Marine Gas Oil - ENG

Product Name: MARINE DISTILLATES
Revision Date: 08 May 2018

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SAFETY DATA SHEET

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE
COMPANY / UNDERTAKING
This SDS meets the EU Safety Data Sheet requirements for this material, with the following exceptions: 1) Supplier
address and relevant telephone numbers refer to an ExxonMobil Europe coordination center, but the actual supply may
come from another affiliate of ExxonMobil in Europe; and 2) No country specific information is included.
1.1. PRODUCT IDENTIFIER
Product Description: Hydrocarbons and Additives
Product Code: 708621-60
Trade Names Trade Names

BUNKER BUNKER GO .001%S -12CFPP(W) DYED
GASOIL GASOIL MARINE WINTER (GOW)
LDO MARINE DIESEL OIL
MARINE GASOIL MARINE GASOIL (MGO)
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED AGAINST
Intended Use: Fuel
Identified Uses:
Manufacture of substance
Distribution of substance
Use as an intermediate
Formulation and (re)packing of substances and mixtures
Lubricants - Industrial
Use as a fuel - Industrial
Functional Fluids - Industrial
Use as a fuel - Professional
Use as a fuel - Consumer
See Section 16 for list of REACH Use Descriptors for Identified Uses shown above.
Uses advised against: This product is not recommended for any industrial, professional or consumer use
other than the Identified Uses above.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET

Supplier: Esso Petroleum Company Ltd.
Ermyn Way
Ermyn House
Leatherhead
KT22 8UX Surrey
Great Britain
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Supplier General Contact: (UK) (+44) (0) 1372 222 000

SDS Internet Address: www.msds.exxonmobil.com
E-Mail: sds.uk@exxonmobil.com
1.4. EMERGENCY TELEPHONE NUMBER

24 Hour Emergency Telephone: (UK) (+44) (0) 1372 222 000
National Poison Control Centre: (UK) 111 / (IE) 01 809 2166
SECTION 2 HAZARDS IDENTIFICATION
2.1. CLASSIFICATION OF SUBSTANCE OR MIXTURE
Classification according to Regulation (EC) No 1272/2008

Flammable liquid: Category 3.
Acute inhalation toxicant: Category 4. Skin irritation: Category 2. Carcinogen: Category 2. Specific target organ
toxicant (repeated exposure): Category 2. Aspiration toxicant: Category 1.
Chronic aquatic toxicant: Category 2.
H226: Flammable liquid and vapour.
H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H332: Harmful if inhaled.
H351: Suspected of causing cancer. H373: May cause damage to organs through prolonged or repeated exposure.
Bone marrow, Liver, Thymus
H411: Toxic to aquatic life with long lasting effects.
2.2. LABEL ELEMENTS
Label elements according to Regulation (EC) No 1272/2008
Pictograms:
Signal Word: Danger

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Hazard Statements:
H226: Flammable liquid and vapour.

H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H332: Harmful if inhaled.
H351: Suspected of causing cancer. H373: May cause damage to organs through prolonged or repeated exposure.
Bone marrow, Liver, Thymus
H411: Toxic to aquatic life with long lasting effects.
Precautionary Statements:
P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and
understood. P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233: Keep container tightly closed. P240: Ground and bond container and receiving equipment. P241: Use
explosion-proof electrical, ventilating and lighting equipment. P242: Use non-sparking tools. P243: Take action to
prevent static discharges. P260: Do not breathe mist / vapours. P264: Wash skin thoroughly after handling. P271:
Use only outdoors or in a well-ventilated area. P273: Avoid release to the environment. P280: Wear protective
gloves/protective clothing/eye protection/face protection.
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302 + P352: IF ON SKIN:
Wash with plenty of soap and water. P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water or shower. P304 + P340: IF INHALED: Remove person to fresh air and
keep comfortable for breathing. P308 + P313: IF exposed or concerned: Get medical advice/attention. P312: Call a
POISON CENTER or doctor/physician if you feel unwell. P331: Do NOT induce vomiting. P332 + P313: If skin
irritation occurs: Get medical advice/attention. P362 + P364: Take off contaminated clothing and wash it before
reuse. P370 + P378: In case of fire: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish.
P391: Collect spillage.
P403 + P235: Store in a well-ventilated place. Keep cool. P405: Store locked up.
P501: Dispose of contents and container in accordance with local regulations.
Contains: Fuels, diesel
2.3. OTHER HAZARDS
Physical / Chemical Hazards:

Material can accumulate static charges which may cause an ignition. Material can release vapours that readily
form flammable mixtures. Vapour accumulation could flash and/or explode if ignited.
Health Hazards:
May cause central nervous system depression. High-pressure injection under skin may cause serious
damage. Under conditions of poor personal hygiene and prolonged repeated contact, some polycyclic
aromatic compounds (PACs) have been suspected as a cause of skin cancer in humans. May be irritating to
the eyes, nose, throat, and lungs.
Environmental Hazards:
No additional hazards. Material does not meet the criteria for PBT or vPvB in accordance with REACH Annex
XIII.
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

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3.1. SUBSTANCES Not Applicable. This material is regulated as a mixture.
3.2. MIXTURES
This material is defined as a mixture.
Reportable hazardous substance(s) complying with the classification criteria and/or with an exposure limit
(OEL)
Name CAS# EC# Registration# Concentration GHS/CLP
* classification
Fuels, diesel 68334-30-5 269-822-7 01-2119484664-27 > 99% [Aquatic Acute 2 H401],
Aquatic Chronic 2 H411,
Acute Tox. 4 H332,
Asp. Tox. 1 H304,
Carc. 2 H351,
Flam. Liq. 3 H226,
Skin Irrit. 2 H315,
STOT RE 2 H373,
Note N
Note - any classification in brackets is a GHS building block that was not adopted by the EU in the CLP regulation (No 1272/2008)
and therefore is not applicable in the EU or in non-EU countries which have implemented the CLP regulation and is shown for
informational purposes only.
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
NOTE: Composition may contain up to 0.5% performance additives and / or dyes.
Note: See SDS Section 16 for full text of hazard statements.
SECTION 4 FIRST AID MEASURES
4.1. DESCRIPTION OF FIRST AID MEASURES
INHALATION
Immediately remove from further exposure. Get immediate medical assistance. For those providing
assistance, avoid exposure to yourself or others. Use adequate respiratory protection. Give supplemental
oxygen, if available. If breathing has stopped, assist ventilation with a mechanical device.
SKIN CONTACT
Remove contaminated clothing. Dry wipe exposed skin and cleanse with waterless hand cleaner and follow
by washing thoroughly with soap and water. For those providing assistance, avoid further skin contact to
yourself or others. Wear impervious gloves. Launder contaminated clothing separately before reuse.
Discard contaminated articles that cannot be laundered. If product is injected into or under the skin, or into any
part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated
immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection
may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the
ultimate extent of injury.
EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance.
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INGESTION
Seek immediate medical attention. Do not induce vomiting.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
Headache, dizziness, drowsiness, nausea and other CNS effects. Itching, pain, redness, swelling of skin.
Local necrosis as evidenced by delayed onset of pain and tissue damage a few hours after injection.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED
If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately.
Contains hydrocarbon solvent/petroleum hydrocarbons; skin contact may aggravate an existing dermatitis.
SECTION 5 FIRE FIGHTING MEASURES
5.1. EXTINGUISHING MEDIA

