Safety Data Sheet: Caustic Soda

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SAFETY DATA SHEET

Caustic Soda
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY UNDERTAKING

PRODUCT NAME Caustic Soda


APPPLICATION pH Control
SUPPLIER International Drilling Fluids and Engineering Services (IDEC) Ltd.
Office # 802, Reef Tower, JLT
P.O. Box 31968, Dubai, UAE
Tel: +971 4 451 8052
Fax: +971 4 451 8032
Emergency Telephone Tel: +971 4 451 8052

2. HAZARDS IDENTIFICATION

Causes severe burns. : CLASSIFICATION C; R35.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Name. EC No CAS-No Content Classification


SODIUM HYDROXIDE SOLID 215-185-5 1310-73-2 60 – 100% C;R35

The Full Text for all R-Phrases are Displayed in Section 16

COMPOSITION COMMENTS
The data shown is in accordance with the latest EC Directives

4. FIRST-AID MEASURES

INHALATION
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get
medical attention if any discomfort continues.
INGESTION
Do not induce vomiting. Immediately give a couple of glasses of water or milk, provided the victim is fully
conscious. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Get medical
attention immediately.
SKIN CONTACT
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention
immediately.
EYE CONTACT
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of
water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention immediately.
Continue to rinse.

5. FIRE-FIGHTING MEASURES

EXTINGUISHING MEDIA
Use fire-extinguishing media appropriate for surrounding materials.

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SPECIAL FIRE FIGHTING PROCEDURES
Containers close to fire should be removed immediately or cooled with water. Do not use water jet as an
extinguisher, as this will spread the fire.
SPECIFIC HAZARDS
By heating and fire, corrosive vapours/gases may be formed.
PROTECTIVE MEASURES IN FIRE
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

6. ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS
Wear protective clothing as described in Section 8 of this safety data sheet.
ENVIRONMENTAL PRECAUTIONS
Do not allow to enter drains, sewers or watercourses.
SPILL CLEAN UP METHODS
Avoid generation and spreading of dust. Shovel into dry containers. Cover and move the containers. Flush the
area with water.

7. HANDLING AND STORAGE

USAGE PRECAUTIONS
Avoid inhalation of dust and contact with skin and eyes.
USAGE DESCRIPTION
Do not add water directly to the product. It may cause a violent reaction.
STORAGE PRECAUTIONS
Store in tightly closed original container in a dry, cool and well-ventilated place.

8. EXPOSURE CONTROL/PERSONAL PROTECTION

SODIUM HYDROXIDE SOLID


STD: WEL
ST: 2 mg/m3
INGREDIENT COMMENTS: WEL = Workplace Exposure Limits

PROTECTIVE EQUIPMENT: Glasses / Mask / Gloves / Coveralls


ENGINEERING MEASURES
Provide adequate general and local exhaust ventilation.
RESPIRATORY EQUIPMENT
No specific recommendation made, but respiratory protection may still be required under exceptional
circumstances when excessive air
contamination exists. Dust filter P2 (for fine dust).
HAND PROTECTION
Use protective gloves made of: Impermeable material. Butyl rubber. Polyvinyl chloride (PVC). Neoprene.
EYE PROTECTION
Wear dust resistant safety goggles where there is danger of eye contact.
OTHER PROTECTION
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
9. PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE Pellets

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COLOUR White
ODOUR Odourless
MOL. WEIGHT 40.01
BOILING POINT (°C) 1390°C 760 mm Hg
MELTING POINT (°C) 318.4°C
RELATIVE DENSITY 2.13 g/cm3 @ 20°C
BULK DENSITY 900 - 1200 kg/m3
VAPOUR PRESSURE 3.5 h Pa @ 800°C
pH-VALUE, DILUTED SOLUTION 14.0 @ 1% SOLUBILITY VALUE (g/100g H2O@20°C) : 50.0

10. STABILITY AND REACTIVITY

STABILITY
Stable under normal temperature conditions and recommended use.
CONDITIONS TO AVOID
Do not add water directly to the product. It may cause a violent reaction.
HAZARDOUS DECOMPOSITION PRODUCTS
By heating and fire, corrosive vapours/gases may be formed.

11. TOXICOLGICAL INFORMATION

INHALATION
Dust may irritate respiratory system or lungs.
INGESTION
Corrosive. Even small amounts may cause serious damage. May irritate and cause stomach pain, vomiting and
diarrhoea.
SKIN CONTACT
Irritating to skin. Irritating and may cause redness and pain.
EYE CONTACT
Irritating to eyes. Particles in the eyes may cause irritation and smarting.

12. ECOLOGICAL INFORMATION

ECOTOXICITY: Contact IDEC’s QHSE Department for ecological information.

13. DISPOSAL CONSIDERATIONS

DISPOSAL METHODS: Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance
with local authority requirements. This material and its container must be disposed of as hazardous waste.

14. TRANSPORT INFORMATION

CORROSIVE

UK ROAD CLASS 8
PROPER SHIPPING NAME SODIUM HYDROXIDE, SOLID
UN NO. ROAD 1823
UK ROAD PACK GR. II
ADR CLASS NO. 8
ADR CLASS Class 8: Corrosive substances.

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ADR PACK GROUP II
HAZARD No. (ADR) 80
HAZCHEM CODE 2W
CEFIC TEC(R) NO. 80GC6-II+III
RID CLASS NO. 8
RID PACK GROUP II
UN NO. SEA 1823
IMDG CLASS 8
IMDG PACK GR. II EMS F-A, S-B
MARINE POLLUTANT No.
UN NO. AIR 1823
AIR CLASS 8
AIR PACK GR. II

15. REGULATORY INFORMATION

LABELLING: Corrosive
RISK PHRASES: R35 causes severe burns.
SAFETY PHRASES
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).
S37/39 Wear suitable gloves and eye/face protection.
UK REGULATORY REFERENCES
Chemicals (Hazard Information & Packaging) Regulations.
EU DIRECTIVES
Dangerous Substance Directive 67/548/EEC. Dangerous Preparations Directive 1999/45/EC.
GUIDANCE NOTES
Workplace Exposure Limits EH40

16. OTHER INFORMATION

INFORMATION SOURCES
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers.
Micromedex. European Chemicals Bureau - ESIS (European Chemical Substances Information).

RISK PHRASES IN FULL


R35 Causes severe burns

Publication Date: August 2013

DISCLAIMER
The statements, information, and data provided in this Safety Data Sheet are believed reliable and accurate by
IDEC and its responsible personnel. The information is furnished without warranty, expressed or implied, as to
accuracy or completeness. The information is obtained from various sources including the manufacturer and
other third party sources. The information may not be valid under all conditions nor if this material is used in
combination with other materials or in any process. Final determination of suitability of any material is the sole
responsibility of the user. It is the obligation of each user of this product to comply with the requirements of all
applicable laws regarding use and disposal of this product.

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