-di-tert-butyl-p-cresol
· Marine pollutant: Yes
Symbol (fish and tree)
· Special marking (ADR): Symbol (fish and tree)
· Special precautions for user Warning: Flammable liquids.
· Danger code (Kemler): 33
· EMS Number: F-E,S-D
· Transport
in bulk according to Annex II
of MARPOL73/78 and the IBC Code Not applicable.
· Transport/Additional information:
· ADR
· Limited quantities (LQ) 1L
· Transport category 2
· Tunnel restriction code D/E
· UN "Model Regulation": UN1993, FLAMMABLE LIQUID, N.O.S., ( toluene, 2,6 di-
tert-butyl-p-cresol ), 3, II

15 Regulatory information
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H225 Highly flammable liquid and vapour.
(Contd. on page 9)
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Page 9/9
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 20.03.2014 Version number 8 Revision: 18.03.2014

Trade name: HFA 8030

(Contd. of page 8)
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H361d Suspected of damaging the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
R11 Highly flammable.
R36/38 Irritating to eyes and skin.
R38 Irritating to skin.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R63 Possible risk of harm to the unborn child.
R65 Harmful: may cause lung damage if swallowed.
R67 Vapours may cause drowsiness and dizziness.
· Department issuing MSDS: Product safety department
· Contact: Mr. G.C. Spruijt
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
·* Data compared to the previous version altered. added reach registration numbers
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