Suitable Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.
Unsuitable Extinguishing Media: Straight streams of water
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE

Hazardous Combustion Products: Aldehydes, Incomplete combustion products, Oxides of carbon, Smoke,
Fume, Sulphur oxides
5.3. ADVICE FOR FIRE FIGHTERS

Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering
streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in
enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces
and to protect personnel.
Unusual Fire Hazards: Hazardous material. Firefighters should consider protective equipment indicated in
Section 8.
FLAMMABILITY PROPERTIES
Flash Point [Method]: >=60°C (140°F) [Typical]
Upper/Lower Flammable Limits (Approximate volume % in air): UEL: 7.0 LEL: 0.6 [test method
unavailable]
Autoignition Temperature: >250°C (482°F) [test method unavailable]
SECTION 6 ACCIDENTAL RELEASE MEASURES
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
regulations.
PROTECTIVE MEASURES
Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if
required, due to toxicity or flammability of the material. See Section 5 for fire fighting information. See
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the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section
8 for advice on the minimum requirements for personal protective equipment. Additional protective
measures may be necessary, depending on the specific circumstances and/or the expert judgment of the
emergency responders.
For emergency responders: Respiratory protection: half-face or full-face respirator with filter(s) for organic
vapor and, when applicable, H2S, or Self Contained Breathing Apparatus (SCBA) can be used depending
on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or
an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are
resistant to aromatic hydrocarbons are recommended. Note: gloves made of polyvinyl acetate (PVA) are
not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if
splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually
adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended.
6.2. ENVIRONMENTAL PRECAUTIONS

Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways,
sewers, basements or confined areas.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP

Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak
if you can do so without risk. All equipment used when handling the product must be grounded. Do not touch
or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A
vapour-suppressing foam may be used to reduce vapour. Absorb or cover with dry earth, sand or other non-
combustible material and transfer to containers. Use clean non-sparking tools to collect absorbed material.
Large Spills: Water spray may reduce vapour, but may not prevent ignition in enclosed spaces.
Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other
shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist
before using dispersants.
Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
consulted. Note: Local regulations may prescribe or limit action to be taken.
6.4. REFERENCES TO OTHER SECTIONS

See Sections 8 and 13.
SECTION 7 HANDLING AND STORAGE
7.1. PRECAUTIONS FOR SAFE HANDLING

Avoid all personal contact. Do not siphon by mouth. Do not use as a cleaning solvent or other non-motor fuel
uses. For use as a motor fuel only. Do not use electronic devices (including but not limited to cellular
phones, computers, calculators, pagers or other electronic devices etc) in or around any fuelling operation or
storage area unless the devices are certified intrinsically safe by an approved national testing agency and to the
safety standards required by national and/or local laws and regulations. Prevent small spills and leakage to
avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source).
Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard
from static accumulation. Consult local applicable standards for guidance. Additional references include
American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray
Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC
CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity).
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Static Accumulator: This material is a static accumulator. A liquid is typically considered a nonconductive,
static accumulator if its conductivity is below 100 pS/m (100x10E-12 Siemens per meter) and is considered a
semiconductive, static accumulator if its conductivity is below 10,000 pS/m. Whether a liquid is nonconductive
or semiconductive, the precautions are the same. A number of factors, for example liquid temperature,
presence of contaminants, anti-static additives and filtration can greatly influence the conductivity of a liquid.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES

The type of container used to store the material may affect static accumulation and dissipation. Keep
container closed. Handle containers with care. Open slowly in order to control possible pressure release.
Store in a cool, well-ventilated area. Storage containers should be earthed and bonded. Fixed storage
containers, transfer containers and associated equipment should be earthed and bonded to prevent
accumulation of static charge. Keep away from incompatible materials.
7.3. SPECIFIC END USES

Section 1 informs about identified end-uses. No industrial or sector specific guidance available.
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1. CONTROL PARAMETERS
EXPOSURE LIMIT VALUES
Exposure limits/standards (Note: Exposure limits are not additive):
Substance Name Form Limit/Standard Note Source

Fuels, diesel Stable TWA 5 mg/m3 Skin ExxonMobil
Aerosol.
Fuels, diesel Vapour. TWA 200 Skin ExxonMobil
mg/m3
Fuels, diesel [total hydrocarb, TWA 100 Skin ACGIH
vapor&aerosol] Inhalable mg/m3
fraction
and
vapour
Note: Information about recommended monitoring procedures can be obtained from the relevant
agency(ies)/institute(s):
UK Health and Safety Executive (HSE)
DERIVED NO EFFECT LEVEL (DNEL)/DERIVED MINIMAL EFFECT LEVEL (DMEL)
Worker
Substance Name Dermal Inhalation
Fuels, diesel 2.9 mg/kg bw/day DNEL, Chronic Exposure, 68 mg/m3 DNEL, Chronic Exposure,
Systemic Effects Systemic Effects
Consumer
Substance Name Dermal Inhalation Oral
Fuels, diesel 1.3 mg/kg bw/day DNEL, 20 mg/m3 DNEL, Chronic NA
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Chronic Exposure, Systemic Exposure, Systemic
Effects Effects
Note: The Derived No Effect Level (DNEL) is an estimated safe level of exposure that is derived from toxicity data in
accord with specific guidance within the European REACH regulation. The DNEL may differ from an Occupational
Exposure Limit (OEL) for the same chemical. OELs may be recommended by an individual company, a governmental
regulatory body or an expert organization, such as the Scientific Committee for Occupational Exposure Limits (SCOEL)
or the American Conference of Governmental Industrial Hygienists (ACGIH). OELs are considered to be safe exposure
levels for a typical worker in an occupational setting for an 8-hour work shift, 40 hour work week, as a time weighted
average (TWA) or a 15 minute short-term exposure limit (STEL). While also considered to be protective of health, OELs
are derived by a process different from that of REACH.
PREDICTED NO EFFECT CONCENTRATION (PNEC)
Substance Name Aqua Aqua Aqua Sewage Sediment Soil Oral

