Books Doubtnut Question Bank
Books Doubtnut Question Bank
Books Doubtnut Question Bank
SOLUTIONS
liquids?
Answer: C
Watch Video Solution
A. CI 2
B. Br 2
C. I
2
D. KCI
Answer: C
3. CuSO 4
.5H2 O , a hydrated salt, is a coordination compound of Cu
2+
solution of
Answer: D
4. Out of molarity (M), molality (m), formality (F) and mole fraction (x)
A. M,m
B. F,x
C. m,x
D. M,x
Answer: C
A. 40M
B. 4M
C. 55.5M
D. Unpredictable
Answer: C
C. Concentration of A = Concentration of B
D. It is not possible to compare the concentration
Answer: A
Answer: C
M
A. m = × 1000
d + M M2
M
B. m = × 1000
1000d − M M2
d + M M2
C. m = × 1000
M
1000d − M M2
D. m = × 1000
M
Answer: B
A. 0.875M
B. 1.00M
C. 1.25M
D. 2.5M
Answer: A
10. For an ideal binary solution (A) and (B), y is the mole fraction of A in
A
A. P Total
vs y
A
B. P Total
vs y
B
1
C. vs y A
PTotal
1
D. vs (y B
+ yA )
PTotal
Answer: C
applicable to
B. an electrolyte in solution
Answer: C
A. p ∘
− p = p
n
B. p = p
∘
(1 − n)
C. p = p
∘
n
Answer: D
1
B. ∝
x solute
C. = x solute
D. ∝ m
Answer: C
16. Which of the following plots does not represent the behaviour of an
C. Plot of p
total
versus x (or x
A B
) is linear
D. Plot of p
total
versus x is non-linear
A
Answer: D
A. x A
= yA
B. x A
> yA
C. x A
< yA
Answer: C
∘
p − ps n2
A. ∘
=
p n1 + n2
∘
p − ps n1
B. ∘
=
p n1 + n2
∘
p − ps n2
C. =
ps n1 + n2
∘
p − ps n1
D. =
ps n1 + n2
Answer: A
Answer: C
B. > 60
C. = 60mL
D. unpredictable
Answer: A
A. ΔH mixing
= 0
B. ΔV mixing
= 0
Answer: D
the solution is
A. = 50mL
B. > 50mL
C. < 50mL
D. unpredictable
Answer: A
23. Which of the following conditions is not correct for ideal solution?
Answer: D
acetone ?
D. Unpredictable
Answer: C
solution?
A. Plot of P Total
vsXA is non-linear
B. Plot of P Total
vsXB is linear
C. Plot of P Total
vsXB is linear with slope = 0
D. Plot of P Total
vsXA is linear with slope = 0
Answer: B
A. Ideal solution
D. Unpredictable behaviour
Answer: B
D. unpredictable
Answer: B
28. In the diagram given in the point D refers to composition where, the
solution exhibits
Answer: A
29. If the vapour pressure of solutions of two liquids are less than those
C. ideal behaviour
Answer: A
called a/an
B. azeotropic mixture
C. isotropic mixture
D. no specific name
Answer: B
Answer: C
solution.
solvent
C. relative number of solute molecules and the nature of solute and
solvent
Answer: B
34. Which of the following property does not depend upon the number of
C. Osmotic pressure
Answer: B
B. Dipole moment
C. Heat of vaporisation
D. Osmotic pressure.
Answer: B
36. Which one of the following solutions exhibits the maximum elevation
in boiling point?
A. 0.1mN aCI
B. 0.1mCaCI 2
C. 0.1mBaCI 2
D. 0.1mF eCI 3
Answer: D
the solute
solvent
solute
Answer: D
Watch Video Solution
38. Which of the following solutions will have the highest boiling point?
A. 0.1M F eCI 3
B. 0.1M BaCI 2
C. 0.1M N aCI
D. 0.1M urea (N H 2
CON H2 )
Answer: D
2
M1 RT
A. K
0
f =
1000ΔHf
2
1000RT
B. K
0
f
=
M1 ΔHf
2
1000M1 T
C. K
0
f =
RΔHf
ΔHf
D. K f =
2
1000M1 RT
0
Answer: A
the molal depression constant of water, the freezing point of the solution
will be
1000Kf n
A.
w
1000Kf n
B. −
w
1000Kf w
C.
n
1000Kf w
D. −
n
Answer: A
A. sodium chloride
B. ice
Answer: B
42. Which of the following aqueous solutions have higher freezing point?
A. 0.1mAl 2 (SO 4 )
3
B. 0.1mBaCl 2
C. 0.1mAlCl 3
D. 0.1mN H 4
Cl
Answer: D
A. 1 : 1 : 1
B. 1 : 2 : 3
C. 1 : 1 : 1.5
D. 2 : 4 : 3
Answer: C
A. 0.1m glucose (C 6
H12 O6 )
B. 0.1mN aCl
C. 0.1m surcose (C 12
H22 O11 )
D. 0.1mBaCl 2
Answer: D
Answer: C
Answer: B
B. Conc. N aCI
C. 50 % N aCI
D. 30 % N aCI
Answer: A
A. AlCl 3
> BaCl2 > U rea
B. BaCl 2
> AlCl3 > U rea
D. BaCl 2
> Urea > AlCl3
Answer: A
Watch Video Solution
Answer: B
measurement is
A. 58.5
D. unpredictable
Answer: B
B. Water
C. Hypertonic solution
D. Hypotonic solution
Answer: C
KCL(π 2 ) is
A. π 1
< π2
B. π 1
> π2
C. π 1
= π2
π1 π2
D. =
π1 + π2 π1 + π2
Answer: A
53. The solutions having same osmotic pressure w.r.t. same semi-
A. Equivalent solutions
B. Ideal solutions
C. Equimolar solutions
D. Isotonic solutions
Answer: D
A. molarity
B. vapour pressure
C. osmotic pressure
D. viscosity
Answer: C
of a dilute solutions is
Answer: C
0.05M N aCl, 0.05M BaCl2 and 0.1M AlCl3 . Which one of the following
pairs is isotonic?
