Books Doubtnut Question Bank

CHEMISTRY
BOOKS - A2Z CHEMISTRY (HINGLISH)
SOLUTIONS
Method Of Expressing Concentration Of Solutions
1. Which of the following concentration factors is affected by changing in
volume or volume dependent ?
A. weight fraction
B. Mole fraction
C. Molality
D. Molarity
Answer: D
Watch Video Solution
2. Calculates the masses of cane sugar and water required to prepare 250
grams of 25 % cane sugar solution-
A. 187.5 grams, 62.5 grams
B. 62.5 grams, 187.5 grams
C. 162.5 grams, 87.5 grams
D. None of these
Answer: B
3. A solution of Al2 (SO4 ) {d = 1.253gm / ml}

3
contain 22 % salt by
weight. The molarity, normality and molality of the solution is
A. 0.825M , 48.3N , 0.805 m

B. 0.805M , 4.83N , 0.825 m
C. 4.83M , 4.83N , 4.83 m
D. None
Answer: B
4. 6.02 × 10 20
molecules of urea are present in 200mL of its solution. The
concentration of urea solution is (N 0

= 6.02 × 10
23
mol
−1
)
A. 0.001M
B. 0.01M
C. 0.02M
D. 0.10M
Answer: C

5. Calculates the molarity and normality of a solution containing 0.5 g of
N aOH dissolved in 500ml solution
A. 0.0025M , 0.025N
B. 0.025M , 0.025N
C. 0.25M , 0.25N
D. 0.025M , 0.0025N
Answer: B
6. If 25ml of N aCl solution is diluted with water to a volume of 500ml
the new concentration of the solution is
A. 0.0125M
B. 0.167M
C. 0.833M
D. 0.0167M
Answer: A
7. An X molal solution of a compound in benzene has mole fraction of
solute = 0.2. The value of X is
A. 14.0
B. 3.2
C. 1.4
D. 2.0
Answer: B

8. Hardness of a water sample is 100ppm CaCO3 . Thus molarity of
CaCO3 is
A. 2 × 10 −3
M
B. 1 × 10 −3
M
C. 2 × 10 −2
M
D. 2 × 10 −4
M
Answer: B
9. Molarity and molality of a solution of caustic soda are respectively
11.12M and 94.12m. The density of the solution is
A. 0.556gmL −1
B. 5.56gmL −1
C. 55.6gmL −1
D. none of these
Answer: A
10. 5ml of H Cl, 20ml of N /2 of H2 SO4 and 30ml of N / 3H N O3 are
mixed together and volume made to one litre.
N
A.
40
N
B.
10
N
C.
20
N
D.
5
Answer: A

11. At 25
∘
C , the density of 15M H2 SO4 is 1.8gcm
−3
. Thus mass
percentage of H 2
SO4 in aqueous solution is
A. 2 %
B. 81.6 %
C. 18 %
D. 1.8 %
Answer: B
12. Which of the following aqueous solutions has the highest
concentration of N a +
?
A. 0.304M N a 2
SO4
B. A solution containing 2.06gN aCl / 100mL
C. A solution having 15.4mgN a +

/ mL
D. All have equal[N a +
]
Answer: C
13. Mole fraction of C

3
H5 (OH )
3
in a solution of 36g of water and 46g of
glycerine is :
A. 0.46
B. 0.36
C. 0.20
D. 0.40
Answer: C

14. In what ratio should a 6.5N H N O3 be diluted with water to get
3.5N H N O3 ?
A. 6 : 7
B. 7 : 6
C. 5 : 6
D. 6 : 5
Answer: B
15. The molality of a urea solution in which 0.0100g of urea, [(N H 2

) CO]
2
is added to 0.3000dm of water at STP is

3
A. 0.555m
B. 5.55 × 10 −4
m
C. 33.3m
D. 3.33 × 10 −2
m
Answer: B
16. 15 grams of methyl alcohol is dissolved in 35 grams of water. What is
the mass percentage of methyl alcohol in solution ?
A. 30 %
B. 50 %
C. 70 %
D. 75 %
Answer: A

17. A 3.5 molal aqueous solution of methyl alcohol (CH3 OH ) is supplied.
What is the mole fraction of methyl alcohol in the solution ?
A. 0.100
B. 0.059
C. 0.086
D. 0.050
Answer: B
18. In which mode of expression, the concentration of a solution remains
independent of temperature?
A. Molarity
B. Normality
C. formality
D. Molality
Answer: D
19. The density of a solution containing 13 % by mass of sulphuric acid is
1.09g / mL . Calculate the molarity and normality of the solution
A. 1.445M
B. 14.45M
C. 144.5M
D. 0.1445M
Answer: A

20. Calculate the molarity of pure water(d = 1g / L)
A. 555M
B. 5.55M
C. 55.5M
D. None
Answer: C
21. Calculate the quantity of sodium carbonates(anhydrous ) required to
prepare 250ml solution
A. 2.65grams
B. 4.95grams
C. 6.25grams
D. None of these
Answer: A
22. 20ml of 0.02M KM nO4 was required to completely oxidise 10ml of
oxalic acid solution. What is the molarity of the oxalic acid solution ?
A. 0.1M
B. 0.4M
C. 1.0M
D. 4.0M
Answer: A
23. Find the molality ofH 2

SO4 solution whose specific gravity is
1.98gml
−1
and 95 % by volume H 2
SO4
A. 7.412
B. 8.412
C. 9.412
D. 10.412
Answer: C
24. Calculate the molality of 1L solution of 93 % H 2

SO4 (Weight/volume)
The density of the solution is 1.84g.
A. 9.42
B. 10.42
C. 11.42
D. 12.42
Answer: B
25. Suppose 5g of acetic acid are dissolved in one litre of ethanol. Assume
no reaction in between them. Calculate molality of resulting solution if
density of ethanol is 0.789 / mL.
A. 0.0856
B. 0.0956
C. 0.1056
D. 0.1156
Answer: C
26. Calculate the molarity and mole fraction of the solute in aqueous
solution containing 3.0g of urea per 250gm of water (Mol. Wt. of urea =
60)
A. 0.2m, 0.00357
B. 0.4m, 0.00357
C. 0.5m, 0.00357
D. 0.7m, 0.00357
Answer: A
27. A solution has 25 % of water,25 % ethanol and 50 % acetic acid by
mass. Calculate the mol e fraction of each component.
A. 0.50, 0.3, 0.19
B. 0.19, 0.3, 0.50
C. 0.3, 0.19, 0.50
D. 0.50, 0.19, 0.3
Answer: D
28. Calculate normality of the mixture obtained by mixing 100ml of
0.1N H Cl and 50ml of 0.25N N aOH solution
A. 0.0467N
B. 0.0367N
C. 0.0267N
D. 0.0167N
Answer: D
29. 300 ml 0.1 M HCl and 200ml of 0.03M H 2

SO4 are mixed. Calculate the
normality of the resulting mixture
A. 0.084N
B. 0.84N
C. 2.04N
D. 2.84N
Answer: A
30. How many kilograms of wet N aOH containing 12 % water are
required to prepare 60 litre of 0.50 N solution ?
A. 1.36Kg
B. 1.50Kg
C. 2.40Kg
D. 4.16
Answer: A

31. 250 mL of a N a2 CO3 solution contains 2.65g of N a2 CO3 . 10mL of
this solution is added to xml of water is obtain 0.001M N a 2

CO3 solution.
The value of x is :
A. 1000
B. 990
C. 9990
D. 90
Answer: B
32. The volumes of two H Cl solution A (0.5M ) and B (0.1M ) to be
mixed for preparing 2 L of 0.2 M H Cl are
A. 0.5L of A + 1.5L of B
B. 1.5L of A + 0.5L of B
C. 1L of A + 1L of B
D. 0.75L of A + 1.25L of B
Answer: A
33. Molality of a solution in aqueous medium is . Calculate its more

0.8
fraction and the percentage by mass of solute if molar mass of solute is
60
A. 4.5 %
B. 4.6 %
C. 4.7 %
D. 4.8 %
Answer: A
34. Two bottles A and B contain 2M and 2m aqueous solution of sulphuric
acid respectively , then
A. A is more concentrated than B
B. B is more concentrated than A
C. Conc. Of A and B are equal.
D. it is important to compare the concentrations
Answer: A
35. What weight of oxalic acid (H2 C2 O4 .2H2 O) is required to prepare
1000mL of N / 10solution?
A. 9.0g
B. 12.6g
C. 6.3g
D. 4.5g
Answer: C
36. A solution contain 1.2046 × 10

24
hydrochloric acid molecules in one
dm
3
of the solution . The strength of the solution is
A. 6N
B. 2N
C. 4N
D. 8N
Answer: B

Relative Lowering Of Vapour Pressure
1. Define molal elevation constant or ebullioscopic constant.
A. the elevation in b.p. which would be produced by dissolving one
mole of solute in 100g of solvent
B. the elevation in b.p. which would be produced by dissolving 1 mole
of solute in 10g of solvent
C. the elevation in b.p. which would be produced by dissolving 1 mole
of solute in 1000g of solvent
D. None of these
Answer: C

2. Mixture of volatile components A and B has a total vapour pressure (in
torr)p=254 − 119x is wherex mole fraction of A in mixture .HenceP

A A
A
∘
and P are(in torr)

∘
B
A. 254, 119
B. 119, 254
C. 135, 254
D. 119, 373
Answer: C
3. The vapour pressure of pure liquid solvent 0.50 atm. When a non-
volatile solute B is added to the solvent, its vapour pressure drops to 0.30
atm. Thus, mole fraction of the component B is
A. 0.6
B. 0.25
C. 0.45
D. 0.75
Answer: A
4. The vapour pressure of pure liquid A is 10 torr and at the same
temperature when 1 g solid B is dissolved in 20g of A , its vapour pressure
is reduced to9.0torr . If the molecular mass of A is 200amu , then the
molecular mass of B is
A. 100amu
B. 90amu
C. 75amu
D. 120amu
Answer: B
5. Calculate the mass of a non-volatile solute ( molecular mass ) which

40
should be dissolved in 114g octane to reduce its vapour pressure to 80 %
A. 20g
B. 30g
C. 10g
D. 40g
Answer: C

6. Vapour pressure of CCL at 25 4
∘
C is 143 mmHg 0.05g of a non-volatile
solute (mol.wt.=65)is dissolved in 100mlCCL4 . find the vapour pressure
of the solution (density of CCL 4

= 158g / cm
2
)
A. 143.99mm
B. 94.39mm
C. 199.34mm
D. 14.197mm
Answer: D
7. Aqueous tension is the vapour pressure of ........ And depends only upon
.........
A. Surface of area container
B. Volume of container
C. Temperature
D. All of the above
Answer: C
8. Among the following substances, the lowest vapour pressure is exerted
by
A. Water
B. Mercury
C. Kerosene
D. Rectified spirit
Answer: B

9. The vapour pressure of pure liquid solvent A is 0.80 atm.When a non
volatile substances B is added to the solvent, its vapour pressure drops
to 0.60atm. Mole fraction of the components B in the solution is:
A. 0.50
B. 0.25
C. 0.75
D. 0.40
Answer: B
10. 18g of glucose (C6 H12 O6 ) is added to 178.2 g of water. The vapour
pressure of water for this aqueous solution at 100 ∘

C is :
A. 752.40torr
B. 759.00torr
C. 7.60torr
D. 76.00torr
Answer: A
11. Two liquids X and Y from an ideal solution at300K, Vapour pressure of
the Solution containing 1mol of X and 3mol of Y is 550 mmHg . At the
same temperature, if 1 mol of Y is further added to this solution ,vapour
pressur of the solutions increases by 100mmHg Vapour pressure (in
mmHg) of X and Y in their pure states will be,respectively
A. 200and300
B. 300 and 400
C. 400 and 600
D. 500 and 600
Answer: C
12. An ideal solution has equal mol-fraction f two volatile components A
and B .in the vapour above the solutions, the mol -fractions of A and B :
A. Are equal both 0.50
B. Are equal but necessarily0.50
C. Are not very likely to be equal
D. Are 1.00 and 0.00resepctively
Answer: B
13. The vapour pressure of pure water at 75