(fresh (marine (intermittent treatment (secondary
water) water) release) plant poisoning)
Fuels, diesel NA NA NA NA NA NA NA
For hydrocarbon UVCBs, no single PNEC value is identified for the overall substance or used in risk assessment
calculations. Therefore, no PNEC values are disclosed in the above table. For further information, please contact
ExxonMobil.
8.2. EXPOSURE CONTROLS
ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
Use explosion-proof ventilation equipment to stay below exposure limits.
PERSONAL PROTECTION
Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.
Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a

level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
respirators to be considered for this material include:
Half-face filter respirator Type AP filter material., European Committee for Standardization (CEN)
standards EN 136, 140 and 405 provide respirator masks and EN 149 and 143 provide filter
recommendations.
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
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Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions.
Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use
conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material
include:
Chemical resistant gloves are recommended. If contact with forearms is likely wear gauntlet style
gloves. Nitrile, minimum 0.38 mm thickness or comparable protective barrier material with a high
performance level for continuous contact use conditions, permeation breakthrough minimum 480
minutes in accordance with CEN standards EN 420 and EN 374.
Eye Protection: If contact with material is likely, chemical goggles are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
Chemical/oil resistant clothing is recommended.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and
protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be
cleaned. Practice good housekeeping.
For Summary of Risk Management Measures across all identified uses, see Annex.
ENVIRONMENTAL CONTROLS
Comply with applicable environmental regulations limiting discharge to air, water and
soil. Protect the environment by applying appropriate control measures to prevent or limit
emissions.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Note: Physical and chemical properties are provided for safety, health and environmental considerations only
and may not fully represent product specifications. Contact the Supplier for additional information.
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid

Colour: Clear (May Be Dyed)
Odour: Petroleum/Solvent
Odour Threshold: No data available
pH: Not technically feasible
Melting Point: No data available
Freezing Point: No data available
Initial Boiling Point / and Boiling Range: > 180°C (356°F) [test method unavailable]
Flash Point [Method]: >=60°C (140°F) [Typical]
Evaporation Rate (n-butyl acetate = 1): No data available
Flammability (Solid, Gas): Not technically feasible
Upper/Lower Flammable Limits (Approximate volume % in air): UEL: 7.0 LEL: 0.6 [test method
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unavailable]
Vapour Pressure: < 0.04 kPa (0.3 mm Hg) at 20 °C [test method unavailable]
Vapour Density (Air = 1): No data available
Relative Density (at 15 °C): 0.85 [test method unavailable]
Solubility(ies): water Negligible
Partition coefficient (n-Octanol/Water Partition Coefficient): > 3.5 [test method unavailable]
Autoignition Temperature: >250°C (482°F) [test method unavailable]
Decomposition Temperature: No data available
Viscosity: >=3 cSt (3 mm2/sec) at 40ºC [test method unavailable]
Explosive Properties: None
Oxidizing Properties: None
9.2. OTHER INFORMATION
Density: 800 kg/m3 (6.68 lbs/gal, 0.8 kg/dm3) - 910 kg/m3 (7.59 lbs/gal, 0.91 kg/dm3) [test method
unavailable]
SECTION 10 STABILITY AND REACTIVITY
10.1. REACTIVITY: See sub-sections below.
10.2. CHEMICAL STABILITY: Material is stable under normal conditions.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur.
10.4. CONDITIONS TO AVOID: Open flames and high energy ignition sources.
10.5. INCOMPATIBLE MATERIALS: Halogens, Strong Acids, Strong Bases, Strong oxidisers
10.6. HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.
SECTION 11 TOXICOLOGICAL INFORMATION
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS
Hazard Class Conclusion / Remarks

Inhalation
Acute Toxicity: (Rat) 4 hour(s) LC50 4100 Moderately toxic. Based on test data for structurally similar
mg/m3 (Vapor and aerosol) materials. Test(s) equivalent or similar to OECD Guideline 403
Irritation: No end point data for material. Elevated temperatures or mechanical action may form vapours,
mist, or fumes which may be irritating to the eyes, nose, throat, or
lungs.
Ingestion
Acute Toxicity (Rat): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar
Test scores or other study results do not materials. Test(s) equivalent or similar to OECD Guideline 401
meet criteria for classification.
Skin
Acute Toxicity (Rabbit): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar
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Test scores or other study results do not materials. Test(s) equivalent or similar to OECD Guideline 434
Skin Corrosion/Irritation (Rabbit): Data Irritating to the skin. Based on test data for structurally similar
available. Test scores or other study results materials. Test(s) equivalent or similar to OECD Guideline 404
Eye
Serious Eye Damage/Irritation (Rabbit): Data May cause mild, short-lasting discomfort to eyes. Based on test
available. Test scores or other study results data for structurally similar materials. Test(s) equivalent or similar
do not meet criteria for classification. to OECD Guideline 405
Sensitisation
Respiratory Sensitization: No end point data Not expected to be a respiratory sensitizer.
for material.
Skin Sensitization: Data available. Test Not expected to be a skin sensitizer. Based on test data for
scores or other study results do not meet structurally similar materials. Test(s) equivalent or similar to OECD
criteria for classification. Guideline 406
Aspiration: Data available. May be fatal if swallowed and enters airways. Based on physico-
chemical properties of the material.
Germ Cell Mutagenicity: Data available. Not expected to be a germ cell mutagen. Based on test data for
Test scores or other study results do not structurally similar materials. Test(s) equivalent or similar to OECD
meet criteria for classification. Guideline 471 475
Carcinogenicity: Data available. Caused cancer in laboratory animals, but the relevance to humans
is uncertain. Based on test data for structurally similar materials.
Test(s) equivalent or similar to OECD Guideline 451
Reproductive Toxicity: No end point data Not expected to be a reproductive toxicant.
for material.
Lactation: No end point data for material. Not expected to cause harm to breast-fed children.
Specific Target Organ Toxicity (STOT)
Single Exposure: No end point data for Not expected to cause organ damage from a single exposure.
material.
Repeated Exposure: Data available. Concentrated, prolonged or deliberate exposure may cause organ
damage. Based on test data for structurally similar materials.
Test(s) equivalent or similar to OECD Guideline 410 413
OTHER INFORMATION
For the product itself:
Target Organs Repeated Exposure: Bone marrow, Liver, Thymus
Vapour concentrations above recommended exposure levels are irritating to the eyes and the respiratory tract, may
cause headaches and dizziness, are anaesthetic and may have other central nervous system effects. Small amounts
of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary
edema.
Diesel fuel: Carcinogenic in animal tests. Caused mutations in-vitro. Repeated dermal exposures to high
concentrations in test animals resulted in reduced litter size and litter weight, and increased fetal resorptions at
maternally toxic doses. Dermal exposure to high concentrations resulted in severe skin irritation with weight loss and
some mortality. Inhalation exposure to high concentrations resulted in respiratory tract irritation, lung
changes/infiltration/accumulation, and reduction in lung function. Diesel exhaust fumes: Carcinogenic in animal tests.
Inhalation exposures to exhaust for 2 years in test animals resulted in lung tumours and lymphoma. Extract of
particulate produced skin tumours in test animals. Caused mutations in-vitro.
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SECTION 12 ECOLOGICAL INFORMATION

