Worksheet-D Block Elements: (n-1) (n-1) (n-1) (n-1)

Worksheet-D block elements
1. The number of d-electrons retained in Fe3+ ion is (At. no. of Fe = 26)

a. 3 c. 6
b. 5 d. 4
2. Of the following outer electronic configurations of atoms, the highest
oxidation state is achieved by which one of them?
a. (n-1)d8 ns2 c. (n-1)d8 ns2
b. (n-1)d5 ns2 d. (n-1)d5 ns-1
3. The transition element that has lowest enthalpy of atomization is
a. Zn(30) c. V (23)
b. Cr (24) d. Mn (25)
4. Which of the following compounds is metallic and ferro-magnetic?

a. MnO2 c. TiO2
b. CrO2 d. VO2
5. In the following reactions, ZnO is, respectively, acting as a/an

(I) ZnO + Na2O Na2ZnO2
(II) ZnO + CO2 ZnCO3
(1) acid and base respectively, Zn (3) base and acid respectively, Zn
is not a transition element and is not a transition element and
atomic size of Zn is less than that atomic size of Zn is more than
of Sc. that of Sc.
(2) acid and base respectively, Zn (4) base and acid respectively, Zn
is transition element and atomic is a transition element and
size of Zn is less than that of Sc. atomic size of Zn is less than that
of Sc.
6. Which of the following statement(s) are true
a) On reaction of KMnO4 with strong inorganic acid which is used in
lead storage battery gives an explosive Mn3O7
b) On reaction of KMnO4 with strong inorganic acid which is used as
catalyst in esterification reaction gives an explosive Mn2O7
c) Potassium magnate(green) reacts with Chlorine gas to give
potassium permanganate (purple)
d) KMnO4 can oxidize NO2- to NO3-
A) Only b C) a, b and d
B) a, c and d D) b, c and d
7. When calomel reacts with NH4 OH solution, the compound formed
is(Nessler’s reagent)
a. NH2 - Hg-Cl b. Hg2 Cl2 NH3 c. Hg (NH3)2 Cl2 d. HgCl2NH3
8. Bronze and German silver have common metals. Those are

a. Zn, Cu b. Cu, Ni c. Zn, Ni d. Cu, Fe
9. CrO3 dissolves in aqueous NaOH to give

a. CrO42- b. Cr (OH)3 c.Cr2O72- d. Cr (OH)2
10. Pick out the correct statements from the following.
a. Cobalt (III) is more stable in octahedral complexes.
b. Zinc forms colored ions or complexes.
c. KMnO4 (acidic/alkaline) is not decolourised by Mohr salt
d. Osmium shows (VIII) oxidation state.
e. Cobalt (II) is more stable in octahedral complexes.
(I) a and b (II) a and c (III) b and d (IV) a and d (V) d and c
11. What is the correct order of spin only magnetic moment

(in BM) of Mn2+, Fe2+, Ni2+ and Co2+?
(a) Mn2+ > Fe2+ > Co2+> Ni2+ (c) Mn2+ > Co2+ > Fe2+ > Ni2+
(b) Fe2+> Co2+ > Mn2+ > Ni2+ (d) Co2+ > Fe2+ > Mn2+> Ni2+
12. For d-block elements the first ionization potential is of the order
a. Zn > Fe > Cu > Cr b. Sc = Ti < V = Cr
c. Zn < Cu < Ni < Co d. V > Cr > Mn > Fe
13. Select the False statement(s) from the following:
i. Monel metal is an alloy of Cu, Ni and have small amount of Fe, Mn
ii. Gun metal is made of Cu, Sn, Zn
iii. oxidation state of iron in Mohr's salt is +3
iv. 'Hydride gap' is referred to Groups 6, 7 and 8 of the periodic table
a. i, iv b. iii, ii c. iii only d. i only
14. Which metal gives hydrogen gas on heating with hot concentrated alkali ?
a. Ag b. Ni c. Zn d. Cu
15. K2Cr2O7 on heating gives K2CrO4 + O2 + X, In the above reaction, X is

a. CrO3 b. Cr2O72- c. Cr2O3 d. CrO5
16. KI and Blue vitriol solutions on mixing will produce