∘
is torr the vapour
296
pressure lowering due to 0.1m solute is
A. 0.533torr
B. 0.296torr
C. 0.333 torr
D. 0.428 torr
Answer: A
14. A sample of 20.0g of a compound (molecular weight 120 )which is non
electrolyte is dissolved in grams of ethanol(C

10.0 2
H5 OH ) . If the vapour
pressure of pure ethanol at the temperature used is 0.250 atm ,what is
the vapour pressure of ethanol above the solution
A. 0.250atm
B. 0.83atm
C. 0.125atm
D. 0.141atm
Answer: D
15. At 120 ∘
C , the vapour pressure of pure cholorobenzene (C 6
H (5)Cl) is
0.736atm. What is the vapour pressure of a solution of 5.00g of
naphthalene (C10 H8 in g
50.0 of chlorobenzene? (assume that
naphthalene is not volatile)
A. 0.736atm
B. 0.091atm
C. 0.677atm
D. 1.00atm
Answer: C

16. Calculate the vapour pressure of a solution at 100 ∘
C containing 3g of
cane sugar in 33g of water.(Atwt.C =12,h=1,O=16)
A. 760mm
B. 756.90mm
C. 758.30mm
D. None of these
Answer: B
17. Lowering of vapour pressure due to a solute in 1 molal aqueous
solution at 100 ∘
C is
a.13.44mmH g ,b. 14.14mmH g ,c.13.2mmH g ,d. 35.2mmH g
A. 13.44mmHg
B. 14.12mmHg
C. 31.2mmHg
D. 35.2mmHg
Answer: A
18. The vapour pressure of a dilute aqueous solution of glucose is 750
mmHg at 373K. The mole fraction of the solute is
1
A.
76
1
B.
7.6
1
C.
38
1
D.
10
Answer: A

19. When 3g of a novolatile solute is dissolved in 50 g of water , the
relative lowering of vapour pressure observed is 0.018N m

−2
. Molecular
weight of the substances is
A. 60
B. 30
C. 40
D. 120
Answer: A
20. One mole of non-volatile solute is dissolved in two moles of water. The
vapour pressure of the solution relative to that water of
A. 2 / 3
B. 1 / 3
C. 1 / 2
D. 3 / 2
Answer: A
21. Dry air was passed successively through a solution of 5g of a solute in
180g water and then through pure water. The loss in weight of
solutionwas 250 g and that of pure solvent g . The molecular weight

0.04
of the solute is
A. 31.25
B. 3.125
C. 312.5
D. None of these
Answer: A
22. The vapour pressure of solvent is 20 torr, while that of its dilute
solution is 17 torr, the mole-fraction of the solvent is
A. 0.6
B. 0.85
C. 0.5
D. 0.7
Answer: B
23. Relative decrease in vapour pressure of an aqueous solution
conataining 2mol
1
[Cu(N H3 ) Cl]
3
Cl in 3mol H2 is . When the given solution reation with
2
excess fo AgN O solution the number moles of AgClproduced is

3
A. 1molAgCl
B. 0.25molAgCl
C. 2molAgCl
D. 0.40molAgCl
Answer: A
24. The degree of dissociation of Ca(N O 3

)
2
in a dilute aqueous solution
containing 7g of salt per 100g of water at 100

∘
C is 70 % . Calculate the
vapour pressure of solution.
A. 748.2 mmHg
B. 1492.6 mmHg
C. 373.2 mmHg
D. 74.03 mmHg
Answer: A
Elevation Of Boiling Point
1. Normal boiling point (TN ) is defined as the temperature when V.P. of
liquid become equal to 1atm and standard boiling point (TS ) is defind
becomes equal to 1bar . Which one is not correct .if water is considered?
A. T N
= 100
∘
C
B. T S
> 100
∘
C
C. T S
< 100
∘
C
D. T S
< TN
Answer: B

2. A solution containing 28g of phosphorus in 315 g CS 2
(b. p.46.3
∘
C boils
at 47.98 ∘
C . If k for CS is 2.34K kg
b 2
mol
−1
. The formula of phosphorus is
(at .massof P=31).
A. P 6
B. P 4
C. P 3
D. P 2
Answer: B
3. Elevation in boiling point of an aqueous solution of a non-electroluyte
solute is 2.01 . What is the depression in freezing point of the solution ?

∘
∘ −1
Kb (H2 O) = 0.52 mol kg
∘ −1
Kf (H2 O) = 1.86 mol kg
A. 7.17 ∘
B. 0.52 ∘
C. 3.57 ∘
D. 0.93 ∘
Answer: A
4. Y g of non-volatile organic substance of molecular mass M is dissolved
in 250g benzene. Molal elevation constant of benzene is Kb . Elevation in
its boiling point is given by:s
A. 1.34K b
B. 0.98K b
C. 2.40K b
D. K b
Answer: B
5. Elevation in boiling point of a molar (1M ) glucose solution
(d = 1.2gml − 1 ) is
A. 1.34K b
B. 0.98K b
C. 2.40K b
D. K b
Answer: B
6. g of a subatance dissolved in
0.15 15g of solvent boiled at a
temperature higher at 0.216 than that of the pure solvent. Calculate the
∘
molecular weight of the substance. Molal elecation constant for the
solvent is 2.16 ∘
C
A. 216
B. 100
C. 178
D. None of these
Answer: B
7. H2 O(1) ⇔ H2 O(g) at 373K, ΔH

∘
= 8.31kcalmol
−1
Thus, boiling
point of 0.1 molal sucrose solution is
A. 373.52K
B. 373.052K
C. 373.06K
D. 374.52K
Answer: C
8. A solution of 0.450 g of urea (mol wt. )in

60 22.5g of water showed
0.170
∘
C of elecation in boiling point. Calculate the molal elevation
constant of water
A. 0.17 ∘
C
B. 0.45 ∘
C
C. 0.51 ∘
C
D. 0.30 ∘
C
Answer: C

9. At the higher altitudes the boiling point of water lowers because
A. temperature of higher altitudes is low
B. atmosphere pressure is low
C. the proportion pressure is low
D. atmospheric pressure becomes more.
Answer: B
10. The elevation in boiling point of a solution of 13.44 g of CuCl2
(molecular weight =134.4, k b

= 0.52Kmolality
−1
) in 1 kg water using
the following information will be:
A. 0.16
B. 0.05
C. 0.1
D. 0.2
Answer: A
11. Which aqueous will have the highest boiling point?
A. 0.015M glucose
B. 0.01M KN O 3
C. 0.015M urea
D. 0.01M N a 2
SO4
Answer: D

12. A solution containing 28 g of phosphorus in g
315 CS2 (b. p.46.3
∘
C
boils at 47.98
∘
C . If kb for CS2 is 2.34K kg mol
−1
. The formula of
phosphorus is (at .massof P=31).
A. P 4
B. P 8
C. P 2
D. None of these
Answer: B
13. A solution of urea in water has boiling point of 100.15

∘
C . Calculate
the freezing point of the same solution if Kf and Kb for water are
1.87Kkgmol
−1
and 0.52Kkgmol −1
, respectively.
A. − 0.54 ∘
C
B. − 0.44 ∘
C
C. − 0.64 ∘
C
D. − 0.34 ∘
C
Answer: A
14. Calculate the normal boiling point of a sample of sea water found to
contain3.5 % of N aCl and 0.13 % of M gCl by mass. The normal boiling

2
of point of water is 100

∘
C and Kb (water) = 0.51Kkgmol
−1
. Assume
that both the salts are completely ionised.
A. 100.655 ∘
C
B. 99.655 ∘
C
C. 101.655 ∘
C
D. 102.655 ∘
C
Answer: A
15. Which will have largest ΔT ?

b
A. 180g glucose in 1kg water
B. 342g sucrose in 1, 000kg water
C. 18g glucose in 100kg water
D. 65g urea in 1kg water
Answer: D
16. An aqueous solution of glucose boils at 100.01 ∘

C .The molal elevation
constant for water is 0.5kmol

−1
kg . The number of molecules of glucose
in the solution containing 100g of water is

A. 6.023 × 10 23
B. 6.023 × 10 22
C. 12.046 × 10 20
D. 12.046 × 10 23
Answer: C
17. The latent heat of vaporisation of water is 9700Cal/mole and if the
b.p.is 100 ∘
C , ebullioscopic constant of water is
A. 0.513 ∘
C
B. 1.026 ∘
C
C. 10.26 ∘
C
D. 1.832 ∘
C
Answer: A
18. If for the sucrose solution elevation in boiling point is 0.1

∘
C then
what will be the boiling point of NaCl solution for same molal
concentration
A. 0.1 ∘
C
B. 0.2 ∘
C
C. 0.08 ∘
C
D. 0.01 ∘
C
Answer: B
19. The molal boiling point constant for water is 0.513 ∘

Ckgmol
−1
. When
0.1mole of sugar is dissolved in ml of water , the solution boils under

200
a pressure of one atmosphere at

A. 100.513 ∘
C
B. 100.0513 ∘
C
C. 100.256 ∘
C
D. 101.025 ∘
C
Answer: C
20. 0.01(M ) solution an acid HA freezes at − 0.0205 ∘

C . If K for water is
f
1.86Kkgmol
−1
, the ionization constant of the conjugate base of the acid
will be (consider molarity) ≅ molarity)
A. 1.1 × 10 −4
B. 1.1 × 10 −3
C. 9 × 10 − 11
D. 9 × 10 − 12
Answer: C
21. The boiling point of 0.1mK4 [F e(CN ) ]

6
is expected to be (Kb for
water = 0.52Kkgmol −1
)
A. 100.52 ∘
C
B. 100.10 ∘
C
C. 100.26 ∘
C
D. 102.6 ∘
C
Answer: C
Depression Of Freezing Point

1. The value of K for water is 1.86 , calculated from glucose solution, The
f
∘
value of K for water calculated for NaCl solution will be,

f
A. = 1.86
B. < 1.86
C. > 1.86
D. zero
Answer: A
2. A solution of x moles of sucrose in grams of water freeze at

100
− 0.2
∘
C As. Ice separates the freezing point goes down to 0.25
∘
C . How
many grams of ice would have separated ?
A. 18grams
B. 20grams
C. 25grams
D. 23grams
Answer: B
3. The freezing point of the dilute solution of acetamide in glacial acetic
acid is 298K. This is the value when crystals of
A. Acetamide first appears
B. Acetic acid from appears
C. Both appear together
D. Ice first appears
Answer: B

4. A solution of a non-volatile solute in water freezes at − 0.40
∘
C . The
vapour pressure of pure water at 298K is 23.51 torr. For water,
Kf = 1.86kmol
−1
kg .Thus ,vapour pressure of the solution (in torr)
A. 23.44
B. 19.64
C. 20.41
D. 22.47
Answer: B
5. In which case depression freezing point is equal to cryscopic for water:
A. 6 % by mass of urea in aqueous solution
B. 100gof sucrose in 100mL solution
C. 9g of urea in 59g aqueous solution

D. 1M KCl solution
Answer: C
6. What frezing point depression would be predicted for 0.2molal
solution of benzoic acid in benzene if latent heat of fusion is 40.00calg −1
at (freezing point)for benzene ?(assume no change in molecular state)
A. 0.52 ∘
B. 5.2 ∘
C. 0.0052 ∘
D. 0.78 ∘
Answer: D

7. How much ethyl alcohol must be added to 1.00L of water so that the
solution will not freeze at − 4 ∘

F ?
A. 122g
B. 512g
C. 670g
D. 495g
Answer: C
8. The amount of urea to be dissolved in 500 cc of water (Kf = 1.86) to
produce a depresssion of 0.186 ∘

C in the freezing point is :
A. 9g
B. 6g
C. 3g
D. 0.3g
Answer: C
9. Freezing point of an aqueous solution is − 0.186

∘
C . Elevation of
boiling point of the same solution is ……..if Kb = 0.512Kmolality

−1
and
Kf = 1.86Kmolality
−1
:
A. 0.186 ∘
C
B. 0.0512 ∘
C
C. 0.092 ∘
C
D. 0.237 ∘
C
Answer: B

