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that can be used to make something useful. If used on a of power. This shows that the anode electrode material
large scale, this seawater will have great potential to strongly influences the performance of the seawater
provide good sources of electrical energy in society to battery. The best anodes to use are zinc or galvanium.
meet the needs of electrical power [6]. The energy crisis Further development of seawater batteries with DC/DC
has become a protracted problem in Indonesia and other converters and Dual in-line Package (DIP) LEDs suits
countries, including Malaysia, for people living in remote innovations in effective and efficient fishing lights for lift
areas [7], [8]. Energy needs will continue to increase along net fishing [17].
with technological advances and population growth. However, from previous research, the resulting
Therefore, the use of seawater is beneficial for overcoming voltage is still minimal, ranging from 1.6 to 3.6 Volts. In
the electrical energy crisis that has hit various countries this research, a seawater lamp will be developed, which
[9]. fishermen can use when fishing at night with greater
Marine energy is a "renewable" alternative energy voltage, current and electric power. This research was
that contains abiotic resources that have the potential to be carried out to produce a higher voltage by connecting
developed. The sea is not only a food source but also has several power sources in series. This study also used a
various energy sources, and its existence is becoming series of LEDs with a size of 5×5 cm, input voltage of 3.7-
increasingly important as fossil fuel energy runs out. The 5v, and 8 watts of power, with 16 LEDs connected in one
potential of the sea is estimated to be four times the world's circuit.
electricity demand, and it is not surprising that various Natural resources, such as coal, oil, and gas, are
developed countries are competing to utilize this energy abundant in Indonesia. However, it has yet to be utilized
[10]. effectively and is still dependent on petroleum as the
Seawater can generate electrical energy by utilizing primary energy source [3]. Because of this, the
electrochemical processes [10]. Electrochemistry is a government issued a renewable energy source policy
change in chemical energy into electrical power due to two stipulated in Law no. 33 of 2007 at 20 paragraph 4
electrodes and an electrolyte as a conductor of electrons concerning energy supply and meeting people's energy
[11]. The type of electrochemical cell used is a voltaic cell needs by seeking alternative energy sources to replace
to produce electrical energy. The voltaic cell, an electrolyte petroleum [18].
of seawater, is given two metals as electrodes connected West Sulawesi is one of the provinces surrounded by
and has a potential difference that makes electrical power. an endless seawater supply. Most people work as
Electrolytes are solutions that decompose into ions, then fishermen who need electrical energy in their daily
become electrical conductors [12]. Ions are charged atoms. activities, including fishing at night. Some people use
Electrolytes can be water, acid-base, or other compounds. diesel generators and kerosene lamps, posing health risks
Electrolytes are generally acids, bases, or salts, and certain and damaging coastal and marine ecosystems. This study
gases can act as electrolytes under certain conditions, such generally aims to determine the potential for utilizing
as high temperature and low pressure [13]. seawater batteries as an alternative source of lighting
Research on the use of seawater to generate energy and a renewable energy source for fishermen. This
electricity has been carried out by several previous study uses the electrolysis solution of two electrodes (Zn
researchers, such as that carried out by Sastromidjojo, by and Cu) with seawater. This seawater battery series is
flowing 2 liters of Parangtritis seawater to the anode and connected to LEDs arranged in parallel to produce bright
cathode circuits in the form of graphite and zinc, which light. The data measured are the electric power (W),
produce electrical energy with a voltage of 1.6 volts [14]. voltage (V), and current (mA) generated by the seawater
Raphael and Aisa Mijeno made a series of LED lights with lamp to determine the durability of the seawater lamp
a glass of water and two spoons of salt [14]. Many before fishermen use it.
countries carry out research and development of new Water covers as much as 70% of the earth's surface,
energy potential. Several studies have been conducted, with 97.5% seawater. This makes it possible to develop
including research on the analysis of the Utilization of Salt seawater lighting products that can be renewable
Water as an Alternative Energy Source Using Used Battery alternative energy sources. The result of this project is a
Carbon Electrodes; the potential of this research is very saltwater-powered lighting product prototype to provide a
good for development [15]. Utilization of Seawater stable supply of electricity, especially in rural areas
Electrolyte as a Source of Electrical Energy for Batteries enabling a better quality of life.
