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C - Sol - Ch-01 - Some Basic Concepts of Chemistry

This document contains sample problems and solutions related to basic chemistry concepts: 1) It provides the weighted average calculation to determine the overall concentration of a solution containing different substances at varying concentrations. 2) It works through determining empirical and molecular formulas from elemental composition data, including calculating percentage compositions. 3) It identifies the number of significant figures in an average value calculation. 4) It calculates the number of significant figures in a value determined using the ideal gas constant. 5) It solves for the molecular weight of an unknown solute based on data about the solution's composition and mass. 6) It shows a stoichiometric calculation to determine the volume of gas produced in a chemical reaction

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47 views2 pages

C - Sol - Ch-01 - Some Basic Concepts of Chemistry

This document contains sample problems and solutions related to basic chemistry concepts: 1) It provides the weighted average calculation to determine the overall concentration of a solution containing different substances at varying concentrations. 2) It works through determining empirical and molecular formulas from elemental composition data, including calculating percentage compositions. 3) It identifies the number of significant figures in an average value calculation. 4) It calculates the number of significant figures in a value determined using the ideal gas constant. 5) It solves for the molecular weight of an unknown solute based on data about the solution's composition and mass. 6) It shows a stoichiometric calculation to determine the volume of gas produced in a chemical reaction

Uploaded by

mysoftinfo.inc
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Chapter 1

Some Basic Concepts of Chemistry


1. Answer (B)
We will have to take weighted average
54  5  90  56  5  57
= 55.95
100
2. Answer (B, C)
(A) If empirical formula of 3 is P3Q4, then molecular formula is (P3Q4)n

3MP 40 2
 3M  4M  100  5
P Q

15MP = 6MP + 8MQ

9MP = 8MQ

 3MP  8MQ
 For P3Q5, % of P =  3M  5M   100 =  100  34.78%
 P Q  23M Q

(B) If empirical formula of compound 3 is P3Q2, we have

3MP 2

3MP  2MQ 5

15MP = 6MP + 4MQ

9MP = 4MQ

If MP = 20

180
MQ   45
4

(C) If empirical formula of 2 is PQ

MP 4 44.44
 M  M  9  100
P Q

9MP = 5MP + 4MQ

5MP = 4MQ

If empirical formula is assumed as P5Q4,

 5MP 
% of P =  5M  4M   100 = 50
 P Q 

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CHEMISTRY ARCHIVE - JEE (Advanced) (Solutions)

Hence P5Q4 is the empirical formula of compound

(D) If empirical formula of I is P2Q, we have

 2MP 
% of P =  2M  M   100 = 50
 P Q 

4MP = 2MP + MQ
2MP = MQ
Hence, atomic weight of P and Q cannot be 70 and 35 respectively.
Hence (B, C) are correct
3. Answer (3)
25.2  25.25  25
Average titre value = = 25.15
3
Siginificant figure is 3.
4. Answer (4)
6.023 × 1023 × 1.380 × 10–23 = 8.312
It has four significant figure.
5. Answer (8)
w 2  1000
m
m2  w 1
1 mL solvent having mass 0.4 g.
1000 mL solvent having mass 400 g
1000 mL solution contain 3.2 × 80 g solute = 256 g
256  1000
 m 8
80  400
6. Answer (6.00 to 6.20)

2Al(s)  3H2SO4 (aq)  Al2 (SO 4 )3 (aq)  3H2 (g)

5.4 50  5
Moles taken
27 1000

= 0.2 moles 0.25 moles

H2SO4 is limiting reagent

 Moles of H2(g) produced = 0.25 moles

Using ideal gas equation : PV = nRT

0.25  0.082  300


 V
1

V = 6.15 L


Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005 Ph.011-47623456

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