10. Equimolar solutions of two non-electroytes in the same solvent have:
A. same b.pt. but different f.pt.
B. same f.pt. but different p.pt.
C. same b.pt. but same f.pt.
D. Different b.pt. but different f.pt.
Answer: C
11. What should be the freezing point of aqueous solution containing 17g
of C2
H (5)OH is 1000g of water (K for water =1.86degkgmol
f
−1
)?
A. − 0.69 ∘
C
B. 0.34 ∘
C
C. 0.0 ∘
C
D. − 0.34 ∘
C
Answer: A
12. Ethylene glycol is used as an antifreeze in a cold cliamate Mass of
ethylene glycol which should be added to 4 kg for water to prevent it
from freezing at −6
∘
C will be (K for water =1.86Kkgmol
f
−1
and molar
mass of ethylene glycol =62gmol −1

)
A. 800g
B. 204.30g
C. 400.00g
D. 304.60g
Answer: A

13. 0.48g of a substance is dissolved in 10.6 g of C
6
H6 .The freezing point
of benzene is lowered by 108 ∘

C . What will be the mol.wt. of the (K for f
benzene =5)
A. 250.2
B. 90.8
C. 125.79
D. 102.5
Answer: C
14. The freezing point of equimolal soution will be highest for :
A. C6
H5 N H3 Cl
B. Ca(N o 3
)
2
C. La(N O 3
)
3
D. C 6
H12 O6
Answer: D
15. The freezing point of 0.2molal K2 SO4 is − 1.1

∘
C . Calculate van't Hoff
factor and percentage degree of dissociation of K2 SO4 . Kf for water is
∘
1.86
A. 97.5
B. 90.75
C. 105.5
D. 85.75
Answer: A

16. A certain substance A tetramerizes in water to the extent of 80 % .A
solution of 2.5g of A in 100g of water lowers the freezing point by 0.3 ∘

C .
The molar mass of A is
a.120 , b.61 ,c.60 ,d.62
A. 122
B. 31
C. 244
D. 62
Answer: D
17. The freezing point of a solution containing 50cm of ethylene glycol in

3
50g of water is found to be − 34

∘
C . Assuming ideal behaviour, Calculate
the density of ethylene glycol (K for water = 1.86Kkgmol

f
−1
).
A. 1.13g / cm 3
B. 2.00g / cm 3
C. 1.8g / cm 3
D. 2.25g / cm 3
Answer: A
18. Cryoscopic constant of a liquid
A. is the decrease in freezing point when 1g of solute is dissolved per
kg of the solvent
B. is the decrease in the freezing point when 1mole of solute of
dissolved per kg of the solvent
C. is the elevation for 1 molar solution
D. is a factor used for calculation of depression in freezing point
Answer: B
View Text Solution
19. Addition of 0.643g of compound to 50ml of benzene (density
= 0.879mol
−1
) lower the freezing point from50.51 ∘
C . If k for benzene
f
is 5.12 the molecule of the compound is
A. 156.00
B. 312.00
C. 78.00
D. 468.000
Answer: A
20. Which of the following solution will have highest freezing point?
A. 2M N aCl Solution
B. 1.5M AlCl Solution
3
C. 1M Al 2
(SO3 )
4
Solution
D. 3M U rea Solution
Answer: D
21. 0.48of a substance is dissolved in 10.6g of C6

H6 .The freezing point of
benzene is lowered by 1.8 ∘

C what will be the mol.wt.of the substance (K f
for benzene =5)
A. 250.2
B. 90.8
C. 125.79
D. 102.5
Answer: C
22. What is the freezing point of a solution containing 8.1gBr in 100g
water assuming the acid to be 90 % ionised(K for water =1.8Kmole

f
−1
)
A. 0.85 ∘
C
B. − 3.53 ∘
C
C. 0 ∘
C
D. − 0.35 ∘
C
Answer: B
23. The freezing point of one molal N aClsolution assuming N aCl to be
100 % dissociated in water is (molal depression constant=1.86)
A. − 1.86 ∘
C
B. − 3.72 ∘
C
C. + 1.8 ∘
C
D. + 3.72 ∘
C
Answer: B
24. Which of the following aqueous molal solution have highest freezing
point
A. Urea
B. Barium chloride
C. Potassium bromide
D. Alluminimum sulphate
Answer: A

25. When a solution w g of urea in Kg of water is cooled to
1
− 0.372
∘
C, 200g of ice is separated .If K for water is 1.86KKgmol
f
−1
,w is
A. 4.8g
B. 12.0g
C. 9.6g
D. 6.0g
Answer: C
26. N aCl is added to1 litre water to such an extent that ΔTf / Kf
1
becomes to ,wt.of N aCl added to
500
A. 5.85g
B. 0.585g
C. 0.0585g
D. 0.0855g
Answer: C
27. Increasing amoutn of H gI is added to

2
1 litre of an aqueous solution
containing0.1mole of KI .Which of the following graphs does represent
the variation of depression in freezing point of the resulting solution
with the amount of H gI added?

2
A.
B.
C.
D.
Answer: C
View Text Solution
28. 3.24gH g(N O3 )

2
(molecules mass 324)dissolved in 1000 g of water
constitutes a solution having a freezing point − 0.0558

∘
C while 21.68g
of H gCl2 (Molecular mass 271 in 2000g of water constitutes a solution
with a freezing point of .The of water is

∘ 1
− 0.0744 C Kf 1.86KKgmol
.About the state of ionisation of the two solids in water can be inferred
that.
A. H g(N O 3
)
2
is fully ionised but H gCl is fully unionised
2
B. H g(N O 3
)
2
and H gCl2 both are completely ionised
C. H g(N O 3
)
2
is fully unionised but H gCl is fully ionised
2
D. BothH g(N O 3
)
2
and H gCl2 are completely unionised
Answer: A
Osmotic Pressure
1. A living cell contains a solution which is isotonic with (M) sugar

0.3
solution .What osmotic pressure develops when the cell is placed in
0.1(M )KCl solution at body temperature?
A. 5.08 atm
B. 2.54 atm
C. 4.92 atm
D. 2.46 atm
Answer: B
2. Two solution (A)containingF ecl 3

(aq) and(B) semipermeable
membrance as shown below.If F eCl3 on reaction with K4 [F e(CN ) ]

6
,produces blue colour of F e4 [F e(CN ) ]

6
, the clue colour will be noticed
in :
∣ (A) (B) ∣
∣ ∣
∣ F eCl3 K4 [F e(CN ) ] ∣
6
A. (A)
B. (B)
C. in Both (A)and(B)
D. neither in (A)nor in(B)
Answer: D
3. Osmotic pressure of 30 % solution of glucose is 1.20 atm and that of
3.42 % solutin of cane sugar is 2.5 atm, The osmotic pressure of the
mixture containing equal volumes of the two solutions will be
A. 2.5 atm
B. 3.7 atm
C. 1.85 atm
D. 1.3 atm
Answer: C
4. Osmosis is involved in one or more processes.
(I) Interchange of nutrients and waste products between tissue cells and
their surroundings.
(II)Reverse osmosis
(III)Excrection of urine
(IV) Evaporation
Select the correct processes.
A. (I) and (III)
B. (I), (II) and (III)
C. (I), (II) and (IV )
D. All of these
Answer: B
5. The osmotic pressure of blood is atm.at310KAn aqueous solution

7.65
of glucose which is isotonic with blood has the percentage (wt./volume)
A. 5.41
B. 3.54
C. 4.53
D. 53.4
Answer: A
6. If 'A' contains 2% NaCl and is separated by a semipermeable
membrance from 'B' which contain 10 % NaCl ,which event will occur ?
A. N aCl will flow from' A' and' B'
B. N aCl will flow from' B' and' A'
C. water will flow from' A' and' B'
D. water will flow from' B' and' A'
Answer: C

7. Which has maximum osmotic pressure at temperatureT K?
A. 150ml of 1.0M urea solution
B. 210ml of 1.0M urea solution
C. Mixture of 150ml of 1.0M urea solution and 210 mL of 1.0M glucose
solution
D. Allof the above are isotonic solutions
Answer: D
8. What is osmolarity of0.20M KCl solution?
A. 0.10 osmol
B. 0.20 osmol
C. 0.30 osmol
D. 0.40 osmol
Answer: D
9. Osmotic pressure of blood is 7.40 atm at 27

∘
C . Number of mol of
glucose to be used per L for an intravenous injection that is to have the
same osmotic pressure as blood is :
A. 0.3
B. 0.2
C. 0.1
D. 0.4
Answer: A

10. A solution of glucose (C6 H12 O6 ) is isotonic with 4g of urea
(N H2 − CO − N H2 ) per litre of solution .The concentration of glucose
is :
A. 4g / L
B. 8g / L
C. 12g / L
D. 14g / L
Answer: C
11. A solution containing0.5g of a non-volatile solute in 0.2dm

3
of the
solution exerts an osmotic pressure of 44.44kP a at 300K . Thus, molar
mass of the solute is
A. 150gmol −1
B. 300gmol −1
C. 140gmol −1
D. 168gmol −1
Answer: C
12. Which statement is false?
A. Two sucrose solutions of same molality prepare different solvents
have sameΔT f
B. Osmotic pressure ,Π = M RT
C. Osmotic pressure for 0.01M aqueous solutions:
BaCl2 > KCl > Ch 3 COOH > Sucrose
D. The vapour pressure of a component over a solution proportional
to its mole fraction.

Answer: A
13. A 5.25 % solution of a substance is isotonic with a 1.5 % solution of
urea (molar mass=60gmol −1

)in the same solvent.If the densities of both
the solutions are assumed to be equal to 1.0gcm

−3
,molar mass of the
substance will be:
A. 90.0gmol −1
B. 115.0gmol −1
C. 105.0gmol −1
D. 210.0gmol −1
Answer: D

14. Consider the separate solution of
0.500M C2 H5 OH (aq. )0.100M M g3 (P O4 ) (aq. ), 0.250M KBr(aq) and 0.12

2
.What is statement is true about these solutions,assuming all salts to be
strong electrolytes?
A. They all have same osmotic pressure
B. 0.100M M g 3
(P O4 ) (aq)
2
has thehighest osmotic pressure.
C. 0.125M N a 3
(P O4 ) (aq)
2
has the highest osmotic pressure
D. 0.5000M C2
H5 OH (aq) has the highest osmotic pressure.
Answer: A
15. A5 % solution of cane sugar (molar mass =342)is isotonic with 1% of
a solution of an known solute.The molar mass of unknown solute in
g/mol is
A. 136.2
B. 171.2
C. 68.4
D. 34.2
Answer: C
16. Two solutions of KN O3 and CH3 COOH are prepared separately.
Molarity of both is 0.1M and osmotic pressure are P1 and P2
respectively. The correct relationship between the osmotic pressure is :
A. P 2
> P1
B. P 1
= P2
C. P 1
> P2
P1 P2
D. =
P1 + P2 P1 + P2
Answer: C
17. The process of getting fresh water from sea water is known as
A. Osmosis
B. Filtration
C. Desaltation
D. Reverse osmosis
Answer: D
18. The wt.of urea dissolved in 100ml solution which produce an osmotic
pressure of 20.4atm,will be
A. 5g
B. 4g
C. 3g
D. 6g
Answer: A
19. In the phenomenon fo osmosis, the membrance allow passage of :
A. Solute only
B. Solvent only
C. Soth solute and solvent
D. None of these
Answer: B

20. A 5.8 % (wt./vol.)NaCl solution will exert an osmotic pressure closest
to which one of the following
A. 5.8 % (wt. / vol. ) sucrose solution
B. 5.8 % (wt. / vol. ) glucose solution
C. 2molal sucrose solution
D. 1molal sucrose solution
Answer: C
21. Osmotic pressure of a sugar solution at 24

∘
C is 2.5 atmosphere
.Determine the concentration of the solution in gram mole per litre.
A. 0.0821moles/litre
B. 1.082moles/litre
C. 0.1025moles/litre
D. 0.0827moles/litre
Answer: C
22. Blood plasma has the following composition (milliequivalent per
litre.). Calculate its osmotic pressure at 37 ∘