A. A and B
B. B and C
C. A and D
D. A and C
Answer: A
A. 0
B. 1
C. 2
D. between 0 -1
Answer: D
A. 1
B. 2
C. 3
D. 1 / 3
Answer: D
59. In case of electrolyte which dissociates in the solution the van Hoff
factor I
A. > unity
B. < unity
C. = unity
D. can be > or < 1
Answer: A
Answer: B
61. The van't Hoff factor (i) for a dilute aqueous solution of glucose is:
A. zero
B. 1
C. 1.5
D. 2.0
Answer: B
A. 9
B. 5
C. 24
D. none of these
Answer: B
A. i > 1
B. i = 1
C. i < 1
D. none of these
Answer: C
A. 1 : 1 : 1
B. 1 : 2 : 3
C. 1 : 1 : 1.5
D. 2 : 6 : 7
Answer: C
65. Which of the following aqueous solutions will have highest freezing
point?
A. 0.1mAI 2
(SO4 )
3
B. 0.1m glucose
C. 0.1mKCI
D. 0.1mCaCI 2
Answer: B
A. i = 1 − α
B. i = 1 + α
C. i = 1 + α /2
D. i = 1 − α /2
Answer: D
dilute solution?
A. i = 11
B. i = 5
C. i = 1 / 11
D. i = 10
Answer: B
A. i = 7
B. i = 3
C. i = 4
D. i = 5
Answer: B
is
A. 4
B. 3
C. 2
D. none of these
Answer: C
solution contains
A. 1 mole of N aOH
Answer: B
molality of solution is
A. 1.25
B. 0.19
C. 0.25
D. 0.30
Answer: B
ideal solution with another liquid B. The mole fration of B in the solution
A. 0.14 torr
B. 560 torr
C. 140 torr
D. 70 torr
Answer: C
pressure is equal to
A. 0.02
B. 0.05
C. 0.1
D. 0.04
Answer: A
A. 90
B. 45
C. 180
D. 360
Answer: A
A. 0.1m
B. 0.5m
C. 1.0m
D. 0.18m
Answer: C
glucose is :
A. 0.05
B. 0.0625
C. 0.9375
D. 0.15
Answer: B
A. 0.9M
B. 0.3M
C. 1.8M
D. 0.18M
Answer: B
A. 4.92 atm
B. 1 atm
C. 0.25 atm
D. 27 atm
Answer: A
A. 0.1M N aCl
B. 0.1M CaCl 2
C. 0.1M CH 3
COON a
D. 0.1M glucose
Answer: D
B. 0 ∘
C
C. 0.0186 ∘
C
Answer: D
B. 119.96
C. 95.58
D. 126.98
Answer: A
the solvent
of the solvent
A. 0.02
B. 1.1
C. 20
D. 196
Answer: A
Answer: B
A. 0.8396
B. 0.0839
C. 0.9
D. 1
Answer: A
Watch Video Solution
A. 504 mm
B. 248.8mm
C. 255.2mm
D. none of these
Answer: B
following relations
Kb × 1000 × wB
A. M B
=
ΔTb × wA
wB × RT
B. M B
=
πV
p0 × wB × MA
C. M B
=
(p0 − p) × wA
ΔTb wB
D. M B
= × 1000
Kb wA
Answer: A
dilute solution?
A. 4
B. 0.25
C. 0.5
D. 5
Answer: A
Watch Video Solution
A. T 1
> T2
B. T 2
> T1
C. T 1
= T2
D. T 1
≥ T2
Answer: B
resulting solution is
A. 1.0M
B. 10.0M
C. M / 100
D. 0.1M
Answer: D
concentration of solution is
A. 0.5N
B. 2.0N
C. 2.5N
D. 1.0N
Answer: D
A. 1.2m
B. 0.4m
C. 0.1m
D. 0.2m
Answer: D
93. The vapour pressure of water at room temperature is 23.8 mm Hg. The
is equal to
A. 2.39mmH g
B. 2.42mmH g
C. 21.42mmH g
D. 21.44mmH g
Answer: C
solution is
A. 0.1M
B. 0.2M
C. 0.25M
D. 0.15M
Answer: A
ideal solution with another liquid B. The mole fraction of B is 0.25 and the
total pressure of the solution is 82.5 torr at 300K. The vapour pressure of
A. 37.5
B. 150
C. 75
D. 187.5
Answer: B
A. 0.2
B. 0.4
C. 0.6
D. 0.8
Answer: C
solution is
A. 4.81 × 10
21
B. 24.08 × 10 21
C. 0.408 × 10 23
D. 6.02 × 10 22
Answer: A
volume to 25
∘
C . What would exist at 25
∘
C ? Vapour pressure of alcohol
at 25 ∘
C is 100 torr
Answer: A
will have
D. none of these
Answer: A
given as
A. Solution process is exothermic
∘
32.4 C
thereafter
Answer: C
B. 2m solution of glucose
C. 1m solution of urea
Answer: B
A. 2.5 ppm
B. 5 ppm
C. 5M
D. 5gmL −1
Answer: B
103. 0.2 moles of HCI and 0.1 moles of calcium chloride were dissolved in
A. 0.04M
B. 0.8M
C. 0.4M
D. 0.08M
Answer: B
A. 0.55M
B. 0.35M
C. 0.787M
D. 3.05M
Answer: C
amount of BaCI 2
.2H2 O required will be
A. 0.250 moles
B. .0025 moles
C. 2.5 moles
D. 6.1g of BaCI 2
.2H2 O
Answer: D
A. > 94
B. 94
C. < 94
D. unpredictable
Answer: A
A. 10
B. 3
C. 0.3
D. unpredictable
Answer: C
0.513
∘
Ckgmol
−1
, the boiling point of 0.69m solution of urea will be:
A. 100.079 ∘
C
B. 103 ∘
C
C. 100.359 ∘
C
D. unpredictable
Answer: A
benzene is
A. 5.08Kkgmol −1
B. 508Kkgmol −1
C. 0.508Kkgmol −1
D. 50.8 ∘
Ckgmol
−1
Answer: A
osmotic pressure 4.98 bar. If the osmotic pressure of solution is 1.52 bar
A. 1.6M
B. 0.61M
C. 0.061M
D. None of these
Answer: C
C6 H6 = 5.1Km
−1
) At. Mass of A and B are
A. 42.64 and 25.58
Answer: B
18g of water is then added to solution, the new vapour pressure becomes