The information given is based on data available for the material, the components of the material, and similar materials.
12.1. TOXICITY
Material -- Expected to be toxic to aquatic organisms. May cause long-term adverse effects in the aquatic
environment.
12.2. PERSISTENCE AND DEGRADABILITY

Biodegradation:
Material -- Expected to be inherently biodegradable
Atmospheric Oxidation:
Majority of components -- Expected to degrade rapidly in air
12.3. BIOACCUMULATIVE POTENTIAL

Majority of components -- Has the potential to bioaccumulate, however metabolism or physical properties
may reduce the bioconcentration or limit bioavailability.
12.4. MOBILITY IN SOIL

More volatile component -- Highly volatile, will partition rapidly to air. Not expected to partition to
sediment and wastewater solids.
Less volatile component -- Low solubility and floats and is expected to migrate from water to the land.
Expected to partition to sediment and wastewater solids.
Majority of components -- Low potential to migrate through soil.
12.5. PERSISTENCE, BIOACCUMULATION AND TOXICITY FOR SUBSTANCE(S)

This product is not, or does not contain, a substance that is a PBT or a vPvB.
12.6. OTHER ADVERSE EFFECTS

No adverse effects are expected.
ECOLOGICAL DATA
Ecotoxicity
Test Duration Organism Type Test Results
Aquatic - Acute Toxicity 48 hour(s) Daphnia magna EL50 1 - 1000 mg/l: data for similar
materials
Aquatic - Acute Toxicity 96 hour(s) Fish LL50 1 - 100 mg/l: data for similar
materials
Aquatic - Acute Toxicity 72 hour(s) Pseudokirchneriella EL50 1 - 100 mg/l: data for similar
subcapitata materials
Aquatic - Chronic Toxicity 72 hour(s) Pseudokirchneriella NOELR 1 - 10 mg/l: data for similar
subcapitata materials
Persistence, Degradability and Bioaccumulation Potential

Media Test Type Duration Test Results: Basis
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Water Ready Biodegradability 28 day(s) Percent Degraded < 60 : similar
material
SECTION 13 DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.
13.1. WASTE TREATMENT METHODS

Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised
incineration at very high temperatures to prevent formation of undesirable combustion products.
REGULATORY DISPOSAL INFORMATION
European Waste Code: 13 07 01*
NOTE: These codes are assigned based upon the most common uses for this material and may not reflect
contaminants resulting from actual use. Waste producers need to assess the actual process used when
generating the waste and its contaminants in order to assign the proper waste disposal code(s).
This material is considered as hazardous waste pursuant to Directive 91/689/EEC on hazardous waste, and
subject to the provisions of that Directive unless Article 1(5) of that Directive applies.
Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue
and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should
be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be
taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with
governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14 TRANSPORT INFORMATION
LAND (ADR/RID)
14.1. UN Number: 1202
14.2. UN Proper Shipping Name (Technical Name): GAS OIL
14.3. Transport Hazard Class(es): 3
14.4. Packing Group: III
14.5. Environmental Hazards: Yes
14.6. Special Precautions for users:
Proper Shipping Name Suffix: Special Provision 640M
Classification Code: F1
Label(s) / Mark(s): 3, EHS
Hazard ID Number: 30
Hazchem EAC: 3Y
Page 14 of 46
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INLAND WATERWAYS (ADNR/ADN)
14.1. UN (or ID) Number: 1202
Hazard ID Number: 30
Label(s) / Mark(s): 3 (N2, F), EHS
SEA (IMDG)
14.1. UN Number: 1202
14.5. Environmental Hazards: Marine Pollutant
Label(s): 3
EMS Number: F-E, S-E
Transport Document Name: **UN1202, GAS OIL, 3, PG III, (>=60°C c.c.), MARINE POLLUTANT**
SEA (MARPOL 73/78 Convention - Annex II):

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not classified according to Annex II
AIR (IATA)
14.1. UN Number: 1202
Label(s) / Mark(s): 3
Transport Document Name: UN1202, GAS OIL, 3, PG III
SECTION 15 REGULATORY INFORMATION
REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS
Listed or exempt from listing/notification on the following chemical inventories (May contain
substance(s) subject to notification to the EPA Active TSCA inventory prior to import to USA): AICS,
DSL, IECSC, KECI, PICCS, TCSI, TSCA
15.1. SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE

SUBSTANCE OR MIXTURE
Applicable EU Directives and Regulations:

