05 - Isotopes and Average Atomic Mass

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5 - Isotopes and Average Atomic Mass SCH3U – Quantities in Chemistry

Date: ______________________________________________

Isotopes and Average Atomic Mass


Isotopes
Isotopes are atoms of the same element with different __________________________________
Not all atoms are created equal
Different numbers of ___________________________ will change atomic mass
Different isotopes have different ___________________________________________
Relative amount of each isotope is called the ___________________________________________
We measure atomic mass in _________________________________________ units (amu or u)
Each proton and neutron has a mass of 1 amu
The atomic mass on the periodic table is not the mass of any given atom, but the
__________________________ of all atoms of that element
We must interpret averages carefully
Average family in Ottawa has 2.9 people (2016 census)

Weighted Averages
Given that the different elements have different abundances, we cannot use a straight
_______________________
A weighted average takes into account the ___________________ of each data point as well as
the _____________________________________________________
Example:
What is the average mass of a weight is there are two 1.00 kg masses, one 2.00 kg mass
and three 3.00 kg masses?

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5 - Isotopes and Average Atomic Mass SCH3U – Quantities in Chemistry

Example:
Magnesium has three stable isotopes
Magnesium-24 (78.99%) Magnesium-25 (10.00%) Magnesium-26 (11.01%)
What is the average atomic mass of Magnesium?

Homework
1. Hydrogen has two main isotopes, 1H (atomic mass of 1.007825 amu) and 2H (atomic
mass of 2.014102 amu). The frequency of 1H is 99.9885% while 2H has a frequency of
0.0115%. What is the average atomic mass of hydrogen?
2. Silicon has three major isotopes as shown in the table below. Calculate the average
atomic mass of silicon.
Table 1: Atomic mass and isotopic frequency of silicon
Isotope Atomic Mass (amu) Isotopic Frequency
28Si 27.976927 92.2297 %
29Si 28.976495 4.6832 %
30Si 29.973770 3.0872 %
3. Titanium has five major isotopes as shown in the table below. Calculate the average
atomic mass of titanium.
Table 2: Atomic mass and isotopic frequency of titanium
Isotope Atomic Mass (amu) Isotopic Frequency
46Ti 45.952629 8.25 %
47Ti 46.951764 7.44 %
48Ti 47.947947 73.72 %
49Ti 48.947871 5.41 %
50Ti 49.944792 5.18 %

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5 - Isotopes and Average Atomic Mass SCH3U – Quantities in Chemistry

4. Molybdenum has seven major isotopes, as shown in the table below. Calculate the
average atomic mass of molybdenum.
Table 3: Atomic mass and isotopic frequency of molybdenum
Isotope Atomic Mass (amu) Isotopic Frequency
92Mo 91.906810 14.84 %
94Mo 93.905088 9.25 %
95Mo 94.905841 15.92 %
96Mo 95.904679 16.68 %
97Mo 96.906021 9.55 %
98Mo 97.905408 24.13 %
100Mo 99.907477 9.63 %

5. Copper has two major isotopes, 63Cu (62.929601 amu) and 65Cu (64.927794 amu).
What are the isotopic frequencies of each isotope?
6. Silver has two major isotopes, 107Ag (106.905093 amu) and 109Ag (108.904756 amu).
What are the isotopic frequencies of each isotope?

Answers
1. 1.00794 amu
2. 28.0854 amu
3. 47.87 amu
4. 95.93 amu
5. 68.95% 63Cu, 31.05% 65Cu
6. 51.747% 107Ag, 48.253% 109Ag

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