Safety Data Sheet: Caustic Soda
Safety Data Sheet: Caustic Soda
Safety Data Sheet: Caustic Soda
Caustic Soda
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY UNDERTAKING
2. HAZARDS IDENTIFICATION
3. COMPOSITION/INFORMATION ON INGREDIENTS
COMPOSITION COMMENTS
The data shown is in accordance with the latest EC Directives
4. FIRST-AID MEASURES
INHALATION
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get
medical attention if any discomfort continues.
INGESTION
Do not induce vomiting. Immediately give a couple of glasses of water or milk, provided the victim is fully
conscious. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Get medical
attention immediately.
SKIN CONTACT
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention
immediately.
EYE CONTACT
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of
water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention immediately.
Continue to rinse.
5. FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA
Use fire-extinguishing media appropriate for surrounding materials.
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SPECIAL FIRE FIGHTING PROCEDURES
Containers close to fire should be removed immediately or cooled with water. Do not use water jet as an
extinguisher, as this will spread the fire.
SPECIFIC HAZARDS
By heating and fire, corrosive vapours/gases may be formed.
PROTECTIVE MEASURES IN FIRE
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
PERSONAL PRECAUTIONS
Wear protective clothing as described in Section 8 of this safety data sheet.
ENVIRONMENTAL PRECAUTIONS
Do not allow to enter drains, sewers or watercourses.
SPILL CLEAN UP METHODS
Avoid generation and spreading of dust. Shovel into dry containers. Cover and move the containers. Flush the
area with water.
USAGE PRECAUTIONS
Avoid inhalation of dust and contact with skin and eyes.
USAGE DESCRIPTION
Do not add water directly to the product. It may cause a violent reaction.
STORAGE PRECAUTIONS
Store in tightly closed original container in a dry, cool and well-ventilated place.
APPEARANCE Pellets
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COLOUR White
ODOUR Odourless
MOL. WEIGHT 40.01
BOILING POINT (°C) 1390°C 760 mm Hg
MELTING POINT (°C) 318.4°C
RELATIVE DENSITY 2.13 g/cm3 @ 20°C
BULK DENSITY 900 - 1200 kg/m3
VAPOUR PRESSURE 3.5 h Pa @ 800°C
pH-VALUE, DILUTED SOLUTION 14.0 @ 1% SOLUBILITY VALUE (g/100g H2O@20°C) : 50.0
STABILITY
Stable under normal temperature conditions and recommended use.
CONDITIONS TO AVOID
Do not add water directly to the product. It may cause a violent reaction.
HAZARDOUS DECOMPOSITION PRODUCTS
By heating and fire, corrosive vapours/gases may be formed.
INHALATION
Dust may irritate respiratory system or lungs.
INGESTION
Corrosive. Even small amounts may cause serious damage. May irritate and cause stomach pain, vomiting and
diarrhoea.
SKIN CONTACT
Irritating to skin. Irritating and may cause redness and pain.
EYE CONTACT
Irritating to eyes. Particles in the eyes may cause irritation and smarting.
DISPOSAL METHODS: Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance
with local authority requirements. This material and its container must be disposed of as hazardous waste.
CORROSIVE
UK ROAD CLASS 8
PROPER SHIPPING NAME SODIUM HYDROXIDE, SOLID
UN NO. ROAD 1823
UK ROAD PACK GR. II
ADR CLASS NO. 8
ADR CLASS Class 8: Corrosive substances.
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ADR PACK GROUP II
HAZARD No. (ADR) 80
HAZCHEM CODE 2W
CEFIC TEC(R) NO. 80GC6-II+III
RID CLASS NO. 8
RID PACK GROUP II
UN NO. SEA 1823
IMDG CLASS 8
IMDG PACK GR. II EMS F-A, S-B
MARINE POLLUTANT No.
UN NO. AIR 1823
AIR CLASS 8
AIR PACK GR. II
LABELLING: Corrosive
RISK PHRASES: R35 causes severe burns.
SAFETY PHRASES
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).
S37/39 Wear suitable gloves and eye/face protection.
UK REGULATORY REFERENCES
Chemicals (Hazard Information & Packaging) Regulations.
EU DIRECTIVES
Dangerous Substance Directive 67/548/EEC. Dangerous Preparations Directive 1999/45/EC.
GUIDANCE NOTES
Workplace Exposure Limits EH40
INFORMATION SOURCES
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers.
Micromedex. European Chemicals Bureau - ESIS (European Chemical Substances Information).
DISCLAIMER
The statements, information, and data provided in this Safety Data Sheet are believed reliable and accurate by
IDEC and its responsible personnel. The information is furnished without warranty, expressed or implied, as to
accuracy or completeness. The information is obtained from various sources including the manufacturer and
other third party sources. The information may not be valid under all conditions nor if this material is used in
combination with other materials or in any process. Final determination of suitability of any material is the sole
responsibility of the user. It is the obligation of each user of this product to comply with the requirements of all
applicable laws regarding use and disposal of this product.
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