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_____________________________________________________________________________________________________________________
1907/2006 [... on the Registration, Evaluation, Authorisation and Restriction of Chemicals ...
and amendments thereto]
92/85/EEC [...pregnant workers...recently given birth or...breastfeeding directive]
94/33/EC [...on the protection of young people at work]
96/82/EC as extended by 2003/105/EC [ ... on the control of major-accident hazards
involving dangerous substances]. Product contains a substance that falls within the criteria defined in Annex I.
Refer to Directive for details of requirements taking into account the volume of product stored on site.
98/24/EC [... on the protection of workers from the risk related to chemical agents at work ...].
Refer to Directive for details of requirements.
1272/2008 [on classification, labelling and packaging of substances and mixtures.. and
amendments thereto]
15.2. CHEMICAL SAFETY ASSESSMENT
REACH Information: A Chemical Safety Assessment has been carried out for one or more substances present in the
material.
SECTION 16 OTHER INFORMATION
IDENTIFIED USES:
Manufacture of substance (PROC1, PROC15, PROC2, PROC3, PROC4, PROC8a, PROC8b, SU10, SU3, SU8, SU9)
Distribution of substance (PROC1, PROC15, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC9, SU3, SU8, SU9)
Use as an intermediate (PROC1, PROC15, PROC2, PROC3, PROC4, PROC8a, PROC8b, SU3, SU8, SU9)
Formulation and (re)packing of substances and mixtures (PROC1, PROC14, PROC15, PROC2, PROC3, PROC4,
PROC5, PROC8a, PROC8b, PROC9, SU10, SU3)
Lubricants - Industrial (PROC1, PROC10, PROC13, PROC17, PROC18, PROC2, PROC3, PROC4, PROC7, PROC8a,
PROC8b, PROC9, SU3)
Use as a fuel - Industrial (PROC1, PROC16, PROC2, PROC3, PROC8a, PROC8b, SU3)
Functional Fluids - Industrial (PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC9, SU3)
Use as a fuel - Professional (PROC1, PROC16, PROC2, PROC3, PROC8a, PROC8b, SU22)
Use as a fuel - Consumer (PC13, SU21)
REFERENCES: Sources of information used in preparing this SDS included one or more of the following: results
from in house or supplier toxicology studies, CONCAWE Product Dossiers, publications from other trade associations,
such as the EU Hydrocarbon Solvents REACH Consortium, U.S. HPV Program Robust Summaries, the EU IUCLID
Data Base, U.S. NTP publications, and other sources, as appropriate.
List of abbreviations and acronyms that could be (but not necessarily are) used in this safety data sheet:
Acronym Full text
N/A Not applicable
N/D Not determined
NE Not established
VOC Volatile Organic Compound
AICS Australian Inventory of Chemical Substances
AIHA WEEL American Industrial Hygiene Association Workplace Environmental Exposure Limits
Page 16 of 46
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ASTM ASTM International, originally known as the American Society for Testing and Materials (ASTM)
DSL Domestic Substance List (Canada)
EINECS European Inventory of Existing Commercial Substances
ELINCS European List of Notified Chemical Substances
ENCS Existing and new Chemical Substances (Japanese inventory)
IECSC Inventory of Existing Chemical Substances in China
KECI Korean Existing Chemicals Inventory
NDSL Non-Domestic Substances List (Canada)
NZIoC New Zealand Inventory of Chemicals
PICCS Philippine Inventory of Chemicals and Chemical Substances
TLV Threshold Limit Value (American Conference of Governmental Industrial Hygienists)
TSCA Toxic Substances Control Act (U.S. inventory)
UVCB Substances of Unknown or Variable composition, Complex reaction products or Biological materials
LC Lethal Concentration
LD Lethal Dose
LL Lethal Loading
EC Effective Concentration
EL Effective Loading
NOEC No Observable Effect Concentration
NOELR No Observable Effect Loading Rate
Classification according to Regulation (EC) No 1272/2008
Classification according to Regulation (EC) Classification procedure

No 1272/2008
Aquatic Chronic 2; H411 Calculation
Carc. 2; H351 Bridging, structurally similar materials
Flam. Liq. 3; H226 Based on test data
Skin Irrit. 2; H315 Bridging, structurally similar materials
STOT RE 2; H373 Bridging, structurally similar materials
KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only):
Flam. Liq. 3 H226: Flammable liquid and vapor; Flammable Liquid, Cat 3
Asp. Tox. 1 H304: May be fatal if swallowed and enters airways; Aspiration, Cat 1
Skin Irrit. 2 H315: Causes skin irritation; Skin Corr/Irritation, Cat 2
Acute Tox. 4 H332: Harmful if inhaled; Acute Tox Inh, Cat 4
Carc. 2 H351: Suspected of causing cancer; GHS Carcinogenicity, Cat 2
STOT RE 2 H373: May cause damage to organs through prolonged or repeated exposure; Target Organ, Repeated,
Cat 2
[Aquatic Acute 2 H401]: Toxic to aquatic life; Acute Env Tox, Cat 2
Aquatic Chronic 2 H411: Toxic to aquatic life with long lasting effects; Chronic Env Tox, Cat 2
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:

Composition: Component Table for REACH information was modified.
GHS Physical Hazards - Header information was added.
GHS Physical Hazards information was added.
GHS Physical/Chemical Classification information was added.
GHS Physical/Chemical Symbol information was added.
GHS Precautionary Statements - Prevention information was modified.
GHS Precautionary Statements - Response information was modified.
GHS Precautionary Statements - Storage information was modified.
Hazard Identification: Physical/Chemical Hazard information was modified.
Page 17 of 46
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Section 01: Company Contact Methods information was modified.
Section 07: Handling and Storage - Handling information was modified.
Section 09: Flash Point ºC(ºF) information was modified.
Section 14: ADNR Technical Name - All information was deleted.
Section 14: ADNR Technical Name - Close parenthesis information was deleted.
Section 14: ADNR Technical Name - Open parenthesis information was deleted.
Section 14: EMS Number information was modified.
Section 14: Hazard Class information was modified.
Section 14: IATA Technical Name - All information was deleted.
Section 14: IATA Technical Name - Open parenthesis information was deleted.
Section 14: IATATechnical Name - Close parenthesis information was deleted.
Section 14: IMO Technical Name - All information was deleted.
Section 14: IMO Technical Name - Close parenthesis information was deleted.
Section 14: IMO Technical Name - Open parenthesis information was deleted.
Section 14: Label(s) information was modified.
Section 14: Proper Shipping Name information was modified.
Section 14: Transport Document Name information was modified.
Section 14: UN Number information was modified.
Section 16: Classification CLP/GHS Table information was modified.
Section 16: Code to PPEs information was modified.
Section 16: HCode Key information was modified.
-----------------------------------------------------------------------------------------------------------------------------------------------------
The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate
and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current
available from ExxonMobil. The information and recommendations are offered for the user's consideration and
examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer
repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to
handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-
publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for
convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any
affiliates in which they directly or indirectly hold any interest.
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Internal Use Only

MHC: 1A, 0B, 2, 0, 4, 1 PPEC: CF
DGN: 7108458XEU (1018053)
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ANNEX
Section 1 Exposure Scenario Title