C
+ 2+ + 2+ − −
Na = 138, Ca = 5.2, K = 4.5, M g = 2.0, Cl = 105, H CO =
3
,Proteins =16, Other =1.0
A. 7.47 atm
B. 7.30 atm
C. 7.29 atm
D. 7.40 atm
Answer: A
23. Sea water is 3.5 % by mass of a salt and has a density 1.04gcm
−3
at
293K .Assuming the salt to be sodium chloride ,calculate the osmotic
pressure of sea water.Assume complete ionisation of the salt-
A. 26.93 atm
B. 29.93 atm
C. 28.93 atm
D. 27.93 atm
Answer: B
24. xg of non-electrolytic compound (molar mass =200) is dissolved in
1.0L of 0.05M N aCl solution. The osmotic pressure of this solution is

found to be 4.92atm at 27 ∘
C . Calculate the value of x. Assume complete
dissociation of N aCl and ideal behaviour of this solution.
A. 16.52g
B. 24.032g
C. 19.959g
D. 12.35g
Answer: C
25. Insulin (C 2
H10 O5 )
n
is dissolved in a suitable solvent and the osmotic
pressure (π) of solutions of various concentrations 3

(g / cm )C is
measured at 20
∘
C . The slope of a plot of π against C is found to be
4.65 × 10
−3
. The molecular weight of insulin is:
A. 4.8 × 10 5
B. 9 × 10 5
C. 3 × 10 5
D. 5.17 × 10 6
Answer: D
26. After removing the hard shell of an egg by dissolving in diluteH Cla
semipermeable membrance can be visible .If such an egg is kept in a
saturated solution of common salt, the size of egg will
A. Shrink
B. Grow
C. Remain unchanged
D. First shrink ,then grow
Answer: A

27. 0.5normal sugar solution is isotonic with
A. 1.0normal glucose solution
B. 1.2normal potassium chloride solution
C. 0.5normal urea solution
D. `5% urea solution
Answer: C
28. If a 6.84 % (wt,vol.)solutionof cane sugar(mol.Wt.=342)is isotonic with
1.52 % (wt. / vol. ) solution of thiocarbamide ,then the molecular weight
of thiocarbamide is
A. 152
B. 76
C. 60
D. 180
Answer: B
29. What is the freezing point of a solution contains 10.0g of glucose
C6 H12 O6 , in 100g of H 2
O ?K
f
= 1.86
∘
C /m
A. − 0.186 ∘
C
B. + 0.186 ∘
C
C. − 0.10 ∘
C
D. − 1.03 ∘
C
Answer: D

30. The order of osmotic prssure of equimolar solutions of BaCl 2
, N aCl
and glucose will be:
A. BaCl 2
> N aCl > glucose
B. N aCl > BaCl2 > glucose
C. glucose > BaCl2 > N aCl
D. glucose > N aCl > BaCl2
Answer: A
31. The osmotic pressure of blood is atm.at310KAn aqueous solution

7.65
of glucose which is isotonic with blood has the percentage (wt./volume)
A. 5.41 %
B. 3.54 %
C. 4.53 %
D. 53.4 %
Answer: A
32. A solution containing8, 6 urea in one litre was found to be isotonic
with a 5% (wt./vot.)solution of an organic non-volatile solute. The
molecular weight of latter is:
A. 348.9
B. 34.89
C. 3489
D. 861.2
Answer: A

33. Solute A is a ternary electrolyte and solute B is non-elctrolyte ,if0.1M
solution of soluteB produces an osmotic pressure of 2P ,then 0.05M
solution of Aat the same temperature will produce on osmotic pressure
equal to
A. P
B. 1.5P
C. 2P
D. 3P
Answer: D
34. Equimolal solutions A and B show depression in freezing point in the
ratio 2 : 1. A remains in the normal state in solution. B will be
A. Normal
B. Dissociated
C. Associated
D. Hydrolysis
Answer: C
35. The wt. of urea dissolved in 100 ml solution which produce an osmotic
pressure of 20.4 atm,will be
A. 5g
B. 4g
C. 3g
D. 6g
Answer: A

36. The relationship between osmotic pressure at 273K when 10g glucose
(P1 ), 10g urea (P2 ) and 10g sucrose (P3 ) are dissolved in 250mL of
water is:
A. P 1
> P2 > P3
B. P 3
> P1 > P2
C. P 2
> P1 > P3
D. P 2
> P3 > P1
Answer: C
37. Osmotic pressure of a urea solution at 10

∘
C is 500 mm. Osmotic
pressure of the solution become 105.3 mm. When it is diluted and
temperature raised to 25 ∘
C .The extent of dilution is
A. 6 times
B. 5 times
C. 7 times
D. 4 times
Answer: B
38. The solution containing 4.0gm of a polyvinyl chloride polymer in 1
litre dioxane was found to have an osmotic pressure 6.0 × 10

−4
atmosphere at 300K ,the value of R used is 0.082litre atmosphere
mole
−1
K
−1
.The molecular mass of the polymer was found to be
A. 3.0 × 10 2
B. 1.6 × 10 5
C. 5.6 × 10 4
D. 6.4 × 10 2
Answer: B
39. pH of 0.1(M )BOH (weal base)is found to be 12 .The solution at
temperature T K will display an osmotic pressure equal to
A. 0.01RT
B. 0.01(RT )
2
C. 0.11RT
D. 1.1RT
Answer: C
40. A 2% solution of cane sugar is isotonic with 0.5 % x solution.The
molecular weight of substance ' x' is [Assume that x does not undergo
association or dissociation]
A. 34.2
B. 85.5
C. 95.58
D. 126.98
Answer: B
Section B Assertion Reasoning
1. Assertion:The boiling and melting point of amides are higher than
corresponding acids.
Reason:It si due to strong intermolecular hydrogen bonding in their
molecules.
A. If both assertion and reason are true and the reason is the correct
explanation of the assertion
B. If both the assertion and reason are true but reason is not the
correct explanation of the assertion
C. If assertion is true but reason is false
D. If assertion is false but reason is true.
Answer: A
2. Assertion :Molar heat of vaporisation of water is greater than benzene.
Reason:Molar heat of vaporisation is the amount of heat required to
vaporise one mole of liquid at constant temperature.

Answer: B
3. Assertion :Molecular mass of benzoic acid when determine by
colligative properties is found high.
Reason: Dimerisationof benzoic acid.

Answer: A
View Text Solution
4. A pressure cooker reduces cooking time because
Answer: A

5. Assertion: CCl and H
4 2
O are immiscible .
Reason : CCl is a polar solvent.

4
Answer: C
6. Assertion:isotonic solution do not show the phenomenon of osmosis.
Reason: Isotonic solution have equal osmotic pressure

Answer: B
View Text Solution
7. Assertion:Osmosis is one sided movement of solvent particles.
Reason :In Osmosis , the net movement of solvent particles from dil.to
conc.solution and from conc.to dil. Solution takes place through
semipermeable membrance,showing finally the direction of dil.to conc.

Answer: D
8. Assertion : Boiling point of water tis 100

∘
C although water boils below
100
∘
C on mountains.
Reason:Boiling point of a liquid is th e temperature at which V.P.of liquids
become equal to 1atm.

Answer: A
9. Assertion: Ebullioscopy or cryoscopy cannot be used for the
determination of molar mass of polymers.
Reason:High molar mass solute leads to very low value of ΔT b

or ΔTf

Answer: A
10. Assertion:For isotonic solutionC 1

= C2
Reason:For isotonic solutionπ 1

= π2 .
Answer: D

11. Assertion:Osmotic pressure of non-aqueous solution can be determine
by Berkeley-Hartley method.
Reason: the semipermeable membrance used in Berkeley-Hartley method
is Cu 2
[F e(CN ) ].
6
Answer: D
12. Assertion:Addition of solvent to a solution always lowers the V.P.
Reason: The increase in relativer surface area given rise to an increases

inV.P. for a given solution.
Answer: D
13. Assertion:A cook cries more in cutting onion rather than cutting an
onion taken out from refrigerator .
Reason:The cold onion has lower vapour pressure of its volatile content.
Answer: A
14. Assertion: A mixture of cyclohexane and ethanol shows -ve deviation
from Raoult's law.
Reason:Cyclohexane reduces the intermolecular attraction between
ethanol molecules.

Answer: D
View Text Solution
15. Assertion (A): 0.1M solution of glucose has same increment in
freezing point than has 0.1M solution of urea.
Reason (R ): K for both has different value.

f

Answer: B
16. Assertion:If red blood cells were removed from the body and placed in
pure water,pressure inside the cells increases.
Reason:The concentration of salt content in the cell increases.
Answer: C
View Text Solution
Aipt Neet Questions
1. A solution contains non-volatile solute of molecular mass M which of

2
the following can be used to calculate the molecular mass of solute in
terms of osmotic pressure?
(m =mass of solute,V=volume of solution,π =osmotic pressure)

2
m2
A. M2
= ( )V RT
π
m2 RT
B. M2
= ( )
V π
m2
C. M2
= ( )πRT
V
m2 π
D. M2
= ( )
V RT
Answer: B

2. A solution has 1: 4 mole ratio of pentane to hexane . The vapour
pressure of pure hydrocarbons at 20

∘
C are 440 mmHgfor pentane and
120mmHg for hexane .The mole
A. 0.786
B. 0.478
C. 0.549
D. 0.200
Answer: B
3. A solution of urea (mol. Mass 60gmol

−1
) boils of 100.18 ∘
C at one one
atmospheric pressure. If kf and Kb for water are 1.86 and
0.512Kkgmol
−1
respectively, the above solution will freeze at:
A. − 6.54 ∘
C
B. 6.54 ∘
C
C. − 0.654 ∘
C
D. 0.654 ∘
C
Answer: C
4. The vapour pressure of two liquid P and Q are 80 torr and 60 torr
respectively. The total vapour pressure obtained by mixing 3 moles of P
and 2 mole of Q would be
A. 68 torr
B. 20 torr
C. 140 torr
D. 72 torr
Answer: D
5. During osmosis, flow of water through a semipermeable membrane is:
A. from both sides of semipermeable membrane with unequal flow
rates
B. from solution having lower concentrated only
C. from solution having higher concentrated only
D. from both sides of semipermeable membrance with equal flow rates
Answer: A
6. A solution containing 10gperdm

3
of urea (mol.wt. = 60gmol
−1
) is
isotonic with a 5% ( mass//vol.) of a non-volatile solute. The molecular
mass of non-volatile solute is:

A. 350
B. 300
C. 250
D. 200
Answer: B
7. 1.0gof a non-electrolyte solute (molar mass 250gmol −1

was dissolved in
51.2 g of benzene. If the freezing point depression constant of benzene is
5.12Kkgmol
−1
the lowering in freezing point will be
A. 0.5K
B. 0.4K
C. 0.2K
D. 0.3K
Answer: B
8. A molal aqueous solution of a weak acid (HX) is 20 per cent

0.5
ionized.The lowering in freezing point of this solution is
(Kf = 1.86K/m for water)
A. 1.12K
B. − 0.56K
C. 0.56K
D. − 1.12K
Answer: A

9. A 0.002M aqueous solution of an ionic compound
[Co(N H3 ) (N O2 )]Cl
5
freezes at − 0.00732 ∘
C . Find the number of moles
of ions which 1 mole of ionic compound produces of being dissolved in
water. (K f
= − 1.86
∘
C / m) .
A. 1
B. 4
C. 3
D. 2
Answer: D
10. A solution of sucrose (molar mass 342gmol

−1
has been produced by
dissolving68.5gsucrose in 1000g water .The freezing point of the solution
obtained will be (K for H f 2

O = 1.86kgmol
−1
)
A. − 0.372 ∘
C
B. − 0.520 ∘
C
C. + 0.372 ∘
C
D. − 0.570 ∘
C
Answer: A
11. The van't Hoff factor i for a compound which undergoes dissociation in
one solvent and association in other solvent is respectively.
A. greater than one and greater than one
B. less than one and greater than one
C. less than one and less than one
D. greater than one and less than one
Answer: D
12. The freezing point depression constant for water is − 1.86

∘
Cm
−1
. if
5.00gN a2 SO4 is dissolved in 45.0gH2 O ,the freezing point is changed by
− 3.82
∘
C ,Calculate the van't Hoff factor for N a 2
SO4
A. 0.381
B. 2.63
C. 2.05
D. 3.11
Answer: B
13. P A
and PB are the vapour pressure of pure liquid components ,Aand
B respectively of an ideal binary solution,If xA represents the mole
fraction of component A, the total pressure of the solution will be

A. P B
+ x A (PB − PA )
B. P A
+ x A (PA − PB )
C. P A
+ x A (PB − PA )
D. P B
+ x A (PA − PB )
Answer: D
14. Which of following compounds can be used as antifreeze in
automobile radiators?
A. Methyl alcohol
B. Glycol
C. Nitrophenol
D. Ethyl alcohol
Answer: B
15. 6.02 × 10
20
molecules of urea are present in 100mL solution. The
concentration of urea solution is:
A. 0.1M
B. 0.001M
C. 0.01M
D. 0.02M
Answer: C
16. Of the following0.10m aqueous solutions,which one will exhibits the
largest freezing point depression?
A. K2
SO4
B. N al 2
(SO4 )
3
C. C 6
H12 O6
D. KCl
Answer: B
17. Which of the following electrolytes has the same value of van't Hoff
factor (i)is that of Al 2

(SO4 )
3
(if all are 100 % ionised?
A. Al(N O 3
)
3
B. K 4
[F e(CN ) ]
6
C. K 2
SO4
D. K 3
[F e(CN ) ]
6
Answer: B

18. The boiling point of 0.2molkg −1
solution of X in water is greater than
equimolal solution of Y in water.Which one of the following statement is
true in the case?
A. Molecular mass of X is less than the molecular mass of Y
B. Y is undergoing dissociation in water while X undergoes no change.
C. X is undergoes dissociation in water.
D. Molecular mass of X is greater then the molecular mass of Y.

