"NEET / AIIMS - 2017 "

1. In the reaction
(1) NaNH2/liq.NH3 (1) NaNH2/liq.NH3
X Y
(2) NH 3CH 2 Br (2) NH 3CH 2 Br

X and Y are :
(1) X = 1 – Butyne; Y = 3 – Hexyne (2) X = 2 – Butyne; Y = 3 – Hexyne
(3) X = 2 – Butyne; Y = 2 – Hexyne (4) X = 1 – Butyne; Y = 2 – Hexyne

2. Among the following the correct order of acidity is :

(1) HClO3 < HClO4 < HClO2 < HClO (2) HClO < HClO2 < HClO3 < HClO4
(3) HClO2 < HClO < HClO3 < HClO4 (4) HClO4 < HClO2 < HClO < HClO3

3. The rate of first order reaction is 0.04 mol l–1 s–1 at 10 seconds and 0.03 mol l–1 s–1 at 20 seconds after intiation of the
reaction. The half – life period of the reaction is :
(1) 24.1 s (2) 34.1 s
(3) 44.1 s (4) 54.1 s

4. In which of the following options the order of arrangement does not agree with the variation of property indicated
against it ?
(1) Al3+ > Mg2+ < Na+ < F – (increasing ionic size)
(2) B < C < N < O (increasing first ionisation enthalpy)
(3) I < Br < Cl < F (increasing electron gain enthalpy)
(4) Li < Na < K < Rb (increasing metallic radius)

5. In a protein molecule various amino acids are linked together by :

(1)  – glycosidid bond (2)  – glycosidic bond
(3) Peptide bond (4) Dative bond

6. Natural rubber has :

(1) All cis – configuration (2) All trans – configuration
(3) Allternate cis – and trans – configuration (4) Random cis – and trans – configuration

7. Which one of the following statements is correct when SO2 is passes through acidified K2Cr2O7 solution ?
(1) The solution turns blue (2) The solution is decolorized
(3) SO2 is reduced. (4) Green Cr2(SO4)3 is formed

8. Lithium has a bcc structure. Its density is 530 kg m–3 and its atomic mass is 6.94g mol–1. Calculate the edge lenth
of a unit cell of Lihium metal. (NA = 6.02  1023 mol–1)
(1) 154 pm (2) 352 pm
(3) 527 pm (4) 264 pm

9. Which of the following is an analgesic ?

(1) Novaligin (2) Penicllin
(3) Streptomycin (4) Chloromycetion

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10. Equal moles of hydrogen and oxygen gases are placed in a container with a pin–hole through which both can
escape. What fraction of the oxygen escapes in the time required for one–half of the hydrogen to escape ?
(1) 1/8 (2) 1/4
(3) 3/8 (4) 1/2

11. Which of the following has longest C – O bond length ? (Free C – O bond length in CO is 1.28Å. )
(1) Ni(CO)4 (2) [Co(CO)4]
2–
(3) [Fe(CO)4] (4) [Mn(CO)6] +

12. The pressure of H2 required to make the potential of H2 – electrode zero in pure water at 298 K is:
(1) 10 –14atm (2) 10 –12atm
(3) 10 –10atm (4) 10 –4atm

13. The addition of a catalyst during a chemical reaction alters which of the following quantities ?
(1) Entropy (2) Inernal Energy
(3) Enthalpy (4) Activation Energy

14. The ionic radii of A+ and B– ions are 0.98  10–10 m and 1.81  10–10 m. The coordination number of each ion in AB is
:
(1) 6 (2) 4
(3) 8 (4) 2

15. Which is the correct statement for the given acids ?

(1) Phosphinic acid is a diprotic acid while Phosphonic acid is a monoprotic acid.
(2) Phosphinic acid is a monoprotic acid while Phosphonic acid is a diprotic acid
(3) Both are triprotic acids.
(4) Both are diprotic acids.

16. Which of the following statements about the composition of the vapour ouver an ideal 1 : 1 molar mixture of
benzene and toluene is correct ? Assume that the temperature is constant at 25°C. (Given, Vapour Pressure Data at
25°C, benzene = 12.8 kPa, toluene = 3.85 kPa)
(1) The vapour will contain a higher percentage of benzene.
(2) The vapour will contain a higher percentage of toluene.
(3) The vapour will contain equal amounts of benzene and toluene.
(4) Not enough information is given to make a prediction.

