1 Demulsifier Eb-8029.me

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REVISION DATE: 22.04.2008 SDS NO.

: 11589

SAFETY DATA SHEET


EB-8029

1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

PRODUCT NAME EB-8029


APPLICATION Demulsifier
SUPPLIER M-I SWACO
Gamle Forusvei 43
4033 Stavanger
NORWAY.
Tel.: +47 51 57 73 00
Fax.: +47 51 57 73 98
ihelland@miswaco.com
CONTACT PERSON Ingrid Helland, telephone: +47 51 57 74 24
EMERGENCY TELEPHONE (24 Hour) Europe +44 (0) 208 762 8322, Asia Pacific +65 633 44 177, China +86 10 5100 3039, Middle
East and Africa +961 3 487 287.

2 HAZARDS IDENTIFICATION

Irritating to eyes.

Limited evidence of a carcinogenic effect.

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Repeated exposure may cause skin dryness or cracking.

Vapours may cause drowsiness and dizziness.

Harmful: may cause lung damage if swallowed.


CLASSIFICATION Xn;R65. Carc 3;R40. Xi;R36. N;R51/53. R66, R67.

3 COMPOSITION/INFORMATION ON INGREDIENTS

Name EC No. CAS-No. Content Classification

Solvent naphtha (petroleum), heavy aromatic 30-60% Xn;R65. Carc 3;R40. N;R51/53. R66,R67.

Fuels, diesel 10-30% Xn;R65. Carc 3;R40. N;R51/53. R66.

BENZENESULPHONIC ACID, C10-16-ALKYL 5-10% Xn;R22. Xi;R38,R41.

The Full Text for all R-Phrases are Displayed in Section 16

COMPOSITION COMMENTS
The data shown is in accordance with the latest EC Directives.

4 FIRST-AID MEASURES

INHALATION
Provide rest, warmth and fresh air. In case of persistent throat irritation or coughing: Seek medical attention and bring these instructions.
Place unconscious person on the side in the recovery position and ensure breathing If respiratory problems, artificial respiration/oxygen.
INGESTION
DO NOT INDUCE VOMITING! Immediately rinse mouth and provide fresh air. Immediately give a couple of glasses of water or milk,
provided the victim is fully conscious. Get medical attention. Never give liquid to an unconscious person. If vomiting occurs, keep head
low so that stomach content doesn't get into the lungs.
SKIN CONTACT
Promptly wash contaminated skin with soap or mild detergent and water. Promptly remove clothing if soaked through and wash as above.
Use suitable lotion to moisturise skin. Get medical attention if any discomfort continues.
EYE CONTACT
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.

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REVISION DATE: 22.04.2008 SDS NO.: 11589
EB-8029
5 FIRE-FIGHTING MEASURES

EXTINGUISHING MEDIA
Water spray, foam, dry powder or carbon dioxide. Dry chemicals, sand, dolomite etc.

SPECIAL FIRE FIGHTING PROCEDURES


Containers close to fire should be removed immediately or cooled with water.

SPECIFIC HAZARDS
Fire or high temperatures create: Carbon monoxide (CO). Carbon dioxide (CO2).

PROTECTIVE MEASURES IN FIRE


Self contained breathing apparatus and full protective clothing must be worn in case of fire.

6 ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS
Wear protective clothing as described in Section 8 of this safety data sheet.

ENVIRONMENTAL PRECAUTIONS
Do not allow to enter drains, sewers or watercourses. Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY
alerted to the Environmental Agency or other appropriate regulatory body.
SPILL CLEAN UP METHODS
Stop leak if possible without risk. Dike far ahead of larger spills for later disposal. Absorb spillage with suitable absorbent material. Shovel
into dry containers. Cover and move the containers. Flush the area with water.

7 HANDLING AND STORAGE

USAGE PRECAUTIONS
Avoid spilling, skin and eye contact.

STORAGE PRECAUTIONS
Store in tightly closed original container in a dry, cool and well-ventilated place. Avoid contact with oxidising agents.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

INGREDIENT COMMENTS
No exposure limits noted for ingredient(s).

PROTECTIVE EQUIPMENT

ENGINEERING MEASURES
Provide adequate general and local exhaust ventilation.

RESPIRATORY EQUIPMENT
In case of inadequate ventilation or risk of inhalation of vapours, use suitable respiratory equipment with combination filter (type A2/P2). At
work in confined or poorly ventilated spaces, respiratory protection with air supply must be used.
HAND PROTECTION
Nitrile gloves are recommended, but be aware that the liquid may penetrate the gloves. Frequent change is advisable.

EYE PROTECTION
Wear approved safety goggles.

OTHER PROTECTION
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.

HYGIENE MEASURES
Wash at the end of each work shift and before eating, smoking and using the toilet. Use appropriate skin cream to prevent drying of skin.
Promptly remove non-impervious clothing that becomes wet or contaminated. Wash contaminated clothing before reuse.