with Copper–Aluminium Electrodes The seawater battery
developed succeeded in turning on LED lamps and
household lamps, with a generated voltage of 1.31 V and II. Theory
an electric current of 13.56 mA. 2-3 batteries arranged in
series produced 2.55 V and 3,6 V [16]. In line with this Sea water
research, the study entitled "Seawater Battery with Al-Cu, Seawater is a mixture of 96.5% pure water and 3.5%
Zn-Cu, and Gal-Cu Electrodes for Fishing Lights" salt, dissolved gases, organic matter, and insoluble
obtained a maximum power of zinc electrodes of 704.17 particles. The salt content in seawater is influenced by
mW, not much different from galvalume's 726.41 mW. In mineral salts in rocks and soil, for example, sodium,
comparison, the aluminum electrode produces 175.75 mW potassium, calcium, and others. The salinity of seawater is
3.5%, meaning that 1 liter (1000 ml) of seawater contains
35 grams of salt [19]. The physical properties of seawater, resistance is called internal resistance, mainly found in the
such as density, compressibility, freezing point, and existing electrolyte material. The rest is on the plate and
temperature, are greatly influenced by the salt content in the end of the connection and marked "r"
seawater. Two properties primarily determined by the sea's
salt amount are electrical conductivity and osmotic
pressure. The main salts contained in seawater are chloride
(55%), sodium (31%), sulfate (8%), magnesium (4%),
calcium (1%), potassium (1%), and the rest less than 1%
consists of Bicarbonate, Bromide, Boric acid, Strontium,
and Florida [19].
Seawater contains an electric current when it contains
a high element of Sodium Chloride (NaCl) which breaks
down into Na+ and Cl-. In the fact of these free-charged
particles, an electric current arises. The emergence of an
electric current by these charges can be used as a cheap and
environmentally friendly source of electrical energy using
the voltaic cell method [20]. Figure 2. Measuring battery voltage and current [22].
Seawater Battery
A voltaic cell consists of two electrodes, namely the
anode and cathode (see Figure 1). The Cu electrode serves
as the cathode, and Zn is the anode. The cathode is the
positive electrode, where the reduction reaction takes
place. Meanwhile, the anode is the negative electrode
where the oxidation reaction occurs [21]. In the reduction
process, some ions or molecules on the positive electrons
(cathode) receive reduction and electrons. Some ions and
molecules give electrons on the negative electrons (anode),
causing the oxidation process.
Figure 3. Flow chart for measuring battery voltage and current
[22].
𝑉𝑏 = 𝐸 − 𝑉 = 𝐼 . 𝑟 (Volts) (1)
Resistance in battery:
𝑟 = 𝑉𝑏 . 𝐼 = 𝐸 − 𝑉. 𝐼 (ohms) (2)
Figure 1. Seawater Battery electrochemical cell
Electrical Motion and Resistance in Batteries Voltage and Current Maximum in Battery
In Figure 2, if the voltage is measured before being In Figure 3, when the "S" switch is connected, the
connected to the load resistance, "RL," then the voltage overall system in the battery will work, in the circuit there
shows "E" volts. After the battery is connected to the load is a load resistance "RL" and an internal resistance "r". the
resistance and the voltage is measured, it will show "V" decrease in current in the circuit is influenced by the
volts lower than the initial voltage. internal resistance of the battery.
In Figure 3, the voltmeter will show an open voltage The electric power generated by the battery is the
of "E" volts before the "S" switch is connected, the sum of the power lost in the battery and the power
ammeter will show that there is an electric current flowing generated by the load resistance. The amount of electric
across the load resistance, and the clamp voltage of the power that the battery will completely release follows
battery is shown by the voltmeter "V" volts after the switch Equation 3.
is connected. The difference in electric voltage between V
and E is caused by the electric current issued by the battery. 𝑃 = 𝑃𝑏 + 𝑃𝐿 = 𝐸 . 𝐼 (watts) (3)
The electric current must pass through the battery
resistance before starting the load resistance. The battery
If the battery is short-circuited, the load resistance electrode used, the more active material that can
becomes zero, and the amperage released is: accommodate electrons to produce more electrical energy.