Title:
Manufacture of substance
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Use Descriptor
Sector(s) of Use SU10, SU3, SU8, SU9
Process Categories PROC1, PROC15, PROC2, PROC3, PROC4, PROC8a,
PROC8b
Environmental Release Categories ERC1
Specific Environmental Release Category ESVOC 1.1.v1
Processes, tasks, activities covered
Manufacture of the substance or use as an intermediate, process chemical or extracting agent. Includes recycling/
recovery, material transfers, storage, maintenance and loading (ncluding marine vessel/barge, road/rail car and bulk
container).
Section 2 Operational conditions and risk management measures
Section 2.1 Control of worker exposure
Product Characteristic
Liquid
Duration, frequency and amount
Covers daily exposures up to 8 hours (unless stated differently)[G2]
Covers percentage substance in the product up to 100 %[G13 ]
Other given operational conditions affecting workers exposure
Assumes a good basic standard of occupational hygiene is implemented [G1]
Operation is carried out at elevated temperature (>20 C above ambient temperature)[OC7]
Contributing Scenarios/
Specific Risk Management Measures and Operating Conditions
(only required controls to demonstrate safe use listed)
General measures applicable to all activities
Control any potential exposure using measures such as contained or enclosed systems, properly designed and
maintained facilities and a good standard of general ventilation. Drain down systems and clear transfer lines prior to
breaking containment. Drain down and flush equipment where possible prior to maintenance. Where there is potential
for exposure: Ensure relevant staff are informed of the nature of exposure and aware of basic actions to minimise
exposures; Ensure suitable personal protective equipment is available; Clear up spills and dispose of waste in
accordance with regulatory requirements; monitor effectiveness of control measures; consider the need for health
surveillance; identify and implement corrective actions.
General measures (Aspiration Hazard)
The H304 risk phrase (May be fatal if swallowed and enters airways) relates to potential for aspiration, a non-
quantifiable hazard determined by physico-chemical properties (i.e. viscosity) that can occur during ingestion and also
if it is vomited following ingestion. A DNEL cannot be derived. Risks from the physicochemical hazards of substances
can be controlled by implementing risk management measures. For substances classified as H304, the following
measures need to be implemented to control the aspiration hazard.
Do not ingest. If swallowed then seek immediate medical attention. Do NOT induce vomiting.
General measures (Flammable Liquid)
Risks from the physicochemical hazards of substances, such as flammability or explosiveness can be controlled by
implementing risk management measures at the workplace. It is recommended to follow the recast ATEX Directive
2014/34/EU. Based on the implementation of a selection of handling and storage risk management measures for the
identified uses, the risk can be regarded as controlled to an acceptable level.
Use in contained systems. Avoid ignition sources – No Smoking. Handle in well ventilated area to prevent formation of
explosive atmosphere. Use equipment and protective systems approved for flammable substances. Restrict line
velocity during pumping to avoid generation of electrostatic discharge. Ground/bond container and receiving
equipment. Use non-sparking tools. Comply with relevant EU/national regulations. Review SDS for additional advice.
General measures (skin irritants)
Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Wear gloves (tested to EN374) if
hand contact with substance likely. Clean up contamination/spills as soon as they occur. wash off any skin
contamination immediately. provide basic employee training to prevent / minimise exposures and to report any skin
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problems that may develop.
General exposures (closed systems) PROC1
No specific measures identified.
Handle substance within a closed system.
General exposures (open systems) PROC4
Wear suitable gloves tested to EN374.
Process sampling PROC3
No other specific measures identified.
Laboratory activities PROC15
No other specific measures identified.
Bulk transfers (closed systems) PROC8b
Bulk transfers (open systems) PROC8b
Equipment cleaning and maintenance PROC8a
Drain down system prior to equipment break-in or maintenance.
Wear chemically resistant gloves (tested to EN374) in combination with 'basic' employee training.
Bulk product storage PROC1
Store substance within a closed system.
Section 2.2 Control of environmental exposure
Product characteristics
Predominantly hydrophobic.
Substance is complex UVCB.
Annual site tonnage (tonnes/year): 600000 tons/yr
Continuous release.
Emission Days (days/year): 300 days/yr
Fraction of EU tonnage used in region: 0.1
Fraction of Regional tonnage used Locally: 0.022
Maximum daily site tonnage (kg/d): 2000000 kg / day
Regional use tonnage (tonnes/year): 27000000 tons/yr
Environmental factors not influenced by risk management
Local freshwater dilution factor [EF1] 10
Local marine water dilution factor: [EF2] 100
Other given operational conditions affecting environmental exposure
Release fraction to air from process (initial release prior to RMM): 0.01
Release fraction to soil from process (initial release prior to RMM): 0.0001
Release fraction to wastewater from process (initial release prior to RMM): 0.0000025
Technical conditions and measures at process level (source) to prevent release
Common practices vary across sites thus conservative process release estimates used.
Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil
If discharging to domestic sewage treatment plant, no onsite wastewater treatment required.
If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of =: >=
0%
Risk from environmental exposure is driven by freshwater sediment.
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Treat air emissions to provide a typical removal (or abatement?) efficiency of: 90 %
Treat onsite wastewater (prior to receiving water discharge) to provide the required removal (or abatement) efficiency
of =: >= 90.3 %
Organisation measures to prevent/limit release from site
Do not apply industrial sludge to natural soils.
Prevent discharge of undissolved substance to or recover from wastewater.
Sludge should be incinerated, contained or reclaimed.
Conditions and measures related to municipal sewage treatment plant
Assumed domestic sewage treatment plant effluent flow is:[STP5] 10000 m3/day
Estimated substance removal from wastewater via domestic sewage treatment is: 94.5 %
The maximum allowable site tonnage (MSafe) based on domestic sewage plant effluent release is: 3600000 kg / day
Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs is: 94.5 %
Conditions and measures related to external treatment of waste for disposal
During manufacturing no waste of the substance is generated [ETW4]
Conditions and measures related to external recovery of waste
During manufacturing no waste of the substance is generated [ERW2]
Section 3 Exposure Estimation
3.1. Health
The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated [G21]
3.2. Environment
The Hydrocarbon Block Method has been used to calculate environmental exposrue with the Petrorisk model.[EE2]
Section 4 Guidance to check compliance with the Exposure Scenario
4.1. Health
Available hazard data do not enable the derivation of a DNEL for dermal irritant effects. [G32]
Available hazard data do not support the need for a DNEL to be established for other health effects.[G36]
Predicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational
Conditions outlined in Section 2 are implemented. [G22]
Risk Management Measures are based on qualitative risk characterisation. [G37]
Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are
managed to at least equivalent levels.[G23]
4.2. Environment
Further details on scaling and control technologies are provided in factsheet
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be
necessary to define appropriate site-specific risk management measures.
If scaling reveals a condition of unsafe use (i.e. RCRs >1), additional RMMs or a site-specific chemical safety
assessment is required.
Required removal efficiency for air can be achieved using on-site technologies, either alone or in combination.
Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in
combination.
Scaled local assessments for EU refineries have been performed using site-specific data and are attached in
PETRORISK file - 'Site-Specific Production' worksheet. [DSU6]
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Title:
Distribution of substance
Use Descriptor
Sector(s) of Use SU3, SU8, SU9
PROC8b, PROC9
Environmental Release Categories ERC4, ERC5, ERC6A, ERC6B, ERC6C, ERC6D, ERC7
Specific Environmental Release Category ESVOC 1.1b.v1
Loading (including marine vessel/barge, rail/road car and IBC loading) and repacking (including drums and small
packs) of substance, including its sampling, storage, unloading, distribution and associated laboratory activities.
Liquid
Assumes use at not more than 20°C above ambient temperature[G15]
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Drum and small package filling PROC9
Storage PROC1
Storage PROC2
Continuous release.
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If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of =:
0%
No secondary wastewater treatment required.
of =: 75.3 %
External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3]
External recovery an recycling of waste should comply with applicable local and/or national regulations [ERW1]
3.1. Health
3.2. Environment
4.1. Health
4.2. Environment
combination.
Page 24 of 46
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Title:
Use as an intermediate
Use Descriptor
Sector(s) of Use SU3, SU8, SU9
PROC8b
Environmental Release Categories ERC6A
Specific Environmental Release Category ESVOC 6.1a.v1
Use as an intermediate (not related to Strictly Controlled Conditions). Includes incidental exposures during recycling/
recovery, material transfers, storage, sampling, associated laboratory activities, maintenance and loading (ncluding