9 PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE Clear liquid


COLOUR Light (or pale) Yellow to Amber

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REVISION DATE: 22.04.2008 SDS NO.: 11589
EB-8029
SOLUBILITY Oil Soluble
RELATIVE DENSITY 0.92 20 °C FLASH POINT (°C) 62 °C CC (Closed cup).

10 STABILITY AND REACTIVITY

STABILITY
Stable under normal temperature conditions and recommended use.

CONDITIONS TO AVOID
Avoid heat, flames and other sources of ignition.

MATERIALS TO AVOID
Strong oxidising substances.

11 TOXICOLOGICAL INFORMATION

GENERAL INFORMATION
Known or suspected carcinogen for humans.

INHALATION
Vapours may cause drowsiness and dizziness.

INGESTION
Harmful: may cause lung damage if swallowed. Pneumonia may be the result if vomited material containing solvents reaches the lungs.

SKIN CONTACT
Prolonged contact may cause dryness of the skin.

EYE CONTACT
Irritating to eyes. Spray and vapour in the eyes may cause irritation and smarting.

12 ECOLOGICAL INFORMATION

ECOTOXICITY
The product contains substances which are toxic to aquatic organisms and which may cause long term adverse effects in the aquatic
environment.
MOBILITY
The product is insoluble in water and will spread on the water surface.

BIOACCUMULATION
The product contains potentially bioaccumulating substances.

DEGRADABILITY
The product contains substances which are not expected to be biodegradable.

13 DISPOSAL CONSIDERATIONS

DISPOSAL METHODS
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.

WASTE CLASS
The definitive European Waste code for this product will depend upon the final use that is made of this material. EWC-code: 07 01 04.
Waste number: 7152. Organic waste without halogen.

14 TRANSPORT INFORMATION

GENERAL .

UK ROAD CLASS 9
PROPER SHIPPING NAME ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Solvent naphtha (petroleum),
heavy arom.)

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REVISION DATE: 22.04.2008 SDS NO.: 11589
EB-8029
UN NO. ROAD 3082 UK ROAD PACK GR. III
ADR CLASS NO. 9 ADR CLASS Class 9: Miscellaneous
dangerous substances and
articles.
ADR PACK GROUP III HAZARD No. (ADR) 90
HAZCHEM CODE 3Z CEFIC TEC(R) NO. 90GM6-III
RID CLASS NO. 9 RID PACK GROUP III
UN NO. SEA 3082 IMDG CLASS 9
IMDG PACK GR. III EMS F-A, S-F
MARINE POLLUTANT No. UN NO. AIR 3082
AIR CLASS 9 AIR PACK GR. III

15 REGULATORY INFORMATION

LABELLING

Harmful Dangerous for the


environment
CONTAINS Solvent naphtha (petroleum), heavy aromatic
Fuels, diesel
BENZENESULPHONIC ACID, C10-16-ALKYL

RISK PHRASES
R36 Irritating to eyes.

R40 Limited evidence of a carcinogenic effect.

R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R66 Repeated exposure may cause skin dryness or cracking.

R67 Vapours may cause drowsiness and dizziness.

R65 Harmful: may cause lung damage if swallowed.

SAFETY PHRASES
S25 Avoid contact with eyes.

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S36/37 Wear suitable protective clothing and gloves.

S61 Avoid release to the environment. Refer to special instructions/safety data sheets.

S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this
container or label.
UK REGULATORY REFERENCES
Chemicals (Hazard Information & Packaging) Regulations.

EU DIRECTIVES
Dangerous Substance Directive 67/548/EEC. Dangerous Preparations Directive 1999/45/EC.

GUIDANCE NOTES
Workplace Exposure Limits EH40.

16 OTHER INFORMATION

INFORMATION SOURCES
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. Micromedex. European
Chemicals Bureau - ESIS (European Chemical Substances Information).
ISSUED BY
Bente K. Sandø
REVISION DATE 22.04.2008
REV. NO./REPL. SDS GENERATED 03.02.2007

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REVISION DATE: 22.04.2008 SDS NO.: 11589
EB-8029
SAFETY DATA SHEET STATUS
Approved.
DATE 03.02.2007

RISK PHRASES IN FULL


R22 Harmful if swallowed.
R38 Irritating to skin.
R40 Limited evidence of a carcinogenic effect.
R41 Risk of serious damage to eyes.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.

DISCLAIMER
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of
the data are obtained from sources beyond our direct supervision. We cannot make any assertions as to its reliability or
completeness; therefore, user may rely only at user's risk. We have made no effort to censor or conceal deleterious aspects of
this product. Since we cannot anticipate or control the conditions under which this information and product may be used, we
make no guarantee that the precautions we have suggested will be adequate for all individuals and/or situations. It is the
obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this
product. Additional information will be furnished upon request to assist the user; however, no warranty, either expressed or
implied, nor liability of any nature with respect to this product or to the data herein is made or incurred hereunder.
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