Hadaf Group of Colleges, Peshawar

PRE-BOARD EXAMINATION APRIL, 2024 Name:

________
Subject: Chemistry (Paper A) Roll
No:_______
Time Allowed: 20 Mints. Intermediate Part II Total Marks: 85
”Section A“
Q. No. I: Choose the correct option. Marks: 18
1. Which one of the given, is an amphoteric oxide? Na2O SiO2 Al2O3 NO2
Which one of the given
2. Carbonates decomposes Li2CO3 Na2CO3 K2CO3 Rb2CO3
on heating?
3. Which one of the given oxides
SiO2 NO2 SO3 Cl2O
does not react with water?
4. The oxidation state of
chromium in CrO2Cl2 2 3 4 6
is…………
5. The coordination number of
iron 9 3 4 6
in [Fe(CN)6] -4 is …..
6. The first transition element in
Ti Sc V Zn
3d series is ………
7. Which of the given is coal gas?
CO + NH3 CO + CH4 CO + H2 CO + C2H2

8. The homolytic fission of C–C bond sp3

in ethane gives an intermediate in sp2 sp d2sp3
which C is …. hybridized.
9. The addition product of Grignard
reagent with formaldehyde gives p-alcohol sec-alcohol t-alcohol Ketone

10.Cu+ (3d10) is ……… Colorless Blue Green Purple

11. In which of the given Methanoic
compounds, the central acid
Methanol Methanal Acetone
atom does not show sp2
hybridization?
12.Which of the given compounds
react with Tollen’s reagent to Acetone Ethanol Ether Ethanal
form silver mirror?
13.The reduction of Wolf Catalytic Ni catalyst
R-CHO to R-CH3 Kishner reduction LiAlH4
is carried out with ………. reduction
14.How many types of NMR protons
8 2 6 4
are there in butanoic acid?
15.In which of the given
disaccharides both the Maltose Lactose Sucrose All of these
structural units are the same?
16.The temperature (oC)
–92 to
range of troposphere is 15 to –56 –56 to –2 –2 to –92 1200
…….
17.Ethoxy ethane reacts Alkyl free
with conc.H2SO4 to Oxonium ion Oxoanion radical Zwitter ion
give……….
18.Which one of the given is PVC Polythene Nylon None of
these
 condensation polymer?

Hadaf Group of Colleges, Peshawar

PRE-BOARD EXAMINATION APRIL, 2024
Subject: Chemistry (Paper A)
Time Allowed: 2 Hrs & 40 Mints Intermediate Part II Total Marks: 85
”Section B“
Q. No. II: Attempt ten questions from the following. Each question carries equal marks. Marks:40
1. How is Al2O3 reacted with an acid and with a base separately?
2. Why Beryllium form covalent chlorides?
3. Why transition metal can form stable co-ordination complexes?
4. Why is preparation of lassaigne solution compulsory for the detection of N, S or halogens in a given
sample?
5. Halide ions act as reducing agent. Compare the reducing strength of Br- ion and Cl- ion.
6. What is a carbonium ion? Explain stability of different types of carbonium ions.
7. Samples of two organic compounds are given to students in the lab to distinguish these as phenol and
alcohol. Write the possible chemical test for this analysis.
8. Why aliphatic amines are stronger bases than NH3?
9. How primary, secondary and tertiary alcohols are distinguished in chemistry lab?
10. Explain briefly glycosidic linkage or bond.
11. How can we reduce pollution produce due to SO2?
12. Give the names of derivatives of carboxylic acids with their functional groups.
13. Why methanoic acid is stronger than ethanoic acid?

Section – C Marks: 27
Q. No. III: Attempt any THREE questions. All questions carry equal marks.
14. (a) How the following react with water. Write complete labelled and balanced reactions
i. Na2O ii. BaO2 iii. KO2 (06)
(b) Explain the amphoteric nature of Be(OH)2 (03)
15. (a) How is ethyl bromide react with aqeous KOH solution? Write complete reaction mechanism. (04)
(b) Discuss the effect of substituent on the reactivity of benzene ring. (05)
16. (a) Explain ozonolysis of alkenes and its application (05)
(b) Differentiate between the stretching and bending vibrations. What are their various types? (04)
17. (a) How does acetaldehyde react with the given reagents?
i. Ethyl magnesium iodide ii. Zn – Hg amalgam and HCl
ii. Lithium aluminium hydride iv. Acidified K2Cr2O7 (04)
(b) Give the names to the following compounds.

i.
.iii ii.
 iv.

v.