marine vessel/barge, road/rail car and bulk container).
Liquid
Operation is carried out at elevated temperature (>20 C above ambient temperature)[OC7]
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Continuous release.
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If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of =:
0%
of =: 93 %
Not applicable as there is no release to wastewater.
This substance is consumed during use and no waste of the substance is generated [ETW5]
This substance is consumed during use and no waste of the substance is generated [ERW3]
3.1. Health
3.2. Environment
4.1. Health
4.2. Environment
combination.
Page 27 of 46
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Title:
Formulation and (re)packing of substances and mixtures
Use Descriptor
Sector(s) of Use SU10, SU3
Process Categories PROC1, PROC14, PROC15, PROC2, PROC3, PROC4,
PROC5, PROC8a, PROC8b, PROC9
Specific Environmental Release Category ESVOC 2.2.v1
Formulation, packing and re-packing of the substance and its mixtures in batch or continuous operations, including
storage, materials transfers, mixing, tabletting, compression, pelletisation, extrusion, large and small scale packing,
sampling, maintenanance and associated laboratory activities.
Liquid
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Bulk transfers PROC8b
Use drum pumps or carefully pour from container.
Mixing operations (open systems) PROC5
Provide extract ventilation to points where emissions occur.
Drum/batch transfers PROC8b
Production of preparations or articles by tabletting, compression, extrusion, pelettisation PROC14
Drum and small package filling PROC9
Storage PROC1
Storage PROC2
Continuous release.
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Release fraction to air from process (after typical onsite RMMs consistent with EU Solvent Emissions Directive
requirements): [OOC11] 0.01
0%
of =: >= 94 %
3.1. Health
3.2. Environment
4.1. Health
4.2. Environment
combination.
Page 30 of 46
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Title:
Lubricants - Industrial
Use Descriptor
Sector(s) of Use SU3
Process Categories PROC1, PROC10, PROC13, PROC17, PROC18, PROC2,
PROC3, PROC4, PROC7, PROC8a, PROC8b, PROC9
Environmental Release Categories ERC4, ERC7
Covers the use of formulated lubricants in closed and open systems including transfer operations, operation of
machinery/engines and similar articles, reworking on reject articles, equipment maintenance and disposal of wastes.
Liquid
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Other skin protection measures such as impervious suits and face shields may be required during high dispersion
activities which are likely to lead to substantial aerosol release, e.g. spraying.
Filling / preparation of equipment from drums or containers PROC8a
Filling / preparation of equipment from drums or containers PROC8b
Initial factory fill of equipment PROC9
Operation and lubrication of high energy open equipment PROC17
Restrict area of openings to equipment.
Operation and lubrication of high energy open equipment PROC18
Restrict area of openings to equipment.
Roller application or brushing PROC10
Wear chemically resistant gloves (tested to EN374) in combination with specific activity training.
Treatment by dipping and pouring PROC13
Spraying PROC7
Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at openings.
Wear suitable gloves (tested to EN374), coverall and eye protection.
Maintenance (of larger plant items) and machine set up PROC8b
Maintenance (of larger plant items) and machine set up Operation is carried out at elevated temperature (>
20°C above ambient temperature). PROC8b
Ensure material transfers are under containment or extract ventilation.
Provide extract ventilation to emission points when contact with warm (> 50°C) lubricant is likely.
Maintenance of small items PROC8a
Remanufacture of reject articles PROC9
Storage PROC1
Storage PROC2
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Continuous release.
0%
of =: >= 57.9 %
3.1. Health
3.2. Environment
4.1. Health
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4.2. Environment
combination.
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Title:
Use as a fuel - Industrial
Use Descriptor
Process Categories PROC1, PROC16, PROC2, PROC3, PROC8a, PROC8b
Covers the use as a fuel (or fuel additive), and includes activities associated with its transfer, use, equipment
maintenance and handling of waste.
Liquid
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Vessel and container cleaning PROC8a
Apply vessel entry procedures including use of supplied compressed air.
Storage PROC1
Storage PROC2
Use as a fuel PROC1
Use as a fuel PROC2
Use as a fuel (closed systems) PROC16
Continuous release.
Release fraction to soil from process (initial release prior to RMM): 0
0%
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of =: >= 62.4 %
The maximum allowable site tonnage (MSafe) based on domestic sewage plant effluent release is: 34000000 kg /
day
Combustion emissions considered in regional exposure assessment [ETW2]
Combustion emissions limited by required exhaust emission controls [ETW1]
3.1. Health
3.2. Environment
4.1. Health
4.2. Environment
combination.
Page 37 of 46
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Title:
Functional Fluids - Industrial
Use Descriptor
Process Categories PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b,
PROC9
Use as functional fluids e.g. cable oils, transfer oils, coolants, insulators, refrigerants, hydraulic fluids in industrial
equipment including maintenance and related material transfers.
Liquid
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Bulk transfers (closed systems) PROC1
Filling of articles/equipment (closed systems) PROC9
Transfer via enclosed lines
Filling / preparation of equipment from drums or containers PROC8a
Ensure operatives are trained to minimise exposures.
General exposures (open systems) Operation is carried out at elevated temperature (> 20°C above ambient
temperature). PROC4
Use dry break couplings for material transfer.
Remanufacture of reject articles PROC9
Equipment maintenance PROC8a
Storage PROC1
Storage PROC2
Continuous release.
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0%
of =: >= 55.9 %
3.1. Health
3.2. Environment
4.1. Health
4.2. Environment
combination.
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Title:
Use as a fuel - Professional
Use Descriptor
Process Categories PROC1, PROC16, PROC2, PROC3, PROC8a, PROC8b
Environmental Release Categories ERC9A, ERC9B
Specific Environmental Release Category ESVOC 9.12b.v1
Covers the use as a fuel (or fuel additive), and includes activities associated with its transfer, use, equipment
maintenance and handling of waste.
Liquid
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Use drum pumps or carefully pour from container.
Drain down and flush system prior to equipment break-in or maintenance.
Vessel and container cleaning PROC8a
Storage PROC1
provide a good standard of general ventilation (not less than 3 to 5 air changes per hour).
or
Ensure operation is undertaken outdoors.
refuelling PROC8b
Use as a fuel PROC1
Use as a fuel PROC2
Continuous release.
Release fraction to air from wide dispersive use (regional only): 0.0001
Release fraction to soil from wide dispersive use (regional only): 0.00001
Release fraction to wastewater from wide dispersive use: 0.00001
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0%
Treat air emissions to provide a typical removal (or abatement?) efficiency of: Not Applicable
of =: >= 67.2 %
3.1. Health
3.2. Environment
4.1. Health
4.2. Environment
combination.
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Title:
Use as a fuel - Consumer
Use Descriptor
Product Categories PC13
Environmental Release Categories ERC9A, ERC9B
Specific Environmental Release Category ESVOC 9.12c.v1
Covers consumer uses in liquid fuels.
Section 2.1 Control of consumer exposure
Liquid
Not applicable
Other given operational conditions affecting consumer exposure
Not applicable
measures need to be implemented to control the aspiration hazard. Do not ingest. If swallowed then seek immediate
medical attention. Do NOT induce vomiting. Just a sip of lamp oil - or even sucking the wick of lamps may lead to life
threatening lung damage. Keep lamps filled with this liquid out of the reach of children.
Risks from the physicochemical hazards of substances can be controlled by implementing risk management
measures. For flammable substances a selection of the following measures need to be implemented to control
unintended ignition of flammable substances. These measures are expected to be suitable to prevent minor accidents
which might occur during consumer use. Based on the implementation of a selection of handling and storage risk
management measures for the identified uses, it is anticipated that there is no immediate concern as the risk should be
controlled to an acceptable level. Use only with adequate ventilation. Avoid ignition sources – No Smoking. Review
SDS for additional advice.
Liquid: Automotive Refuelling PC13
Covers concentrations up to 100 %
Covers use up to 1 times per day
Covers use up to 52 days/yr
Covers skin contact area up to 210 cm2
For each use event, covers use amounts up to 37500 grams
Covers outdoor use. 0.6 Air changes per hour
Covers use in room size of 100 m³
Covers exposure up to 0.05 hour(s)
Liquid, vapour pressure < 0,5 kPa at STP.
Liquid, Garden Equipment - Use PC13
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Covers outdoor use. 0.6 Air changes per hour
Covers exposure up to 2 hour(s)
Liquid: Garden Equipment - Refueling PC13
Covers use in a one car garage (34 m3) under typical ventilation. 1.5 Air changes per hour
Covers exposure up to 0.03 hour(s)
Continuous release.
Release fraction to air from wide dispersive use (regional only): 0.0001
Release fraction to soil from wide dispersive use (regional only): 0.00001
Release fraction to wastewater from wide dispersive use: 0.00001
3.1. Health
The ECETOC TRA tool has been used to estimate consumer exposures unless otherwise indicated.[G30]
Page 45 of 46
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3.2. Environment
4.1. Health
4.2. Environment
Page 46 of 46
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Marine Gas Oil - ENG