2.9kP a at 298K. The solutions obey Raoult's law and are not dilute, molar
mass of solute is
A. 23gmol −1
B. 34gmol −1
C. 43gmol −1
D. 32gmol −1
Answer: A
A. 10.08kP a
B. 12.08kP a
C. 8.3kP a
D. 10.3kP a
Answer: B
mixture of N a 2
CO3 and N aH CO is 3
A. 100mL
B. 200mL
C. 157.9mL
D. 159.7mL
Answer: C
115. If all symbols have their usual meaning, then for a non-volatile non-
ΔTf
electrolyte solute Lt m→ 0
( ) is equal to
m
A. zero
B. Infinity
C. ΔT f
D. Kf
Answer: D
C. evaporate 50 mL water
D. evaporate 50 mL solution
Answer: D
A. 1.01
B. 1.02
C. 1.10
D. 1.20
Answer: C
0.52
∘
C(Kb for water = 0.52Kmolality
−1
. The mole fraction of urea in
)
this solution is :
A. 0.982
B. 0.018
C. 0.0567
D. 0.943
Answer: B
solute is 100% ionised ay b.pt of water. The f.pt of the same solution is
− 1.80
∘
C . Hence AB(K
b
/ Kf = 0.3)
Answer: C
1.86Km
−1
, the solution freezes at
A. − 1.58 ∘
C
B. − 1.86 ∘
C. − 3.16 ∘
C
D. − 3.58 ∘
C
Answer: B
A. 0.30M
B. 0.10M
C. 0.50M
D. 0.20M
Answer: A
(density of H g = 13.6gcm
−3
)
A. 0.76mm
B. 70.28mm
C. 74.42mm
D. 760mm
Answer: C
View Text Solution
A. 120,75
B. 120,195
C. 120,45
D. 75,45
Answer: C
B. 2mol
C. 1mol
D. 0.5mol
Answer: C
125. A mixture contains 1 mole of volatile liquid A(P =100mm Hg) and 3
A
∘
A. 85 mm Hg
B. 86 mm Hg
C. 90 mm Hg
D. 92 mm Hg
Answer: B
A. 6.17m
B. 3.09m
C. 1.54m
D. 0.77m
Answer: A
A. 2 mol
B. 1 mol
C. 3 mol
D. 4 mol
Answer: B
solution is 0.02046
∘
, 1m urea solution freezes at − 1.86
∘
C . Assuming
A. 2
B. 3
C. 3.2
D. 4.2
Answer: B
A. 1.1RT
B. 0.1RT
C. 0.11RT
D. 0.01RT
Answer: C
A. 14.12 Torr
B. 312 Torr
C. 13.45 Torr
D. 352 Torr
Answer: C
Revision Question
D. no colligative effect
Answer: B
A. Nature of solute
B. Nature of solvent
C. ΔH solution
Answer: B
A. ΔT f
B. π
C. ΔT b
D. K b
Answer: D
A. Boiling point
B. Osmosis
C. Freezing point
D. Osmotic pressure.
Answer: D
Answer: A
Answer: C
A. Nollet
B. Pfeffer
C. Traube
D. Dutrochet
Answer: A
A. density
B. normality
C. molar concentration
D. volume
Answer: C
solute is
A. 13.6
B. 34
C. 68
D. 136
Answer: D
be
A. 100.75 ∘
C
B. 100.5 ∘
C
C. 100 ∘
C
D. 100.25 ∘
C
Answer: D
concentration of N O −
3
ions in the mixture will be
A. 0.1M
B. 0.05M
C. 0.2M
D. 0.15M
Answer: B
A. 9.6
B. 2.4
C. 9.6 × 10 3
D. 4.3 × 10 2
Answer: A
13. At25 ∘
C the highest osmotic pressure is exhibited by 0.1M solution of
A. CaCI 2
B. KCI
C. Glucose
D. Urea
Answer: A
A. AI 2
(SO4 )
3
B. N aCI
C. AI(N O 3
)
3
D. N a 2
SO4
Answer: A
A. 0.93 ∘
C
B. − 0.93 ∘
C
C. 1.86 ∘
C
D. − 1.86 ∘
C
Answer: B
N aCl is
A. 0.1
B. 0.01
C. 0.2
D. 0.0196
Answer: D
A. 0.2
B. 0.06
C. 0.4
D. 0.88
Answer: C
C. osmotic pressure
sugar at 150 ∘
C is
A. 4 atm
B. 5.07 atm
C. 3.55 atm
D. 2.45 atm
Answer: B
B. 63
C. 53
D. 45
Answer: B
solution is
A. 1
B. 0.1
C. 0.5
D. 4
Answer: A
Watch Video Solution
A. Molar concentration
B. Molality
C. Normality
D. None of these
Answer: A
23. Which of the following method is used for measuring the osmotic
A. Ostwald method
D. Haber's method
Answer: B
A. 250K
B. 298K
C. 51.6k
D. 12.5K
Answer: B
temperature ?
A. Normality
B. Mass-volume percent
C. Molality
D. Molarity
Answer: C
solvent is equal to
B. Moles of solute
C. Mole fraction of solvent
D. Moles of solvent
Answer: A
aqueous solution is
A. 2M
B. 0.5M
C. 1M
D. 0.05M
Answer: B
A. 10mL
B. 40mL
C. 20mL
D. 80mL
Answer: B
1.538g mL −1
) Vapour pressure of solution is :
A. 141.93mm
B. 94.39mm
C. 199.34mm
D. 143.99mm
Answer: A
A. 4.18M
B. 8.14M
C. 18.4M
D. 18M
Answer: C
(P1 ), 10g urea (P2 ) and 10g sucrose (P3 ) are dissolved in 250mL of
water is:
A. P 1
> P2 > P3
B. P 3
> P1 > P2
C. P 2
> P1 > P3
D. P 2
> P3 > P1
Answer: C
A. g/lit
B. mol/lit
C. kg/lit
D. None of these
Answer: B
A. increasing temperature
B. decreasing temperature
C. increasing volume
D. None of these
Answer: A
B. 0.1M glucose
C. 0.1M M gSO 4
D. 0.1M BaCI 2
Answer: D
A. 84 % H CI
B. 22.2 % H CI
C. 63 % H CI
D. 20.2 % H CI
Answer: D
A. 1
B. 2
C. 3
D. 4
Answer: C
37. Which of the following 0.10M aqueous solution will have the lowest
freezing point?