Answer: C
View Text Solution
19. What is the fraction of the solute in a 1.00 m aqueous solution ?
A. 0.0354
B. 0.0177
C. 0.177
D. 1.770
Answer: B
20. At 100
∘
C the vapour pressure of a solution of 6.5g of an solute in
100g water is 732mm .If K

b
, the boiling point of this solution will
= 0.52
be :
A. 103 ∘
C
B. 101 ∘
C
C. 100 ∘
C
D. 102 ∘
C
Answer: B
21. Which of the following statements about the composition of the
vapour over an ideal 1: 1 mol mixture of benzene and toluene is correct?
Assume that the temperature is constant at 25

∘
C . (Given: vapour
pressure Date at 25 ∘
C , benzene=12.8 kP, toluene=3.85 kPa)
A. Not enough information is given to make a prediction.
B. The vapour will contain a higher percentage of benzene .
C. The vapour will contain a higher percentage of toluen.
D. The vapour will contain equal amounts of benzene and toluene.

Answer: B
22. If molarity of the dilute solutions is doubled ,the value of molal
depression constant(K )will be:

f
A. halved
B. triple
C. unchanged
D. doubled
Answer: C
23. Which of the following is dependent on temperature?

A. Molarity
B. Mole fraction
C. Weight percentage
D. Molality
Answer: A
Aiims Questions
1. If 5.85g of N aClare dissolved in90g of water,the moles fraction ofN aCl
is
A. 0.1
B. 0.2
C. 0.3
D. 0.0196
Answer: D
2. What will be the molarity of a solution containing 5g of sodium
hydroxide in250ml solution?
A. 0.5
B. 1.0
C. 2.0
D. 0.1
Answer: A
3. If g of
5.85 (molecular weight58.5)is dissolved in water and the
N aCl
solution is made up to 0.5litre , the molarity of the solution will be

A. 0.2
B. 0.4
C. 1.0
D. 0.1
Answer: A
4. To prepare a solution of concentrated of of

0.03g / ml AgN O3 ,what
amount of AgN O should be added in 60ml of solution

3
A. 1.8
B. 0.8
C. 0.18
D. None of these
Answer: A
5. How many g of dibasic acid (mol.wt.200) should be present in 100ml of
its aqueous solution to give decinormal strength?
A. 1g
B. 2g
C. 10g
D. 20g
Answer: A
6. The molarity of a solution of N a 2

O3 having10.6g / 500mlof solution is
A. 0.2M
B. 2M
C. 20M
D. 0.02M
Answer: A
7. Molecular weight of glucose is 180. A solution of glucose which
contains 18gper litre is
A. 2 molal
B. 1 molal
C. 0.1 molal
D. 18 molal
Answer: C

8. 0.5 M of H 2
SO4 is diluted from 1 litre to 10 litre, normality of resulting
solution is
A. 1N
B. 0.1N
C. 10N
D. 11N
Answer: B
9. An aqueous solution of glucose is 10 % in strength ,The volume in
which 1g mole of it dissolved will be
A. 18 litre
B. 9 litre
C. 0.9 litre
D. 1.8 litre
Answer: D
10. When 1.80g glucose dissolved in 90gofH2 O ,the mole fraction of
glucose is
A. 0.00399
B. 0.00199
C. 0.0199
D. 0.998
Answer: B

11. A5 molar solution of H2 SO4 is diluted from 1litre to litres. What is
10
the normality of the solution?
A. 0.25N
B. 1N
C. 2N
D. 7N
Answer: B
12. Normality of 2M sulphuric acid is
A. 2N
B. 4N
C. N / 2
D. N / 4
Answer: B
13. What is the molarity of H 2

SO4 solution that has a density 1.84 g/c c at
35
∘
C and contains 98% by weight?
A. 4.18M
B. 8.14M
C. 18.4
D. 18M
Answer: C
14. Which of the following is a colligative property?

A. Osmotic pressure
B. Boiling pressure
C. Vapour pressur
D. Freezing point
Answer: A
15. The vapour pressure of benzene at a certain temperature is 640mm of
Hg A non-volatile and non-electrolyte solid weighing 2.175g is added to
39.08g of benzene .the vapour pressure of the solution is 600mm of Hg.
What is the molecular weight of solid substance ?
A. 49.50
B. 59.6
C. 69.5
D. 79.8
Answer: C
16. The average osmotic pressure of human blood is 7.8 bar at 37

∘
C .
What is the concentration of an aqueous N aClsolution that could be
used in the blood stream ?
A. 0.16mol / L
B. 0.32mol / L
C. 0.60mol / L
D. 0.45mol / L
Answer: B

17. The osmotic pressure in atmosphere of 10 % solution of cane sugar at
69
∘
C is
A. 724
B. 824
C. 8.21q
D. 7.21
Answer: C
18. The molal boiling point constant for water is 0.513 ∘

Ckgmol
−1
. When
0.1 mole of sugar is dissolved in ml of water , the solution boils under

200
a pressure of one atmosphere at
A. 100.513 ∘
C
B. 100.0513 ∘
C
C. 100.256 ∘
C
D. 101.025 ∘
C
Answer: C
19. The freezing point of a solution prepared from 1.25g of non-
electrolyte and 20g of water is 271.9K . If the molar depression constant
is 1.86Kmol −1
, then molar mass of the solute will be
A. 105.7
B. 106.7
C. 115.3
D. 93.9
Answer: A

20. Osmotic pressure of 0.1M solution of N aCland N aSO will be 4
A. same
B. osmotic pressure ofN aClsolution will be more thanN a 2

SO4
solution
C. osmotic pressure ofN a 2

SO4 solution will be more thanN aCl
D. osmotic pressure ofN a 2

SO4 will be less than that of N aCl solution
Answer: C
21. At25 ∘
C the highest osmotic pressure is exhibited by 0.1M solution of
A. CaCl 2
B. KCl
C. Glucose
D. Urea
Answer: A
22. An azeotropic mixture of H Cl and water has
A. 84 % H Cl
B. 22.2 % H Cl
C. 63 % H Cl
D. 20.2 % H Cl
Answer: D

23. The boiling point fo water (100
∘
C become 100.52
∘
C , if 3 grams of a
nonvolatile solute is dissolved in 200ml of water. The molecular weight of
solute is
(K for water is 0.6K.kg mol

b
−1
)
A. 12.2g mol −1
B. 15.4g mol
C. 17.3g mol −1
D. 20.4g mol
Answer: C
24. The depression in freezing point of 0.1M aqueous solution of
H CL, CuSO4 and K2 SO4 are in the ratio.
A. 1 : 1 : 1.5
B. 1 : 2 : 3
C. 1 : 1 : 1
D. 2 : 4 : 3
Answer: A
25. When 45gm solution is dissolved in 600gm water freezing point lower
by 2.2K,calcuate molar mass of solute (K f

= 1.86kg mol
−1
)
A. 63.4
B. 80gm
C. 90gm
D. 21gm
Answer: A

26. Assertion : Molecular mass of bezxoic acid when determined by
colligative properties is found high.
Reason : Dimerisation of benzene acid.
A. If both the assertion and reason are true and reason is a true
explanation of the assertion.
Answer: A
View Text Solution
27. Assertion : A mixture of cyclohexane and ethanol shows -ve deviation
from Raoult's law .

Reason : Cyclohexane reduces the intermolcular attraction between
ethanol molecules.
Answer: D
View Text Solution
28. A pressure cooker reduces cooking time because

Answer: A
29. Assertion: CCl and H

4 2
O are immiscible .
Reason : CCl is a polar solvent.

4

Answer: C
30. Assertion : isotonic solution do not show the phenomenon of
osmosis.
Reason : Isotonic solution have equal osmotic pressure
Answer: B
View Text Solution
31. Assertion : Azeotropic mixtures are formed only by non-ideal solution
and they may have boiling points either greater than both the
components or lesser than both the components.
Reason : The composition of the vapour phase is same as that of the
liquid phase of an azeotropic mixtures.
Answer: A
View Text Solution

32. Assertion : When one solvent mixed with other solvent vapour
pressure of one increases and other decreases.
Reason : When any solute added into solvent ,vapour pressure of solvent
decreases
Answer: B
View Text Solution
Section D Chapter End Test

1. On adding solute to a solvent having vapour pressure 0.80atm ,vapour
pressure reduces to 0.60atm.Mole fraction of solute is
A. 0.25
B. 0.75
C. 0.50
D. 0.33
Answer: A
2. A solution containing 30g of a non-volatile solute in exactly 90g of
water has a vapour pressure of 21.85mm of 25 ∘

C . Further 18g of water
is then added to the solution, the new vapour pressure becomes
22.15mm of Hg at 25C . Calculate the (a) molecular mass of the solute
and (b) vapour pressure of water at 25 ∘

C .
A. 74.2
B. 75.6
C. 67.83
D. 78.7
Answer: C
3. Vapour pressure of a solution of 5gof non-electrolyte in 100g water at a
particular temperature is 2985N / m .The vapour pressure of pure water

2
is 3000N / m .The molecular weight of the solute is

2
A. 60
B. 120
C. 180
D. 380
Answer: C
4. An azeotropic mixture of H Cl and water has
A. 84 % H Cl
B. 22.2 % H Cl
C. 63 % H Cl
D. 20.2 % H Cl
Answer: D
5. The osmotic pressure at 17 ∘

C of aqueous solution containing 1.75g of
sucrose per 150mlsolution is
A. 0.8 atm
B. 0.08 atm
C. 8.1 atm
D. 9.1 atm
Answer: A
6. of solution of
1.2 N aCl is isotonic with 7.2 of solution of glucose
.Calculate the van't Hoff factor of N aClsolution?
A. 2.36
B. 1.50
C. 1.95
D. 1.00
Answer: C

7. 0.6gof a solute is dissolved in 0.1litre of a solvent which develops an
osmotic pressure of 1.23 at m at 27

∘
C .The molecular mass of the
substance is
A. 149.5g mol −1
B. 120g mol −1
C. 430g mol −1
D. None of these
Answer: B
8. The boiling point of a solution of 0.1050g of a substance in 15.84g of
ether was found to be 0, 1

∘
C higher than that of pure ether.What is the
molecular weight of the substance [Molecular elevation constant of ether
is 2.16]`
A. 144.50
B. 143.18
C. 140.28
D. 146.66
Answer: B
9. Boiling point fo chloroform was raised by 0.323K ,when0.5143g of
anthrance was dissolved in 35g of chloroform .Molecular mass of
anthracene is
−1
(Kb f or CH Cl3 = 3.9K.kg mol )
A. 79.42g / mol
B. 132.32g / mol
C. 177.42g / mol
D. 242.32g / mol
Answer: C
10. The boiling point fo water (100