[24].
𝐼 = 𝐸𝑟 (ampere) (4) A copper wire is connected to each electrode at one
end, and the other is connected to alligator clips. Two
III. Method similar devices are made for current production and
This section describes the experimental procedure electrochemical characteristics.
used for this research and the parameters to be studied,
such as Voltage, Current, and electric power generated by
Seawater Lamp Durability
seawater lamps. Details of the experimental procedure for
The open circuit voltage is measured by connecting
each parameter to be studied will be explained in this
the positive and dangerous electrodes. A digital multimeter
section.
for four days (96 hours) measured current, volts, and
electric power. This experiment aims to measure the
Materials and instruments electrode's durability in a seawater solution. To achieve
The research used seawater as an electrolysis solution this goal, voltage, current, and resistance changes are
and two Zn and Cu electrodes placed in an acrylic recorded every 4 hours. This corresponds to the ideal time
container with a size of (14×7.5×16) cm. used by fishermen when fishing at night.
Aktif dari Limbah Tandan Sawit pada Prototipe Baterai,” Listrik,” J. Tek. Elektro Univ. Tanjungpura, vol. 2, no. 1,
J. Fis. FLUX, vol. 14, no. 1, p. 27, Jul. 2017, doi: pp. 1–10, 2019, [Online]. Available:
10.20527/flux.v14i1.3777. https://jurnal.untan.ac.id/index.php/jteuntan/article/view/3
[14] S. Z. N. Haq, E. Kurniawan, and M. Ramdhani, “Analisis 4942.
Pembangkit Elektrik Menggunakan Media Air Garam [23] N. Ueoka, N. Sese, M. Sue, A. Kouzuma, and K.
Sebagai Larutan Elektrolit,” in e-Proceeding of Engin, Watanabe, “Sizes of Anode and Cathode Affect
2018, pp. 3830–3837, [Online]. Available: Electricity Generation in Rice Paddy-Field Microbial Fuel
https://openlibrarypublications.telkomuniversity.ac.id/ind Cells,” J. Sustain. Bioenergy Syst., vol. 06, no. 01, pp. 10–
ex.php/engineering/article/view/8089. 15, 2016, doi: 10.4236/jsbs.2016.61002.
[15] A. Bachtiar et al., “Studi Analisis Pemanfaatan Air Garam [24] A. Satriady, W. Alamsyah, A. H. Saad, and S. Hidayat,
Sebagai Sumber Energi Alternatif Menggunakan “Pengaruh Luas Elektroda terhadap Karakteristik Baterai
Elektroda Karbon Baterai Bekas,” Ensiklopedia J., vol. 5, Lifepo4.,” J. Mater. dan Energi Indones., vol. 6, no. 2, pp.
no. 1, pp. 359–366, 2022, [Online]. Available: 43–48, 2016, doi: 10.24198/jmei.v6i02.10959.
https://jurnal.ensiklopediaku.org/ojs-2.4.8- [25] A. Susanto, M. S. Baskoro, S. H. Wisudo, M. Riyanto,
3/index.php/ensiklopedia/article/view/958. and F. Purwangka, “Performance of Zn-Cu and Al-Cu
[16] Z. Anisa and D. Setyaningrum, “Pemanfaatan Elektrolit Electrodes in Seawater Battery at Different Distance and
Air Laut Sebagai Sumber Energi Listrik Baterai Dengan Surface Area,” Int. J. Renew. Energy Res., vol. 7, no. 1,
Elektroda Tembaga - Aluminium,” Sainmatika J. Ilm. pp. 298–303, 2017, doi: 10.20508/ijrer.v7i1.5506.g7018.
Mat. dan Ilmu Pengetah. Alam, vol. 19, no. 2, pp. 156– [26] O. A. Rybalkina, M. V. Sharafan, V. V. Nikonenko, and
162, Dec. 2022, doi: 10.31851/sainmatika.v19i2.9583. N. D. Pismenskaya, “Two Mechanisms of H+/OH− Ion
[17] A. Susanto, M. S. Baskoro, S. H. Wisudo, M. Riyanto, Generation in Anion-exchange Membrane Systems with
and F. Purwangka, “Seawater Battery with Al-Cu, Zn-Cu, Polybasic Acid Salt Solutions,” J. Memb. Sci., vol. 651, p.
