Scribd
Upload
45 views4 pages

C Sol Ch-16 General+Principles+and+Processes+Of

This document contains multiple choice questions about the general principles and processes of isolating elements. It discusses the extraction of metals such as zinc, silver, copper, aluminum, iron, tin, gold, and lead from their ores. The questions cover topics like identification of ores, reduction processes, electrolytic refining, self-reduction reactions, and extraction methods including roasting and smelting.

Uploaded by

mysoftinfo.inc
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
45 views4 pages

C Sol Ch-16 General+Principles+and+Processes+Of

This document contains multiple choice questions about the general principles and processes of isolating elements. It discusses the extraction of metals such as zinc, silver, copper, aluminum, iron, tin, gold, and lead from their ores. The questions cover topics like identification of ores, reduction processes, electrolytic refining, self-reduction reactions, and extraction methods including roasting and smelting.

Uploaded by

mysoftinfo.inc
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 4

Chapter 16

General Principles and Processes of


Isolation of Elements
1. Answer (B)

2ZnS + 3O2 2ZnO + 2SO2


+ carbon

Zn + CO
2. Answer (D)
Haematite Fe2O3 Fe+3
Magnetite Fe3O4 Fe+2 and Fe+3
3. Answer (B)



Ag2S  4NaCN 
 2Na[Ag(CN)2 ]  Na2 S

Na 2 S 2  2O2 
 Na 26 SO 4
2Na[Ag1(CN)2 ]  Zn  Na2 [Zn(CN)4 ]  2Ag0 
4. Answer (A)
Silver, copper and lead are commonly found in earth's crust as Ag2S (silver glance), CuFeS2 (Copper pyrites)
and PbS (Galena).
5. Answer (C)
CuCO3Cu(OH)2  Malachite
Fe3O4  Magnetite
ZnCO3  Calamine
Na3AlF6  Cryolite
6. Answer (A, D)
12001300C
SnO2  2C Sn  2CO
if after contain Fe and Cu as impurity.
7. Answer (C, D)
Al2O3 and MgCO3.CaCO3 are separately reduced by electrolytic reduction.
8. Answer (B, C, D)

Cu2 S  2Cu2O  6Cu  SO2

Since, CuSO4 as well as CuO both on heating produces Cu2O as shown below so, they also produce Cu on
heating with Cu2S.
 1
2CuO  Cu2O  O2
2

 1
CuSO 4  CuO  SO2  O2
2
Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005 Ph.011-47623456
ARCHIVE - JEE (Advanced) (Solutions) CHEMISTRY

9. Answer (B, C, D)
In electrolytic refining of blister Cu, acidified CuSO4 is used as electrolyte, pure Cu deposits at Cathode and
impurities sattle as anode mud.
10. Answer (A, B, C)
Extraction of Cu from copper pyrite (CuFeS2) involves following steps:
Step 1: Pulverisation or crushing of copper pyrite ore.
Step 2: Concentration of the ore by froth-flotation method.
Step 3: Self-reduction during partial roasting.
CuFeS2 + O2  Cu2S + FeS + SO2
Cu2S + O2  Cu2O + SO2

2Cu2O + Cu2S  6Cu  SO2


(blister copper )

FeS + O2  FeO + SO2

FeO + SiO2 
 FeSiO3
(flux) (slag)

Step 4: Refining of blister copper : Refining is done by electrolytic refining method.


11. Answer (A, C, D)
Extraction of gold is done by leaching with dil. solution of NaCN in the presence of air (O2).

Au + NaCN + O2   Au(CN)2  + OH–


–

(Q) (R)

[Au(CN)2 ]– + Zn   Zn(CN)4  + Au


2–

(R) (T) (Z) (S)

R is [Au(CN)2]–.
Q is O2.
Z is [Zn(CN)4]2–.
12. Answer (A, B, C, D)
Al2O3 + 2NaOH + 3H2O  2Na[Al(OH)4]
2Na[Al(OH)4] + 2CO2  Al2O3xH2O + 2NaHCO3

Al2O3xH2O  Al2O3(s) + xH2O


1473K

13. Answer (A, C, D)

PbS  2PbO  3Pb  SO2

Self reduction is taking place between PbS and PbO.