∘
C become 100.52
∘
C , if 3 grams of a
nonvolatile solute is dissolved in 200ml of water. The molecular weight of
solute is
(K for water is 0.6K.kg mol

b
−1
)
A. 12.2g mol −1
B. 15.4g mol
C. 17.3g mol −1
D. 20.4g mol
Answer: C

11. Normal boiling point of water is 373K . Vapour pressure of water at
298K is 23mm enthalpy of vaporisation is 40.656kJ mol

−1
if atmopheric
pressure becomes 23mm, the water will boil at:
A. 250K
B. 294K
C. 51.6
D. 12.5K
Answer: B
12. A0.2 molal aqueous solution of a week acid (HX) is 20 % ionised,The
frrezing point of this solution is (Given k f

= 1.86
∘
Ckgmol
−1
for water) :
A. − 0.31 ∘
C
B. − 0.45 ∘
C
C. − 0.53 ∘
C
D. − 0.90 ∘
C
Answer: B
13. A 0.001 molal solution of [P t(N H 3

) Cl4 ]
4
in water had freezing point
depression of 0.0054 ∘
C . If K for water is
f
1.80 , calculating the number f
Cl
−
ions furnished.
A. [P t(N H 3
) Cl3 ]Cl
4
B. [P t(N H 3
) Cl3 ]Cl2
4
C. [P t(N H 3
) Cl3 ]Cl3
4
D. [P t(N H 3
) Cl3 ]Cl4 ]
4
Answer: B

14. An aqueous solution of a weak monobasic acid containing 0.1g in 21.7
g of water freezes at272.813K.If the value of Kf for water is 1.86K / m
,what is the molecular mass of the monobasic acid
A. 50g / mol
B. 46g / mol
C. 55g / mol
D. 60g / mol
Answer: D
15. Kf
of1, 4 − dioxane is4.9mol
−1
for 1000g .The depression in freezing
point for a0.001m solution in dioxane is
A. 0.0049
B. 4.9 + 0.001
C. 4.9
D. 0.49
Answer: A
16. How many litres ofCO atSTP will be formed when

2
of
100ml
0.1M H2 SO4 reacts with excess of N a 2

SO3 ?
A. 22.4
B. 2.24
C. 0.224
D. 5.6
Answer: C

17. A solution is obtained by dissolving 12g of urea(mol.wt.60)in a litre of
water.Another solution is obtained by dissolving 68.4g of cane sugar
(mol.wt.342)`in a litre of water at are the same temperature .The lowering
of vapour pressure in the first solution is
A. same as that of 2 solution

nd
B. Nearly one-fifth of the 2 solution

nd
C. Double that of 2 solution

nd
D. Nearly five times that of 2 solution

nd
Answer: A
18. The vapour pressures of ethanol and methanol are 42.0mm and
88.0mmH g respectively .An ideal solution is formed at the same

temperature by mixing 46.0g of ethanol with 16.0g of methanol. The mole
fraction of methanol in the vapour is:
A. 0.467
B. 0.502
C. 0.513
D. 0.556
Answer: C
19. Which of the following plots represent the behaviour of an ideal
binary liquid solutions?
A. Plot ofP total

vsYA (mol fraction ofAin vapour phase)
B. Plot ofP total

vsYB is linear
1
C. Plot of vsYA is linear
Ptotal
1
D. Plot of vsYB is non- linear
Ptotal
Answer: C
View Text Solution
20. For a binary ideal lqiuid solutions,the total pressure of the solution is
given as
A. P Total
= P
∗
A
+ (P
∗
A
− P
∗
B
)XA
B. P Total
= P
∗
B
+ (P
∗
A
− P
∗
B
)XA
C. P Total
= P
∗
A
+ (P
∗
B
− P
∗
A
)XA
D. P Total
= P
∗
B
+ (P
∗
B
− P
∗
A
)XA
Answer: B

21. The relationship between the values of osmotic pressures of0.1M
solutionsofKN O 3
(P1 ) andCH 3
COOH (P2 ) is
A. P 1
> P2
B. P 2
> P1
C. P 1
= P2
D. P 1
/ (P1 + P2 ) = P2 / ((P1 + P2 )
Answer: A
22. The vapour pressure of solvent is 20 torr, while that of its dilute
solution is 17 torr , the mole-fraction of the solvent is
A. 0.6
B. 0.4
C. 0.5
D. 0.7
Answer: B
23. N aCl is added to1 litre water to such an extent that ΔTf / Kf
1
becomes to ,wt.of N aCl added to
500
A. 5.85g
B. 0.585
C. 0.0585g
D. None of these
Answer: C

24. If the total vapour presure of the liquid mixtureAandBis given by the
equation:P = 180XA + 90 then the ratio of the vapour pressure of the
pure liquids A and B is given by :
A. 3 : 2
B. 4 : 1
C. 3 : 1
D. 6 : 2
Answer: C
25. The vapour pressure of ethanol and methanol are 44.0mmH g and
88.0mmH g , respectively. An ideal solution is formed at the same
temperature by mixing 60g of ethanol with 40g of methanol. Calculate the
total vapour pressure of the solution and the mole fraction of methanol
in the vapour.
A. 0.66
B. 0.55
C. 0.11
D. 0.33
Answer: A
26. The molality of a urea solution in which 0.0200g of urea,
(N H2 )CON H2 is added to 0.400dm of water at STP is

3
A. 0.555molal
B. 5.55 × 10 −4
molal
C. 8.33 × 10 −2
molal
D. 33.3molal
Answer: C
27. The vapour pressure of benzene at 80

∘
C is lowered by 10 mm by
dissoving 2 g of a non-volatile substance in 78 g of benzene. The vapour
pressure of pure benzene at 80 C is 750 mm. The molecular weight of the

∘
substance will be :
A. 15
B. 150
C. 1500
D. 148
Answer: D
28. Asssertion : Azeotropic mixtures are formed only by non-ideal
solutions and they may have boiling points either greater than both the
components or less than both the compounds.
Reason : The composition of the vapour phase is same as that of the
liquid phase of an azeotropic mixture.
D. If assertion is reason both are false.
Answer: B
View Text Solution
29. Assertion :Molar heat of vaporisation of water is greater than
benzene.
Reason:Molar heat of vaporisation is the amount of heat required to
vaporise one mole of liquid at constant temperature.
Answer: B
30. Assertion : Isotonic solution do not show the phenomenon of
osmosis.
Reason : Isotonic solution have equal osmotic pressure.

Answer: B
View Text Solution
Others
1. Variation of K H
(Henry's law constant) with temperature T is shown by
following graphs I − IV
correct representation is
A. IV
B. III
C. I
D. II
Answer: C

2. Which of the following units is useful in relating concentration of
solution with its vapour pressure?
A. Mole fraction
B. Parts per million
C. Mass percentage
D. Molarity
Answer: A
3. An unopened soda has an aqueous concentration of CO2 at25 equal

∘
to 0.0408 molal.Thus ,pressure of CO2 gas in the can is
(KH = 0.034mol / kgbar)
A. 0.671bar
B. 1.49bar
C. 1.41bar
D. 1.71 bar
Answer: C
4. Relation between the volume of gas (2) that dissolves in a fixed volume
of solvent (1) and the partial pressure of gas (2) is (n = total moles,
t
K1
and K are Henry's constants)

2
A. n 1
RT / n2
B. n 2
RT / K2 p2
C. n RT / K
t 2
D. None of these
Answer: C

5. The pressure under which liquid and vapour can co-exist at equilibrium
is called the
A. Limiting vapour pressure
B. Real vapour pressure
C. Normal vapour pressure
D. Saturated vapour pressure
Answer: B
6. What is the concentration of O in a freshwater stream in equilibrium

2
with air at 30
∘
C and 2.0 bar ? Given, KH (Henry's law constant) of
O2 = 2.0 × 10
−3
mol / kg bar at 30 ∘
C .
A. 8.736 × 10 −3
g / kg
B. 1.344 × 10 −3
g / kg
C. 24.04g / kg
D. 114.5g / kg
Answer: B
7. CO(g) is dissolved in H 2
O at 30 C and 0.020 atm. Henry's law constant
∘
for this system is 6.20 × 10 atm. Thus mole fraction CO(g) is

4
A. 1.72 × 10 −7
B. 3.22 × 10 −7
C. 0.99
D. 0.01
Answer: B

8. The solubility of N 2
(g) in water exposed to the atmosphere, when the
partial pressure is 593mm is 5.3 × 10 −4

M. Its solubility at 760 mm and at
the same temperature is
A. 4.1 × 10 −4
M
B. 6.8 × 10 −4
M
C. 1500M
D. 2400M
Answer: B
9. The vapour pressure of a liquid in a closed container depends upon
A. Amount of liquid
B. Surface area of the container

C. Temperature
D. None of these
Answer: C
10. A sample of air saturated with benzene (vapour pressure = 100 mm Hg
at 298 K , 750 mm Hg pressure . If it is isothermally compressed to one
third of its initial volume , the final pressure of the system is :
A. 2250 torr
B. 2150 torr
C. 2050 torr
D. 1950 torr
Answer: C

11. H2 S gas is used in qualitative analysis of inorganic cations. Its
solubility in water at STP is 0.195molKg −1

. Thus, Henry's law constant (in
atm molal −1
) for H 2
S is
A. 2.628 × 10 −4
B. 5.128
C. 0.185
D. 3.826 × 10 3
Answer: B
12. Why does the use of pressure cooker reduce cooking time ?
A. Boiling point of water involved in cooking is increased
B. heat is more evenly distributed in the cooking space

C. The higher pressure inside the cooker crushes the food material
D. Cooking involve chemical changes helped by a rise in temperature
Answer: A
13. Observe the P-T phase diagrams for a given substance A. Then melting
point of A(s), boiling point of A(l), critical point of A and triple point of A
(at their respective pressure) are respectively-

A. T 1
, T2 , T3 , T4
B. T 4
, T3 , T1 , T2
C. T 3
, T4 , T2 , T1
D. T 2
, T1 , T3 , T4
Answer: C
14. According to William Henry, the solubility of a gas in liquid depends on
the pressure of the gas. If 'm' is the molality of the gas and 'P' is its
pressure then which of the following plot is in accordance with the law:
A.
B.
C.
D.
Answer: B
15. A solid dissolves in water if
A. Lattice energy is greater than hydration energy
B. Lattice energy is less than hydration energy.

C. Lattice energy is equal to hydration energy.
D. Dissolution is endothermic
Answer: B
16. The boiling points of C6 H6 , CH3 OH , C6 H5 N H2 and C6 H5 N O2 are
80
∘
C, 65
∘
C, 184
∘
C, and 212 ∘
C respectively. Which of the following will
have highest vapour pressure at room temperature ?
A. C6
H6
B. CH 3
OH
C. C6
H5 N H2
D. C 6
H5 N O 2
Answer: B

17. During the evaporation of liquid
A. The Temperature of the liquid will rise
B. The temperature of the liquid will fall
C. May rise or fall depending on the nature
D. The temperature remains unaffectd
Answer: B
18. At the higher altitudes the boiling point of water lowers because
A. Atmospheric pressure is low
B. Temperature is low
C. Atmospheric pressure is high
D. none of these
Answer: A
19. An ideal solution has two components A and B. If A is more volatile
than B and also P

∘
A
> PT , then the correct relation between mole
fraction of A in liquid (X) and vapour (Y ) phase is :
A. X A
= YA
B. X A
> YA
C. X A
< YA
D. Nothing can be said
Answer: C

20. A solution has 1: 4 mole ratio of pentane to hexane . The vapour
pressure of pure hydrocarbons at 20

∘
C are 440 mmHgfor pentane and
120mmHg for hexane .The mole fraction of pentane at vapour phase
would be
A. 0.786
B. 0.549
C. 0.478
D. 0.200
Answer: C
21. Given P − x curve for a non ideal liquid mixture (fig.) Identify the
correct T − x curve for the same mixture.