Gal-Cu Electrodes for Fishing Lamp,” Int. J. Renew. 120449, Jun. 2022, doi: 10.1016/j.memsci.2022.120449.
Energy Res., vol. 7, no. 4, pp. 1857–1868, 2017, doi: [27] M. N. Hidayat, F. Mayrullah, and Sapto Wibowo,
10.20508/ijrer.v7i4. “Pemodelan Baterai Air Garam dan Pengujian Salinitas
[18] DPR-RI, “Undang-Undang No. 33 Tahun 2007 tentang Elektrolit Berbasis PLC,” J. ELTIKOM, vol. 6, no. 2, pp.
energi, Pasal 20 ayat 4.” Jakarta, 2007. 226–238, Nov. 2022, doi: 10.31961/eltikom.v6i2.577.
[19] R. Rizal, “Perancangan Lampu LED Elektrolit Berbahan [28] Y. Umniyati, “Preliminary Experiments on Potential Use
Bakar Air Laut Sebagai Sumber Energi,” Universitas of Salt-Water Battery 4 for Cheap Electric Storage: Work
Muhammadiyah Mataram, 2021. In Progress,” J. Ilmu dan Inov. Fis., vol. 5, no. 1, pp. 74–
[20] I. Nuriskasari, D. Handaya, M. T. N. Ramadhan, H. Z. 81, Feb. 2021, doi: 10.24198/jiif.v5i1.31282.
Alghifary, and P. Nuraisah, “Rancang Bangun [29] J.-K. Kim et al., “Eco-friendly Energy Storage System:
Pembangkit Listrik Tenaga Air Gambut Menggunakan Seawater and Ionic Liquid Electrolyte,” ChemSusChem,
Logam Bekas sebagai Elektroda,” Austenit, vol. 13, no. 1, vol. 9, no. 1, pp. 42–49, Jan. 2016, doi:
pp. 1–7, 2021, doi: 10.5281/zenodo.4735749. 10.1002/cssc.201501328.
[21] G. A. Pauzi, N. A. Pratiwi, A. Surtono, and S. W. [30] E. Morabet, K. R. A., K. A. R., and A. M., “Saltwater a
Suciyati, “Analisis Pengaruh Variasi PH Larutan Acid Viable Source of Energy for Sustainable Rural
Zinc Pada Sel Volta Dua Kompartemen dengan Elektrode Development,” in 16th International Conference on
Cu(Ag)-Zn,” J. Energy, Mater. Instrum. Technol., vol. 3, Environmental Science and Technology, 2019, pp. 205–
no. 1, pp. 21–30, Feb. 2022, doi: 10.23960/jemit.v3i1.88. 206, [Online]. Available:
[22] R. N. Yudi, I. Yusuf, and A. Hiendro, “Studi Performa https://cest2019.gnest.org/sites/default/files/presentation_f
Baterai Air Laut dengan Membandingkan Elektrolit ile_list/cest2019_00205_oral_paper.pdf.
Larutan Garam dan Air Laut Untuk Menghasilkan Energi
Declarations
Author contribution : Muh. Ridwan Kadir and Hardi Hamzah are in charge of the entire research project.
He also leads the creation and data capture of research in collaboration with all
authors. Nurul Afiqah Arsyad, Syarifah Nuraeni Alaydrus, Wenny Puspita and Sahrul
participated in delaying data collection, transcription and analysis. He also revised
the Manuscript. Muhammad Nurkhalis Agriawan is responsible for the creation and
design of the media as well as in the preparation of manuscripts and analysis of
research data. All authors approved the final manuscript.
Funding statement : This research is the output of the Program Kreatifitas Mahasiswa (PKM) which is
funded by the Kementrian Pendidikan, Kebudayaan, Riset, dan Teknologi
(Kemdikbud Ristek) through the Directorate General of Belmawa.
Conflict of interest : All authors certify that they have no competing interests.
Additional information : No additional information is available for this paper.