a. Cu2l2 + K2SO4 b. Cul2+K2SO4+I2 c. Cul2 + K2SO4 d. Cu2l2+K2SO4+I2
17. Select the False statement from the following:
i. Transition metal ions show color because of d-d transitions
ii. Transition metal ion exists in its highest oxidation state, It is
expected to behave as an oxidizing agent
iii. In photography we use AgBr
iv. KMnO4 in basic medium is reduced to Mn2+
18. Which of the following is the green colored powder produced when
ammonium dichromate is used in fire works ?
a. CrO3 b. CrO(O2 ) c. Cr2O3 d. Cr
19. Copper sulphate solution reacts with KCN and gives
a.
b. K3[Cu(CN)4] d. Cu(CN)2
c. CuCN e. K2[Cu(CN)4 ]
20. Which of the following is amphoteric among the following are?
CuO, NiO, V2O5, MnO2, Mn2O3 Mn2O7, MnO
a. CuO, NiO b. V2O5, Mn2O3 c. MnO, Mn2O3 d. V2O5, MnO2
21. When acidified potassium dichromate reacts with H2O2 a blue color is
produced due to formation of
a. CrO3 b. Cr2O72- c. Cr2O3 d. CrO5
22. Carbon content of
a. steel is in between those of cast iron and wrought iron
b. cast iron is in between those of steel and wrought iron
c. wrought iron is in between those of steel and cast iron
d. steel is higher than that of pig iron
23. Which of the following arrangements does not represent the correct order of
the property stated against it?
a. Ni2+ < Cr2+ < Mn2+ < Fe2+ (paramagnetic behavior)
b. Ni2+ < Co2+ < Fe2+ < Mn2+ (ionic size)
c. Co 3+ < Fe3+ < Cr3+ < Sc3+ (stability in aqueous solution)
d. Sc < Ti< Cr< Mn (number of oxidation states)
24. On the basis of data given below,
E-Sc3+/Sc2+ = −0.37 E-Cr2+/Cr = −0.90
E-Mn3+/Mn2+ = 1.57 E-Cu2+/Cu = 0.34
a) Sc3+ has good stability due of [Ar]3d04s0 configuration.

b) Mn3+ is more stable than Mn2+
c) Cr2+is reducing in nature.
d) Copper does not give H2 on reaction with dil. H2SO4
25. The following two reactions HNO3 with Zn are given as (equations are not
balanced)
a. Zn + cone. HNO3 Zn (NO3)2 + X + H2O
b. Zn + dil. HNO3 Zn (NO3)2 + Y + H2O
In reactions I and II, the compounds X and Y respectively, are
(a) NO2 and NO (b) NO2 and NO2
(c) NO and NO2 (d) NO2 and NH4NO3
26. Which pair of compounds is expected to show similar color in aqueous
medium?
(a) FeCl3 and CuCl2 (c) VOCl2 and FeCl2
(b) VOCl2 and CuCl2 (d) FeCl2 and MnCl2
27. Which one of the following nitrates will leave behind a metal on strong
heating?
(a) Ferric nitrate (c) Copper nitrate
(b) Manganese nitrate (d) Silver nitrate
28. Copper becomes green when exposed to moist air for a long period. This is due
to
a) the formation of a layer of cupric oxide on the surface of copper.
b) the formation of a layer of basic carbonate of copper on the surface of
copper.
c) the formation of a layer of cupric hydroxide on the surface of copper.
d) the formation of basic copper sulphate layer on the surface
29. Which of the following statements is false?

a. CrO42- is tetrahedral in shape
b. Cr2O72- has Cr - O - Cr bond
c. Na2Cr2O7 is used as titrant in titrations
d. Na2Cr2O7 is less soluble than K2Cr2O7
30. Choose the correct reaction to prepare mercurous chloride(calomel)

(a) HgCl2 + Hg on heating (b) Hg + Cl 2 on heating
(c) HgCl2 + SnCl2 on heating (d) Both (a) and (c)
1. (B) 2. (B) 3. (A) 4. (A) 5. (1) 6. (D)

7. (A) 8. (A) 9. (A) 10. (IV) 11. (A) 12. (A)
13. (C) 14. (C) 15. (C) 16. (D) 17. (D) 18. (C)
19. (A) 20. (D) 21. (D) 22. (A) 23. (A) 24. (B)
25. (D) 26. (B) 27. (D) 28. (B) 29. (C) 30. (D)
ANSWER KEY :-
E Sethurama Subramaniam, 1st year

Qns are arranged from easy medium and
the hard …
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Worksheet-D block elements

1. The number of d-electrons retained in Fe3+ ion is (At. no. of Fe = 26)

4. Which of the following compounds is metallic and ferro-magnetic?

5. In the following reactions, ZnO is, respectively, acting as a/an

8. Bronze and German silver have common metals. Those are

9. CrO3 dissolves in aqueous NaOH to give

11. What is the correct order of spin only magnetic moment

15. K2Cr2O7 on heating gives K2CrO4 + O2 + X, In the above reaction, X is

16. KI and Blue vitriol solutions on mixing will produce

a) Sc3+ has good stability due of [Ar]3d04s0 configuration.

29. Which of the following statements is false?

30. Choose the correct reaction to prepare mercurous chloride(calomel)

1. (B) 2. (B) 3. (A) 4. (A) 5. (1) 6. (D)

E Sethurama Subramaniam, 1st year

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