A.
B.
C.
D.
Answer: B
View Text Solution
22. The vapour pressure of two liquid P and Q are 80 torr and 60 torr
respectively. The total vapour pressure obtained by mixing 3 moles of P
and 2 mole of Q would be
A. 68 torr
B. 20 torr
C. 140 torr
D. 72 torr
Answer: D
23. Consider a binary mixture of volatile liquides. If at , the

XA = 0.4
vapour pressure of solution is 580 torr then the mixture could be
(p
A
∘
= 300torr, P
B
∘
= 800torr) :
A. CH Cl 3
− CH3 COCH3
B. C6
H5 CI − C6 H5 Br
C. C6
H6 − C6 H5 CH3
D. nC 6
H14 − nC7 H16
Answer: A

24. The lubricating action of an oil is more if it possess:
A. high vapour pressure
B. low power pressure
C. high surface tension
D. high destiny
Answer: B
25. Which of the following plots does not represent the behaviour of an
ideal binary liquid solutions?
A. plot of p versus x (mole fraction of A in liquid phase) is linear

A A
B. plot of p versus x is linear

B B
C. Plot of ptotal
versus is (orx B
) linear
D. Plot of p total
versus x is non-linear
A
Answer: D
View Text Solution
26. Which of the following is correct for a solution showing positive
deviations from Raoult's law?
A. ΔV = + ve, ΔH = + ve
B. ΔV = − ve, ΔH = − ve
C. ΔV = + ve, ΔH = − ve
D. ΔV = − ve, ΔH = + ve
Answer: A

27. If liquids A and B from an ideal solution
A. The entropy of mixing is zero
B. The Gibbs free energy is zero
C. The Gibbs free energy as well as the entropy of mixing are each zero
D. The enthalpy of mixing of zero
Answer: D
28. Water and ethanol from non-ideal solution with positive deviation
Raoult's law. This solution will have vapour pressure
A. equal to vapour pressure of pure water
B. less than vapour pressure of pure water
C. more than vapour pressure of pure water
D. less than vapour pressure of pure ethanol

Answer: C
29. Mole fraction of toluene in the vapour which is in equilibrium with a
solution containing benzene and toluene having 2 moles each is Given :
Saturation vapour pressure of benzene = 120 torr Saturation vapour
pressure of toluene = 80 torr
A. 0.5
B. 0.25
C. 0.6
D. 0.4
Answer: D

30. For an ideal binary liquid solution with P
∘
A
> P
∘
B
xA and yA
represent the mole fraction of A in liquid phase and vapour phase
respectively whereas x and B

yB represent the mole fraction of B in liquid
phase and vapour phase respectively, therefore which of the following
relation is correct?
A. x A
= yA
B. x A
> yA
xA yA
C. <
xB yB
xA yA
D. >
xB yB
Answer: C
31. Total Vapour pressure of mixture of 1molA(p 0
A
= 150torr) and 2molB
(p
0
B
= 240torr) is 200torr. In this case
A. There is positive deviation from Raoult's law
B. there is negative deviation from Raoult's law
C. there is no deviation from Raoult's law
D. molecular masses of A and B are also required for calculating the
deviation
Answer: B
32. Which of the following is less than zero for ideal solutions ?
A. ΔH mix
B. ΔV mix
C. ΔG mix
D. ΔS mix
Answer: C
33. If Vapour pressure of pure liquids 'A' & 'B' are 300 and 800 torr
respectively at 25
∘
C . When these two liquids are mixed at this
temperature to from a solution in which mole percentage of 'B' is 92, then
the total vapour pressure is observed to be 0.95 atm. Which of the
following is true for this solution.
A. ΔV mix
> 0
B. ΔH mix
< 0
C. ΔV mix
= 0
D. ΔH mix
= 0
Answer: B
34. Which of the following shows negative deviation from Raoult's law?
A. CH Cl 3
and CH3 COCH3
B. CH Cl 3
and C2 H5 OH
C. C6
H5 CH3 and C6 H6
D. C6
H6 and CCl4
Answer: A
35. A maximum or minima obtained in the temperature, composition
curve of a mixture of two liquids indicates:
A. an azeotropic mixture
B. an eutectic formation
C. that the liquids are immiscible with one another
D. that the liquids are partially miscible at the maximum or minimum
Answer: A
36. A liquid is kept in a closed vessel. If a glass plate (negligible mass) with
a small hole is kept on top of the liquid surface, then the vapour pressure
of the liquid in the vessel is :
A. More than what would be if the glass plate were removed
B. same as what would be if the glass plate were removed
C. less than what would be if the glass plate were removed
D. cannot be predicted
Answer: B
37. Given at 350K, p

A
∘
= 300torr and p
B
∘
= 800torr the composition of
the mixture having a normal boiling point of 350K is

A. X A
= 0.08
B. X A
= 0.06
C. X A
= 0.04
D. X A
= 0.02
Answer: A
38. The vapour pressure of the solution of two liquids A(P ∘

= 80mm)
and B(P ∘
= 120mm) is found to 100mm when . The result
x A = 0.4
shows that
A. solution exhibits ideal behaviour
B. solution shows positive deviations
C. solution shows negative deviations
D. solution will show positive deviations for lower concentration and
negative deviations for higher concentrations.

Answer: C
39. In mixture A and B ,components show -ve deviations as:
A. ΔV mix
is +ve
B. A-B interation is weaker than A-A and B-B interation
C. ΔH mix
is +ve
D. A-B interation is stronger than A-A and B-B interation
Answer: D
40. If liquids A and B from an ideal solution, than :
A. ΔG mix
= 0
B. ΔH mixing
= 0
C. ΔG mix
= 0, ΔSmix = 0
D. ΔS mix
= 0
Answer: B
41. Which liquids pair shows a positive deviation from Raoult's law?
A. Acetone -chloroform
B. Benzene -methanol
C. Water-nitric acid
D. Water-hydrochloric acid
Answer: B

42. Benzene and toluene form nearly ideal solutions.At 20
∘
C , the vapour
pressure of benzene is 75 torr. The partial vapour pressure of benzene at
20
∘
C for a solution containing 78gbenzene and 46gtouene is torr is
A. 50
B. 25
C. 375
D. 53.5
Answer: A
43. A mixture of ethyl alcohol and propyl alcohol has a vapour pressure of
290mm at 300K .The vapour pressure of propyl alcohol is 200mm .if the
mole fraction of ethyl alcohol is 0.6 ,its vapour pressure (in mm)at the
same temperature will be

A. 350
B. 300
C. 700
D. 360
Answer: A
44. At 80 ∘
C , the vapour pressure of pure liquid A is 520mm Hg and that
of pure liquid B is 1000mmH g . If a mixture of solution A and B boils at
80 ∘ C and 1atm pressure, the amount of A in the mixture is
(1atm = 760mmH g)
a. 50mol % , b.52mol % ,c.34mol % ,d.48mol %
A. 52mol percent
B. 34mol percent
C. 48mol percent
D. 50mol percent
Answer: D
45. The vapour pressure of water at20 ∘

C is 17.5mmH g .if 18g of glucose
(C6 H12 O6 is added to 178.2g of water at20 ∘

C , the vapour pressure of the
resulting solution will be,
A. 17.675mmH g
B. 15.750mmH g
C. 16.500mmH g
D. 17.325mmH g
Answer: D

46. For A and B to form an ideal solution which of the following
conditions should be satisfied?
A. ΔH miξng
= 0
B. ΔV miξng
= 0
C. ΔS miξng
= 0
D. All three conditions mentioned above.
Answer: D
47. A binary liquid solution of n-heptane and ethyl alcohol is prepared
which of the following statements correctly represents the behaviour of
this liquid solution?
A. The solution formed is an ideal solution

B. The solution formed is a non - ideal solution with positive
deviations from Raoult's law.
C. The solution formed is a non- ideal solution with negative
deviations from Raoult's law
D. Normal-heptane exhibits postive deviations , whereas ethyl alcohol
exhibits negative deviations from Raoult's law
Answer: B
48. The mole fraction of toluene in vapour phase which is in equlibrium
with a solution of benzene and toluene having a mole fraction of toluene
0.500 is (vapour pressure of pure benzene and pure toluene are 119 torr
and 37.0 torr respectively at the same temperature).
A. 0.5
B. 0.763
C. 0.237
D. 1
Answer: C
49. Two liquids are mixed together to from a mixture which boils at same
temperature and their boiling point is higher than the boiling point of
either of them so they shows .
A. no deviation from Raoult's law
B. positive deviation from Raoult's law
C. Negative deviation from Raoult's law
D. positive and negative deviation from Raoult's law depends upon the
composition
Answer: C
50. At35 ∘
C the vapour of pure chlorofrom si atm and that of pure
0.359
acetone is 0.453atm.Asolution containing 1mole of chloroform and 4mole
of acetone has a vapoor pressure of (in atm)
A. 0.400
B. 0.812
C. 0.094
D. 0.434
Answer: D
51. When a solution of CH CI is mixed with a solution of acetone,ΔV

3 mix
is
A. Positive
B. Negative
C. Zero
D. Cannot be predicted
Answer: D
52. The vapour pressure of hexane (C6 H14 ) and heptane (C7 H16 ) at
50
∘
C are 408 torr and 141 torr, respectively. The composition of the
vapour above a binary solution composition a mole fraction of 0.300
hexane is (y6 = mol fraction of hexane and y7 = mol fraction of
heptane)
A. Y 6
= 0.8, Y7 = 0.2
B. Y 6
= 0.554, Y7 = 0.446
C. Y 6
= 0.300, Y7 = 0.700
D. Y 6
= 0.871, Y7 = 0.129
Answer: B
53. Benzene (C6 H6 , 78g / mol) and toluene (C7 H8 , 92g / mol) from an
ideal solution. At 60
∘
C the vapour pressure of pure benzene and pure
toluene are0.575atm and0.184,respectively . The mole fraction of benzene
in solution of these two chemicals that has a vapour pressure of 0.350
atm at60 ∘
C
A. 0.154
B. 0.690
C. 0.486
D. 0.190
Answer: A

54. At 25 ∘
C the vapour prssure of benzene ,C 6
H6 (78g / mole) ,is 93.2 torr
and that of toluene ,C 7

H8 (92g / mol) ,is 28.2torr .A solution of 1.0mole fo
C6 H6 and 1.0 mol of C7 H8 id prepared. Calculate the mole fraction of
C6 H6 in the vapour above this solution (assume the solution is ideal.)
A. 0.607
B. 0.768
C. 0.232
D. 0.393
Answer: B
55. At 334K the vapour pressure of benzene(C 6

H6 ) is 0.526atm and that
of toluene(C 7
H8 ) is 0.188atm. In a solution containing0.500mole of
benzene and0.500mole of toluene , what is the vapour pressure of
toluene above the solution at334K ?
A. 0.188atm
B. 0.10atm
C. 0.357atm
D. 0.094
Answer: D
56. The van't Hoff factory i for a compound which undergo dissociationin
one solvent and association in other solvent is respectively:
A. greater than one and greater than one
B. less than one greater than one
C. less than one and less than one

D. greater than one and less than one
Answer: D
57. A compound M X2 has observed and normal molar masses
65.6 and 164 respectively .Calculated the apparent degree of ionization
of M X :
2
A. 75 %
B. 85 %
C. 65 %
D. 25 %
Answer: A

58. The freezing point of 0.2molal K2 SO4 is − 1.1
∘
C . Calculate van't Hoff
factor and percentage degree of dissociation of K2 SO4 . Kf for water is
∘
1.86
A. 97.5
B. 90.75
C. 105.5
D. 85.75
Answer: A
59. The degree of dissociation (α) of a weak electrolyte, A x

By is related
to van't Hoff's factor (i) by the expression:
x + y − 1
A. α =
i − 1
i − 1
B. α =
x + y + 1
i − 1
C. α =
x + y + 1
x + y + 1
D. α =
i − 1
Answer: C
60. P tCl4 .6H2 O can exist as hydrated complex 1 molal aq.solution has
depression in freezing point of 3.72

∘
C Assume 100 % ionisation and
Kf (H2 O = 1.86
∘
mol
−1
)kg then complex is
A. [P t(H 2
O) ]Cl4
6
B. [P t(H 2
O) Cl2 ]Cl2 .2H2 O
4
C. [P t(H 2
O) Cl3 ]Cl.3H2 O
3
D. [P t(H 2
O) Cl4 ].4H2 O
2
Answer: C

61. When30g of this acid C11 H8 O2 is dissolved in g benzene ,a freezing
60
point depression of 2K is observedK f

(benzene) = 1.72K mol
−1
kg] . The
van't Hoff factor
A. 1
B. 0.4
C. 2
D. 3
Answer: B
62. Osmolarity of 0.02M potassium ferrocyanide solution 300K si (assuem
solute is 100 % ionized)
A. 0.10 osmol
B. 0.20 osmol
C. 0.02 osmol
D. 0.004 osmol
Answer: A
63. When only a little quantity ofH gCl is added to excess

