PAG 1 - Reactivity Trends

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OCR (B) Chemistry GCSE

PAG 1: Reactivity Trends


(chemistry only)
Notes

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Reactivity of Metals

Aim
To investigate and confirm the order of reactivity of a series of metals, and the magnetic nature of
iron after displacement.

Equipment list
● Pipette
● Laminated copy of figure 1
● Wooden splint
● Magnet (wrapped in clingfilm)

Chemicals required
● Iron(II) sulfate solution
● Copper(II) sulfate solution
● Lead nitrate solution
● Magnesium sulfate solution
● Magnesium ribbon
● Lead foil
● Copper foil
● Iron nails

Method
1. Take the laminated copy of figure 1 and place it flat on the workbench. If you do not have a
laminated copy, place a paper copy in a plastic wallet.
2. Using a dropping pipette, place 5 drops of the appropriate solution in each of the labelled
white circles on the laminated diagram.
3. Start in the top left box on figure 1. Place 4 pieces of magnesium in the grey Mg circle on
the laminated diagram.
4. Use a wooden splint to carefully move a piece of magnesium into each of the four solutions.
Each solution should contain one piece of magnesium.
5. Observe each drop carefully, and record all observations.
6. Repeat steps 4-5 for iron, lead and copper.
7. Wrap the magnet in cling film. Hold the magnet close to the iron sulfate drops containing
the different metals. Record any observations.

Key points
● If there is no change observed when the metal is added to the solution, then the solid metal
is less reactive than the metal in the aqueous ionic compound.
● If the metal formed in the drop of iron sulfate moves when a magnet is held near it, iron has
been displaced from the iron sulfate solution.

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Diagram

Figure 1 Reaction Setup

Safety precautions
● Magnesium is very flammable so ensure there are no open flames in the laboratory.
● Eye protection must be worn at all times.
● Wash hands after coming into contact with any of the chemical substances used.
● Wash hands after touching the metal pieces, especially lead foil.
● Dispose of each mixture by passing it through a sieve into a waste beaker.

Analysis of results
Observations:
Magnesium (Mg) Lead (Pb) Copper (Cu) Iron (Fe)

MgSO​4 No change observed No change No change No change observed


observed observed

CuSO​4 Small black solid Lead pieces got No change Dark grey coating on
pieces on metal darker observed the nail
Fastest rate Fastest rate

FeSO​4 Black solid coats No change No change No change observed


metal observed observed
Magnet: Moved
Slowest rate

Pb(NO​3​)​2 ‘Furry’ black solid No change No change Grey coating on the


formed on metal observed observed nail
Medium rate Slowest rate

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● The observation results show that the order of reactivity is:
Cu<Pb<Fe<Mg
● No reactions took place with copper. This observation shows copper was not able
to displace any of the metals.
● Lead displaced copper, but not iron or magnesium.
● Iron displaced copper and lead, but not magnesium.
● Magnesium displaced copper quickly and lead and iron slowly.
● Particles of iron cover the solid magnesium when it is reacted with iron sulfate
solution.

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