A. AI 2
(SO4 )
3
B. C 6
H12 O6
C. C 12
H12 O11
D. KI
Answer: A
higher by 0.216 ∘
C than that of the pure solvent. Find out the molecular
A. 1.01
B. 10.1
C. 100
D. 10
Answer: C
pressure?
A. 0.1M N aCI
B. 0.1M glucose
C. 0.1M BaCI 2
D. 0.1M glucose
Answer: C
A. 1m
B. 0.5m
C. 0.2m
D. 2m
Answer: C
− 0.186
∘
C(Kf = 1.86
∘
,K
b
= 0.512
∘
) . What is the elevation in boiling
point?
A. 0.186
B. 0.512
0.512
C.
1.86
D. 0.0512
Answer: D
A. Surface tension
B. Osmotic pressure
C. Viscosity
D. Refractive index
Answer: B
43. An ideal solution was obtained by mixing methanol and ethanol. If the
fraction) will be
Answer: B
is 1.86Kmol −1
, then molar mass of the solute will be
A. 105.7
B. 106.7
C. 115.3
D. 93.9
Answer: A
A. Henry's law
B. Raoult's law
C. Ostwald's law
D. Arrhenius law
Answer: B
A. − 1.86 ∘
C
B. − 0.93 ∘
C
C. − 0.093 ∘
C
D. 0.93 ∘
C
Answer: C
A. 171.2
B. 68.4
C. 34.2
D. 136.2
Answer: B
non-volatile solute was added to the solvent. The mole fraction of solute
A. 0.8
B. 0.6
C. 0.4
D. 0.2
Answer: C
A. Hypertonic
B. Hypotonic
C. Isotonic
D. Normal
Answer: C
A. N solution
B. 2N solution
C. N / 2 solution
D. 3N solution
Answer: B
A. Acidic
B. Basic
C. Neutral
D. Slightly acidic
Answer: C
52. How many grams of a dibasic acid (Mol. Wt. =200) should be present in
A. 1g
B. 2g
C. 10g
D. 20g
Answer: A
A. 49.5
B. 59.6
C. 69.6
D. 79.82
Answer: C
of a solvent is 0.1 ∘
C . The molal elevation constant of the liquid is-
A. 0.01K / m
B. 0.1K / m
C. 1K / m
D. 10K / m
Answer: D
A. molarity
B. molality
C. Normality
D. formality
Answer: B
A. 2.46 atm
B. 24.6 atm
C. 1.21 atm
D. 12.1 atm
Answer: B
A. Molality = normality
B. Molarity = normality
Answer: B
A. − 1.86 ∘
C
B. 0.186 ∘
C
C. − 0.0186 ∘
C
D. − 0.0093 ∘
C
Answer: D
A. Diffusion pressure
B. Atmospheric pressure
C. osmotic pressure
D. Turgor pressure
Answer: C
Answer: C
A. Osmotic pressure
Answer: D
A. Henry's law
B. Raoult's law
C. Distribution law
Answer: B
3% solution of glucose (M. mass 180). The molar mass of the substance is
A. 60
B. 120
C. 180
D. 360
Answer: A
64. The aqueous solution that has the lowest vapour pressure at a given
temperature, is
B. 0.1mBaCI 2
C. 0.1mN aCI
D. 0.1m glucose
Answer: A
(Na=23)?
A. 60g
B. 6g
C. 4g
D. 40g
Answer: B
decinormal concentration is
A. 400cm 3
B. 500cm 3
C. 450cm 3
D. 100cm 3
Answer: A
67. Which one of the following aqueous solution will have the lowest
freezing point?
A. 0.1m urea
B. 0.1m sucrose
C. 0.1mCH 3
COOH
D. 0.1mCaCI 2
Answer:
A. melting point
B. sublimation point
C. inversion point
D. boiling point
Answer:
A. 156
B. 145
C. 150
D. 108
Answer: A
A. 36.5
B. 18.25
C. 32.05
D. 42.1
Answer: C
Answer: C
72. The vapour pressure of a solution (P) and the vapour pressure of the
solvent (P
∘
) are related to each others as (x 1 is the mole fraction of
solvent)
A. P = P
∘
x2
B. P = P
∘
x1
C. P ∘
= P x1
D. P ∘
= P x2
Answer: B
B. temperature
Answer: D
B. ΔH mix
< 0
Answer: B
pressure.