2
Kl(aq) to
obtain a clear solution ,which of the following is true for this solution?
(no.volume change on mixing)
A. Its boiling and freezing poins remain same
B. Its boiling point is lowered
C. Its vapour pressure become lower
D. Its boiling point is raised
Answer: B
64. which of the following has been arranged in order of decreasing
freezing point?
A. 0.05M KN O 3
> 0.04M CaCl2 > 0.140M sugar > 0.075M CuSO4
B.
0.04M BaCl2 > 0.140M sucrose > 0.075M CuSO4 > 0.05M KN O3
C.
0.075M CuSO4 > 0.140M sucrose > 0.04M BaCl2 > 0.05M KN O3
D.
0.075M CuSO4 > 0.05M N aN O3 > 0.140M sucrose > 0.04M BaCl2
Answer: A

65. The freezing point depression of 0.001mKx [F e(CN ) ]
6
is
7.10 × 10
−3
K .Determine the value of x .Given ,K f
= 1.86Kkgmol
−1
for
water
A. 3
B. 4
C. 2
D. 5
Answer: A
W
66. π 1
, π 2 , π 3 and π 4 are the osmotic pressure of 5% ( solution of
)
V
ure ,frutose ,sucrose andKCl respectively at certain temperatures.The
correct order of their magnitude is
A. π 1
> π4 > π2 > π3
B. π 1
> π4 > π2 > π3
C. π 4
> π1 > π2 > π3
D. π 4
> π1 > π3 > π2
Answer: C
67. Moles of K2 SO4 to be dissolved in 12 moles of water of lower its
vapour pressure by 10mm Hg at a temperature at which vapour pressure
of pure water is 50mm Hg is
A. 3 mol
B. 2 mol
C. 1 mol
D. 0.5 mol
Answer: C
68. If for the sucrose solution elevation in boiling point is 0.1

∘
C then
what will be the boiling point of NaCl solution for same molal
concentration
A. 0.1 ∘
C
B. 0.08 ∘
C
C. 0.2 ∘
C
D. 0.01 ∘
C
Answer: C
69. For 0.1M solution ,the colligative property will follow the order
A. N aCl > N a2 SO4 > N a3 P O4

B. N aCl > N a2 SO4 ≈ N a3 P O4
C. N aCl < N a2 SO4 < N a3 P O4
D. N aCl < N a2 SO4 = N a3 P O4
Answer: C
70. If α is the degree of dissociation of N2 SO4 , the van'tHoff factor (i)
used for calculating the molecular mass is
A. 1 + α
B. 1 + 2α
C. 1 − α
D. 1 − 2α
Answer: B

71. pH of a 0.1M monobasic acid is found to be ,Hence its osmotic
2
pressure at a given temp.TK is-
A. 0.1RT
B. 0.11RT
C. 1.1RT
D. 0.01RT
Answer: B
72. Which has the highest boiling point?
A. 0.1mN 2
SO4
B. 0.1mAl(N O 3
)
3
C. 0.1mM gCl 2
D. 0.1mC 6
H12 O6 (glucose)
Answer: C
73. The van't Hoff factory i for an infinitely dilute solution of N aSO is :
4
A. 1 / 2
B. 1 / 3
C. 3
D. 2
Answer: C

74. 1mol each of the following solutes are taken in 5mol water,
(a)N aCl (b)K 2

SO4 ( C)N a(3)P O (d) glucose
4
Assuming 100 % ionisation of the electrolyte ,relative decrease in vapour
pressure will be in order
A. A < B < C < D
B. D < C < B < A
C. D < A < B < C
D. equal
Answer: C
75. Aluminium phosphate is 100 % ionised in molal aqueous

0.01
solution,Hence,ΔT b
/ Kb is :
A. 0.01
B. 0.015
C. 0.0175
D. 0.02
Answer: D
76. 1.0 molal aqueous solution of an electrolyte X 3

Y2 is 25 % ionized. The
boilling point of solution is (K for H

b 2
O = 0.52Kkg / mol )
A. 375.5K
B. 374.04K
C. 377.12K
D. 373.25K
Answer: B

77. Aqueous solution of barium phosphate which is 100 % ionised has
ΔTf / Kf as 0.05.Hence ,given solution is
A. 0.01 molal
B. 0.02 molal
C. 0.04 molal
D. 0.05 molal
Answer: A
78. A0.2 molal aqueous solution of a week acid (HX) is 20 % ionised,The
frrezing point of this solution is (Given k f

= 1.86
∘
Ckgmol
−1
for water) :
A. − 0.45 ∘
C
B. − 0.90 ∘
C
C. − 0.31 ∘
C
D. − 0.53 ∘
C
Answer: A
79. Phenol associates in benzene to certain extent to form a dimer. A
solution containing 20 × 10
−3
kg of phenol in 1.0kg of benzene hs its
freezing point depressed by 0.69K. Calculate the fraction of phenol that
has dimerized. (K for benzene is 5.12Kkgmol

f
−1
).
A. 746.24
B. 646.24
C. 846.24
D. 546.23
Answer: A
80. A solution of crab haemovyanin, a pigmented protein extracted from
crabs,was prepared by dissolving 0.750gin125cm

3
of aqueous medium.AT
4
∘
C an osmotic pressure rise of mm of the solution was observed.
2.6
The solution has a density of 1.00g / cm .Determine the molecular weight

3
of the protein.
A. 53.14 × 10 5
g / mol
B. 52.14 × 10 5
g / mol
C. 51.14 × 10 5
g / mol
D. 54.14 × 10 5
g / mol
Answer: A

81. A complex of iron and cyanide ions is 100 % ionised ar 1m (molal). If its
elevation in b.p.is 2.08 then the complex is (K b

= 0.52
∘
mol
−1
kg) ,
A. K 3
[F e(CN ) ]
6
B. F e(CN ) 2
C. K 4
[F e(CN ) ]
6
D. F e(CN ) 4
Answer: A
82. The fraction of phenol dimerised in benzene if 20g of phenol in 1kg
benzene exhibits a freezing point depression of 0.69K(Kf benzene
=5.12),(Mw phenol=94).What is the value of Van't Hoff for (i) in this
reaction ?
A. 0.63
B. 0.37
C. 0.46
D. 064
Answer: A
83. A solution containing 2.675g of COCl3 .6N H3 (molar mass
= 267.5gmol
−1
) is passed through a cation exchanger, The chloride ions
obtined in solution were treated with excess of AgN O3 to give4.78g of
AgCl(molar mass = 143.5gmol

−1
.The formula of the complex is
(Atomic mass of Ag = 108u )
A. [Co(N H 3
) ]Cl3
6
B. [CoCl 2
(N H3 ) ]Cl
4
C. [CoCl 3
(N H3 ) ]
3
D. [CoCl(N H 3
) ]Cl2
5
Answer: A
84. If sodium sulphate is considered to be completely dissociated into
cations and anions in aqueous solution,the change in freezing point of
water(ΔT ),when
f
mole of sodium sulphate is dissoved in
0.01 1 kg of
water,is (K f
= 1.86Kkgmol
−1
)
A. 0.0372K
B. 0.0558K
C. 0.0744K
D. 0.0186K
Answer: B

85. Which salt may show the same value of vant Hoff factor (i)as that of
K4 F e(CN )
6
in very dilute solution state?
A. Al 2
(SO4 )
3
B. N aCl
C. Al(N O 3
)
3
D. N a 2
SO4
Answer: A
86. The freezing point of a 0.05 molal solution of a non-electrolyte in
water is:
(Kf
= 1.86molality
−1
)
A. − 1.86 ∘
C
B. − 0.93 ∘
C
C. − 0.093 ∘
C
D. 0.93 ∘
C
Answer: C
87. Which of the following aqueous solution shas osmotic presseure
nearest to that of an equimolar solution of K

4
[F e(CN ) ]
6
A. N a 2
SO4
B. BaCl 2
C. Al 2
(SO4 )
3
D. C12
H22 O11
Answer: C

88. Which aqueous solution would process the lowest boiling point?
A. 1 % N aClsolution
B. 1 % urea solution
C. 1% Glucose solution
D. 1 % sucrose solution
Answer: D
89. An aqueous solution boils at 100.50

∘
C .The freezing point of the
solution would be (Kb for water = 0.51

∘
C / m), (Kf for water
= 1.86
∘
C /m ) [no association or dissociation]
A. 0 ∘
C
B. − 1.86 ∘
C
C. − 1.82 ∘
C
D. + 1.82 ∘
C
Answer: B
90. For an ideal solution containing a non-volatille solute, which of the
following expression is correct represented?
where m is the molality of the solution andK is molal elevation constant.

b
A. ΔT b
= Kb × m
B. ΔT b
= Kb × M
C. ΔT b
= Kb × 2m
D. ΔT b
= Kb × 2M
Answer: A

91. 20 g of a binary electrolyte(mol.wt.=100)are dissolved in 500 g of
water.The freezing point of the solution is
− 0.74
∘
CKf = 1.86Kmolality
−1
.the degree of ionization of the
electrolyte is
A. 50 %
B. 75 %
C. 10 %
D. 0 %
Answer: D
92. The ratio of the value of any collogative property for K4 [F e(CN ) ]
6
solution to that of F e 4
[F e(CN ) ]
6 3
(prussian blue,)solution is nearly
A. 1
B. 0.71
C. 1.4
D. Less than 1
Answer: B

Books Doubtnut Question Bank

Uploaded by

Copyright:

Available Formats

Books Doubtnut Question Bank

Uploaded by

Document Information

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Books Doubtnut Question Bank

Uploaded by

Copyright:

Available Formats

CHEMISTRY

BOOKS - A2Z CHEMISTRY (HINGLISH)

Method Of Expressing Concentration Of Solutions

1. Which of the following concentration factors is affected by changing in

volume or volume dependent ?

grams of 25 % cane sugar solution-

A. 187.5 grams, 62.5 grams

B. 62.5 grams, 187.5 grams

C. 162.5 grams, 87.5 grams

Watch Video Solution

3. A solution of Al2 (SO4 ) {d = 1.253gm / ml}

weight. The molarity, normality and molality of the solution is

A. 0.825M , 48.3N , 0.805 m

C. 4.83M , 4.83N , 4.83 m

Watch Video Solution

concentration of urea solution is (N 0

Watch Video Solution

N aOH dissolved in 500ml solution

Watch Video Solution

6. If 25ml of N aCl solution is diluted with water to a volume of 500ml

the new concentration of the solution is

Watch Video Solution

7. An X molal solution of a compound in benzene has mole fraction of

solute = 0.2. The value of X is

Watch Video Solution

Watch Video Solution

9. Molarity and molality of a solution of caustic soda are respectively

11.12M and 94.12m. The density of the solution is

Watch Video Solution

10. 5ml of H Cl, 20ml of N /2 of H2 SO4 and 30ml of N / 3H N O3 are

mixed together and volume made to one litre.

Watch Video Solution

Watch Video Solution

12. Which of the following aqueous solutions has the highest

B. A solution containing 2.06gN aCl / 100mL

C. A solution having 15.4mgN a +

Watch Video Solution

13. Mole fraction of C

Watch Video Solution

Watch Video Solution

15. The molality of a urea solution in which 0.0100g of urea, [(N H 2

is added to 0.3000dm of water at STP is

Watch Video Solution

16. 15 grams of methyl alcohol is dissolved in 35 grams of water. What is

the mass percentage of methyl alcohol in solution ?

Watch Video Solution

What is the mole fraction of methyl alcohol in the solution ?

Watch Video Solution

18. In which mode of expression, the concentration of a solution remains

Watch Video Solution

19. The density of a solution containing 13 % by mass of sulphuric acid is

1.09g / mL . Calculate the molarity and normality of the solution

Watch Video Solution

Watch Video Solution

21. Calculate the quantity of sodium carbonates(anhydrous ) required to

prepare 250ml solution

Watch Video Solution

22. 20ml of 0.02M KM nO4 was required to completely oxidise 10ml of

Watch Video Solution