In the Bessemer converter : The raw material for the Bessemer converter is matte, i.e., Cu2S + FeS (little).
Here air blasting is initially done for slag formation and SiO2 is added from external source.
3
FeS  O2  FeO  SO2 
2
SiO2  FeO  FeSiO3 (slag)
During slag formation, the characteristic green flame is observed at the mouth of the Bessemer converter which
indicates the presence of iron in the form of FeO. Disappearance of this green flame indicates that the slag
formation is complete. Then air blasting is stopped and slag is removed.

Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005 Ph.011-47623456


CHEMISTRY ARCHIVE - JEE (Advanced) (Solutions)

Again air blasting is restarted for partial roasting before self reduction, until two-thirds of Cu2S is converted
into Cu2O. After this, only heating is continued for the self reduction process.

3
Cu2 S  O2  Cu2O  SO2 
2
Cu2 S  2Cu2 O  6Cu(l)  SO 2  (self reduction)

and Cu2S  2O2  Cu2SO4

Cu2 S  Cu2SO 4  4Cu  2SO2  (self reduction)

Thus the molten Cu obtained is poured into large container and allowed to cool and during cooling the dissolved
SO2 comes up to the surface and forms blisters. It is known as blister copper.

2Na[Au(CN)2 ]  Zn  Na2 [Zn(CN)4 ]  2Au 

14. Answer (B, C, D)

(A) The reduction of Al2O3 with coke (C) at a temperature > 2500°C is not carried out due to the formation
of carbides.

(B) It is correct as neutralisation of aluminate solution is done by passing CO2 gas to precipitate hydrated alumina.
(C) Reaction of powdered one is carried out with hot concentrated NaOH at 473 K – 523 K and 35 – 36 bar pressure.
(D) Electrolysis of Al2O3 is done mixed with Na3AlF6 to produce Al and CO2. It is a correct statement.
15. Answer (A, B, C)

(A) Limestone is added to remove silica as impurity.

(B) Pig iron obtained from blast furnace contains 4% carbon and many other impurities (eg. S, P, Si, Mn) in small
amount.

(C) Coke (C) converts CO2 in CO.

C + CO2  2CO

(D) Exhaust gases consist of CO and CO2.

Hence, (A, B, C) are correct.


16. Answer (A)
Partial roasting of chalcopyrite
O2 / 
CuFeS2   Cu2S  FeO
17. Answer (D)

FeO  SiO2  FeSiO3


gauge flux slag

18. Answer (C)

Cu2S + Cu2O  6Cu + SO2

19. Answer A(p); B(q); C(p, r); D(p, s)


20. Answer A(P, Q, S); B(T); C(Q, R); D(R)

Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005 Ph.011-47623456


ARCHIVE - JEE (Advanced) (Solutions) CHEMISTRY

Siderite  FeCO3
Malachite  CuCO3
Cu(OH)2
Bauxite  Al2O3·xH2O or
AlOx(OH)3 – 2x 0 < x < 1
Calamine  ZnCO3
Argentite  Ag2S

21. Answer (6.40 – 6.50)


2PbS + 3O2  2PbO + 2SO2
2PbO + PbS  3Pb + SO2
3 moles of O2 produce 3 moles of lead
96 kg of oxygen produce 621 kg of lead.

621
1 kg of oxygen produce = 6.468 = 6.47 kg
96



Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005 Ph.011-47623456

You might also like

pFad - Phonifier reborn

Pfad - The Proxy pFad of © 2024 Garber Painting. All rights reserved.

Note: This service is not intended for secure transactions such as banking, social media, email, or purchasing. Use at your own risk. We assume no liability whatsoever for broken pages.


Alternative Proxies:

Alternative Proxy

pFad Proxy

pFad v3 Proxy

pFad v4 Proxy