m2
A. M 2
= [ ]V RT
π
m2 RT
B. M 2
= [ ]
V π
m2
C. M 2
= [ ]nRT
V
m2 π
D. M 2
= [ ]
V RT
Answer: B
Answer: B
expression is used
B. milligram percent
C. microgram percent
Answer:
78. Identify the mixture that shows positive deviations from Raoult's law
A. CH CI 3
+ (CH3 ) CO
2
B. (CH 3
) CO + C6 H5 N H2
2
C. CH CI 3
+ C6 H6
D. (CH 3
) CO + CS2
2
Answer: D
79. 2.5 litre of 1M N aOH solution is mixed with another 3 litre solution
A. 0.80M
B. 1.0M
C. 0.73M
D. 0.50M
Answer: C
80. At room temperature the mole fraction of a solution is 0.25 and the
vapour pressure of the solvent is 0.80 atm. Then the lowering of vapour
pressure is
A. 0.75
B. 0.6
C. 0.2
D. 0.8
Answer: C
A. 148
B. 158
C. 168
D. 178
Answer: B
A. ΔH soln
= ΔH3 − ΔH1 − ΔH2
B. ΔH soln
= ΔH1 + ΔH2 + ΔH3
C. ΔH soln
= ΔH1 + ΔH2 − ΔH3
D. ΔH soln
= ΔH1 − ΔH2 − ΔH3
Answer: B
ionization is 0.3. Taking Kf for water as 1.85, the freezing point of the
A. − 0.480 ∘
C
B. − 0.360 ∘
C
C. − 0.260 ∘
C
D. + 0.480 ∘
C
Answer: A
B. 0.14
C. 0.28
D. 0.35
Answer: A
D. the free energy as well as the entropy of mixing are each zero
Answer: A
N / 10 solution is
A. 45cm 3
B. 400cm 3
C. 450cm 3
D. 100cm 3
Answer: B
acid
napthalene
Answer: C
Answer: A
A. 9.8063g
B. 7.3548g
C. 3.6774g
D. 4.903g
Answer: D
0.2mole / kg of CuSO is
4
A. 0.3
B. 0.6
C. 0.9
D. 0.2
Answer: C
91. 3.65grams of HCI dissolved in 16.2g of water. The mole fraction of HCI
A. 0.4
B. 0.3
C. 0.2
D. 0.1
Answer: D
A. [P t(N H 3
) CI3 ]CI
4
B. [P t(N H 3
) CI2 ]CI2
4
C. [P t(N H 3
) CI]CI3
4
D. [P t(N H 3
) CI4 ]
4
Answer: B
mixed together and volume made to one litre. The normality of the
resulting solution is
N
A.
5
N
B.
10
N
C.
20
N
D.
40
Answer: D
94. What is the effect of the addition of sugar on the boiling and freezing
points of water?
Answer: D
A. CO(N H 2
)
2
B. C6
H12 O6
C. N aCI
D. None of these
Answer: A
Watch Video Solution
− 0.186
∘
C . Calculate ΔT if :
b
−1 −1
Kf = 1.86K kg mol and Kb = 0.521K kg mol
A. 0.521
B. 0.0521
C. 1.86
D. 0.0186
Answer: B
97. Which one of the following aqueous solution will exhibit highest
boiling point?
A. 0.01M N a 2
SO4
B. 0.015M glucose
C. 0.015M urea
D. 0.01M KN O 3
Answer: A
98. 6.02 × 10
20
molecules of urea are present in 100 mL of its solution.
(Avogadro constant, N A
23
= 6.02 × 10 mol
−1
)
A. 0.001M
B. 0.1M
C. 0.002M
D. 0.01
Answer: D
Watch Video Solution
A. 48 % H CI
B. 22.2 % H CI
C. 36 % H CI
D. 20.2 % H CI
Answer: D
A. 1 / 76
B. 1 / 7.6
C. 1 / 38
D. 1 / 10
Answer: A
solution is
A. 29.2mL
B. 17.5mL
C. 175mL
D. 145mL
Answer: A
A. 0.2N
B. 0.4N
C. 0.8N
D. 0.6N
Answer: B
103. Which of the following solutions will have the highest b.d?
A. 0.1M F eCI 3
B. 0.1M BaCI 2
C. 0.1M N aCI
D. 0.1M Urea
Answer: A
A. Comphor
B. Nepththalene
C. Benzene
D. Water
Answer: A
statement is
A. Henry law
C. Raoult's law
D. Le-Chatelier's principle
Answer: C
dm
3
of the solution. The strength of the solution is
A. 6N
B. 2N
C. 4N
D. 8N
Answer: B
Watch Video Solution
A. 0.16mol / L
B. 0.32mol / L
C. 0.60mol / L
D. 0.45mol / L
Answer: A
D. it is volatile
Answer: C
109. The statement "the relative lowering of the vapour pressure is equal
to the ratio of the molecules of the solute to the total number of the
A. Hess's law
B. Dalton's law
C. Raoult's law
D. Charle's law
Answer: C
Watch Video Solution
A. Decrease the freezing point of water in the winter and increase the
Answer: A
solution is
A. 4g
B. 1g
C. 2g
D. 5g
Answer: B
6N H CI are
Answer: B
D. Osmotic pressure
Answer: D
A. 1 + α
B. 1 − α
C. 1 + 2α
D. 1 − 2α
Answer: C
A. 50
B. 25
C. 37.5
D. 53.5
Answer: A
Watch Video Solution
A. 1.20M
B. 1.50M
C. 1.344M
D. 2.70M
Answer: C
117. The vapour pressure of two liquids 'P' and 'Q' are 80 and 60 torr
B. 20 torr
C. 68 torr
D. 72 torr
Answer: D
0.512Kkgmol
−1
respectively, the above solution will freeze at,
A. − 6.54 ∘
C
B. 6.54 ∘
C. 0.65 ∘
C
D. − 0.654 ∘
C
Answer: D
resulting solution is
A. 1N
B. 0.1N
C. 10N
D. 11N
Answer: B
120. Which of the following solutions are isotonic with one another?
A. 1 and 4
B. 2 and 3
C. 1,2 and 4
D. 2,3 and 4
Answer: C
mixed and the volume of the mixture is made 1000 mL by adding water.
A. 1N
B. 2N
C. 3N
D. 4N
Answer: A
122. Equal volumes of ethylene glycol (molar mass = 62) and water (molar
mass = 18) are mixed. The depression in freezing point of water is (given
Kf of water = 1.86Kmol
−1
kg and specific gravity of ethylene glycol is
1.11)
A. 0.0033
B. 3.33
C. 0.333
D. 33.3
Answer:
A. 19.0
B. 19.602
C. 19.402
D. 19.202
Answer: B
Answer: C
required is
A. 10mL
B. 20mL
C. 40mL
D. 60mL
Answer: C
naphthalene = 80.1
∘
CΔTf = 0.661
∘
C. Lf = 35.7cal / g of
A. S 2
B. S 4
C. S 6
D. S 8
Answer: D
A. 3.2
B. 2
C. 4
D. 3.4
Answer: A
Answer: C
A. 0.027
B. 0.036
C. 0.018
D. 0.009
Answer: C
D. can't determine
Answer: C
B. 0.25
C. 0.52
D. 0.2
Answer: D
isotonic solutions?