17. The correct statement regarding the comparison of staggered and eclipsed conformations of ethane, is:
(1) The staggered conformation of ethane is less stable than eclipsed conformation, because staggered
conformation has torsional strain.
(2) The eclipsed conformation of ethane is more stable than staggered conformation, because eclipsed
conformation has no torsional strain.
(3) The eclipsed conformation of ethane is more stable than staggered conformation even though the eclipsed
conformation has torsional strain.
(4) The staggered conformation of ethane is more stable than eclipsed conformation, because staggered
conformation has no torsional strain.

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18. For the following reactions:

(a) CH3CH2CH2Br + KOH  CH3CH = CH2 + KBr + H2O

H3C CH3 H3C CH3

(b) + KOH + KBr
Br OH

Br
(c) + Br2
Br
Which of the following statements is correct ?
(1) (a) and (b) are elimination reaction and (c) is addition reaction.
(2) (a) is elimination, (b) is substitution and (c) is addition reaction.
(3) (a) is elimination, (b) and (c) are substitution reaction.
(4) (a) is substitution, (b) and (c) are addition reactions.

19. The correct statement regarding RNA and DNA, respectively is :

(1) The sugar component in RNA is arabinose and the sugar component in DNA is 2' – deoxyribose.
(2) The sugar component in RNA is ribose and the sugar component in DNA is 2' – deoxyribose.
(3) The sugar component in RNA is arabinose and the sugar component in DNA is ribose.
(4) The sugar component in RNA is 2' – deoxyribose and the sugar component in DNA is arabinose.

20. The correct statement regarding the basicity of arylamines is :

(1) Arylamines are generally less basic than alkylamines because the nitrogen lone-pair electrons are delocalized
by interaction with the aromatic rign  electron system.
(2) Arylamines are generally more basic than alkylamines because the nitrogen lone-pair electrons are delocalized
by interaction with the aromatic ring  electron system.
(3) Arylamines are generally more basic than alkylamines because of aryl group.
(4) Arylamines are generally more basic than alkylamines, because the nitrogen atom in arylamines is
sp –hybridized.

21. The function of “Sodium pump” is a biological process operating in each and every cell of all animals. Which of
the following biologically important ions is also a constituent of thish pump ?
(1) Ca2+ (2) Mg2+
(3) K+ (4) Fe2+

22. “Metals are usually not found as nitrates in their ores”, Out of the following two (a and b) reasons which is/are
true for the above observation ?
(a) Metal nitrates are highly unstable
(b) Metal nitrates are highly soluble in water
(1) a and b are true (2) a and b are false
(3) a is false but b is true (4) a is true but b is false

23. Solubility of the alkaline earth’s metal sulphates in water decreases in the sequence :
(1) Mg > Ca > Sr > Ba (2) Ca > Sr > Ba > Mg
(3) Sr > Ca > Mg > Ba (4) Ba > Mg > Sr > Ca

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24. Which of the following pairs of ions are isoelectronic and isostructural ?

(1) CO 32  ,SO 2-
3
(2) ClO3 , CO 32-

(3) SO32 , NO -3 (4) ClO3 ,SO 32-

25. Which of the following options represents the correct bond order ?

(1) O-2 > O 2 > O 2+ (2) O-2 < O 2 < O 2+

(3) O-2 > O 2 < O 2+ (4) O-2 < O 2 > O 2+

26. Which one is not equal to zero for an ideal solution ?

(1)  mix (2) Smix

(3) Vmix (4) P = Pobserved  PRaoult

27. A mixture of gases contains H2 and O2 gases in the ratio of 1:4 (w/w). What is the molar ratio of the two gases in
the mixture ?
(1) 1 : 4 (2) 4 : 1
(3) 16 : 1 (4) 2 : 1

28. A given metal crystallizes out with a cubic structure having edge length of 361 pm. If there are four metal atoms in
one unit cell, what is the radius of one atom ?
(1) 40 pm (2) 127 pm
(3) 80 pm (4) 108 pm