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Marine Gas Oil - ENG

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Product Name: MARINE DISTILLATES

Revision Date: 08 May 2018

SAFETY DATA SHEET

Trade Names Trade Names

1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET

Supplier General Contact: (UK) (+44) (0) 1372 222 000

1.4. EMERGENCY TELEPHONE NUMBER

SECTION 2 HAZARDS IDENTIFICATION

2.1. CLASSIFICATION OF SUBSTANCE OR MIXTURE

Classification according to Regulation (EC) No 1272/2008

2.2. LABEL ELEMENTS

Label elements according to Regulation (EC) No 1272/2008

Signal Word: Danger

H226: Flammable liquid and vapour.

Contains: Fuels, diesel

2.3. OTHER HAZARDS

Physical / Chemical Hazards:

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

This material is defined as a mixture.

NOTE: Composition may contain up to 0.5% performance additives and / or dyes.

Note: See SDS Section 16 for full text of hazard statements.

SECTION 4 FIRST AID MEASURES

4.1. DESCRIPTION OF FIRST AID MEASURES

SECTION 5 FIRE FIGHTING MEASURES

5.1. EXTINGUISHING MEDIA

Unsuitable Extinguishing Media: Straight streams of water

5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE

5.3. ADVICE FOR FIRE FIGHTERS

SECTION 6 ACCIDENTAL RELEASE MEASURES

6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES

6.2. ENVIRONMENTAL PRECAUTIONS

6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP

6.4. REFERENCES TO OTHER SECTIONS

SECTION 7 HANDLING AND STORAGE

7.1. PRECAUTIONS FOR SAFE HANDLING

7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES

7.3. SPECIFIC END USES

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1. CONTROL PARAMETERS

EXPOSURE LIMIT VALUES

Exposure limits/standards (Note: Exposure limits are not additive):

Substance Name Form Limit/Standard Note Source

DERIVED NO EFFECT LEVEL (DNEL)/DERIVED MINIMAL EFFECT LEVEL (DMEL)

PREDICTED NO EFFECT CONCENTRATION (PNEC)

Substance Name Aqua Aqua Aqua Sewage Sediment Soil Oral

8.2. EXPOSURE CONTROLS

Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

9.2. OTHER INFORMATION

SECTION 10 STABILITY AND REACTIVITY

10.1. REACTIVITY: See sub-sections below.

10.2. CHEMICAL STABILITY: Material is stable under normal conditions.

10.3. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION

11.1. INFORMATION ON TOXICOLOGICAL EFFECTS

Hazard Class Conclusion / Remarks

SECTION 12 ECOLOGICAL INFORMATION