D. 0.1M Ba(N O 3
)
2
and 0.1M N a 2
SO4 .
Answer: D
Watch Video Solution
134. The mass of glucose that would be dissolved in 50g of water in order
A. 1g
B. 3g
C. 6g
D. 8g
Answer: B
A. H N O 3
+ H2 O solution
B. C2
H5 OH + H2 O solution
C. C6
H6 + C6 H5 CH3 solution
D. None of these
Answer: A
A. one
B. two
C. three
D. four
Answer: C
A. 25
B. 1
C. 5
D. 250
Answer: C
138. The van't Hoff factor for a solute that associates in solution is
A. zero
B. 1
C. less than 1
ionisation in electrolytes :
I. 0.1m urea
II. 0.04mAl 2
(SO4 )
3
III. 0.0.5mCaCl 2
Answer: B
Watch Video Solution
A. exothermic temperature
B. exotehrmic till 60 ∘
C and endothermic after 60 ∘
C
C. endothermic till 60 ∘
C and exothermic there-after
D. endothermic
Answer: C
A. hypotonic
B. isotonic
C. equimolar
D. hypertonic
Answer: B
142. Phenol dimerises in benzene having van't Hoff factor 0.54. what is the
degree of association?
A. 0.46
B. 0.54
C. 0.27
D. 0.92
Answer: D
A. 0.70
B. 0.50
C. 0.60
D. 0.80
Answer: A
Watch Video Solution
144. Two liquids X and Y form an ideal solution. The mixture has a vapour
pressure of 400 mm at 300 K when mixed in the molar ratio 1:1. when
mixed in the molar ratio of 1:2 at the same temperatre the vapour
pressure of the mixture is 350 mm. The vapour pressure of the two pure
A. 250mm, 550mm
B. 350mm, 450mm
C. 350mm, 700mm
D. 550mm, 250mm
Answer:
B. 0.5N H 2
SO4
C. 1N H 2
SO4
D. 2N H 2
SO4
Answer: A
A. 0.37 ∘
C
B. 0.74 ∘
C
C. 0.185 ∘
C
D. 0 ∘
C
Answer: A
Watch Video Solution
A. 1
B. 18
C. 55.5
D. None of these
Answer: C
A. 10Kgrammol −1
B. 1.0Kkgmol −1
C. 10Kkgmol −1
D. 10Kkg mol
Answer: C
A. 1M solution of glucose
C. 6% solution of glucose
Answer: A
point
A. 0.1M KN O 3
B. 0.1M N a 3
P O4
C. 0.1M BaCI 2
D. 0.1M K 2
SO4
Answer: B
A. 6M
B. 18M
C. 10M
D. 4M
Answer: B
meanings, the van't Hoff factor 'i' cannot be calculated by which of the
following expression ?
A. πV = ∈ RT
B. ΔT f
= iKf m
C. ΔT b
= iKb m
∘
p − psolution n
D. solvent
∘
= i( )
p N + n
solvent
Answer: D
A. 136.2
B. 68.4
C. 34.2
D. 171.2
Answer: B
A. 0.512m
B. 0.195m
C. 1.95m
D. 5.12m
Answer: C
equilibrium:
Answer: A
temperature ?
A. Molality only
Answer: B
A. 1.4g
B. 3.2g
C. 25.4mg
D. 2.24mg
Answer: D
order (molar masses of N aCI, KCI, BaCI2 and urea are respectively
at this temperature
Answer:
Watch Video Solution
159. The difference between the boiling point and freezing point of an
A. 34.2g
B. 342g
C. 7.2g
D. 72g
Answer: D
A. 4870 Pa
B. 4.87 Pa
C. 0.00487 Pa
D. 0.33 Pa
Answer: A
Answer: A
Watch Video Solution
1
A.
20
1
B.
38
1
C.
76
1
D.
760
Answer: B
163. The vapour pressure of a pure liquid is 0.80 atm. When a non-volatile
solute is added to this liquid, its vapour pressure drops to 0.60 atm. The
B. 0.2
C. 0.25
D. 0.85
Answer: C
A. 0.2
B. 0.4
C. 0.8
D. 1
Answer: B
Watch Video Solution
pressure measurement
Answer: D
solute
B. Relative lowering of vapour pressure is equal to mole fraction of
the solvent
solute
Answer: C
A. 51022gmol −1
B. 122044gmol −1
C. 31011gmol −1
D. 61038gmol −1
Answer: D
containing 3 g L
−1
of the compound exerts the same osmotic pressure
compound is :
A. CH 2
O
B. C2
H4 O 2
C. C4
H8 O 4
D. C3
H6 O 3
Answer: B
A. C2
H4 O 2
B. C3
H6
C. C4
H8 O 4
D. C6
H12 O6
Answer:
from freezing at −6
∘
C will be (K for water =1.86Kkgmol
f
−1
and molar
B. 804.328g
C. 204.30g
D. 400.00g
Answer: B
x + y − 1
A. α =
i − 1
i − 1
B. α =
(x + y − 1)
i − 1
C. α =
x + y + 1
x + y − 1
D. α =
i − 1
Answer: B
Watch Video Solution
A. 0.050
B. 0.100
C. 0.190
D. 0.086
Answer: D
173. Dissolving 120g of urea (mol wt 60) in 100 g of water gave solution of
A. 1.78M
B. 2.00M
C. 2.05M
D. 2.22M
Answer: C
K3 [F e(CN ) ]
6
(Mol. wt. 329) in 100g of water (K
f
= 1.86Kkgmol
−1
) is
A. − 2.3 × 10 −2
B. − 5.7 × 10 −2
C. − 5.7 × 10 −3
D. − 1.2 × 10 −2
Answer: A
Watch Video Solution
− 3.82
∘
C ,Calculate the van't Hoff factor for N a 2
SO4
A. 2.05
B. 2.63
C. 3.11
D. 0.83
Answer: B
A. 0.1770
B. 0.0177
C. 0.0344
D. 0.83
Answer: B
B. benzene toluene
C. acetone-chloroform
D. n-hexane-n-heptane
Answer: C
Answer: C
water is 1.86 ∘
C /m , the freezing point of the solution will be.