Hadaf Group of Colleges, Peshawar

PRE-BOARD EXAMINATION APRIL, 2024 Name:
________
Subject: Chemistry (Paper B) Roll
No:_______
Time Allowed: 20 Mints. Intermediate Part II Total Marks: 85
”Section A“
Q. No. I: Choose the correct option. Marks: 18
1. Which one of the given, is basic oxide? Na2O SiO2 Al2O3 NO2
2. Which one of the given
Carbonates does not decomposes on Li2CO3 Na2CO3 SrCO3 CaCO3
heating?
3. Which of the following oxides insoluble
SO3 NO2 SiO2 Cl2O
in water?
4. The oxidation state of Manganese in
K2MnO4 is -5 +3 +5 +6

5. The coordination number of Co in

[Co(NH3)4Cl2]Br is 6 5 4 2

6. Element shows abnormal electronic

configuration in 3d series of transition Cu Co V Zn
elements is
7. Which of the given is coal gas? CO + NH3 CO + H2 CO + CH4 CO + C2H2
8. If 11 moles of H2 gas and 5moles of CO C5H8
gas react by FT process than the product C5H10 C5H12 C11H24
formed is
9. The addition product of Grignard
reagent with formaldehyde gives Rectified spirit Absolute alcohol Ethyl alcohol All of these
 acid to an alcohol is Kishner HCl catalyst LiAlH4
carried out by reduction
14. How many types of NMR protons
1 2 3 4
are there in butanone?

Hadaf Group of Colleges, Peshawar

PRE-BOARD EXAMINATION APRIL, 2024
Subject: Chemistry (Paper B)
Time Allowed: 2 Hrs & 40 Mints Intermediate Part II Total Marks: 85
”Section B“
Q. No. II: Attempt ten questions from the following. Each question carries equal marks. Marks:40
1. Describe the reactions of Phosphorus with Chlorine.
2. Why BeCl2 is covalent and not ionic?
3. Why transition elements exhibit variable oxidation states? What are their common oxidation states?
4. What is Lassaigne solution? How it is prepared?
5. Both CO2 and SiO2 are oxides of same group but CO2 exist as gas and SiO2 dioxide exist as high
boiling point solids. Why?
6. Define carbocations. Give their types and relative stabilities.
7. How can you distinguish 1 – alkyne from other non-terminal alkynes?
8. Why aliphatic amines are stronger bases than NH3?
9. How primary, secondary and tertiary alcohols are distinguished in chemistry lab?
10. Explain briefly glycoside linkage or bond.
11. Isoprene is used in the synthesis of synthetic rubber. It contains 88.17%Carbon and 11.83% hydrogen.
Its molecular mass is about 68amu. Find its empirical and molecular formula.
12. Give the names of derivatives of carboxylic acids with their functional groups.
13. All carboxylic acids have same functional group but have different acidic strength. Justify the
statement

“Section C” Marks: 27
Q. No. III: Attempt any THREE questions. All questions carry equal marks.
14. (a) Describe the reactions chlorides of C, Si and Pb with water. (06)
(b) Explain the amphoteric nature of Be(OH)2 ()
15. (a) Give two methods for the preparation of alcohols. (03)
(b) Discuss the effect of substituent on the reactivity of benzene ring. (06)
16. (a) Explain ozonolysis of alkenes and its application (05)
(b) Differentiate between the stretching and bending vibrations. What are their various types? (04)
17. (a) How does ethanal react with the given reagents?
i. Ethyl magnesium iodide iii. Zn – Hg amalgam and HCl
ii. Lithium aluminium hydride iv. Acidified K2Cr2O7 (04)
 (b) Give IUPAC names to the following compounds.
.
i. ii.
.iii

iv. v.