Scribd
Upload
2K views2 pages

STPM 2022 Sem 3 Mock Ans

The document appears to be an answer scheme for a chemistry exam. It provides answers to multiple choice and structured questions on various chemistry topics. The answers reference organic reactions, functional groups, properties of compounds, polymerization reactions, and more. Key details identified include references to isomerism, hybridization, functional groups of compounds, types of chemical reactions, products of reactions, and polymer structures.

Uploaded by

g-65251693
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
2K views2 pages

STPM 2022 Sem 3 Mock Ans

The document appears to be an answer scheme for a chemistry exam. It provides answers to multiple choice and structured questions on various chemistry topics. The answers reference organic reactions, functional groups, properties of compounds, polymerization reactions, and more. Key details identified include references to isomerism, hybridization, functional groups of compounds, types of chemical reactions, products of reactions, and polymer structures.

Uploaded by

g-65251693
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 2

MOCK ANSWER SCHEME FOR STPM 2022

962 / 3 : CHEMISTRY PAPER 3


16. a) SN1 [1] b) 2-bromo-2-methylpropane [1] b) Each structure X, Y, Z [1] x 3 ; Equation [1] x 2 [5]
Type of reaction [1]

c) [1]
d) i. prevent the formation of alkanes or alkenes or alkynes [1]
ii. First step : CH3CHO Second step : H3O+ [2]
iii. cooling agents and lubricants / additive in paints, plastics
and rubber as a plasticiser / flame retardant (fire extinguisher)

17. a) CH3CH2CH2COOCH3 [1]


b) i. P : CH3CH2CH2COOH Q : CH3OH [1]
ii. P : CH3CH2CH2COCl [1] 20. a) m1-m3 : structure of A, B, C [3]
c) i. ethanamine / ethylamine [1]
ii) CH3CH2CH2COCl + CH3CH2NH2 → (heat)
CH3CH2CH2CONHCH2CH3 + CH3CH2NH3Cl [1]
d) P is more soluble in water while methyl butanoate is
sparingly soluble in water [1]
b) m4 : elimination : excess conc. H2SO4 ; reflux [1]
- since P can form hydrogen bond with water ester cannot [1]
m5 : ozonolysis : 1) O3 in CH2Cl2 , cold [1]
m6 : 2) DMS [1]
18 a) m1 – m5 : Each structure [1] x 5 [5]
c) m7-m9 : Each arrow [1] x 2 intermediate [1] [3]

b) m6 : equation m7 : major product m8 : minor product [1]


CH3CH2CH=CH2 + HCl → d) m10 – m12 : two reagent [1] x 2 Equation [1] [3]
U CH3CH2CHClCH3 + V : CH3CH2CH2CH2Cl
(major) (minor)
* wide range of answer will probably be accepted
m9 : U is major since it follows Markovnikoff’s rule [1]
e)m13 : Test : Fehling’s solution / Tollens’ reagent / Iodoform
m10 : in the addition of H-Cl to unsaturated C=C, H is
m14 : propanal gives brick-red precipitate (FS) / silver mirror
preferred to add to C with more H [1]
(TR) while propanone shows no observable changes or
c) m11 : 3o carbon radical is more stable [1]
propanone give yellow precipitate (Iodoform) while propanal
m12 – m15 : each steps [1] x 4 [4]
shows no observable changes [1]
m15 : equation : [1]

19. a) Each step and reagent/condition [1] x 9 [9]


Section A

CH3CH(OH)CH2CH=CHCH3 is sparingly soluble in water since it has 7 C. It has 2 functioning group. It exhibit
1. D
both geometrical and optical isomerism, and has 2 sp2 and 4 sp3 C hybrid orbital and 1 sp3 O hybrid orbital
Noradrenaline has C* atom hence optical active. It has 4 functioning group (phenol, 20 alcohol, 10 amine,
2. A
benzene). It can dehydrate as it has 2o alcohol and can undergoes coupling reaction with benzenediazonium ion
3. C Cl• (electrophile) ; NO2+ (electrophile) ; AlH4- (nucleoophile) ; H+ (electrophile)
Phenol has lower melting point than benzoic acid (form dimer) ; chloroethane has lower melting point than
4. D bromoethane (higher RMM) ; n-butane has higher melting point than methylpropane (branch) ; methyl ethyl ether
has lower melting point than propan-1-ol (hydrogen bond)
Toluene can undergoes free radical substitution (-CH3) and addition (benzene) and electrophilic aromatic
5. C
substitution reaction (ortho para subst)

6. D

7. B Chlorobenzene does not undergoes hydrolysis under atmospheric pressure


8. B Since vitamin B1 has 10 alcohol, it react faster with Na
X form cyanohydrin of CH3CH2CH(OH)CN. Therefore it can undergoes dehydration to form CH3CH=CHCN ; it
9. A hydrolysed to form CH3CH2CH(OH)COOH ; it’s a nucleophilic addition ; X cannot be formed from haloalkane
and hydrogen cyanide/
Ethanoyl chloride is liquid ; It react with phenol in alkaline condition to form ester and primary amine to form 20
10. C
amide ; It does not form dimer
C6H5COCl + CH3CH2CH2OH → (one way) C6H5COOCH2CH2CH3 (sweet smell) + HCl (white fume) ; does not
11. A
required catalyst.
Alanine can form only one dipeptide Ala-ala ; it is optical active and can react with R-COCl to form HCl ; it is
12. A
neutral as it form zwitterion.
Due to aniline, it form salt when react with acid (neutralization) and react to form benzenediazonium chloride
13. A/B
when react with NaNO2/HCl 0-5oC.

14. C Nylon 6,6 is polyamide, PVC is addition polymer ; terylene is polyester ; rubber is addition polymer

15. D Monomer is CH2=CHCOOH and react via addition polymerization.

You might also like

pFad - Phonifier reborn

Pfad - The Proxy pFad of © 2024 Garber Painting. All rights reserved.

Note: This service is not intended for secure transactions such as banking, social media, email, or purchasing. Use at your own risk. We assume no liability whatsoever for broken pages.


Alternative Proxies:

Alternative Proxy

pFad Proxy

pFad v3 Proxy

pFad v4 Proxy