A. − 0.1 ∘
C
B. − 0.54 ∘
C
C. − 0.3 ∘
C
D. − 0.24 ∘
C
Answer: D
A. C2
H4 O 2
B. C3
H6 O 3
C. C4
H8 O 2
D. C6
H12 O6
Answer:
A. P A
+ XA (PB − PA )
B. P A
+ XA (PA − PB )
C. P B
+ XA (PB − PA )
D. P B
+ XA (PA − PB )
Answer: D
is 2
∘
C . Assuming concentration of solute is much lower than the
is:
(take k b
= 0.76Kkgmol
−1
)
A. 724
B. 740
C. 736
D. 718
Answer: A
1.0kg of water, how many grams of ethylene glycol (C2 H6 O2 ) must you
A. 27g
B. 72g
C. 93.3g
D. 39g
Answer: C
184. 6.02 × 10 20
molecules of urea are present in 100 ml of its solution.
A. 0.02M
B. 0.01M
C. 0.001M
D. 0.1M
Answer: B
B. 0.875M
C. 1.00M
D. 1.75M
Answer: B
186. How many grams of concentrated nitric acid solution should be used
A. 45.0 g conc. H N O 3
B. 90.0 g conc. H N O 3
C. 70.0 g conc. H N O 3
D. 54.0 g conc. H N O 3
Answer: B
constant temperature
temperature
Answer: A::B::D
respectively and x and x are the mole fraction of the solvent and solute
1 2
respectively, then
A. P s
= P
∘
2x 2
B. P ∘
− Ps = P
∘
x2
C. P s
= P
∘
x1
D. (P ∘
− Ps ) / Ps = x 1 / (x 1 + x 2 )
Answer: B::C
and temperature (T )?
1
A. π ∝ if T is constant
V
B. π ∝ T if V is constant
C. π ∝ V if T is constant
D. πV is constant if T is constant
Answer: A::B::D
concentration of a solution?
A. Molarity
B. Molality
C. Normality
D. Mole fraction
Answer: B::D
independent of temperture?
A. Mass percentage
B. Volume percentage
C. Strength
D. Molarity
Answer: A::B
A. temperature
B. surface area
C. nature of liquid
D. external pressure
Answer: A::C
Answer: A::B::C
C. ΔH mixing
is positive
D. ΔH mixing
is negative
Answer: A::C
B. ΔH mixing
is negative
C. ΔV mixing
is negative
interactions.
Answer: A::B::C::D
Watch Video Solution
A. The vapour pressure of the solution is less than that of pure water
solvent
Answer: A::D
11. An azeotropic solution of two liquids has a boiling point lower than
D. is saturated
Answer: C
A. intermolecular forces
B. potential energy
C. temperature
D. None of these
Answer: D
Answer: A
iodide, then:
Answer: A
independent of temperature?
A. Molarity
B. Normality
C. Formality
D. Molality
Answer: D
A. C6
H5 N H3 CI (aniline hydrochloride)
B. Ca(N O 3
)
2
C. La(N O 3
)
3
D. C6
H12 O6 (glucose)
Answer: D
A. 0.33
B. 0.066
C. 0.3 × 10 −2
D. 3
Answer: C
A. decrease in molality
B. decrease in molarity
D. decrease in % (ww).
Answer: B
the solute is
A. 180
B. 90
C. 270
D. 200
Answer: A
volume
A. 0.4
B. 0.1
C. 0.2
D. 0.8
Answer: B
of dissociation is
A. 91.3 %
B. 87 %
C. 100 %
D. 74 %
Answer: B
Watch Video Solution
A. 40 mL
B. 20 mL
C. 10 mL
D. 4 mL
Answer: A
equilibrium:
A. liquid solvent, solid solvent
Answer: A
N a2 SO4 is
A. 25 %
B. 50 %
C. 75 %
D. 85 %
Answer: C
25. The elevation in boiling point, when 13.44g of freshly prepared CuCI
2
−1
Kb (H2 O) = 0.52kgKmol , mol.wt ofCuCI2 = 134.4gm]
A. 0.05
B. 0.10
C. 0.16
D. 0.20
Answer: C
A. 2.28molkg −1
B. 0.44molkg −1
C. 1.14molkg −1
D. 3.28molkg −1
Answer: A
27. 18g of glucose (C6 H12 O6 ) is added to 178.2g of water. The vapour
A. 76.00 Torr
B. 752.40 Torr
C. 759.00 Torr
D. 7.60 Torr
Answer: B
rates
Answer: A
Answer: D
30. A 5 % solution (by mass) of cane sugar in water has freezing point of
271 K. Calculate the freezing point of a 5% glucose (by mass) in water. The
A. 271K
B. 273.15K
C. 269.07K
D. 277.23K
Answer: C
a density of 1.80gmL
−1
. Volume of acid required to make one litre of
A. 5.55mL
B. 11.10mL
C. 16.65mL
D. 22.20mL
Answer: A
solution is
A. − 0.56K
B. − 1.12K
C. 0.56K
D. 1.12K
Answer: D
A. 1.45
B. 1.04
C. 1.88
D. 1.22
Answer: D
A. 210.0gmol −1
B. 90.0gmol −1
C. 115.0gmol −1
D. 105.0
Answer: A
Watch Video Solution
A. 0.5
B. 1
C. 2
D. 3
Answer: A
36. At 80 ∘
C , the vapour pressure of pure liquid 'A' is 520 mm Hg and that
= 760mmH g)
A. 48 mol percent
B. 50 mol percent
C. 52 mol percent
D. 34 mol percent
Answer: B
A. 16.500mmH g
B. 17.325mmH g
C. 17.675mmH g
D. 15.750mmH g
Answer: B
freezes at − 0.00732
∘
C .Number of moles of ions which 1 mole of ionic
A. 1
B. 2
C. 3
D. 4
Answer: B
of the solution ?
law
law.
Answer: B
40. The Henry's law constant for the solubility of N gas in water at 298K
2
is 5
1.0 × 10 atm . The mole fraction of N2 in air is . The number of
0.8
moles of N from air dissolved in
2
10 moles of water at 298K and 5atm .