29. When initial concentration of a reactant is doubled in a reaction, its half – life period is not affected. The order of
the reaction is :
(1) Zero (2) First
(3) Second (4) More than zero but less than first

30. Maximum bond angle at nitrogen is present in which of the following

(1) NO2 (2) NO2

(3) NO2 (4) NO3

31. Cobalt (III) Chloride forms several octahedral complexes with ammonia. Which of the following will not give test for
chloride ions with silver nitrate at 25°C?
(1) CoCl3.3NH3 (2) CoCl3.4NH3
(3) CoCl3.5NH3 (4) CoCl3.6NH3

32. The boiling point of 0.2 mol kg–1 solution of X in water is greater than equimolal solution of Y in water. Which one
of the following statements is true in this case?
(1) X is undergoing dissociation in water
(2) Molecular mass of X is greater than the molecular mass of Y
(3) Molecular mass of X is less than the molecular mass of Y
(4) Y is undergoing dissociation in water, while X undergoes no change

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33. Which one of the following electrolytes has the same value of van’t Hoff’s factor (i) as that of Al2(SO4)3 (if all are
100 % ionized) ?
(1) K2SO4 (2) K3[Fe(CN)6]
(3) Al(NO3)3 (4) K4[Fe(CN)6]

34. The correct bond order in the following species is :

(1) O 22  O +2  O 2 (2) O 22  O 2  O2

(3) O 2  O2  O 
2
(4) O 2  O 2  O 
2

35. The angular momentum of electron in ‘d’ orbital is equal to :

(1) 6 h (2) 2 h

(3) 2 3 h (4) 0 h

36. The Ksp of Ag2CrO4, AgCl, AgBr and AgI are, respectively, 1.1  10–12, 1.8  10–10, 5.0  10–13, 8.3  10–17. Which one
of the following salts will precipitate last if AgNO3 solution is added to the solution containing equal moles of
NaCl, NaBr, NaI and Na2CrO4
(1) Agl (2) AgCl
(3) AgBr (4) AgCrO4

37. Which property of colloidal solution is independent of charge on the colloidal particles ?
(1) Coagulation (2) Electrophoresis
(3) Electro–osmosis (4) Tyndall effect

38. Which of the following statements is correct for a reversible process in a state of equilibrium ?
(1) G  2.30 RTlogK (2) G  2.30 RTlogK
(3) G°  2.30 RTlogK (4) G° 2.30 RTlogK

39. Bithional is generally added to the soaps as an additive to function as a/an :

(1) Softener (2) Dryer
(3) Buffering agent (4) Antiseptic

40. The electrolytic reduction of nitrobenzene in strongly acidic medium mroduces :

(1) P – Aminophenol (2) Azoxybenzene
(3) Azobenzene (4) Aniline

41. In which of the following compounds, the C – Cl bond ionization shall give most stable carbonium ion ?

CH3 CH3
H
C Cl C Cl
(1) (2)
CH3 CH3 CH3

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H
CH
H
Cl

C Cl
(3) (4) H
O2NH2C

42. The reaction

CH3 CH3
- NaCl
CH3 C ONa + CH3CH2Cl CH3 C O - CH2 CH3

CH3 CH3

(1) Williamson Synthesis (2) Williamson continuous etherification process

(3) Etard reaction (4) Gattterman - Koch reaction

43. The reaction of C6H5CH = CHCH3 with HBr produces

(1) C6H5CHCH2CH3 (2) C6H5CH2CHCH3
| |
Br Br

(3) C6H5CH2CH2CH2Br (4) CH = CHCH3

Br

44. Given

H3C CH3 CH3

CH3
CH3
CH3
O O O

(I) (II) (III)

Which of the given compounds can exhibit tautomerism ?
(1) I and II (2) I and III
(3) II and III (4) I, II and III

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45. Given

H3C CH3 H3C CH2 H2C CH2

CH3 CH3 CH2

(I) (II) (III)

The enthalpy of hydrogenation of these compounds will be in the order as :

(1) I > II > III (2) III > II > I
(3) II > III > I (4) II > I > III

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