Pressure is:
A. 4 × 10 −4
B. 4.0 × 10 −5
C. 5 × 10 −4
D. 4.0 × 10 −6
Answer: A
41. An aqueous solution is 1.00 molal in KI . Which change will cause the
A. addition of N a 2
SO4
C. addition of water
D. addition of NaCI
Answer: C
A. − 0.520 ∘
C
B. + 0.372 ∘
C
C. − 0.570 ∘
C
D. − 0.372 ∘
C
Answer: D
i − 1
A. α =
x + y + 1
x + y − 1
B. α =
i − 1
x + y + 1
C. α =
i − 1
i − 1
D. α =
x + y − 1
Answer: D
freezing at −6
∘
C will be (Kf for water = 1.86Kkgmol
−1
, and molar
A. 204.30g
B. 400.08g
C. 304.60g
D. 804.32g
Answer: D
A. 0.190
B. 0.080
C. 0.050
D. 0.100
Answer: D
− 3.82
∘
C . Calculate the van't Hoff factor for N a 2
SO4 .
A. 3.11
B. 0.381
C. 2.05
D. 2.61
Answer: D
A. 1.78M
B. 2.00M
C. 2.05M
D. 2.22M
Answer: C
Paragraph 1
water −1
(K = 1.86Kkgmol )
f
ethanol −1
(K ) = 2.0Kkgmol )
f
water −1
(K ) = 0.52Kkgmol )
b
A. 268.7K
B. 268.5K
C. 234.2K
D. 150.9K
Answer: D
Watch Video Solution
Paragraph 2
does not after the properties of either liquid. Hence liquid exerts its own
point of any system is the temperature at which its total vapour pressure
If we mix two immiscible liquids A and B then boiling point of the mixture
will be (Given p
A
∘
> p
B
∘
)
Paragraph
water −1
(K = 1.86Kkgmol )
f
ethanol −1
(K ) = 2.0Kkgmol )
f
water −1
(K ) = 0.52Kkgmol )
b
ethanol −1
(K ) = 1.2Kkgmol )
b
A. 39.3mmH g
B. 36.0mmH g
C. 29.5mmH g
D. 28.8mmH g
Answer: B
water −1
(K = 1.86Kkgmol )
f
ethanol −1
(K ) = 2.0Kkgmol )
f
water −1
(K ) = 0.52Kkgmol )
b
ethanol −1
(K ) = 1.2Kkgmol )
b
Water is added to the solution M such that the mole fraction of water in
A. 380.4K
B. 376.2K
C. 375.5K
D. 354.7K
Answer: B
does not after the properties of either liquid. Hence liquid exerts its own
point of any system is the temperature at which its total vapour pressure
D. Mixture of N2
(g) and O 2
(g)
Answer: A
does not after the properties of either liquid. Hence liquid exerts its own
point of any system is the temperature at which its total vapour pressure
in liquid solution are 0.45 and .55 respectivel. Then find out the total
300 K.
A. 104.25mm of Hg
B. 205mm of Hg
C. 27.75mm of hg
D. 35 mm of Hg
Answer: B
does not after the properties of either liquid. Hence liquid exerts its own
point of any system is the temperature at which its total vapour pressure
becomes equal to the prevailing pressure, so by knowing the miscibility of
what will be the effect on the boiling point of the mixture at constant
temperature?
B. Decrease
C. Increases
D. Can't predict
Answer: A
does not after the properties of either liquid. Hence liquid exerts its own
point of any system is the temperature at which its total vapour pressure
becomes equal to the prevailing pressure, so by knowing the miscibility of
is done. If p
∘
quinoline
= 7.9 torr and p
∘
water
= 732.04 torr at the boiling
point of 98.9
∘
C . Find out the relative masses of water and quinoline in
A. W water
: Wquinoline : : 13 : 1
B. W water
: Wquinoline : : 1 : 1
C. W water
: Wquinoline : : 1 : 14
D. W Water
: Wquinoline : : 7.1 : 1
Answer: A
following example. If the correct matches are A-p, A-s, B-q, B-r, C-p, C-q and
ColumnI ColumnII
following example. If the correct matches are A-p, A-s, B-q, B-r, C-p, C-q and
ColumnI ColumnII
solution of urea (mol mass = 60) and 100mL of 3.42 % of cane sugar
0.86 is.........
factor is.....
Answer: D
2. Assertion : The molality of the solution does not change with change in
tempc- nature.
Answer: A
Reason: Ethyl alcohol and water form non ideal solution with negative
deviation.
Answer: C
4. Assertion: ΔH mix
and ΔV mix
for an ideal solution is zero
Answer: A
Answer: A
Watch Video Solution
Answer: A
7. Assertion: Van't Hoff' s factor for benzoic acid is less than one.
Answer: C
osmotic pressure.
Reason: A normal solution means a solution in which the solute does not
associate or dissociate.
Answer: C
solution is unity.
Answer: C
Answer: A
Answer: C
dissolving one mole of each of the solute in 1000g of water, they will
Answer: A
dissolving one mole of each of the solute in 1000g of water they will show
different lowering in freezing point.
Answer: C
concentrations.
Reason: Solution which have the same osmotic pressure at the same
Answer: A
Answer: A
at a given temperature.
Answer: D
Reason: The solutions which follow the Raoult's law at any temperature
and concentration are known as ideal solution.Most of the solution show
Answer: A
Answer: A
undergo dissociation.
Answer: C
View Text Solution
Answer: B
B. 298K
C. 277K
D. none of these
Answer: C
0
∘
C . The mass of ice
Answer: C
Watch Video Solution
D. none of these
Answer: D
Answer: A
D. None of these
Answer: C
D. None of these
Answer: A
7. The beakers A and B containing pure water (A) and an aqueous solution
of sugar (B) are placed in a closed glass container. The temperature of the
with time
with time
Answer: A
A. low temperatures
B. high temperatures
C. normal temperatures
D. None of these
Answer: D
time
D. none of these
Answer: B
A. − 0.15 ∘
C
B. + 0.15 ∘
C
C. − 0.51 ∘
C
D. − 0.17 ∘
C
Answer: A
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